The seasonal and source variations of flavonoid contents in Scutellariae Radix were investigated by using the materials collected at the same place in Liaoning Province, China, during three years, 1990~1992, and in s...The seasonal and source variations of flavonoid contents in Scutellariae Radix were investigated by using the materials collected at the same place in Liaoning Province, China, during three years, 1990~1992, and in seven other provinces in China. Four principal flavonoids in the plant roots, i.e., baicalin, baicalein, wogonin 7 O glucuronide and wogonin were analyzed by using a reversed phase chromatographic system with a chemically bonded ODS silica gel column and phosphate buffer methanol (68:32 and 1:1) as mobile phase. The contents of the four compounds combined in the herb collected at Chengde, Hebei Province are the highest. The results show that the best time for harvesting the roots in Liaoning Province is the end of August.展开更多
Borehole-to-surface electrical imaging (BSEI) uses a line source and a point source to generate a stable electric field in the ground. In order to study the surface potential of anomalies, three-dimensional forward ...Borehole-to-surface electrical imaging (BSEI) uses a line source and a point source to generate a stable electric field in the ground. In order to study the surface potential of anomalies, three-dimensional forward modeling of point and line sources was conducted by using the finite-difference method and the incomplete Cholesky conjugate gradient (ICCG) method. Then, the damping least square method was used in the 3D inversion of the formation resistivity data. Several geological models were considered in the forward modeling and inversion. The forward modeling results suggest that the potentials generated by the two sources have different surface signatures. The inversion data suggest that the low- resistivity anomaly is outlined better than the high-resistivity anomaly. Moreover, when the point source is under the anomaly, the resistivity anomaly boundaries are better outlined than when using a line source.展开更多
In this study,experimental and numerical simulation methods were combined to simulate the changing course of the temperature and velocity fields in nine different fire scenes. The characteristics of smoke movement in ...In this study,experimental and numerical simulation methods were combined to simulate the changing course of the temperature and velocity fields in nine different fire scenes. The characteristics of smoke movement in shafts with different fire source position factors(h/H) were quantitatively investigated,and the non-dimensional fitting function between the fire source position factors and the maximum temperature was deduced. The results showed that the location of the neutral plane moved upward as the fire source rose,and all the generated smoke spread to the upper areas;however,there was barely any smoke in the lower areas. The maximum temperature was inversely proportional to the fire source position factor;the higher the source position is,i.e. the higher the ratio factor is,the lower the maximum temperature is in the shaft. The experimental verification of the fire dynamics simulator(FDS) showed good results.展开更多
Silicon-based material is an important anode material for next-generation lithium-ion batteries.In order to overcome its shortcomings,carbon coating is often employed to improve the electrochemical performance.However...Silicon-based material is an important anode material for next-generation lithium-ion batteries.In order to overcome its shortcomings,carbon coating is often employed to improve the electrochemical performance.However,the carbon source,carbon content,and different contact and mixing schemes between carbon sources and silicon are all complex factors and need to be clarified.In this study,nano-silicon is coated by the chemical vapor deposition method using different carbon sources,such as acetylene,methane,propane,and propylene.Carbon content after coating is designed to stay at the same level to reduce the experimental error.Results show the sample with higher conductivity provides higher cycle performance.Propylene is the best choice of the four carbon sources studied in this work.These results indicate that the selection of the carbon source is an important factor that plays a significant role in electrochemical performance.展开更多
