As a key to improve the performance of the interbay automated material handling system (AMHS) in 300 mm semiconductor wafer fabrication system, the real- time overhead hoist transport (OHT) dispatching problem has...As a key to improve the performance of the interbay automated material handling system (AMHS) in 300 mm semiconductor wafer fabrication system, the real- time overhead hoist transport (OHT) dispatching problem has received much attention. This problem is first formu- lated as a special form of assignment problem and it is proved that more than one solution will be obtained by Hungarian algorithm simultaneously. Through proposing and strictly proving two propositions related to the char- acteristics of these solutions, a modified Hungarian algo- rithm is designed to distinguish these solutions. Finally, a new real-time OHT dispatching method is carefully designed by implementing the solution obtained by the modified Hungarian algorithm. The experimental results of discrete event simulations show that, compared with con- ventional Hungarian algorithm dispatching method, the proposed dispatching method that chooses the solution with the maximum variance respectively reduces on average 4 s of the average waiting time and average lead time of wafer lots, and its performance is rather stable in multiple dif- ferent scenarios of the interbay AMHS with different quantities of shortcuts. This research provides an efficient real-time OHT dispatching mechanism for the interbay AMHS with shortcuts and bypasses.展开更多
Resorbable bioceramics are attractive for medical applications such as bone substitution. Biochemical analysis on cells cultured on these biomaterials is vital to predict the impact of the materials in vivo and RNA ex...Resorbable bioceramics are attractive for medical applications such as bone substitution. Biochemical analysis on cells cultured on these biomaterials is vital to predict the impact of the materials in vivo and RNA extraction is an essential step in gene expression study using RT-qPCR. In this study, we describe simple modifications to the TRIzol? RNA extraction protocol widely used in biology and these allow high-yield extraction of RNA from cells on resorbable calcium phosphates. Without the modifications, RNA is trapped in the co-precipitated calcium compounds, rendering TRIzol? extraction method infeasible. Among the modifications, the use of extra TRIzol? to dilute the lysate before the RNA precipitation step is critical for extraction of RNA from porous ?-tricalcium phosphate (?-TCP) discs. We also investigate the rationale behind the undesirable precipitation so as to provide clues about the modifications required for other resorbable materials with high application potential in bone tissue engineering.展开更多
A1203-Si composite specimens were prepared using fused corundum, ultra-fine α-A1203 and Si powder as starting materials and resin as binder. Effects of sintering atmospheres on properties, phase composition and micro...A1203-Si composite specimens were prepared using fused corundum, ultra-fine α-A1203 and Si powder as starting materials and resin as binder. Effects of sintering atmospheres on properties, phase composition and microstructure of specimens after firing at 1 500 ℃ were investigated. The results show that: ( 1 ) after .firing in oxidizing or weak oxidizing atmosphere, there is some Si in the specimens and some glass phases containing mullite form on specimen surface, the density and strength at room temperature are relatively high, but hot modulus of rupture and thermal shock resistance are relatively poor; (2) after firing in, weak reducing or reducing atmosphere, Si reacts completely with CO or N2forming whisk-phere, Si reacts completely with CO or N2forming whisk-er-like SiC, granular Si2N20 or 0'-SiAION, and the er-like SiC, granular Si2N20 or O'-SiMON, and the thermo-mechanical properties of specimens are enhanced;(3) after firing in nitrogen atmosphere, Si reacts completely with N2, CO or G forming wbisker-like SiC and columnar β-SiA10N crystals, the hot modulus of rupture and thermal shock resistance of specimens are enhanced noticeably.展开更多
The main objective of this paper is to study the singular natureof the crack-tip stress and electric displacement field in afunctionally gradient piezoelectric medium having materialcoefficients with a discontinuous d...The main objective of this paper is to study the singular natureof the crack-tip stress and electric displacement field in afunctionally gradient piezoelectric medium having materialcoefficients with a discontinuous derivative. The problem isconsidered for the simplest possible loading and geometry, namely,the anti-plane shear stress and electric displacement in -plane oftwo bonded half spaces in which the crack is parallel to theinterface.展开更多
To improve the cyclic stability at high temperature and thermal stability, the spherical Al2O3-modified Li(Ni0.5Co0.2Mn0.3)O2 was synthesized by a modified co-precipitation method, and the physical and electrochemic...To improve the cyclic stability at high temperature and thermal stability, the spherical Al2O3-modified Li(Ni0.5Co0.2Mn0.3)O2 was synthesized by a modified co-precipitation method, and the physical and electrochemical properties were studied. The TEM images showed that Li(Ni0.5Co0.2Mn0.3)O2 was modified successfully with nano-Al2O3. The discharge capacity retention of Al2O3-modified Li(Ni0.5Co0.2Mn0.3)O2 maintained about 99% after 200 cycles at high temperature(55 ℃), while that of the bare one was only 86%. Also, unlike bare Li(Ni0.5Co0.2Mn0.3)O2, the Al2O3-modified material cathode exhibited good thermal stability.展开更多
