Sound pressure amplitude will be attenuated with propagation distance in a certain rule when sound wave is propagated in shallow sea.When processing the attenuated signal,time-variant gain circuit is usually used to c...Sound pressure amplitude will be attenuated with propagation distance in a certain rule when sound wave is propagated in shallow sea.When processing the attenuated signal,time-variant gain circuit is usually used to compensate its diffusion loss.In this paper,spherical diffusion loss is compensated by digital potentiometer and operational circuit and further investigation is also made on compensation of cylindrical diffusion loss and transition from spherical diffusion loss to cylindrical diffusion loss.Finally,a new compensation model is proposed for unknown propagation loss for the purpose of adjusting the dynamic range of signal to meet the requirement of A/D conversion.展开更多
It has been certificated that corridors can help giant pandas to keep their habitat from fragmenting. However there are still losses during the process of moving along corridors. In this study, a mathematical model wi...It has been certificated that corridors can help giant pandas to keep their habitat from fragmenting. However there are still losses during the process of moving along corridors. In this study, a mathematical model with Allee effect is carried out to describe the diffusion of giant pandas between n patches. Some criteria are obtained to keep the system persisting. It is proved that the system has a unique positive w-periodic solution which is globally asymptotically stable. The ecological meanings of these findings are discussed following the results. And some numerical simulations in the Qinling Mountain giant panda nature reservation area are also presented in the end.展开更多
Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical char...Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical characteristics of light hydrocarbons on the migration features,dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed,and the effect of migration on specific light hydrocarbon indexes is further discussed.The study indicates that,natural gas from the Lower Shihezi Formation(Pix)in the Dongsheng gas field displays higher iso-C5-7contents than n-C5-7contents,and the C6-7light hydrocarbons are composed of paraffins with extremely low aromatic contents(<0.4%),whereas the C7light hydrocarbons are dominated by methylcyclohexane,suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution.The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging,and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation.Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio,as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values.The dissolution causes the increase of isoheptane values of the light hydrocarbons,whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5-7contents compared to the iso-C5-7contents.展开更多
The caprock is one of the key factors for a reservoir, especially for a gas reservoir. Whether the caprocks can block off the gas is of significance for the accumulation and preservation of the gas reservoir. In this ...The caprock is one of the key factors for a reservoir, especially for a gas reservoir. Whether the caprocks can block off the gas is of significance for the accumulation and preservation of the gas reservoir. In this paper, we use the Amplitude versus offset （AVO） seismic technique to determine the lateral extension of the hydrocarbon concentration sealing caprocks. The essence of this technique is to detect the variations of the reservoir bed physical properties by monitoring the variations of the reflection coefficient of seismic waves upon the interfaces between different lithologies. Generally it is used to indicate hydrocarbon directly. For the hydrocarbon concentration sealing caprocks, the change of hydrocarbon concentration may cause the change of physical properties of the caprocks. Therefore it is possible to evaluate the hydrocarbon concentration sealing ability of the caprocks by AVO. This paper presents a case study using AVO to determine the lateral extension of the hydrocarbon concentration sealing caprocks. The result shows that this method is helpful for the exploration of the region.展开更多
The diffusion and loss of lithium polysulfides(LiPSs)in lithium-sulfur batteries(LSBs)reduce the sulfur utilization rate and the catalytic conversion efficiency of sulfur species,resulting in early battery failure.Li_...The diffusion and loss of lithium polysulfides(LiPSs)in lithium-sulfur batteries(LSBs)reduce the sulfur utilization rate and the catalytic conversion efficiency of sulfur species,resulting in early battery failure.Li_(2)ZnTi_(3)O_(8)(LZTO),characterized by its stable spinel structure,exhibits high Li+conductivity and holds great potential as an effective adsorbent for LiPSs.This study proposes a collaborative design concept of LZTO host–separator modifier,which offers a complementary and matching approach in the cathode side,effectively addressing the challenges associated with dissolution and inadequate conversion of LiPSs.Density functional theory(DFT)calculation substantiates the pronounced chemical affinity of LZTO towards LiPSs.More importantly,the high efficiency ion transport channels are achieved in separator coating due to the presence of the LZTO particles.Furthermore,the catalytic efficacy of LZTO is validated through meticulous analysis of symmetric batteries and Tafel curves.Consequently,the LZTO host–separator modifier-based cell displays satisfactory rate capability(1449 and 1166 mAh·g^(−1)at 0.1 and 0.5 C)and an impressively capacity(606 mAh·g^(−1)after 500 cycles at 1 C).The coordinated strategy of host–separator modifier is supposed to have wide applications in LSBs.展开更多
Most conventional aerosol neutralizers are based on radioactive sources, which are controlled by strict regulations restricting their handling, transport, and storage. The TSI 3087 soft X-ray （SXR） neutralizer circu...Most conventional aerosol neutralizers are based on radioactive sources, which are controlled by strict regulations restricting their handling, transport, and storage. The TSI 3087 soft X-ray （SXR） neutralizer circumvents these legal restrictions. The aim of the present work is to compare the performance of a standalone SXR aerosol neutralizer with that of conventional radioactive aerosol neutralizers based on 85Kr （TSI 3077） and 241Am （Grimm 5522） by performing field tests in a real environmental scenario. The results obtained when the SXR neutralizer was connected to a mobility particle sizer spectrometer （MPS）, different from the device suggested by the manufacturer, were comparable with those obtained with the use of radioactive aerosol neutralizers. In changing the neutralizer, the particle number concentrations, measured with the MPS connected to the SXR neutralizer, almost remained within the 10% uncertainty bounds for the particle size interval 10-300 nm, when diffusion losses inside the SXR tube were considered. Based on our comparisons, the SXR neutralizer can be regarded as a standalone instrument that could solve the problems associated with legal restrictions on radioactive neutralizers and fulfil the need for a portable instrument for different field test purposes.展开更多
文摘Sound pressure amplitude will be attenuated with propagation distance in a certain rule when sound wave is propagated in shallow sea.When processing the attenuated signal,time-variant gain circuit is usually used to compensate its diffusion loss.In this paper,spherical diffusion loss is compensated by digital potentiometer and operational circuit and further investigation is also made on compensation of cylindrical diffusion loss and transition from spherical diffusion loss to cylindrical diffusion loss.Finally,a new compensation model is proposed for unknown propagation loss for the purpose of adjusting the dynamic range of signal to meet the requirement of A/D conversion.
