Evolution of Apatites in the Diagenesis

Apatites occurring in sedimentary rocks are carbonate fluorapatites (C-F apatites) with differentCO_2 contents. During diagenesis. the CO_2 in the C-F apatites gradually decreased with the increasing strengthof diagenesis. resulting in the systematic changes in refractive index. specific gravity, cell parameters and crystalchemistry of apatites. On the basis of X-ray diffraction and IR spectroscopic analyses, the author proposes twoparameters for determining diagenetic stages. i.e.. the crystallinity index (CR) and sharpness index (SH). Thesetwo parameters serve as new criteria for the determination. which due to the common existence of phosphorousnodules and bands and argillo-crystalline cement in sedimentary rocks, most likely have wide prospects for ap-plication.

Diagenetic fluids evolution of Oligocene Huagang Formation sandstone reservoir in the south of Xihu Sag, the East China Sea Shelf Basin： constraints from petrology, mineralogy,and isotope geochemistry

The Oligocene Huagang Formation is the main sandstone reservoir in the Xihu Sag, situated in the east of the East China Sea Shelf Basin. With an integrated approach of thin-section petrography, ultra-violet fluorescence microscopy, scanning electron microscopy, and isotope geochemistry, the different diagenetic features were identified, the typical diagenetic parasequences were established, and the diagenetic fluids evolution history were reconstructed for the Oligocene Huagang Formation sandstone reservoir in the south of Xihu Sag. The Huagang Formation sandstone reservoir is now in Period B of the mesodiagenesis, which has undergone significant diagenetic alterations such as mechanical compaction, Pore-lining chlorite cement, feldspar dissolution, quartz cementation and dissolution, and carbonate cementation. Three types of carbonate cements（early siderite,medium ferrocalcite and late ankerite） were identified in the Huagang Formation sandstone reservoir. The carbon and oxygen isotopic compositions of carbonate cements show that the early calcite precipitate from alkaline lacustrine environment whereas the late carbonate cements were closely related to the organic acids. To the Huagang Formation sandstone reservoir, it has experienced two main episodes of dissolution during diagenesis.The early dissolution is that unstable components such as feldspar, lithic fragments, and carbonate cement were dissolved by acidic water. The second dissolution is that quartz and other silicate minerals were dissolved under the alkaline condition. Two main phases of hydrocarbon charging occurred in this study area. The first hydrocarbon emplacement was prior to the medium carbonate cementation but posterior to feldspar dissolution and the onset of quartz cementation at the end of the Miocene. The second hydrocarbon charging occurred in the Quaternary period after the late carbonate precipitation.

Dissolution mechanism of a deep-buried sandstone reservoir in a deep water area:A case study from Baiyun Sag,Zhujiang River(Pearl River)Mouth Basin

Dissolution mechanism and favorable reservoir distribution prediction are the key problems restricting oil and gas exploration in deep-buried layers.In this paper,the Enping Formation and Zhuhai Formation in Baiyun Sag of South China Sea was taken as a target.Based on the thin section,scanning electron microscopy,X-ray diffraction,porosity/permeability measurement,and mercury injection,influencing factors of dissolution were examined,and a dissolution model was established.Further,high-quality reservoirs were predicted temporally and spatially.The results show that dissolved pores constituted the main space of the Paleogene sandstone reservoir.Dissolution primarily occurred in the coarse-and medium-grained sandstones in the subaerial and subaqueous distributary channels,while dissolution was limited in fine-grained sandstones and inequigranular sandstones.The main dissolved minerals were feldspar,tuffaceous matrix,and diagenetic cement.Kaolinization of feldspar and illitization of kaolinite are the main dissolution pathways,but they occur at various depths and temperatures with different geothermal gradients.Dissolution is controlled by four factors,in terms of depositional facies,source rock evolution,overpressure,and fault activities,which co-acted at the period of 23.8–13.8 Ma,and resulted into strong dissolution.Additionally,based on these factors,high-quality reservoirs of the Enping and Zhuhai formations are predicted in the northern slope,southwestern step zone,and Liuhua uplift in the Baiyun Sag.