A non-linear optical（NLO） material was synthesized by means of a simple method.This material can be applied in electro-optical（EO） devices,such as EO switches and modulators.The Disperse Red 1（DR1） was doped in ...A non-linear optical（NLO） material was synthesized by means of a simple method.This material can be applied in electro-optical（EO） devices,such as EO switches and modulators.The Disperse Red 1（DR1） was doped in polymethyl-methacrylate-co-glycidyl methacrylate（PMMA-co-GMA） as the NLO active chromophore.The synthesis process and material structure were expressed.The thermal properties,surface morphology and optical characteristics of the material were investigated by means of differential scanning calorimetry（DSC）,thermogravimetric analysis（TGA）,atomic force microscopy（AFM）,and m-lines technique.Using the reflection technique,the value of the electro-optical coefficient γ 33 was measured as 11 pm/V at a wavelength of 1310 nm.An EO switch with nanosecond response based on this material has been fabricated.展开更多
Films were prepared from mixtures of copolymers of 4-nitro-4'-[N-methylacryloyloxyethyl, N'-ethyl] amino azobenzene with glycidyl methacrylate (chromophore content: 6 mol%) and copolymers containing anhydride ...Films were prepared from mixtures of copolymers of 4-nitro-4'-[N-methylacryloyloxyethyl, N'-ethyl] amino azobenzene with glycidyl methacrylate (chromophore content: 6 mol%) and copolymers containing anhydride units, which was obtained by the reaction of 4-nitro-4'-[N-hydroxyethyl, N'-ethyl] amino azobenzene with polymethacryloyl chloride (chromophore content: 25 mol %). During thermal poling process the anhydride reacts with the epoxy group and the resulting crosslinked network structure will stabilize the second harmonic generation in the poled film. The second harmonic generation of the poled film shows a maximum with the variation of composition this is presumed to be due to the effects of the increasing of concentration, orientation order as well as orientation stability of chromophore groups during crosslinking.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.61107019,61177027,61077041,60807029)the Science Foundation for Young Scientists of Jilin Province,China(No. 20100174)+1 种基金the Science and Technology Development Plan of Jilin Province,China(No.20110315)the Program for Special Funds of Basic Science & Technology of Jilin University,China(Nos.201103071,201100253,200905005)
文摘A non-linear optical（NLO） material was synthesized by means of a simple method.This material can be applied in electro-optical（EO） devices,such as EO switches and modulators.The Disperse Red 1（DR1） was doped in polymethyl-methacrylate-co-glycidyl methacrylate（PMMA-co-GMA） as the NLO active chromophore.The synthesis process and material structure were expressed.The thermal properties,surface morphology and optical characteristics of the material were investigated by means of differential scanning calorimetry（DSC）,thermogravimetric analysis（TGA）,atomic force microscopy（AFM）,and m-lines technique.Using the reflection technique,the value of the electro-optical coefficient γ 33 was measured as 11 pm/V at a wavelength of 1310 nm.An EO switch with nanosecond response based on this material has been fabricated.
文摘Films were prepared from mixtures of copolymers of 4-nitro-4'-[N-methylacryloyloxyethyl, N'-ethyl] amino azobenzene with glycidyl methacrylate (chromophore content: 6 mol%) and copolymers containing anhydride units, which was obtained by the reaction of 4-nitro-4'-[N-hydroxyethyl, N'-ethyl] amino azobenzene with polymethacryloyl chloride (chromophore content: 25 mol %). During thermal poling process the anhydride reacts with the epoxy group and the resulting crosslinked network structure will stabilize the second harmonic generation in the poled film. The second harmonic generation of the poled film shows a maximum with the variation of composition this is presumed to be due to the effects of the increasing of concentration, orientation order as well as orientation stability of chromophore groups during crosslinking.
