Three Zn^Ⅱ coordination polymers, [Zn（py）（H2O）（dpa）]n 1, [Zn2（4,4’-bipy）2（dpa）2]n 2 and [Zn（bpe）（H2O）2（Hdpa）2]n 3 （py=pyridine, H2dpa=diphenic acid, 4,4＇-bipy-4,4＇-bipyridine, bpe = 1,2-bis（4-pyr...Three Zn^Ⅱ coordination polymers, [Zn（py）（H2O）（dpa）]n 1, [Zn2（4,4’-bipy）2（dpa）2]n 2 and [Zn（bpe）（H2O）2（Hdpa）2]n 3 （py=pyridine, H2dpa=diphenic acid, 4,4＇-bipy-4,4＇-bipyridine, bpe = 1,2-bis（4-pyridyl）ethane）, were synthesized and characterized by X-ray single-crystal structure determination. 1 crystallizes in monoclinic, space group C2/c with a = 23.014（3）, b = 8.7184（13）, c = 18.091（3）A° ,8 = 95.964（3）°, V=3610.2（9）A°^3, Z=8, C19H15NO5Zn, Mr=402.69, Dc=1.482 g/cm^3, F（000）=1648, μ（MoKa）=1.389 mm^-1 the final R=0.0431 and wR = 0.1120 for 4239 observed reflections with 1〉2σ（I）. 2 crystallizes in orthorhombic, space group Fddd with a=23.1613（5）, b=24.0324（6）, c=29.4785（1）A°, V= 16408.4（5） A°3, Z=32, C24H16N2O4Zn, Mr=461.76, Dc=1.495 g/cm^3, F（000）=7552, μ（MoKa）=1.232 mm^-1, the final R=0.0542 and wR=0.1724 for 3632 observed reflections with 1〉2σ（I）. 3 crystallizes in orthorhombic, space group C2/c with a=19.142（4）, b = 13.862（3）, c = 15.625（3） A°,β=122.404（3）°, V= 3500.3（11）A°^3, Z=8, C2oHiTNO5Zn0.50, Mr=384.03, Dc=1.457 g/cm^3,F（000）=1592,μ（MoKα）=0.766 mm^-1, the final R=0.0400 and wR=0.1210 for 4024 observed reflections with I 〉 2σ（I）.展开更多
The title compound, [Cu（dpa）（2,2＇-bipy）（H2O）2]n 1 （H2dpa = diphenic acid and 2,2＇- bipy = 2,2＇-bipyridine）, has been synthesized and its structure was determined by single-crystal X-ray diffraction. The cry...The title compound, [Cu（dpa）（2,2＇-bipy）（H2O）2]n 1 （H2dpa = diphenic acid and 2,2＇- bipy = 2,2＇-bipyridine）, has been synthesized and its structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group P212121 with a = 10.597（4）, b = 11.317（4）, c = 17.630（7）A, V = 2114.3（14）A^3, C24H20CuN2O6, Mr = 495.97, Z = 4, Dc = 1.558 g/cm^3, μ = 1.079 mm^-1, F（000） = 1020, Flack value = 0.052（18）, R = 0.0430 and wR = 0.1016 for 3381 observed reflections （Ⅰ 〉 2σ（Ⅰ））. In compound 1, the dpa ligands link metal ions into helical structures in the same direction.展开更多
文摘Three Zn^Ⅱ coordination polymers, [Zn（py）（H2O）（dpa）]n 1, [Zn2（4,4’-bipy）2（dpa）2]n 2 and [Zn（bpe）（H2O）2（Hdpa）2]n 3 （py=pyridine, H2dpa=diphenic acid, 4,4＇-bipy-4,4＇-bipyridine, bpe = 1,2-bis（4-pyridyl）ethane）, were synthesized and characterized by X-ray single-crystal structure determination. 1 crystallizes in monoclinic, space group C2/c with a = 23.014（3）, b = 8.7184（13）, c = 18.091（3）A° ,8 = 95.964（3）°, V=3610.2（9）A°^3, Z=8, C19H15NO5Zn, Mr=402.69, Dc=1.482 g/cm^3, F（000）=1648, μ（MoKa）=1.389 mm^-1 the final R=0.0431 and wR = 0.1120 for 4239 observed reflections with 1〉2σ（I）. 2 crystallizes in orthorhombic, space group Fddd with a=23.1613（5）, b=24.0324（6）, c=29.4785（1）A°, V= 16408.4（5） A°3, Z=32, C24H16N2O4Zn, Mr=461.76, Dc=1.495 g/cm^3, F（000）=7552, μ（MoKa）=1.232 mm^-1, the final R=0.0542 and wR=0.1724 for 3632 observed reflections with 1〉2σ（I）. 3 crystallizes in orthorhombic, space group C2/c with a=19.142（4）, b = 13.862（3）, c = 15.625（3） A°,β=122.404（3）°, V= 3500.3（11）A°^3, Z=8, C2oHiTNO5Zn0.50, Mr=384.03, Dc=1.457 g/cm^3,F（000）=1592,μ（MoKα）=0.766 mm^-1, the final R=0.0400 and wR=0.1210 for 4024 observed reflections with I 〉 2σ（I）.
基金This work was financially supported by the Foundation of Lishui University
文摘The title compound, [Cu（dpa）（2,2＇-bipy）（H2O）2]n 1 （H2dpa = diphenic acid and 2,2＇- bipy = 2,2＇-bipyridine）, has been synthesized and its structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group P212121 with a = 10.597（4）, b = 11.317（4）, c = 17.630（7）A, V = 2114.3（14）A^3, C24H20CuN2O6, Mr = 495.97, Z = 4, Dc = 1.558 g/cm^3, μ = 1.079 mm^-1, F（000） = 1020, Flack value = 0.052（18）, R = 0.0430 and wR = 0.1016 for 3381 observed reflections （Ⅰ 〉 2σ（Ⅰ））. In compound 1, the dpa ligands link metal ions into helical structures in the same direction.