基金This work is supported by the National Science Foundation of China （No. Z13060）, Beijing Higher Education Young Elite Teacher Project of China （No. YETP1655）, Beijing Talents Fund （No. 2012D005017000003）, Simulation and Evaluation of Indoor Environmental Comfort Improvement （No. 2013BAJ02B0404） and Youth Foundation of Beijing University of Civil Engineering and Architecture （No. Z12082）.
文摘It has been certificated that corridors can help giant pandas to keep their habitat from fragmenting. However there are still losses during the process of moving along corridors. In this study, a mathematical model with Allee effect is carried out to describe the diffusion of giant pandas between n patches. Some criteria are obtained to keep the system persisting. It is proved that the system has a unique positive w-periodic solution which is globally asymptotically stable. The ecological meanings of these findings are discussed following the results. And some numerical simulations in the Qinling Mountain giant panda nature reservation area are also presented in the end.
基金Supported by the National Natural Science Foundation of China(42172149,U2244209)Sinopec Science and Technology Research Project(P23230,P22132)。
文摘Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical characteristics of light hydrocarbons on the migration features,dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed,and the effect of migration on specific light hydrocarbon indexes is further discussed.The study indicates that,natural gas from the Lower Shihezi Formation(Pix)in the Dongsheng gas field displays higher iso-C5-7contents than n-C5-7contents,and the C6-7light hydrocarbons are composed of paraffins with extremely low aromatic contents(<0.4%),whereas the C7light hydrocarbons are dominated by methylcyclohexane,suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution.The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging,and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation.Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio,as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values.The dissolution causes the increase of isoheptane values of the light hydrocarbons,whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5-7contents compared to the iso-C5-7contents.
文摘The caprock is one of the key factors for a reservoir, especially for a gas reservoir. Whether the caprocks can block off the gas is of significance for the accumulation and preservation of the gas reservoir. In this paper, we use the Amplitude versus offset （AVO） seismic technique to determine the lateral extension of the hydrocarbon concentration sealing caprocks. The essence of this technique is to detect the variations of the reservoir bed physical properties by monitoring the variations of the reflection coefficient of seismic waves upon the interfaces between different lithologies. Generally it is used to indicate hydrocarbon directly. For the hydrocarbon concentration sealing caprocks, the change of hydrocarbon concentration may cause the change of physical properties of the caprocks. Therefore it is possible to evaluate the hydrocarbon concentration sealing ability of the caprocks by AVO. This paper presents a case study using AVO to determine the lateral extension of the hydrocarbon concentration sealing caprocks. The result shows that this method is helpful for the exploration of the region.
基金supported by the National Natural Science Foundation of China(No.22278347)State Key Laboratory of Physical Chemistry of Solid Surface(No.2021X21)State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources.
文摘The diffusion and loss of lithium polysulfides(LiPSs)in lithium-sulfur batteries(LSBs)reduce the sulfur utilization rate and the catalytic conversion efficiency of sulfur species,resulting in early battery failure.Li_(2)ZnTi_(3)O_(8)(LZTO),characterized by its stable spinel structure,exhibits high Li+conductivity and holds great potential as an effective adsorbent for LiPSs.This study proposes a collaborative design concept of LZTO host–separator modifier,which offers a complementary and matching approach in the cathode side,effectively addressing the challenges associated with dissolution and inadequate conversion of LiPSs.Density functional theory(DFT)calculation substantiates the pronounced chemical affinity of LZTO towards LiPSs.More importantly,the high efficiency ion transport channels are achieved in separator coating due to the presence of the LZTO particles.Furthermore,the catalytic efficacy of LZTO is validated through meticulous analysis of symmetric batteries and Tafel curves.Consequently,the LZTO host–separator modifier-based cell displays satisfactory rate capability(1449 and 1166 mAh·g^(−1)at 0.1 and 0.5 C)and an impressively capacity(606 mAh·g^(−1)after 500 cycles at 1 C).The coordinated strategy of host–separator modifier is supposed to have wide applications in LSBs.
文摘Most conventional aerosol neutralizers are based on radioactive sources, which are controlled by strict regulations restricting their handling, transport, and storage. The TSI 3087 soft X-ray （SXR） neutralizer circumvents these legal restrictions. The aim of the present work is to compare the performance of a standalone SXR aerosol neutralizer with that of conventional radioactive aerosol neutralizers based on 85Kr （TSI 3077） and 241Am （Grimm 5522） by performing field tests in a real environmental scenario. The results obtained when the SXR neutralizer was connected to a mobility particle sizer spectrometer （MPS）, different from the device suggested by the manufacturer, were comparable with those obtained with the use of radioactive aerosol neutralizers. In changing the neutralizer, the particle number concentrations, measured with the MPS connected to the SXR neutralizer, almost remained within the 10% uncertainty bounds for the particle size interval 10-300 nm, when diffusion losses inside the SXR tube were considered. Based on our comparisons, the SXR neutralizer can be regarded as a standalone instrument that could solve the problems associated with legal restrictions on radioactive neutralizers and fulfil the need for a portable instrument for different field test purposes.
