To deal with the problem of low computational precision at the nodes near the source and satisfy the requirements for computational efficiency in inversion imaging and finite-element numerical simulations of the direc...To deal with the problem of low computational precision at the nodes near the source and satisfy the requirements for computational efficiency in inversion imaging and finite-element numerical simulations of the direct current method, we propose a new mesh refinement and recoarsement method for a two-dimensional point source. We introduce the mesh refinement and mesh recoarsement into the traditional structured mesh subdivision. By refining the horizontal grids, the singularity owing to the point source is minimized and the topography is simulated. By recoarsening the horizontal grids, the number of grid cells is reduced significantly and computational efficiency is improved. Model tests show that the proposed method solves the singularity problem and reduces the number of grid cells by 80% compared to the uniform grid refinement.展开更多
The strategies that minimize the overall solution time of multiple linear systems in 3D finite element method (FEM) modeling of direct current (DC) resistivity were discussed. A global stiff matrix is assembled and st...The strategies that minimize the overall solution time of multiple linear systems in 3D finite element method (FEM) modeling of direct current (DC) resistivity were discussed. A global stiff matrix is assembled and stored in two parts separately. One part is associated with the volume integral and the other is associated with the subsurface boundary integral. The equivalent multiple linear systems with closer right-hand sides than the original systems were constructed. A recycling Krylov subspace technique was employed to solve the multiple linear systems. The solution of the seed system was used as an initial guess for the subsequent systems. The results of two numerical experiments show that the improved algorithm reduces the iterations and CPU time by almost 50%, compared with the classical preconditioned conjugate gradient method.展开更多
Electrochemical impedance spectroscopy (EIS) is widely used in fuel cell impedance analysis. However, for ohmic resistance (R Ω), EIS has some disadvantages such as long test period and complex data analysis with equ...Electrochemical impedance spectroscopy (EIS) is widely used in fuel cell impedance analysis. However, for ohmic resistance (R Ω), EIS has some disadvantages such as long test period and complex data analysis with equivalent circuits. Therefore, the current interruption method is explored to measure the value of RΩ in direct methanol fuel cells (DMFC) at different temperatures and current densities. It is found that RΩ decreases as temperature increase, and decreases initially and then increases as current density increases. These results are consistent with those measured by the EIS technique. In most cases, the ohmic resistances with current interruption (R iR ) are larger than those with EIS (R EIS ), but the difference is small, in the range from –0.848% to 5.337%. The errors of R iR at high current densities are less than those of R EIS . Our results show that the R iR data are reliable and easy to obtain in the measurement of ohmic resistance in DMFC.展开更多
Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of th...Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of the prepared Sn thin film were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),inductively coupled plasma atomic emission spectrometry(ICP),cyclic voltammetry(CV) and galvanostatic charge/ discharge(GC) measurements. It is found that the Sn film is consists of pure Sn with an average particle diameter of 100 nm. The thickness of the film is about 320 nm. The initial lithium insertion capacity of the Sn film is 771 mA·h/g. The reversible capacity of the film is 570 mA·h/g and kept at 270 mA·h/g after 20 cycles.展开更多
To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Tindikala-Boutou (Eastern-Cameroon) area al...To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Tindikala-Boutou (Eastern-Cameroon) area along the Kadey River have been made through electrical sounding and profiling following Schlumberger array. The instrument is the resistive meter Syscal Junior 48 (IRIS Instrument). The data have been processed and modelled with Res2Dinv and Winsev softwares, and then interpolated with Surfer software. Investigation method used is the Direct Current (DC) method. Interpretations and analyses of results from the investigation method highlight weak zones or conductive discontinuities. The latter has been identified as shear zones within granitic structures of the Precambrian basement, according to the geologic and tectonic background of the area. The structural trend of these shear zones is E-W approximately. The mineralization characterized by conductive zones proves the presence of clay minerals disseminated in weathered quartz vein, which cross the shear zones. The intense activities of gold washers encountered in the studied area are able to attest the presence of clay minerals concentrations.展开更多
