With the benefit fierce competition in the steel industry market in recent years,double cold reduction products have been developed towards strength improvement and thickness reduction.The traditional cold-rolling lub...With the benefit fierce competition in the steel industry market in recent years,double cold reduction products have been developed towards strength improvement and thickness reduction.The traditional cold-rolling lubrication process with a fixed flow rate and concentration cannot solve the problems,which are uncontrollable plate shape and the excessive consumption of lubricating oil.Moreover,based on the analysis of the traditional direct aplication lubrication system of double cold reduction mill,a set of design scheme suitable for the emulsion pipeline direct mixing lubrication system of double cold reduction mill unit was proposed.The design completed the selection of key components,which included the static mixer and atomization nozzle selection,pump and oil pump design selection,pipeline design selection,flow type selection,pressure gauge selection,electronic control cabinet design selection and other eight aspects.Equipment of the emulsion pipeline direct mixing lubrication system of double cold reduction has been developed.Comparing with characteristics of the traditional direct aplication lubrication system,the emulsion pipeline direct mixing lubrication system was better applied to the production practice of a 1220 double cold reduction mill.The consumption of ton of steel was reduced by 9.6%.The rolling energy consumption and fuel consumption comprehensive costs decreased by 10.7%,and the strip steel section thickness difference was reduced by 19.3%.In addition,the plate shape quality defect rate decreased by 25.6%,otherwise creating a large economic benefit for the unit and promoting the application value.展开更多
Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The dis...Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The distributions of number concentration, volume concentration, and average diameter of nanoparticles are obtained. The results show that the coherent structures have an important effect on the distributions of number concentration, volume concentration and average diameter of nanoparticles via continuously transporting and diffusing the nanoparticles to the area of low particle concentration. In the streamwise direction, the number concentration of nanoparticles decreases, while the volume concentration and the average diameter increase. The distributions of number concentration, volume concentration and average diameter of nanoparticles are spatially inhomogeneous. The characteristic time of nucleation is shorter than that of coagulation. The nucleation takes place more easily in the area of low temperature because where the number concentration of nanoparticles is high, while the intensity of coagulation is mainly affected by the number concentration. Both nucleation and coagulation result in the variation of average diameter of nanoparticles.展开更多
Metal organic frameworks(MOFs)constructed from natural/biological units(amino acids)are prospective candidates as catalysts in CO2chemistry owing to their natural origin and high abundance of Lewis acid/base sites and...Metal organic frameworks(MOFs)constructed from natural/biological units(amino acids)are prospective candidates as catalysts in CO2chemistry owing to their natural origin and high abundance of Lewis acid/base sites and functional groups.Herein,we report the catalytic efficiency of an amino‐acid‐based Cu‐containing MOF,denoted as CuTrp(Trp=L‐tryptophan).The CuTrp catalyst was synthesized by direct mixing at room temperature using methanol as a solvent-a synthetic route with notable energy efficiency.The catalyst was characterized using various physicochemical techniques,including XRD,FT‐IR,TGA,XPS,ICP‐OES,FE‐SEM,and BET analysis.The catalytic activity of CuTrp was assessed in the synthesis of cyclic carbonates from epoxides and CO2.The CuTrp operated in synergy with the co‐catalyst tetrabutylammonium bromide under solvent‐free conditions.Several reaction parameters were studied to identify the optimal reaction conditions and a reaction mechanism was proposed based on experimental evidence and previous density functional theory studies.The CuTrp also exhibited satisfactory stability in water and could be reused more than three times without any significant loss of activity.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
A coal slurry mixing tank is a key piece of equipment in the preparation of coal slurry for direct coal liquefaction.It is a gas-liquid-solid three-phase mixing device.Based on the performance of the existing coal slu...A coal slurry mixing tank is a key piece of equipment in the preparation of coal slurry for direct coal liquefaction.It is a gas-liquid-solid three-phase mixing device.Based on the performance of the existing coal slurry mixing equipment,a type of test equipment for horizontal continuous coal slurry preparation was developed,but to this point has limited research results.The test equipment consists of a mixing cylinder,mixer,stirring impeller and other components.Slurry mixing experiments were undertaken using the prototype,testing the performance of the device.A mathematical model was proposed specifically for the operation of a coal slurry mixing tank that is horizontally operated with high slurry concentration and rotary flow.The flow field in the horizontal coal mixing tank was simulated with the computational fluid dynamic (CFD) method.The experimental results match well with the CFD simulation results.Results show that the test device of a coal slurry mixing tank can be used to model the mixing of pulverized coal and the solvent oil.A strong correlation was obtained.展开更多
