Propylene carbonate (PC) has a great potential to be used as an energy storage medium in the compact pulsed power sources due to its high dielectric constant and large resistivity. We investigate both the positive a...Propylene carbonate (PC) has a great potential to be used as an energy storage medium in the compact pulsed power sources due to its high dielectric constant and large resistivity. We investigate both the positive and negative breakdown characteristics of PC. The streamer patterns are obtained by ultra-high-speed cameras. The experimental results show that the positive breakdown voltage of PC is about 135% higher than the negative one, which is abnormal compared with the common liquid. The shape of the positive streamer is filamentary and branchy, while the negative streamer is tree-like and less branched. According to these experimental results, a charge layer structure model at the interface between the metal electrode and liquid is presented. It is suggested that the abnormal polarity effect basically arises from the electric field strength difference in the interface between both electrodes and PC. What is more, the recombination radiation and photoionization also play an important role in the whole discharge process.展开更多
Chemical effects in different aqueous solutions induced by plasma with glow discharge electrolysis (GDE) and contact glow discharge electrolysis (CGDE) are described in this paper. The experimental and discharge char...Chemical effects in different aqueous solutions induced by plasma with glow discharge electrolysis (GDE) and contact glow discharge electrolysis (CGDE) are described in this paper. The experimental and discharge characteristics are also reviewed. These are followed by a discussion of their mechanisms of both anodic and cathodic CGDE..展开更多
In this paper, a two-dimensional nanometer scale tip-plate discharge model has been employed to study nanoscale electrical discharge in atmospheric conditions. The field strength dis- tributions in a nanometer scale t...In this paper, a two-dimensional nanometer scale tip-plate discharge model has been employed to study nanoscale electrical discharge in atmospheric conditions. The field strength dis- tributions in a nanometer scale tip-to-plate electrode arrangement were calculated using the finite element analysis (FEA) method, and the influences of applied voltage amplitude and frequency as well as gas gap distance on the variation of effective discharge range (EDR) on the plate were also investigated and discussed. The simulation results show that the probe with a wide tip will cause a larger effective discharge range on the plate; the field strength in the gap is notably higher than that induced by the sharp tip probe; the effective discharge range will increase linearly with the rise of excitation voltage, and decrease nonlinearly with the rise of gap length. In addition, probe dimension, especially the width/height ratio, affects the effective discharge range in different manners. With the width/height ratio rising from 1 : 1 to 1 : 10, the effective discharge range will maintain stable when the excitation voltage is around 50 V. This will increase when the excitation voltage gets higher and decrease as the excitation voltage gets lower. Fhrthermore, when the gap length is 5 nm and the excitation voltage is below 20 V, the diameter of EDR in our simulation is about 150 nm, which is consistent with the experiment results reported by other research groups. Our work provides a preliminary understanding of nanometer scale discharges and establishes a predictive structure-behavior relationship.展开更多
On the basis of considering electrochemical reactions and collision relations in detail, a direct numerical simulation model of a helicon plasma discharge with three-dimensional two-fluid equations was employed to stu...On the basis of considering electrochemical reactions and collision relations in detail, a direct numerical simulation model of a helicon plasma discharge with three-dimensional two-fluid equations was employed to study the characteristics of the temporal evolution of particle density and electron temperature. With the assumption of weak ionization, the Maxwell equations coupled with the plasma parameters were directly solved in the whole computational domain. All of the partial differential equations were solved by the finite element solver in COMSOL Multiphysics^(TM) with a fully coupled method. In this work, the numerical cases were calculated with an Ar working medium and a Shoji-type antenna. The numerical results indicate that there exist two distinct modes of temporal evolution of the electron and ground atom density, which can be explained by the ion pumping effect. The evolution of the electron temperature is controlled by two schemes: electromagnetic wave heating and particle collision cooling. The high RF power results in a high peak electron temperature while the high gas pressure leads to a low steady temperature. In addition, an OES experiment using nine Ar I lines was conducted using a modified CR model to verify the validity of the results by simulation, showing that the trends of temporal evolution of electron density and temperature are well consistent with the numerically simulated ones.展开更多
A varied class method is applied to calculate the effective discharges and their variations after the Three Gorges Dam(TGD)construction based on the mean daily flow discharge and suspended sediment concentration field...A varied class method is applied to calculate the effective discharges and their variations after the Three Gorges Dam(TGD)construction based on the mean daily flow discharge and suspended sediment concentration field data from 1981 to 2016.For comparison,the bankfull discharges are also determined according to the cross-section profiles and flow discharge-stage relations.Our results show that a bimodal effective discharge curve usually exists at the fixed sites,which generates two effective discharges(Q_(e1) and Q_(e2))within the moderate flow range.Under the quasi-equilibrium circumstances of the pre-dam period,effective discharges are closely related to the mean annual runoff,with a narrow range of regional variations in occurrence frequency.Our analyses draw the conclusion that the relatively higher unsaturation degrees of the pre-dam effective discharges caused by dam interception and riverbed coarsening are the primary cause of the increase in effective discharges from Yichang to Shashi,while the more frequent low and medium discharges due to flow regulation drive the decrease in effective discharges from Jianli to Datong.The slightly elevated flood levels and descending bankfull levels collaboratively result in the decrease of bankfull discharges from Yichang to Shashi,while the lowered bed elevation causes the increase in bankfull discharges from Luoshan to Datong.Overall,the bankfull discharge in the Middle and Lower Yangtze River is larger than effective discharge and approaches the 1.5-year recurrence interval discharge.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 51677190the Hunan Provincial Natural Science Foundation of China under Grant No 2017JJ1005
文摘Propylene carbonate (PC) has a great potential to be used as an energy storage medium in the compact pulsed power sources due to its high dielectric constant and large resistivity. We investigate both the positive and negative breakdown characteristics of PC. The streamer patterns are obtained by ultra-high-speed cameras. The experimental results show that the positive breakdown voltage of PC is about 135% higher than the negative one, which is abnormal compared with the common liquid. The shape of the positive streamer is filamentary and branchy, while the negative streamer is tree-like and less branched. According to these experimental results, a charge layer structure model at the interface between the metal electrode and liquid is presented. It is suggested that the abnormal polarity effect basically arises from the electric field strength difference in the interface between both electrodes and PC. What is more, the recombination radiation and photoionization also play an important role in the whole discharge process.
