Research and development of 3PP coating steel pipes

The industrial application of an exterior three-layer anticorrosive polypropylene coating system(3PP)on large-diameter(larger than Φ600 mm)steel pipes was developed using an experimental process simulation study and the optimization of raw materials inspection,steel pipe surface pretreatments,and water cooling control on a coating application process.The coating properties meet ISO standard 21809 on buried or submerged 3PP pipelines used in the petroleum and natural gas industries.Differential scanning calorimetry and X-ray diffraction were used to analyze the crystallinities and grain sizes of polypropylene(PP)top coats with different cooling rates.Increasing the melt cooling rate reduces the crystallinity and grain size of the PP top coat and enhances its strength and toughness.

Disbond detection with piezoelectric wafer active sensors in RC structures strengthened with FRP composite overlays

The capability of embedded piezoelectric wafer active sensors(PWAS)to perform in-situ nondestructive evaluation(NDE)for structural health monitoring(SHM)of reinforced concrete(RC)structures strengthened with fiber reinforced polymer(FRP)composite overlays is explored.First,the disbond detection method were developed on coupon specimens consisting of concrete blocks covered with an FRP composite layer.It was found that the presence of a disbond crack drastically changes the electromecfianical(E/M)impedance spectrum lneasurcd at the PWAS terlninals.The spectral changes depend on the distance between the PWAS and the crack tip.Second,large scale experiments were conducted on a RC beam strengthened with carbon fiber reinforced polymer(CFRP)composite overlay.The beam was subject to an accelerated fatigue load regime in a three-point bending configuration up to a total of 807,415 cycles.During these fatigue tests,the CFRP overlay experienced disbonding beginning at about 500,000 cycles.The PWAS were able to detect the disbonding before it could be reliably seen by visual inspection.Good correlation between the PWAS readings and the position and extent of disbond damage was observed.These preliminary results demonstrate the potential of PWAS technology for SHM of RC structures strengthened with FRP composite overlays.

An electrochemical method for evaluating the resistance to cathodic disbondment of anti-corrosion coatings on buried pipelines

Methods for evaluating the resistance to cathodic disbondment （RCD） of anti-corrosion coatings on buried pipelines were reviewed. It is obvious that these traditional cathodic disbondment tests （CDT） have some disadvantages and the evaluated results are only simple figures and always rely on the subjective experience of the operator. A new electrochemical method for evaluating the RCD of coatings, that is, the potentiostatic evaluation method （PEM）, was developed and studied. During potentiostatic anodic polarization testing, the changes of stable polarization current of specimens before and after cathodic disbonding （CD） were measured, and the degree of cathodic disbondment of the coating was quantitatively evaluated, among which the equivalent cathodic disbonded distance AD was suggested as a parameter for evaluating the RCD. A series of testing parameters of the PEM were determined in these experiments.

Effect of sulfate-reducing bacteria on corrosion of X80 pipeline steel under disbonded coating in a red soil solution

Effect of sulfate-reducing bacteria on the corrosion behaviors of API-X80 pipeline steel has been studied in crevices under simulated disbonded coatings in red soil solution.The results show that there are amounts of SRB in the crevice under the simulated disbonded coating in the red soil solution during the whole period of experiment.The electrochemical impedance spectroscopy shows that SRB can enhance the corrosion of the steel in the crevice under the simulated disbonded coating,and the thermodynamic analyses indicate that SRB can accelerate the corrosion of steel using not only sulfate but also ferric hydroxide as electron acceptors.