Low valence vanadium oxide(VO2-x) thin films were prepared on SiO2/Si substrates at room temperature by direct current facing targets reactive magnetron sputtering, and then proc- essed through rapid thermal annealing...Low valence vanadium oxide(VO2-x) thin films were prepared on SiO2/Si substrates at room temperature by direct current facing targets reactive magnetron sputtering, and then proc- essed through rapid thermal annealing. The effects of the annealing on the structure and phase transition property of VO2 were discussed. X-ray photoelectron spectroscopy, X-ray diffraction tech- nique and Fourier transform infrared spectroscopy were employed to study the phase composition and structure of the thin films. The resistance-temperature property was measured. The results show that VO2 thin film is obtained after annealed at 320 ℃ for 3 h, its phase transition tempera- ture is 56 ℃, and the resistance changes by more than 2 orders. The vanadium oxide thin films are applicable in thermochromic smart windows, and the deposition and annealing process is compatible with micro electromechanical system process.展开更多
This paper reports that a series of silver oxide (AgzO) films are deposited on glass substrates by direct-current reactive magnetron sputtering at a substrate temperature of 250 ℃ and an oxygen flux ratio of 15:18...This paper reports that a series of silver oxide (AgzO) films are deposited on glass substrates by direct-current reactive magnetron sputtering at a substrate temperature of 250 ℃ and an oxygen flux ratio of 15:18 by modifying the sputtering power (SP). The AgxO films deposited apparently show a structural evolution from cubic biphased (AgO + Ag20) to cubic single-phased (Ag20), and to biphased (Ag20 + AgO) structure. Notably, the cubic single-phased Ag20 fihn is deposited at the SP = 105 W and an AgO phase with (220) orientation discerned in the Ag^O films deposited using the SP 〉 105 W. The transmissivity and refiectivity of the AgxO films in transparent region decrease with the increase the SP, whereas the absorptivity inversely increases with the increase of the SP. These results may be due to the structural evolution and the increasing film thickness. A redshift of the films' absorption edges determined in terms of Tauc formula clearly occurs from 3.1 eV to 2.73 eV with the increase of the SP.展开更多
A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along ...A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along six (06) profiles of 1500 m in length for a total of 64 geoelectrical stations’ survey conducted through a variable mesh 100 m × 200 m, or 100 m × 300 m. The equipment used is the DC resistivimeter Syscal Junior 48 (Iris Instrument). Processing and modelling of field data are made by using the Res2Dinv, Qwseln and Surfer software. The investigation methods used are electrical resistivity (DC) and induced polarization (IP) methods. The analyses and interpretations have helped to highlight areas of weakness or conductive discontinuities (fractures, faults, shear zones, etc.) in Precambrian gneiss formations, sometimes undergoing weathering processes. They identify the weathering or mineralogical accumulation horizons, the most promising is a mineralization channel identified in the NE-SW direction. The highlighted mineralization is characterized by strong gradients of chargeability or polarization. Samples and other geological evidences observed in the area are used to associate the most polarizable structures with ferriferous formations. Weakly polarizable and particularly conductive backgrounds identified by the inverse pseudo-sections are thought to be sulphate minerals or groundwater targets for future hydrogeological studies.展开更多
To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Ngoura area (Tindikala-Boutou villages) hav...To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Ngoura area (Tindikala-Boutou villages) have been made through electrical sounding and profiling following Schlumberger array. The instrument is the resistivimeter Syscal Junior 48 (IRIS Instrument) which uses the electrical current. The data have been processed and modelled with Res2Dinv and Winsev softwares then interpolated with Surfer software. Electrical methods used are the Direct current (DC) and the Induced Polarization (IP). Interpretation and analyses of results from each investigation method highlight weak zones or conductive discontinuities and mineralized zones. Conductive zones have been identified as shear zones within granitic structures of the Precambrian basement, according to the geologic and tectonic background of the area. The structural trend of these shear zones is E-W. The mineralization within it is N-S and characterized by high values of chargeability, essentially in the eastern part of the area under study. This mineralization proves the presence of metalliferous or sulphide heaps disseminated in weathered quartz veins which cross shear zones. Also, the poor mineralization and conductive structures in shear zones characterize the groundwater zones. The intense activities of gold washers encountered in the area enable to link that mineralization to gold within quartz veins. The near surface gold mineralization is eluvial or alluvial, and in depth this mineralization is primary.展开更多