A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material...A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material,the paper derives the macroscopic constitutive laws for homogenous equivalent medium. By changing the shape parameter of circular particles,the effect of pore shape on macroscopic constitutive laws is explored. Yield surfaces with different pore shapes are obtained. About voids,a two-scale conception is introduced,which regards main void as macroscopic scale and secondary cavities as microscopic scale. The macroscopic potential involving main and secondary voids is achieved. The proposed macroscopic constitutive law taking microscopic features as influence factors is helpful for exploring the macroscopic mechanical properties of porous medium when numerical simulation is required.展开更多
A 1-octadecanol(OD)/1,3:2,4-di-(3,4-dimethyl) benzylidene sorbitol(DMDBS)/expander graphite(EG) composite was prepared as a form-stable phase change material(PCM) by vacuum melting method. The results of fie...A 1-octadecanol(OD)/1,3:2,4-di-(3,4-dimethyl) benzylidene sorbitol(DMDBS)/expander graphite(EG) composite was prepared as a form-stable phase change material(PCM) by vacuum melting method. The results of field emission-scanning electron microscopy(FE-SEM) showed that 1-octadecanol was restricted in the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR) results showed that no chemical reaction occurred among the components of composite PCM in the preparation process. The gel-to-sol transition temperature of the composite PCMs containing DMDBS was much higher than the melting point of pure 1-octadecanol. The improvements in preventing leakage and thermal stability limits were mainly attributed to the synergistic effect of the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. Differential scanning calorimeter(DSC) was used to determine the latent heat and phase change temperature of the composite PCMs. During melting and freezing process the latent heat values of the PCM with the composition of 91% OD/3% DMDBS/6% EG were 214.9 and 185.9 kJ·kg-1, respectively. Its degree of supercooling was only 0.1 ℃. Thermal constant analyzer results showed that its thermal conductivity(κ) changed up to roughly 10 times over that of OD/DMDBS matrix.展开更多
Thermodynamic models for molecular-beam epitaxy(MBE) growth of ternary Ⅲ-Ⅴ semiconductor materials are proposed.These models are in agreement with our experimental materials InGaP/GaAs and InGaAs/InP,and reported ...Thermodynamic models for molecular-beam epitaxy(MBE) growth of ternary Ⅲ-Ⅴ semiconductor materials are proposed.These models are in agreement with our experimental materials InGaP/GaAs and InGaAs/InP,and reported GaAsP/GaAs and InAsP/InP in thermodynamic growth.The lattice strain energy △G and thermal decomposition sensitive to growth temperature are demonstrated in the models simultaneously.△G is the function of the alloy composition,which is affected by flux ratio and growth temperature directly.The calculation results reveal that flux ratio and growth temperature mainly influence the growth process.Thermodynamic model of quaternary InGaAsP/GaAs semiconductor material is discussed also.展开更多
Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- ...Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- tion of the AH method, which has rigorous mathematical foundation of the AH method, and also simplicity as the RVE method. This implementation can be easily realized using commercial software as a black box, and can use all kinds of elements available in commercial software to model unit cells with rather complicated microstructures, so the model may remain a fairly small scale. Several examples were car- fled out to demonstrate the simplicity and effectiveness of the new implementation.展开更多
Some compensation methods have been pro- posed to mitigate the degradation of radiation characteris- tics caused by composite material radomes, however most of them are complex and not applicable for large radomes, fo...Some compensation methods have been pro- posed to mitigate the degradation of radiation characteris- tics caused by composite material radomes, however most of them are complex and not applicable for large radomes, for example, the modification of geometric shape by grinding process. A novel and simple compensation strat- egy based on phase modification is proposed for large reflector antenna-radome systems. Through moving the feed or sub-reflector along axial direction opportunely, the modification of phase distribution in the original aperture of an enclosed reflector antenna can be used to reduce the phase shift caused by composite material radomes. The distortion of far-field pattern can be minimized. The modification formulas are proposed, and the limitation of their application is also discussed. Numerical simulations for a one-piece composite materials sandwich radome and a 40 m multipartite composite materials sandwich radome verify that the novel compensation strategy achieves sat- isfactory compensated results, and improves the distortion of the far-field pattern for the composite material radomes. For one-piece dielectric radome, more than 60% phasedifference caused by radome is reduced. For multipartite radome, the sidelobe level improves about 1.2 dB, the nulling depth improves about 3 dB. The improvement of far-field pattern could be obtained effectively and simply by moving the feed or sub-reflector according to phase shift of the radome.展开更多