Hypoxia is increasingly reported off the Changjiang River Estuary with the confluence of multiple high volume nutrient sources.The Regional Ocean Modeling System coupled with a biological model was used to analyze the...Hypoxia is increasingly reported off the Changjiang River Estuary with the confluence of multiple high volume nutrient sources.The Regional Ocean Modeling System coupled with a biological model was used to analyze the effect of different nutrient sources on the development of hypoxia off the Changjiang River Estuary.By comparing to observed data,our model suitably captured the regional dynamics of chlorophyll a,dissolved oxygen,and nutrient concentration.A series of sensitivity experiments were conducted to investigate the hypoxia response to the various nutrient sources,such as loading from the Changjiang River,Kuroshio and Taiwan Warm Current.Our model results indicated that nutrients from different sources significantly influenced the hypoxia off the Changjiang River Estuary,and it was mostly affected by nutrients sourced from the Kuroshio.The nutrients input from the Changjiang River had larger impacts on the hypoxia in the north of 30°N than that in the south of 30°N.The nutrients sourced from the Taiwan Strait had a least influence on the hypoxia off the Changjiang River Estuary.展开更多
The techniques of stress relief mining in low-permeability coal seams and pillarless gob side retained roadway entry using Y-type ventilation and gas drainage systems were developed to control gas outbursts and applie...The techniques of stress relief mining in low-permeability coal seams and pillarless gob side retained roadway entry using Y-type ventilation and gas drainage systems were developed to control gas outbursts and applied successfully. However, as the mining depth increasing, parts of the gas drainage system are not suitable for mines with high gas emissions. Because larger mining depths cause higher ground stresses, it becomes extremely difficult to maintain long gob side roadways. The greater deformation suffered by the roadway is not favorable lor borehole drilling for continuous gas drainage. To solve these problems, Y-type ventilation and gas drainage systems installed from a roof roadway were designed for drainage optimization. This system was designed based on a gas-enrichment zone analysis developed from mining the 11-2 coal seam in the Zhuji Mine at Huainan, Anhui Province, China. The method of Y-type gas extraction from different mine areas was applied to the panel 1112(1) in the Zhuji Mine. The absolute gas emission rate was up to 116.3 m^3/min with an average flow of 69.1 m^3/min at an average drainage concentration of nearly 85 %. After the Y-type method was adopted, the concentration of gas in the return air was 0.15 %-0.64 %, averaging 0.39 % with a ventilation rate of 2100-2750 m^3/min. The gas management system proved to be efficient, and the effective gas control allowed safe production to continue .展开更多
Because of the differences of hydrocarbon accumulation between in-source and out-of-source oil pools, the demand for source kitchen is different. Based on the establishment of source-to-reservoir correlation in the kn...Because of the differences of hydrocarbon accumulation between in-source and out-of-source oil pools, the demand for source kitchen is different. Based on the establishment of source-to-reservoir correlation in the known conventional accumulations, and the characteristics of shale oil source kitchens as well, this paper discusses the differences of source kitchens for the formation of both conventional and shale oils. The formation of conventional oil pools is a process of hydrocarbons enriching from disperse state under the action of buoyancy, which enables most of the oil pools to be formed outside the source kitchens. The source rock does not necessarily have high abundance of organic matter, but has to have high efficiency and enough amount of hydrocarbon expulsion. The TOC threshold of source rocks for conventional oil accumulations is 0.5%, with the best TOC window ranging from 1% to 3%. The oil pools formed inside the source kitchens, mainly shale oil, are the retention of oil and gas in the source rock and there is no large-scale hydrocarbon migration and enrichment process happened, which requires better quality and bigger scale of source rocks. The threshold of TOC for medium to high maturity of shale oil is 2%, with the best range falling in 3%–5%. Medium to low mature shale oil resource has a TOC threshold of 6%, and the higher the better in particular. The most favorable kerogen for both high and low-mature shale oils is oil-prone type of I–II1. Carrying out source rock quality and classification evaluation and looking for large-scale and high-quality source rock enrichment areas are a scientific issue that must be paid attention to when exploration activity changes from out-of-source regions to in-source kitchen areas. The purpose is to provide theoretical guidance for the upcoming shale oil enrichment area selection, economic discovery and objective evaluation of resource potential.展开更多
Benzoic acid as a source of proton is widely used in the technology of manufacture of proton exchanged ( PE) waveguide .But the diffusing speed of proton is too fast to make the waveguide stable in the pure benzoic ac...Benzoic acid as a source of proton is widely used in the technology of manufacture of proton exchanged ( PE) waveguide .But the diffusing speed of proton is too fast to make the waveguide stable in the pure benzoic acid. The characteristic of waveguide is improved with mixture of benzoic acid and lithium benzoate .展开更多