文摘Chemical effects in different aqueous solutions induced by plasma with glow discharge electrolysis (GDE) and contact glow discharge electrolysis (CGDE) are described in this paper. The experimental and discharge characteristics are also reviewed. These are followed by a discussion of their mechanisms of both anodic and cathodic CGDE..
基金supported in part by External Cooperation Program of Chinese Academy of Sciences(No.GJHZ1218)National Natural Science Foundation of China(No.61004133)SSSTC JRP awards 2011(IZLCZ2 138953)
文摘In this paper, a two-dimensional nanometer scale tip-plate discharge model has been employed to study nanoscale electrical discharge in atmospheric conditions. The field strength dis- tributions in a nanometer scale tip-to-plate electrode arrangement were calculated using the finite element analysis (FEA) method, and the influences of applied voltage amplitude and frequency as well as gas gap distance on the variation of effective discharge range (EDR) on the plate were also investigated and discussed. The simulation results show that the probe with a wide tip will cause a larger effective discharge range on the plate; the field strength in the gap is notably higher than that induced by the sharp tip probe; the effective discharge range will increase linearly with the rise of excitation voltage, and decrease nonlinearly with the rise of gap length. In addition, probe dimension, especially the width/height ratio, affects the effective discharge range in different manners. With the width/height ratio rising from 1 : 1 to 1 : 10, the effective discharge range will maintain stable when the excitation voltage is around 50 V. This will increase when the excitation voltage gets higher and decrease as the excitation voltage gets lower. Fhrthermore, when the gap length is 5 nm and the excitation voltage is below 20 V, the diameter of EDR in our simulation is about 150 nm, which is consistent with the experiment results reported by other research groups. Our work provides a preliminary understanding of nanometer scale discharges and establishes a predictive structure-behavior relationship.
基金funding from National Natural Science Foundation of China under grant agreement No. 11305265 (research on the acceleration mechanism of an electric double layer in a helicon plasma with a divergent magnetic field)
文摘On the basis of considering electrochemical reactions and collision relations in detail, a direct numerical simulation model of a helicon plasma discharge with three-dimensional two-fluid equations was employed to study the characteristics of the temporal evolution of particle density and electron temperature. With the assumption of weak ionization, the Maxwell equations coupled with the plasma parameters were directly solved in the whole computational domain. All of the partial differential equations were solved by the finite element solver in COMSOL Multiphysics^(TM) with a fully coupled method. In this work, the numerical cases were calculated with an Ar working medium and a Shoji-type antenna. The numerical results indicate that there exist two distinct modes of temporal evolution of the electron and ground atom density, which can be explained by the ion pumping effect. The evolution of the electron temperature is controlled by two schemes: electromagnetic wave heating and particle collision cooling. The high RF power results in a high peak electron temperature while the high gas pressure leads to a low steady temperature. In addition, an OES experiment using nine Ar I lines was conducted using a modified CR model to verify the validity of the results by simulation, showing that the trends of temporal evolution of electron density and temperature are well consistent with the numerically simulated ones.
基金This work was supported by the National Key Research and Development Program of China(No.2016YFC0402101)the National Natural Science Foundation of China(Grant Nos.51779184).We would like to thank the Yangtze River Water Resources Commission for providing important field data.The instructive suggestions by the editors and anonymous reviewers are gratefully acknowledged.
文摘A varied class method is applied to calculate the effective discharges and their variations after the Three Gorges Dam(TGD)construction based on the mean daily flow discharge and suspended sediment concentration field data from 1981 to 2016.For comparison,the bankfull discharges are also determined according to the cross-section profiles and flow discharge-stage relations.Our results show that a bimodal effective discharge curve usually exists at the fixed sites,which generates two effective discharges(Q_(e1) and Q_(e2))within the moderate flow range.Under the quasi-equilibrium circumstances of the pre-dam period,effective discharges are closely related to the mean annual runoff,with a narrow range of regional variations in occurrence frequency.Our analyses draw the conclusion that the relatively higher unsaturation degrees of the pre-dam effective discharges caused by dam interception and riverbed coarsening are the primary cause of the increase in effective discharges from Yichang to Shashi,while the more frequent low and medium discharges due to flow regulation drive the decrease in effective discharges from Jianli to Datong.The slightly elevated flood levels and descending bankfull levels collaboratively result in the decrease of bankfull discharges from Yichang to Shashi,while the lowered bed elevation causes the increase in bankfull discharges from Luoshan to Datong.Overall,the bankfull discharge in the Middle and Lower Yangtze River is larger than effective discharge and approaches the 1.5-year recurrence interval discharge.