High strength refractory organic stream is produced during the production of 2-phenylamino-3-methyl-6-di-n-butylaminofluoran (One Dye Black 2, abbr. ODB 2), a novel heat-sensitive material with a promising market. I...High strength refractory organic stream is produced during the production of 2-phenylamino-3-methyl-6-di-n-butylaminofluoran (One Dye Black 2, abbr. ODB 2), a novel heat-sensitive material with a promising market. In this study, a combination of acidificationprecipitation, primary biological treatment, Fenton's oxidation and another biological treatment was successfully used for the removal of COD from 18000-25000 mg/L to below 200 mg/L from the ODB 2 production wastewater in a pilot experiment. A COD removal of 70%-80% was achieved by acidification-precipitation under a pH of 2.5-3.0. The first step biodegradafion permitted an average COD removal of 70% under an hydraulic residence time (HRT) of 30 h. By batch tests, the optimum conditions of Fenton's oxidation were acquired as: Fe^2+ dose 6.0 mmol/L; H2O2 dose 3000 mg/L; and reaction time 6 h. The second step biological treatment could ensure an effluent COD below 200 mg/L under an HRT of 10 h following the Fenton's treatment.展开更多
The new electrorheologicai (ER) material, a particle material composed of Y4O(OH)9(NO3) and NH4NO3, was obtained. They display better ER performance. The shear stress of the suspension of Y4O (OH)9 (NO3) ( ...The new electrorheologicai (ER) material, a particle material composed of Y4O(OH)9(NO3) and NH4NO3, was obtained. They display better ER performance. The shear stress of the suspension of Y4O (OH)9 (NO3) ( NH4NO3 )2.8 material in dimethyl silicone oil reaches 1469 Pa at an electric field strength (E) of 4.2 kV·mm^-1 and the shear rate (7) of 150 s^-1 The relative shear stress, τ E/τ0( τE and τ0 are the shear stresses at E = 4.2 and 0 kV·mm^-1 respectively), is up to 29, which is 19 times that of pure Y2O3 material. The dielectric and conductive property of the materials play important roles in the modification of the ER effect of the particle materials. The researches on these new ER materials are very useful for obtaining a better understanding on the mechanism of the ER effect and finding an ideal ER material.展开更多
Direct carbon solid oxide fuel cells(DC-SOFCs)are promising,green,and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures.Developing suitable anode materials for...Direct carbon solid oxide fuel cells(DC-SOFCs)are promising,green,and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures.Developing suitable anode materials for DC-SOFCs is a substantial scientific challenge.Herein we investigated the use of La_(0.75)Sr_(0.25)Cr_(0.5)Mn_(0.5)O_(3)-δ−Ce_(0.8)Gd_(0.2)O_(1.9)(LSCM−GDC)composite electrodes as anodes for La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3)-δelectrolyte-based DC-SOFCs,with Camellia oleifera shell char as the carbon fuel.The LSCM−GDC-anode DC-SOFC delivered a maximum power density of 221 mW/cm^(2) at 800℃ and it significantly improved to 425 mW/cm^(2) after Ni nanoparticles were introduced into the LSCM−GDC anode through wet impregnation.The microstructures of the prepared anodes were characterized,and the stability of the anode in a DC-SOFC and the influence of catalytic activity on open circuit voltage were studied.The above results indicate that LSCM–GDC anode is promising to be applied in DC-SOFCs.展开更多
A new lithium ion battery cathode material, composite oxide LiNi y Co z Mn 1- y-z O 2, was synthesized. The structure and physical properties of the material, including composition, distribution of size, density and s...A new lithium ion battery cathode material, composite oxide LiNi y Co z Mn 1- y-z O 2, was synthesized. The structure and physical properties of the material, including composition, distribution of size, density and specific surface area, were discussed. The characteristic of charge and discharge, reversible specific capacity and cycle property were also studied. The relationship between the structure and properties of the composite oxides was explored. The results show that the composite oxide with a reasonable composition is beneficial to the improvement and enhancement of the properties.展开更多
A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with...A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.展开更多
基金Supported by National Natural Science Foundation of China(Grant No.51275307)
文摘As a key to improve the performance of the interbay automated material handling system (AMHS) in 300 mm semiconductor wafer fabrication system, the real- time overhead hoist transport (OHT) dispatching problem has received much attention. This problem is first formu- lated as a special form of assignment problem and it is proved that more than one solution will be obtained by Hungarian algorithm simultaneously. Through proposing and strictly proving two propositions related to the char- acteristics of these solutions, a modified Hungarian algo- rithm is designed to distinguish these solutions. Finally, a new real-time OHT dispatching method is carefully designed by implementing the solution obtained by the modified Hungarian algorithm. The experimental results of discrete event simulations show that, compared with con- ventional Hungarian algorithm dispatching method, the proposed dispatching method that chooses the solution with the maximum variance respectively reduces on average 4 s of the average waiting time and average lead time of wafer lots, and its performance is rather stable in multiple dif- ferent scenarios of the interbay AMHS with different quantities of shortcuts. This research provides an efficient real-time OHT dispatching mechanism for the interbay AMHS with shortcuts and bypasses.
