Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocaps...Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis（2-iodoethoxy）ethane（BIEE） crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.展开更多
基金supported by the National Natural Science Foundation of China(No.41402037)the Natural Science Foundation of Anhui Province Education Department(Nos.AQKJ2015B002 and KJ2014A141)
文摘Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis（2-iodoethoxy）ethane（BIEE） crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
