In the context of racing to carbon neutrality,the pipe-embedded building system makes the opaque envelopes gradually regarded as the multi-functional element,which also provides an opportunity for thermal insulation s...In the context of racing to carbon neutrality,the pipe-embedded building system makes the opaque envelopes gradually regarded as the multi-functional element,which also provides an opportunity for thermal insulation solutions to transform from high to zero-carbon attributes.Based on the re-examination of the heat transfer process of conventional pipe-embedded radiant(CPR)walls,the modular pipe-embedded radiant(MPR)wall integrated with thermal diffusive materials is proposed to enhance the heat transfer capacity of CPR walls in the direction parallel to the wall surface,thereby forming a more stable and continuous invisible thermal barrier layer inside the opaque envelopes.A comprehensive thermal and energy-saving analysis study regarding the influence mechanism of several key factors of MPR walls,e.g.,the inclination angle of the filler cavity(θ-value),geometry size of the filler cavity(a:b-value)and thermal conductivity of the filler(λf-value),is conducted based on a validated numerical model.Results show that the dynamic thermal behaviors of MPR walls can be significantly improved due to that the radial thermal resistance in the filler cavity of MPR walls can be reduced by 50%,while the maximum extra exterior surface heat loss caused by the optimization measures is only 2.1%.Besides,a better technical effect can be achieved by setting the major axis of the filler cavity towards the room side,where the interior surface heat load/total injected heat first decreases/increases and then increases/decreases with the increase of theθ-value.In particular,the MPR wall withθL=60°can obtain the best performance when other conditions remain the same.Moreover,the performance indicators of MPR walls can be further improved with the increase of the cavity size(a:b-value),while showing a trend of rapid improvement in theλf-value range of 2–5λC and slow improvement increase in theλf-value range of 5–12λC.In addition,the improvement effect brought by optimizing theθ-value is more obvious as the a:b-value orλf-value increases.展开更多
This study is to combine a coastal high-resolution (2′×2′) two-way coupled wave-tide-surge numerical model (including 3 main physical mechanisms) with a material transport/diffusion model for understanding the ...This study is to combine a coastal high-resolution (2′×2′) two-way coupled wave-tide-surge numerical model (including 3 main physical mechanisms) with a material transport/diffusion model for understanding the law of material transport/diffusion. Results show that the law of material trans- port/diffusion driven by background current field simulated by the coupled wave-tide-surge model is dif- ferent from that simulated by pure tide-surge, and more different from traditional ones driven by tidal current. The coupled background current should be taken into account for the simulation.展开更多
Aesthetics,referred frequently to as a philosophical term,has played a starring role in forming and evolving a number of aspects of human society,including arts,politics,economics,ethics,etc.Indeed,exploring and inves...Aesthetics,referred frequently to as a philosophical term,has played a starring role in forming and evolving a number of aspects of human society,including arts,politics,economics,ethics,etc.Indeed,exploring and investigating the aesthetic phenomena in the scientific field have aroused insightful research findings,which in turn has stimulated research interests in such a science-aesthetics field.In particular,better-evaluated aesthetic aspects of the materials field are expected to be uncovered upon the exceedingly-exposed fundamental breakthroughs in researching the basic structure and functionality of materials.In this report,we glimpse into the aesthetic simplicity of energy materials and comprehend specifically the mass transfer functionalities of key categories of energy materials through an intuitive and bottom-up approach.Our effort aspires to shed new lights on the functionality understanding and manipulation of functional materials in general.展开更多
Silver nanoclusters(NCs) embedded in soda-lime glass was synthesized by the electric fieldassisted diffusion(EFAD) and successive annealing. The samples were characterized by UV-Vis absorption spectroscopy, photol...Silver nanoclusters(NCs) embedded in soda-lime glass was synthesized by the electric fieldassisted diffusion(EFAD) and successive annealing. The samples were characterized by UV-Vis absorption spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy(XPS), and lifetime measurements. The experimental results show that the growth of silver clusters is favored by the annealing temperature and dwell time. The as-diffused and annealed glass samples show photoluminescence around 550 nm under UV excitation, which can be associated with the presence of L-center and Ag3~+ cluster. And the increasing of the annealing temperature and dwell time results in an appearance of the SPR peak and the decreasing of the luminescence intensities because the Ag3~+ clusters grow up into the Ag nanoparticles.展开更多
基金the National Natural Science Foundation of China(No.52208103)the Youth Fund of Anhui Natural Science Foundation(No.2208085QE163 and No.2108085QE241)+2 种基金the Anhui Province University Outstanding Scientific Research and Innovation Team(No.2022AH010021)the Opening Fund of State Key Laboratory of Green Building in Western China(No.LSKF202303)the Housing and Urban-Rural Construction Science and Technology Program of Anhui Province(No.2022-YF062).