文摘Resorbable bioceramics are attractive for medical applications such as bone substitution. Biochemical analysis on cells cultured on these biomaterials is vital to predict the impact of the materials in vivo and RNA extraction is an essential step in gene expression study using RT-qPCR. In this study, we describe simple modifications to the TRIzol? RNA extraction protocol widely used in biology and these allow high-yield extraction of RNA from cells on resorbable calcium phosphates. Without the modifications, RNA is trapped in the co-precipitated calcium compounds, rendering TRIzol? extraction method infeasible. Among the modifications, the use of extra TRIzol? to dilute the lysate before the RNA precipitation step is critical for extraction of RNA from porous ?-tricalcium phosphate (?-TCP) discs. We also investigate the rationale behind the undesirable precipitation so as to provide clues about the modifications required for other resorbable materials with high application potential in bone tissue engineering.
基金financially supported by Henan Scientific and Technological Research Projects (112102210095 )Science Fund for Distinguished Young Scholars of Henan Province ( No.124100510019) the Education Department of Henan Province Foundation (14A430030)
文摘A1203-Si composite specimens were prepared using fused corundum, ultra-fine α-A1203 and Si powder as starting materials and resin as binder. Effects of sintering atmospheres on properties, phase composition and microstructure of specimens after firing at 1 500 ℃ were investigated. The results show that: ( 1 ) after .firing in oxidizing or weak oxidizing atmosphere, there is some Si in the specimens and some glass phases containing mullite form on specimen surface, the density and strength at room temperature are relatively high, but hot modulus of rupture and thermal shock resistance are relatively poor; (2) after firing in, weak reducing or reducing atmosphere, Si reacts completely with CO or N2forming whisk-phere, Si reacts completely with CO or N2forming whisk-er-like SiC, granular Si2N20 or 0'-SiAION, and the er-like SiC, granular Si2N20 or O'-SiMON, and the thermo-mechanical properties of specimens are enhanced;(3) after firing in nitrogen atmosphere, Si reacts completely with N2, CO or G forming wbisker-like SiC and columnar β-SiA10N crystals, the hot modulus of rupture and thermal shock resistance of specimens are enhanced noticeably.
基金the National Natural Science Foundation of China (No.10072041)the National Excellent Young Scholar Fund of China (No.10125209)the Teaching and Research Award Program for Outstanding Young Teachers in Higher Education Institutions of MOE,P.R.C..
文摘The main objective of this paper is to study the singular natureof the crack-tip stress and electric displacement field in afunctionally gradient piezoelectric medium having materialcoefficients with a discontinuous derivative. The problem isconsidered for the simplest possible loading and geometry, namely,the anti-plane shear stress and electric displacement in -plane oftwo bonded half spaces in which the crack is parallel to theinterface.