基金This work is supported by the Natural Science Foundation of Hebei Province(Grant No.E20160203385)the Heavy Machinery Collaborative Innovation Program(Grant No.ZX01-20140400-05)。
文摘With the benefit fierce competition in the steel industry market in recent years,double cold reduction products have been developed towards strength improvement and thickness reduction.The traditional cold-rolling lubrication process with a fixed flow rate and concentration cannot solve the problems,which are uncontrollable plate shape and the excessive consumption of lubricating oil.Moreover,based on the analysis of the traditional direct aplication lubrication system of double cold reduction mill,a set of design scheme suitable for the emulsion pipeline direct mixing lubrication system of double cold reduction mill unit was proposed.The design completed the selection of key components,which included the static mixer and atomization nozzle selection,pump and oil pump design selection,pipeline design selection,flow type selection,pressure gauge selection,electronic control cabinet design selection and other eight aspects.Equipment of the emulsion pipeline direct mixing lubrication system of double cold reduction has been developed.Comparing with characteristics of the traditional direct aplication lubrication system,the emulsion pipeline direct mixing lubrication system was better applied to the production practice of a 1220 double cold reduction mill.The consumption of ton of steel was reduced by 9.6%.The rolling energy consumption and fuel consumption comprehensive costs decreased by 10.7%,and the strip steel section thickness difference was reduced by 19.3%.In addition,the plate shape quality defect rate decreased by 25.6%,otherwise creating a large economic benefit for the unit and promoting the application value.
基金supported by the Major Program of National Natural Science Foundation of China (10632070)
文摘Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The distributions of number concentration, volume concentration, and average diameter of nanoparticles are obtained. The results show that the coherent structures have an important effect on the distributions of number concentration, volume concentration and average diameter of nanoparticles via continuously transporting and diffusing the nanoparticles to the area of low particle concentration. In the streamwise direction, the number concentration of nanoparticles decreases, while the volume concentration and the average diameter increase. The distributions of number concentration, volume concentration and average diameter of nanoparticles are spatially inhomogeneous. The characteristic time of nucleation is shorter than that of coagulation. The nucleation takes place more easily in the area of low temperature because where the number concentration of nanoparticles is high, while the intensity of coagulation is mainly affected by the number concentration. Both nucleation and coagulation result in the variation of average diameter of nanoparticles.
文摘Metal organic frameworks(MOFs)constructed from natural/biological units(amino acids)are prospective candidates as catalysts in CO2chemistry owing to their natural origin and high abundance of Lewis acid/base sites and functional groups.Herein,we report the catalytic efficiency of an amino‐acid‐based Cu‐containing MOF,denoted as CuTrp(Trp=L‐tryptophan).The CuTrp catalyst was synthesized by direct mixing at room temperature using methanol as a solvent-a synthetic route with notable energy efficiency.The catalyst was characterized using various physicochemical techniques,including XRD,FT‐IR,TGA,XPS,ICP‐OES,FE‐SEM,and BET analysis.The catalytic activity of CuTrp was assessed in the synthesis of cyclic carbonates from epoxides and CO2.The CuTrp operated in synergy with the co‐catalyst tetrabutylammonium bromide under solvent‐free conditions.Several reaction parameters were studied to identify the optimal reaction conditions and a reaction mechanism was proposed based on experimental evidence and previous density functional theory studies.The CuTrp also exhibited satisfactory stability in water and could be reused more than three times without any significant loss of activity.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
基金Project (No. 2008C21021) supported by the Science and Technology Research Program of Zhejiang Province, China
文摘A coal slurry mixing tank is a key piece of equipment in the preparation of coal slurry for direct coal liquefaction.It is a gas-liquid-solid three-phase mixing device.Based on the performance of the existing coal slurry mixing equipment,a type of test equipment for horizontal continuous coal slurry preparation was developed,but to this point has limited research results.The test equipment consists of a mixing cylinder,mixer,stirring impeller and other components.Slurry mixing experiments were undertaken using the prototype,testing the performance of the device.A mathematical model was proposed specifically for the operation of a coal slurry mixing tank that is horizontally operated with high slurry concentration and rotary flow.The flow field in the horizontal coal mixing tank was simulated with the computational fluid dynamic (CFD) method.The experimental results match well with the CFD simulation results.Results show that the test device of a coal slurry mixing tank can be used to model the mixing of pulverized coal and the solvent oil.A strong correlation was obtained.