A geophysical investigation of subsurface structures using the Syscal Junior 48 resistivity-meter was conducted in Ngoura subdivision (East Cameroon) following a combined geoelectrical direct current (DC) approach inv...A geophysical investigation of subsurface structures using the Syscal Junior 48 resistivity-meter was conducted in Ngoura subdivision (East Cameroon) following a combined geoelectrical direct current (DC) approach involving Resistivity and IP methods. This investigation was allowed to collect data on forty-five (45) profiling lines at three acquisition levels (AB = 100 m, MN = 10 m;AB = 200 m, MN = 20 m and AB = 500 m, MN = 50 m) and two electric panels L1 and L4, using the Schlumberger array. Processing, modeling and interpretation of data collected using the Winsev, Res2Dinv and Surfer software helped in highlighting a conductive and strongly mineralized discontinuity in granite formations, which lined up with the NE-SW Kadei tectonic line. It extends beyond 100 m depth over an average width of 600 m. The mineralization associated with this discontinuity is identified by a high concentration of disseminated metalliferous minerals in quartz or pegmatite veins. The mining reconnaissance works in the study area and those of several authors have characterized this anomaly to a lode gold quartz or large pegmatite. The results of this study correlate with geological and tectonic data for the region marked by NE-SW Kadei tectonic line. Therefore, they confirm the reliability of a geoelectrical DC investigation method combining Resistivity and IP to the identification of ore bodies.展开更多
基金financially supported by the National Natural Science Foundation of China(No.41574127 and 41174104)the National Key Technology R&D Program for the 13th five-year plan(No.2016ZX05018006-006)
文摘To deal with the problem of low computational precision at the nodes near the source and satisfy the requirements for computational efficiency in inversion imaging and finite-element numerical simulations of the direct current method, we propose a new mesh refinement and recoarsement method for a two-dimensional point source. We introduce the mesh refinement and mesh recoarsement into the traditional structured mesh subdivision. By refining the horizontal grids, the singularity owing to the point source is minimized and the topography is simulated. By recoarsening the horizontal grids, the number of grid cells is reduced significantly and computational efficiency is improved. Model tests show that the proposed method solves the singularity problem and reduces the number of grid cells by 80% compared to the uniform grid refinement.
基金Projects(40974077,41164004)supported by the National Natural Science Foundation of ChinaProject(2007AA06Z134)supported by the National High Technology Research and Development Program of China+2 种基金Projects(2011GXNSFA018003,0832263)supported by the Natural Science Foundation of Guangxi Province,ChinaProject supported by Program for Excellent Talents in Guangxi Higher Education Institution,ChinaProject supported by the Foundation of Guilin University of Technology,China
文摘The strategies that minimize the overall solution time of multiple linear systems in 3D finite element method (FEM) modeling of direct current (DC) resistivity were discussed. A global stiff matrix is assembled and stored in two parts separately. One part is associated with the volume integral and the other is associated with the subsurface boundary integral. The equivalent multiple linear systems with closer right-hand sides than the original systems were constructed. A recycling Krylov subspace technique was employed to solve the multiple linear systems. The solution of the seed system was used as an initial guess for the subsequent systems. The results of two numerical experiments show that the improved algorithm reduces the iterations and CPU time by almost 50%, compared with the classical preconditioned conjugate gradient method.
基金Supported by the National High Technology Research and Development Program of China (2007AA05Z150) the National Natural Science Foundation of China (50911140287 50973055)
文摘Electrochemical impedance spectroscopy (EIS) is widely used in fuel cell impedance analysis. However, for ohmic resistance (R Ω), EIS has some disadvantages such as long test period and complex data analysis with equivalent circuits. Therefore, the current interruption method is explored to measure the value of RΩ in direct methanol fuel cells (DMFC) at different temperatures and current densities. It is found that RΩ decreases as temperature increase, and decreases initially and then increases as current density increases. These results are consistent with those measured by the EIS technique. In most cases, the ohmic resistances with current interruption (R iR ) are larger than those with EIS (R EIS ), but the difference is small, in the range from –0.848% to 5.337%. The errors of R iR at high current densities are less than those of R EIS . Our results show that the R iR data are reliable and easy to obtain in the measurement of ohmic resistance in DMFC.