基金Funded by the National High Technology Research and Development Program of China(863 Program)(No.2015AA034600)Province Science and Technology in Anhui(No.1301021011)
文摘To improve the cyclic stability at high temperature and thermal stability, the spherical Al2O3-modified Li(Ni0.5Co0.2Mn0.3)O2 was synthesized by a modified co-precipitation method, and the physical and electrochemical properties were studied. The TEM images showed that Li(Ni0.5Co0.2Mn0.3)O2 was modified successfully with nano-Al2O3. The discharge capacity retention of Al2O3-modified Li(Ni0.5Co0.2Mn0.3)O2 maintained about 99% after 200 cycles at high temperature(55 ℃), while that of the bare one was only 86%. Also, unlike bare Li(Ni0.5Co0.2Mn0.3)O2, the Al2O3-modified material cathode exhibited good thermal stability.
基金Sponsored by the National Natural Science Foundation of China(Grant No.10972162)
文摘A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material,the paper derives the macroscopic constitutive laws for homogenous equivalent medium. By changing the shape parameter of circular particles,the effect of pore shape on macroscopic constitutive laws is explored. Yield surfaces with different pore shapes are obtained. About voids,a two-scale conception is introduced,which regards main void as macroscopic scale and secondary cavities as microscopic scale. The macroscopic potential involving main and secondary voids is achieved. The proposed macroscopic constitutive law taking microscopic features as influence factors is helpful for exploring the macroscopic mechanical properties of porous medium when numerical simulation is required.
基金Funded by Science and Technology Support Program of Hubei Province of China(No.2015BAA111)
文摘A 1-octadecanol(OD)/1,3:2,4-di-(3,4-dimethyl) benzylidene sorbitol(DMDBS)/expander graphite(EG) composite was prepared as a form-stable phase change material(PCM) by vacuum melting method. The results of field emission-scanning electron microscopy(FE-SEM) showed that 1-octadecanol was restricted in the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR) results showed that no chemical reaction occurred among the components of composite PCM in the preparation process. The gel-to-sol transition temperature of the composite PCMs containing DMDBS was much higher than the melting point of pure 1-octadecanol. The improvements in preventing leakage and thermal stability limits were mainly attributed to the synergistic effect of the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. Differential scanning calorimeter(DSC) was used to determine the latent heat and phase change temperature of the composite PCMs. During melting and freezing process the latent heat values of the PCM with the composition of 91% OD/3% DMDBS/6% EG were 214.9 and 185.9 kJ·kg-1, respectively. Its degree of supercooling was only 0.1 ℃. Thermal constant analyzer results showed that its thermal conductivity(κ) changed up to roughly 10 times over that of OD/DMDBS matrix.
基金Projects(06YFJZJC01100,08JCYBJC14800)supported by Applied Basic Study Foundation of Tianjin,ChinaProject(2006AA03Z413)supported by the Hi-tech Research and Development Program of China
文摘Thermodynamic models for molecular-beam epitaxy(MBE) growth of ternary Ⅲ-Ⅴ semiconductor materials are proposed.These models are in agreement with our experimental materials InGaP/GaAs and InGaAs/InP,and reported GaAsP/GaAs and InAsP/InP in thermodynamic growth.The lattice strain energy △G and thermal decomposition sensitive to growth temperature are demonstrated in the models simultaneously.△G is the function of the alloy composition,which is affected by flux ratio and growth temperature directly.The calculation results reveal that flux ratio and growth temperature mainly influence the growth process.Thermodynamic model of quaternary InGaAsP/GaAs semiconductor material is discussed also.
基金supported by the National Natural Science Foundation of China(91216201)
文摘Representative volume element (RVE) method and asymptotic homogenization (AH) method are two widely used methods in predicting effective properties of pe- riodic materials. This paper develops a novel implementa- tion of the AH method, which has rigorous mathematical foundation of the AH method, and also simplicity as the RVE method. This implementation can be easily realized using commercial software as a black box, and can use all kinds of elements available in commercial software to model unit cells with rather complicated microstructures, so the model may remain a fairly small scale. Several examples were car- fled out to demonstrate the simplicity and effectiveness of the new implementation.
基金Supported by National Natural Science Foundation of China(Grant Nos.51475348,51305322 and 51490660)Open Foundation of State Key Laboratory of Mechanical Transmissions(SKLMT-KFKT-201409)Fundamental Research Funds for the Central Universities of China
文摘Some compensation methods have been pro- posed to mitigate the degradation of radiation characteris- tics caused by composite material radomes, however most of them are complex and not applicable for large radomes, for example, the modification of geometric shape by grinding process. A novel and simple compensation strat- egy based on phase modification is proposed for large reflector antenna-radome systems. Through moving the feed or sub-reflector along axial direction opportunely, the modification of phase distribution in the original aperture of an enclosed reflector antenna can be used to reduce the phase shift caused by composite material radomes. The distortion of far-field pattern can be minimized. The modification formulas are proposed, and the limitation of their application is also discussed. Numerical simulations for a one-piece composite materials sandwich radome and a 40 m multipartite composite materials sandwich radome verify that the novel compensation strategy achieves sat- isfactory compensated results, and improves the distortion of the far-field pattern for the composite material radomes. For one-piece dielectric radome, more than 60% phasedifference caused by radome is reduced. For multipartite radome, the sidelobe level improves about 1.2 dB, the nulling depth improves about 3 dB. The improvement of far-field pattern could be obtained effectively and simply by moving the feed or sub-reflector according to phase shift of the radome.
