A new organic/inorganic hybrid nonlinear optical (NLO) material was developed by the sol-gel process of an alkoxysilane dye with tetraethoxysilane. A NLO moiety based on 4-nitro-4 ' -hydroxy azobenzene was covalen...A new organic/inorganic hybrid nonlinear optical (NLO) material was developed by the sol-gel process of an alkoxysilane dye with tetraethoxysilane. A NLO moiety based on 4-nitro-4 ' -hydroxy azobenzene was covalently bonded to the triethoxysilane derivative, i.e, gamma -isocyanatopropyl triethoxysilane. The preparation process and properties of the sol-gel derived NLO polymer were studied and characterized by SEM, FTIR,H-1-NMR, UV-Vis, DSC and second harmonic generation (SHG) measurement. The results indicated that the chemical bonding of the chromophores to the inorganic SiO2 networks induces low dipole alignment relaxation and preferable orientational stability. The SHG measurements also showed that the bonded polymer film containing 75 wt% of the akoxysilane dye has a high electro-optic coefficient (r(33)) of 7.1 pm/V at 1.1 mum wavelength, and exhibit good SHG stability, the r(33) values can maintain about 92.7% of its initial value at room temperature for 90 days, and can maintain about 59.3% at 100 degreesC for 300 min.展开更多
Chlorophyll a(naturally occurring Mg porphyrene)has been entrapped in nano/porous silica gel using sol-gel method at room temperature,producing a stable composite.HR TEM observationreveals regular nanoscale[around 15-...Chlorophyll a(naturally occurring Mg porphyrene)has been entrapped in nano/porous silica gel using sol-gel method at room temperature,producing a stable composite.HR TEM observationreveals regular nanoscale[around 15-20 nm diameter]distribution of aggregated polycrystalinechlorophylla within porous silica matrix.UV-vis study also corroborates the presence of variousaggregated chlorophyll a species within the system.Low field measurement shows almost 400times enhancement of dielectric constant(1700)with incorporation of only 0.125 mg/ml of chlorophyll and the loss is 0.5 at room temperature at 100 Hz.The dielectric constant of the composite reaches 2500 as chlorophyll concentration becomes 1 mg/ml.Observed strong space charge response to the external field and strong frequency dispersion of the dielectric properties ofthe composite can be attributed to the long-range electron delocalization[nomadic polarization]in chlorophyl a aggregates.The electric modulus(M*)formalism used in this study enabled us todistinguish and separate various relaxation processes.It is found that with increasing chlorophyll concentration D.C.relaxation time decreases exponentially at room temperature.It is shown that observed relaxations do not perfectly follow the Debye response in high frequency region due toheterogeneous distribution of chlorophyll aggregates.The low values of room temperature acti-vation energy calculated from Arrhenius plot reveal that polaronic hopping phenomena is absent at grain-interfacial region due to low thermal energy.展开更多
Using the first-principles method based on the density functional theory(DFT), the work function of seven different Ga N(0001) e1 × 1T surface models is calculated. The calculation results show that the optim...Using the first-principles method based on the density functional theory(DFT), the work function of seven different Ga N(0001) e1 × 1T surface models is calculated. The calculation results show that the optimal ratio of Cs to O for activation is between 3∶1 and 4∶1. Then, Cs/O activation and stability testing experiments on reflection-mode negative electron affinity Ga N photocathodes are performed. The surface model [Ga N(Mg): Cs]Cs-O after being activated with cesium and oxygen is used. The experiment results illustrate that the adsorption of O contained in the residual gas increases the surface potential barrier and the reduction of the effective dipole quantity is the basic cause of the quantum efficiency decay.展开更多
基金This work was supported by the Postdoctoral Science Foundation of Guangdong Province (No. 9644) and the Natural Science Fund of Guangdong Province(No. 990629).
文摘A new organic/inorganic hybrid nonlinear optical (NLO) material was developed by the sol-gel process of an alkoxysilane dye with tetraethoxysilane. A NLO moiety based on 4-nitro-4 ' -hydroxy azobenzene was covalently bonded to the triethoxysilane derivative, i.e, gamma -isocyanatopropyl triethoxysilane. The preparation process and properties of the sol-gel derived NLO polymer were studied and characterized by SEM, FTIR,H-1-NMR, UV-Vis, DSC and second harmonic generation (SHG) measurement. The results indicated that the chemical bonding of the chromophores to the inorganic SiO2 networks induces low dipole alignment relaxation and preferable orientational stability. The SHG measurements also showed that the bonded polymer film containing 75 wt% of the akoxysilane dye has a high electro-optic coefficient (r(33)) of 7.1 pm/V at 1.1 mum wavelength, and exhibit good SHG stability, the r(33) values can maintain about 92.7% of its initial value at room temperature for 90 days, and can maintain about 59.3% at 100 degreesC for 300 min.
文摘Chlorophyll a(naturally occurring Mg porphyrene)has been entrapped in nano/porous silica gel using sol-gel method at room temperature,producing a stable composite.HR TEM observationreveals regular nanoscale[around 15-20 nm diameter]distribution of aggregated polycrystalinechlorophylla within porous silica matrix.UV-vis study also corroborates the presence of variousaggregated chlorophyll a species within the system.Low field measurement shows almost 400times enhancement of dielectric constant(1700)with incorporation of only 0.125 mg/ml of chlorophyll and the loss is 0.5 at room temperature at 100 Hz.The dielectric constant of the composite reaches 2500 as chlorophyll concentration becomes 1 mg/ml.Observed strong space charge response to the external field and strong frequency dispersion of the dielectric properties ofthe composite can be attributed to the long-range electron delocalization[nomadic polarization]in chlorophyl a aggregates.The electric modulus(M*)formalism used in this study enabled us todistinguish and separate various relaxation processes.It is found that with increasing chlorophyll concentration D.C.relaxation time decreases exponentially at room temperature.It is shown that observed relaxations do not perfectly follow the Debye response in high frequency region due toheterogeneous distribution of chlorophyll aggregates.The low values of room temperature acti-vation energy calculated from Arrhenius plot reveal that polaronic hopping phenomena is absent at grain-interfacial region due to low thermal energy.
基金supported by the National Natural Science Foundation of China (Nos. 61308089 and 61440065)the Public Technology Applied Research Project of Zhejiang Province (No. 2013C31068)+1 种基金the Applied Research Project of Zhejiang Provincial Education Department (Nos. Y201432598 and 201328587)the China Postdoctoral Science Foundation funded project (No. 2014M551596)
文摘Using the first-principles method based on the density functional theory(DFT), the work function of seven different Ga N(0001) e1 × 1T surface models is calculated. The calculation results show that the optimal ratio of Cs to O for activation is between 3∶1 and 4∶1. Then, Cs/O activation and stability testing experiments on reflection-mode negative electron affinity Ga N photocathodes are performed. The surface model [Ga N(Mg): Cs]Cs-O after being activated with cesium and oxygen is used. The experiment results illustrate that the adsorption of O contained in the residual gas increases the surface potential barrier and the reduction of the effective dipole quantity is the basic cause of the quantum efficiency decay.