The traditional matched field processing localization need complicated computation to get the replica field and has high dependence on environment parameters and acoustic field model. To overcome the shortcoming, virt...The traditional matched field processing localization need complicated computation to get the replica field and has high dependence on environment parameters and acoustic field model. To overcome the shortcoming, virtual receiver technique is used for source ranging. A virtual receiver is constructed by correlating the two signals of the guide source and the objective source received by a vertical line array. Then, the slope of the interference striation of the virtual field is estimated using relevant signal processing method. Combining with the waveguide invariant/3, the range of the objective source is determined. Through the numerical simulations and data processing collected from the experiment carried out in the South China Sea in 2004, the virtual receiver technique for broadband source ranging under the slope- bottom shallow water environment is discussed. As the frequency increases, the frequency bands should be broadened to obtain complete interference striation for good ranging results. In data processing, the receiving array spacing is too large to promise the orthogonality of the modes as the frequency increases and ranging results become worse.展开更多
Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas ge...Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter (solid bitumen and heavy oil), and kerogen. order of crude oil (light oil and condensate), dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln(CffC3) can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln(CJC2)-(δ13C1-δ13C2) can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.展开更多
A closed-form approximate maximum likelihood(AML) algorithm for estimating the position and velocity of a moving source is proposed by utilizing the time difference of arrival(TDOA) and frequency difference of arr...A closed-form approximate maximum likelihood(AML) algorithm for estimating the position and velocity of a moving source is proposed by utilizing the time difference of arrival(TDOA) and frequency difference of arrival(FDOA) measurements of a signal received at a number of receivers.The maximum likelihood(ML) technique is a powerful tool to solve this problem.But a direct approach that uses the ML estimator to solve the localization problem is exhaustive search in the solution space,and it is very computationally expensive,and prohibits real-time processing.On the basis of ML function,a closed-form approximate solution to the ML equations can be obtained,which can allow real-time implementation as well as global convergence.Simulation results show that the proposed estimator achieves better performance than the two-step weighted least squares(WLS) approach,which makes it possible to attain the Cramér-Rao lower bound(CRLB) at a sufficiently high noise level before the threshold effect occurs.展开更多
文摘The seasonal and source variations of flavonoid contents in Scutellariae Radix were investigated by using the materials collected at the same place in Liaoning Province, China, during three years, 1990~1992, and in seven other provinces in China. Four principal flavonoids in the plant roots, i.e., baicalin, baicalein, wogonin 7 O glucuronide and wogonin were analyzed by using a reversed phase chromatographic system with a chemically bonded ODS silica gel column and phosphate buffer methanol (68:32 and 1:1) as mobile phase. The contents of the four compounds combined in the herb collected at Chengde, Hebei Province are the highest. The results show that the best time for harvesting the roots in Liaoning Province is the end of August.
基金sponsored by the National Major Project(No.2016ZX05014-001)the National Natural Science Foundation of China(No.41172130 and U1403191)the Fundamental Research Funds for the Central Universities(No.2-9-2015-209)
文摘Borehole-to-surface electrical imaging (BSEI) uses a line source and a point source to generate a stable electric field in the ground. In order to study the surface potential of anomalies, three-dimensional forward modeling of point and line sources was conducted by using the finite-difference method and the incomplete Cholesky conjugate gradient (ICCG) method. Then, the damping least square method was used in the 3D inversion of the formation resistivity data. Several geological models were considered in the forward modeling and inversion. The forward modeling results suggest that the potentials generated by the two sources have different surface signatures. The inversion data suggest that the low- resistivity anomaly is outlined better than the high-resistivity anomaly. Moreover, when the point source is under the anomaly, the resistivity anomaly boundaries are better outlined than when using a line source.