基金Projects(50771046 20373016) supported by the National Natural Science Foundation of China+2 种基金Project(05200534) supported by the Natural Science Foundation of Guangdong Province, ChinaProject(2006A10704003) supported by the Key Project of Guangdong Province, ChinaProject(2006Z3-D2031) supported by the Key Project of Guangzhou City, China
文摘Sn thin film on Cu foil substrate as the anode of lithium ion battery was prepared by direct current magnetron sputtering(DCMS). The surface morphology,composition and thickness and the electrochemical behaviors of the prepared Sn thin film were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),inductively coupled plasma atomic emission spectrometry(ICP),cyclic voltammetry(CV) and galvanostatic charge/ discharge(GC) measurements. It is found that the Sn film is consists of pure Sn with an average particle diameter of 100 nm. The thickness of the film is about 320 nm. The initial lithium insertion capacity of the Sn film is 771 mA·h/g. The reversible capacity of the film is 570 mA·h/g and kept at 270 mA·h/g after 20 cycles.
文摘To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Tindikala-Boutou (Eastern-Cameroon) area along the Kadey River have been made through electrical sounding and profiling following Schlumberger array. The instrument is the resistive meter Syscal Junior 48 (IRIS Instrument). The data have been processed and modelled with Res2Dinv and Winsev softwares, and then interpolated with Surfer software. Investigation method used is the Direct Current (DC) method. Interpretations and analyses of results from the investigation method highlight weak zones or conductive discontinuities. The latter has been identified as shear zones within granitic structures of the Precambrian basement, according to the geologic and tectonic background of the area. The structural trend of these shear zones is E-W approximately. The mineralization characterized by conductive zones proves the presence of clay minerals disseminated in weathered quartz vein, which cross the shear zones. The intense activities of gold washers encountered in the studied area are able to attest the presence of clay minerals concentrations.
基金Natural Science Foundation of Tianjin(No.043100811)the Key Program of Natural Science Foundation of Tianjin(No.08JCZDJC17500)
文摘Low valence vanadium oxide(VO2-x) thin films were prepared on SiO2/Si substrates at room temperature by direct current facing targets reactive magnetron sputtering, and then proc- essed through rapid thermal annealing. The effects of the annealing on the structure and phase transition property of VO2 were discussed. X-ray photoelectron spectroscopy, X-ray diffraction tech- nique and Fourier transform infrared spectroscopy were employed to study the phase composition and structure of the thin films. The resistance-temperature property was measured. The results show that VO2 thin film is obtained after annealed at 320 ℃ for 3 h, its phase transition tempera- ture is 56 ℃, and the resistance changes by more than 2 orders. The vanadium oxide thin films are applicable in thermochromic smart windows, and the deposition and annealing process is compatible with micro electromechanical system process.
基金supported by the National Natural Science Foundation of China (Grant No. 60807001)the National Basic Research Program of China (Grant No. 2011CB201605)the Foundation of Henan Educational Committee (Grant No. 2010A140017)
文摘This paper reports that a series of silver oxide (AgzO) films are deposited on glass substrates by direct-current reactive magnetron sputtering at a substrate temperature of 250 ℃ and an oxygen flux ratio of 15:18 by modifying the sputtering power (SP). The AgxO films deposited apparently show a structural evolution from cubic biphased (AgO + Ag20) to cubic single-phased (Ag20), and to biphased (Ag20 + AgO) structure. Notably, the cubic single-phased Ag20 fihn is deposited at the SP = 105 W and an AgO phase with (220) orientation discerned in the Ag^O films deposited using the SP 〉 105 W. The transmissivity and refiectivity of the AgxO films in transparent region decrease with the increase the SP, whereas the absorptivity inversely increases with the increase of the SP. These results may be due to the structural evolution and the increasing film thickness. A redshift of the films' absorption edges determined in terms of Tauc formula clearly occurs from 3.1 eV to 2.73 eV with the increase of the SP.