文摘In the context of racing to carbon neutrality,the pipe-embedded building system makes the opaque envelopes gradually regarded as the multi-functional element,which also provides an opportunity for thermal insulation solutions to transform from high to zero-carbon attributes.Based on the re-examination of the heat transfer process of conventional pipe-embedded radiant(CPR)walls,the modular pipe-embedded radiant(MPR)wall integrated with thermal diffusive materials is proposed to enhance the heat transfer capacity of CPR walls in the direction parallel to the wall surface,thereby forming a more stable and continuous invisible thermal barrier layer inside the opaque envelopes.A comprehensive thermal and energy-saving analysis study regarding the influence mechanism of several key factors of MPR walls,e.g.,the inclination angle of the filler cavity(θ-value),geometry size of the filler cavity(a:b-value)and thermal conductivity of the filler(λf-value),is conducted based on a validated numerical model.Results show that the dynamic thermal behaviors of MPR walls can be significantly improved due to that the radial thermal resistance in the filler cavity of MPR walls can be reduced by 50%,while the maximum extra exterior surface heat loss caused by the optimization measures is only 2.1%.Besides,a better technical effect can be achieved by setting the major axis of the filler cavity towards the room side,where the interior surface heat load/total injected heat first decreases/increases and then increases/decreases with the increase of theθ-value.In particular,the MPR wall withθL=60°can obtain the best performance when other conditions remain the same.Moreover,the performance indicators of MPR walls can be further improved with the increase of the cavity size(a:b-value),while showing a trend of rapid improvement in theλf-value range of 2–5λC and slow improvement increase in theλf-value range of 5–12λC.In addition,the improvement effect brought by optimizing theθ-value is more obvious as the a:b-value orλf-value increases.
基金Supported by the Distinguished Overseas Youth Scholar Grant from NSFC (No.40428001, No.40576018)the National Basic Research Program of China (973 Program) (No. 2005CB422301).
文摘This study is to combine a coastal high-resolution (2′×2′) two-way coupled wave-tide-surge numerical model (including 3 main physical mechanisms) with a material transport/diffusion model for understanding the law of material transport/diffusion. Results show that the law of material trans- port/diffusion driven by background current field simulated by the coupled wave-tide-surge model is dif- ferent from that simulated by pure tide-surge, and more different from traditional ones driven by tidal current. The coupled background current should be taken into account for the simulation.
基金supported by the National Natural Science Foundation under Gran No.21403031Fundamental Research Funds for the Chinese Centra Universities under Grant No.ZYGX2014J088 and No.ZYGX2015Z003
文摘Aesthetics,referred frequently to as a philosophical term,has played a starring role in forming and evolving a number of aspects of human society,including arts,politics,economics,ethics,etc.Indeed,exploring and investigating the aesthetic phenomena in the scientific field have aroused insightful research findings,which in turn has stimulated research interests in such a science-aesthetics field.In particular,better-evaluated aesthetic aspects of the materials field are expected to be uncovered upon the exceedingly-exposed fundamental breakthroughs in researching the basic structure and functionality of materials.In this report,we glimpse into the aesthetic simplicity of energy materials and comprehend specifically the mass transfer functionalities of key categories of energy materials through an intuitive and bottom-up approach.Our effort aspires to shed new lights on the functionality understanding and manipulation of functional materials in general.
基金Funded by the Shanghai Science and Technology Committee(12nm0504700)
文摘Silver nanoclusters(NCs) embedded in soda-lime glass was synthesized by the electric fieldassisted diffusion(EFAD) and successive annealing. The samples were characterized by UV-Vis absorption spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy(XPS), and lifetime measurements. The experimental results show that the growth of silver clusters is favored by the annealing temperature and dwell time. The as-diffused and annealed glass samples show photoluminescence around 550 nm under UV excitation, which can be associated with the presence of L-center and Ag3~+ cluster. And the increasing of the annealing temperature and dwell time results in an appearance of the SPR peak and the decreasing of the luminescence intensities because the Ag3~+ clusters grow up into the Ag nanoparticles.