文摘In this study,experimental and numerical simulation methods were combined to simulate the changing course of the temperature and velocity fields in nine different fire scenes. The characteristics of smoke movement in shafts with different fire source position factors(h/H) were quantitatively investigated,and the non-dimensional fitting function between the fire source position factors and the maximum temperature was deduced. The results showed that the location of the neutral plane moved upward as the fire source rose,and all the generated smoke spread to the upper areas;however,there was barely any smoke in the lower areas. The maximum temperature was inversely proportional to the fire source position factor;the higher the source position is,i.e. the higher the ratio factor is,the lower the maximum temperature is in the shaft. The experimental verification of the fire dynamics simulator(FDS) showed good results.
基金Project supported by Beijing Natural Science Foundation(Grant No.2182065)the National Natural Science Foundation of China(Grant No.11922202)。
文摘Silicon-based material is an important anode material for next-generation lithium-ion batteries.In order to overcome its shortcomings,carbon coating is often employed to improve the electrochemical performance.However,the carbon source,carbon content,and different contact and mixing schemes between carbon sources and silicon are all complex factors and need to be clarified.In this study,nano-silicon is coated by the chemical vapor deposition method using different carbon sources,such as acetylene,methane,propane,and propylene.Carbon content after coating is designed to stay at the same level to reduce the experimental error.Results show the sample with higher conductivity provides higher cycle performance.Propylene is the best choice of the four carbon sources studied in this work.These results indicate that the selection of the carbon source is an important factor that plays a significant role in electrochemical performance.
基金The Fund of Southern Marine Science and Engineering Guangdong Laboratory under contract No.SML2020Sp008the National Key Research and Development Program of China under contract Nos 2016YFC1401605 and 2016YFC1401802。
文摘Hypoxia is increasingly reported off the Changjiang River Estuary with the confluence of multiple high volume nutrient sources.The Regional Ocean Modeling System coupled with a biological model was used to analyze the effect of different nutrient sources on the development of hypoxia off the Changjiang River Estuary.By comparing to observed data,our model suitably captured the regional dynamics of chlorophyll a,dissolved oxygen,and nutrient concentration.A series of sensitivity experiments were conducted to investigate the hypoxia response to the various nutrient sources,such as loading from the Changjiang River,Kuroshio and Taiwan Warm Current.Our model results indicated that nutrients from different sources significantly influenced the hypoxia off the Changjiang River Estuary,and it was mostly affected by nutrients sourced from the Kuroshio.The nutrients input from the Changjiang River had larger impacts on the hypoxia in the north of 30°N than that in the south of 30°N.The nutrients sourced from the Taiwan Strait had a least influence on the hypoxia off the Changjiang River Estuary.
基金Acknowledgments This work was supported by the National Nat- ural Science Foundation of China (41172147), the Anhui Province Science and Technology Research Plan (12010402110), and the Shanxi Province One Hundred Distinguished Professor Plan project.
文摘The techniques of stress relief mining in low-permeability coal seams and pillarless gob side retained roadway entry using Y-type ventilation and gas drainage systems were developed to control gas outbursts and applied successfully. However, as the mining depth increasing, parts of the gas drainage system are not suitable for mines with high gas emissions. Because larger mining depths cause higher ground stresses, it becomes extremely difficult to maintain long gob side roadways. The greater deformation suffered by the roadway is not favorable lor borehole drilling for continuous gas drainage. To solve these problems, Y-type ventilation and gas drainage systems installed from a roof roadway were designed for drainage optimization. This system was designed based on a gas-enrichment zone analysis developed from mining the 11-2 coal seam in the Zhuji Mine at Huainan, Anhui Province, China. The method of Y-type gas extraction from different mine areas was applied to the panel 1112(1) in the Zhuji Mine. The absolute gas emission rate was up to 116.3 m^3/min with an average flow of 69.1 m^3/min at an average drainage concentration of nearly 85 %. After the Y-type method was adopted, the concentration of gas in the return air was 0.15 %-0.64 %, averaging 0.39 % with a ventilation rate of 2100-2750 m^3/min. The gas management system proved to be efficient, and the effective gas control allowed safe production to continue .
