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ZnO-Embedded Expanded Graphite Composite Anodes with Controlled Charge Storage Mechanism Enabling Operation of Lithium-Ion Batteries at Ultra-Low Temperatures
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作者 Kun Ryu Michael J.Lee +1 位作者 Kyungbin Lee Seung Woo Lee 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第4期31-39,共9页
As lithium(Li)-ion batteries expand their applications,operating over a wide temperature range becomes increasingly important.However,the lowtemperature performance of conventional graphite anodes is severely hampered... As lithium(Li)-ion batteries expand their applications,operating over a wide temperature range becomes increasingly important.However,the lowtemperature performance of conventional graphite anodes is severely hampered by the poor diffusion kinetics of Li ions(Li^(+)).Here,zinc oxide(ZnO) nanoparticles are incorporated into the expanded graphite to improve Li^(+)diffusion kinetics,resulting in a significant improvement in lowtemperature performance.The ZnO-embedded expanded graphite anodes are investigated with different amounts of ZnO to establish the structurecharge storage mechanism-performance relationship with a focus on lowtemperature applications.Electrochemical analysis reveals that the ZnOembedded expanded graphite anode with nano-sized ZnO maintains a large portion of the diffusion-controlled charge storage mechanism at an ultra-low temperature of-50℃ Due to this significantly enhanced Li^(+)diffusion rate,a full cell with the ZnO-embedded expanded graphite anode and a LiNi_(0.88)Co_(0.09)Al_(0.03)O_(2)cathode delivers high capacities of 176 mAh g^(-1)at20℃ and 86 mAh g^(-1)at-50℃ at a high rate of 1 C.The outstanding low-temperature performance of the composite anode by improving the Li^(+)diffusion kinetics provides important scientific insights into the fundamental design principles of anodes for low-temperature Li-ion battery operation. 展开更多
关键词 diffusive and capacitive charge storages expanded graphite composites anode lithium-ion battery low-temperature operation transition metal oxide
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Study on the High Speed Si Phototransistor
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作者 Chen Bingruo Gao Fanrong Wang Biao 《Wuhan University Journal of Natural Sciences》 CAS 1997年第4期49-52,共4页
In order to reduce collector capacitance, the high speed Si phototransistor with grid pattern is presented. The advantages and disadvantages of grid pattern are analyzed. Through optimum design of geometries, device c... In order to reduce collector capacitance, the high speed Si phototransistor with grid pattern is presented. The advantages and disadvantages of grid pattern are analyzed. Through optimum design of geometries, device configurations and material parameters and reduction of the diffusion capacitance and the base resistance, the response time of Si phototransistor is shorter than 0.7 μs for the first time. 展开更多
关键词 response time barrier capacitance diffusion capacitance base resistance
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Micro-light-emitting-diode array with dual functions of visible light communication and illumination
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作者 黄涌 郭志友 +1 位作者 孙慧卿 黄鸿勇 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第10期490-495,共6页
We demonstrate high-speed blue 4 ×4 micro-light-emitting-diode (LED) arrays with 14 light-emitting units (two light-emitting units are used as the positive and negative electrodes for power supply, respectivel... We demonstrate high-speed blue 4 ×4 micro-light-emitting-diode (LED) arrays with 14 light-emitting units (two light-emitting units are used as the positive and negative electrodes for power supply, respectively) comprising multiple quantum wells formed of GaN epitaxial layers grown on a sapphire substrate, and experimentally test their applicability for being used as VLC transmitters and illuminations. The micro-LED arrays provide a maximum -3-dB frequency response of 60.5 MHz with a smooth frequency curve from 1 MHz to 500 MHz for an optical output power of 165 mW at an injection current of 30 mA, which, to our knowledge, is the highest response frequency ever reported for blue GaN-based LEDs operating at that level of optical output power. The relationship between the frequency and size of the device single pixel diameter reveals the relationship between the response frequency and diffusion capacitance of the device. 展开更多
关键词 light-emitting devices optical communications diffusion capacitance
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Effect of the Dynamic Resistance on the Maximum Output Power in Dynamic Modelling of Photovoltaic Solar Cells
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作者 Siaka Touré 《Open Journal of Modelling and Simulation》 2022年第1期48-57,共10页
<span style="font-family:Verdana;">Several studies on PV solar cells are found in</span> <span style="font-family:Verdana;"><span style="font-family:Verdana;"><... <span style="font-family:Verdana;">Several studies on PV solar cells are found in</span> <span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">the </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">literature which use static models. Those models are mainly one-diode, two-diode or three-diode models. In the dynamic modelling</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">,</span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;"> a variable parallel capacitance is incorporated. Unlike the previous studies which do not clearly establish a relationship between the capacitance and the voltage, in the present paper, the link between the capacitance and the voltage is investigated and established. In dynamic modelling investigated in this paper, the dynamic resistance is introduced in the modelling of the solar cell. It is introduced in the current-voltage characteristic. The value of the dynamic resistance is evaluated at the maximum po</span><span style="font-family:Verdana;">wer point and its effect on the maximum power is investigated. The study</span> <span style="font-family:Verdana;">shows for the first time, that the dynamic resistance must be introduced in</span> <span style="font-family:Verdana;">the current-voltage characteristic, because it has an influence on the PV cell </span><span style="font-family:Verdana;">output</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">.</span></span></span> 展开更多
关键词 Photovoltaic Solar Cells Dynamic Modelling Dynamic Resistance diffusion capacitance Transition capacitance
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