文摘A geophysical survey was conducted in the Kelle-Bidjocka village, Messondo subdivision, in the Centre Region, Cameroon. The data acquisition was made by combining Schlumberger profiling and electrical soundings along six (06) profiles of 1500 m in length for a total of 64 geoelectrical stations’ survey conducted through a variable mesh 100 m × 200 m, or 100 m × 300 m. The equipment used is the DC resistivimeter Syscal Junior 48 (Iris Instrument). Processing and modelling of field data are made by using the Res2Dinv, Qwseln and Surfer software. The investigation methods used are electrical resistivity (DC) and induced polarization (IP) methods. The analyses and interpretations have helped to highlight areas of weakness or conductive discontinuities (fractures, faults, shear zones, etc.) in Precambrian gneiss formations, sometimes undergoing weathering processes. They identify the weathering or mineralogical accumulation horizons, the most promising is a mineralization channel identified in the NE-SW direction. The highlighted mineralization is characterized by strong gradients of chargeability or polarization. Samples and other geological evidences observed in the area are used to associate the most polarizable structures with ferriferous formations. Weakly polarizable and particularly conductive backgrounds identified by the inverse pseudo-sections are thought to be sulphate minerals or groundwater targets for future hydrogeological studies.
文摘To achieve the current study, geoelectrical surveys along six (06) profiles of 4 km long in a 100 m × 200 m grid defined according to the triangulation principle in the Ngoura area (Tindikala-Boutou villages) have been made through electrical sounding and profiling following Schlumberger array. The instrument is the resistivimeter Syscal Junior 48 (IRIS Instrument) which uses the electrical current. The data have been processed and modelled with Res2Dinv and Winsev softwares then interpolated with Surfer software. Electrical methods used are the Direct current (DC) and the Induced Polarization (IP). Interpretation and analyses of results from each investigation method highlight weak zones or conductive discontinuities and mineralized zones. Conductive zones have been identified as shear zones within granitic structures of the Precambrian basement, according to the geologic and tectonic background of the area. The structural trend of these shear zones is E-W. The mineralization within it is N-S and characterized by high values of chargeability, essentially in the eastern part of the area under study. This mineralization proves the presence of metalliferous or sulphide heaps disseminated in weathered quartz veins which cross shear zones. Also, the poor mineralization and conductive structures in shear zones characterize the groundwater zones. The intense activities of gold washers encountered in the area enable to link that mineralization to gold within quartz veins. The near surface gold mineralization is eluvial or alluvial, and in depth this mineralization is primary.
文摘A geophysical investigation of subsurface structures using the Syscal Junior 48 resistivity-meter was conducted in Ngoura subdivision (East Cameroon) following a combined geoelectrical direct current (DC) approach involving Resistivity and IP methods. This investigation was allowed to collect data on forty-five (45) profiling lines at three acquisition levels (AB = 100 m, MN = 10 m;AB = 200 m, MN = 20 m and AB = 500 m, MN = 50 m) and two electric panels L1 and L4, using the Schlumberger array. Processing, modeling and interpretation of data collected using the Winsev, Res2Dinv and Surfer software helped in highlighting a conductive and strongly mineralized discontinuity in granite formations, which lined up with the NE-SW Kadei tectonic line. It extends beyond 100 m depth over an average width of 600 m. The mineralization associated with this discontinuity is identified by a high concentration of disseminated metalliferous minerals in quartz or pegmatite veins. The mining reconnaissance works in the study area and those of several authors have characterized this anomaly to a lode gold quartz or large pegmatite. The results of this study correlate with geological and tectonic data for the region marked by NE-SW Kadei tectonic line. Therefore, they confirm the reliability of a geoelectrical DC investigation method combining Resistivity and IP to the identification of ore bodies.