基金Supported by the China National Science and Technology Major Project(2016ZX05046,2017ZX05001)RIPED Scientific Research and Technology Development Project(2018ycq02)。
文摘Because of the differences of hydrocarbon accumulation between in-source and out-of-source oil pools, the demand for source kitchen is different. Based on the establishment of source-to-reservoir correlation in the known conventional accumulations, and the characteristics of shale oil source kitchens as well, this paper discusses the differences of source kitchens for the formation of both conventional and shale oils. The formation of conventional oil pools is a process of hydrocarbons enriching from disperse state under the action of buoyancy, which enables most of the oil pools to be formed outside the source kitchens. The source rock does not necessarily have high abundance of organic matter, but has to have high efficiency and enough amount of hydrocarbon expulsion. The TOC threshold of source rocks for conventional oil accumulations is 0.5%, with the best TOC window ranging from 1% to 3%. The oil pools formed inside the source kitchens, mainly shale oil, are the retention of oil and gas in the source rock and there is no large-scale hydrocarbon migration and enrichment process happened, which requires better quality and bigger scale of source rocks. The threshold of TOC for medium to high maturity of shale oil is 2%, with the best range falling in 3%–5%. Medium to low mature shale oil resource has a TOC threshold of 6%, and the higher the better in particular. The most favorable kerogen for both high and low-mature shale oils is oil-prone type of I–II1. Carrying out source rock quality and classification evaluation and looking for large-scale and high-quality source rock enrichment areas are a scientific issue that must be paid attention to when exploration activity changes from out-of-source regions to in-source kitchen areas. The purpose is to provide theoretical guidance for the upcoming shale oil enrichment area selection, economic discovery and objective evaluation of resource potential.
基金This work is supported by science and technology bureau of Shanghai under the fundation of special project of Optical Science and Technology.
文摘Benzoic acid as a source of proton is widely used in the technology of manufacture of proton exchanged ( PE) waveguide .But the diffusing speed of proton is too fast to make the waveguide stable in the pure benzoic acid. The characteristic of waveguide is improved with mixture of benzoic acid and lithium benzoate .
基金supported by the National Natural Science Foundation of China(10774156)
文摘The traditional matched field processing localization need complicated computation to get the replica field and has high dependence on environment parameters and acoustic field model. To overcome the shortcoming, virtual receiver technique is used for source ranging. A virtual receiver is constructed by correlating the two signals of the guide source and the objective source received by a vertical line array. Then, the slope of the interference striation of the virtual field is estimated using relevant signal processing method. Combining with the waveguide invariant/3, the range of the objective source is determined. Through the numerical simulations and data processing collected from the experiment carried out in the South China Sea in 2004, the virtual receiver technique for broadband source ranging under the slope- bottom shallow water environment is discussed. As the frequency increases, the frequency bands should be broadened to obtain complete interference striation for good ranging results. In data processing, the receiving array spacing is too large to promise the orthogonality of the modes as the frequency increases and ranging results become worse.
基金supported by Petroleum & Chemical United Fund Project(Grant No. 40739902)
文摘Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter (solid bitumen and heavy oil), and kerogen. order of crude oil (light oil and condensate), dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln(CffC3) can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln(CJC2)-(δ13C1-δ13C2) can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.
基金National High-tech Research and Development Program of China (2010AA7010422,2011AA7014061)
文摘A closed-form approximate maximum likelihood(AML) algorithm for estimating the position and velocity of a moving source is proposed by utilizing the time difference of arrival(TDOA) and frequency difference of arrival(FDOA) measurements of a signal received at a number of receivers.The maximum likelihood(ML) technique is a powerful tool to solve this problem.But a direct approach that uses the ML estimator to solve the localization problem is exhaustive search in the solution space,and it is very computationally expensive,and prohibits real-time processing.On the basis of ML function,a closed-form approximate solution to the ML equations can be obtained,which can allow real-time implementation as well as global convergence.Simulation results show that the proposed estimator achieves better performance than the two-step weighted least squares(WLS) approach,which makes it possible to attain the Cramér-Rao lower bound(CRLB) at a sufficiently high noise level before the threshold effect occurs.