基金Project supported by the National Natural Science Foundation of China (No.50525824)Natural Science Fund of Xinjiang Province of China (No.200432109).
文摘High strength refractory organic stream is produced during the production of 2-phenylamino-3-methyl-6-di-n-butylaminofluoran (One Dye Black 2, abbr. ODB 2), a novel heat-sensitive material with a promising market. In this study, a combination of acidificationprecipitation, primary biological treatment, Fenton's oxidation and another biological treatment was successfully used for the removal of COD from 18000-25000 mg/L to below 200 mg/L from the ODB 2 production wastewater in a pilot experiment. A COD removal of 70%-80% was achieved by acidification-precipitation under a pH of 2.5-3.0. The first step biodegradafion permitted an average COD removal of 70% under an hydraulic residence time (HRT) of 30 h. By batch tests, the optimum conditions of Fenton's oxidation were acquired as: Fe^2+ dose 6.0 mmol/L; H2O2 dose 3000 mg/L; and reaction time 6 h. The second step biological treatment could ensure an effluent COD below 200 mg/L under an HRT of 10 h following the Fenton's treatment.
文摘The new electrorheologicai (ER) material, a particle material composed of Y4O(OH)9(NO3) and NH4NO3, was obtained. They display better ER performance. The shear stress of the suspension of Y4O (OH)9 (NO3) ( NH4NO3 )2.8 material in dimethyl silicone oil reaches 1469 Pa at an electric field strength (E) of 4.2 kV·mm^-1 and the shear rate (7) of 150 s^-1 The relative shear stress, τ E/τ0( τE and τ0 are the shear stresses at E = 4.2 and 0 kV·mm^-1 respectively), is up to 29, which is 19 times that of pure Y2O3 material. The dielectric and conductive property of the materials play important roles in the modification of the ER effect of the particle materials. The researches on these new ER materials are very useful for obtaining a better understanding on the mechanism of the ER effect and finding an ideal ER material.
基金Project(2019YFC1907405)supported by the National Key R&D Program of ChinaProject(GJJ200809)supported by the Education Department Project Fund of Jiangxi Province,ChinaProject(2020BAB214021)supported by the Natural Science Foundation of Jiangxi Province,China。
文摘Direct carbon solid oxide fuel cells(DC-SOFCs)are promising,green,and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures.Developing suitable anode materials for DC-SOFCs is a substantial scientific challenge.Herein we investigated the use of La_(0.75)Sr_(0.25)Cr_(0.5)Mn_(0.5)O_(3)-δ−Ce_(0.8)Gd_(0.2)O_(1.9)(LSCM−GDC)composite electrodes as anodes for La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3)-δelectrolyte-based DC-SOFCs,with Camellia oleifera shell char as the carbon fuel.The LSCM−GDC-anode DC-SOFC delivered a maximum power density of 221 mW/cm^(2) at 800℃ and it significantly improved to 425 mW/cm^(2) after Ni nanoparticles were introduced into the LSCM−GDC anode through wet impregnation.The microstructures of the prepared anodes were characterized,and the stability of the anode in a DC-SOFC and the influence of catalytic activity on open circuit voltage were studied.The above results indicate that LSCM–GDC anode is promising to be applied in DC-SOFCs.
文摘A new lithium ion battery cathode material, composite oxide LiNi y Co z Mn 1- y-z O 2, was synthesized. The structure and physical properties of the material, including composition, distribution of size, density and specific surface area, were discussed. The characteristic of charge and discharge, reversible specific capacity and cycle property were also studied. The relationship between the structure and properties of the composite oxides was explored. The results show that the composite oxide with a reasonable composition is beneficial to the improvement and enhancement of the properties.
基金the Natural Science Foundation of Jiangsu province (Grant No Bk2001031)
文摘A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.