Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

Defects‑Rich Heterostructures Trigger Strong Polarization Coupling in Sulfides/Carbon Composites with Robust Electromagnetic Wave Absorption

Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.

Integration of Electrical Properties and Polarization Loss Modulation on Atomic Fe–N‑RGO for Boosting Electromagnetic Wave Absorption

Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band structure of graphene,regulating its bandgap and electrical properties by introducing heteroatoms is considered a feasible solution.Herein,metal-nitrogen doping reduced graphene oxide(M–N-RGO)was prepared by embedding a series of single metal atoms M–N_(4) sites(M=Mn,Fe,Co,Ni,Cu,Zn,Nb,Cd,and Sn)in RGO using an N-coordination atom-assisted strategy.These composites had adjustable conductivity and polarization to optimize dielectric loss and impedance matching for efficient EMWA performance.The results showed that the minimum reflection loss(RL_(min))of Fe–N-RGO reaches−74.05 dB(2.0 mm)and the maximum effective absorption bandwidth(EAB_(max))is 7.05 GHz(1.89 mm)even with a low filler loading of only 1 wt%.Combined with X-ray absorption spectra(XAFS),atomic force microscopy,and density functional theory calculation analysis,the Fe–N_(4) can be used as the polarization center to increase dipole polarization,interface polarization and defect-induced polarization due to d-p orbital hybridization and structural distortion.Moreover,electron migration within the Fe further leads to conduction loss,thereby synergistically promoting energy attenuation.This study demonstrates the effectiveness of metal-nitrogen doping in regulating the graphene′s dielectric properties,which provides an important basis for further investigation of the loss mechanism.

Low‑Temperature Oxidation Induced Phase Evolution with Gradient Magnetic Heterointerfaces for Superior Electromagnetic Wave Absorption

Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.

Effects of mesoscale gravity waves on sporadic E simulated by a one-dimensional dynamic model

In addition to being driven by tidal winds,the sporadic E(Es)layers are modulated by gravity waves(GWs),although the effects are not yet comprehensively understood.In this article,we discuss the effects of mesoscale GWs on the Es layers determined by using a newly developed model,MISE-1D(one-dimensional Model of Ionospheric Sporadic E),with low numerical dissipation and high resolution.Driven by the wind fields resolved by the high-resolution version of the Whole Atmosphere Community Climate Model with thermosphere and ionosphere extension(WACCM-X),the MISE-1D simulation revealed that GWs significantly influence the evolution of the Es layer above 100 km but have a very limited effect at lower altitudes.The effects of GWs are diverse and complex,generally including the generation of fluctuating wavelike structures on the Es layer with frequencies similar to those of the GWs.The mesoscale GWs can also cause increases in the density of Es layers,or they can disperse or diffuse the Es layers and increase their thickness.In addition,the presence of GWs is a key factor in sustaining the Es layers in some cases.

Statistical analysis on the validity of the cold plasma approximation for chorus waves based on Van Allen Probe observations and their effects on radiation belt electrons

Theoretical analysis has demonstrated that the dispersion relation of chorus waves plays an essential role in the resonant interaction and energy transformation between the waves and magnetospheric electrons.Previous quantitative analyses often simplified the chorus dispersion relation by using the cold plasma assumption.However,the applicability of the cold plasma assumption is doubtful,especially during geomagnetic disturbances.We here present a systematic statistical analysis on the validity of the cold plasma dispersion relation of chorus waves based on observations from the Van Allen Probes over the period from 2012 to 2018.The statistical results show that the observed magnetic field intensities deviate substantially from those calculated from the cold plasma dispersion relation and that they become more pronounced with an increase in geomagnetic activity or a decrease in background plasma density.The region with large deviations is mainly concentrated in the nightside and expands in both the radial and azimuthal directions as the geomagnetic activity increases or the background plasma density decreases.In addition,the bounce-averaged electron scattering rates are computed by using the observed and cold plasma dispersion relation of chorus waves.Compared with usage of the cold plasma dispersion relation,usage of the observed dispersion relation considerably lowers the minimum resonant energy of electrons and lowers the scattering rates of electrons above tens of kiloelectronvolts but enhances those below.Furthermore,these differences are more pronounced with the enhancement of geomagnetic activity or the decrease in background plasma density.

Graphene Aerogel Composites with Self‑Organized Nanowires‑Packed Honeycomb Structure for Highly Efficient Electromagnetic Wave Absorption

With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.

An investigation on the wind profiles and gravity wave dynamics in MLT region based on the meteor radars from the Meridian Project

The meteor radar can detect the zenith angle,azimuth,radial velocity,and altitude of meteor trails so that one can invert the wind profiles in the mesosphere and low thermosphere(MLT)region,based on the Interferometric and Doppler techniques.In this paper,the horizontal wind field,gravity wave(GW)disturbance variance,and GW fluxes are analyzed through the meteor radar observation from 2012−2022,at Mohe(53.5°N,122.4°E)and Zuoling(30.5°N,114.6°E)stations of the(Chinese)Meridian Project.The Lomb−Scargle periodogram method has been utilized to analyze the periodic variations for time series with observational data gaps.The results show that the zonal winds at both stations are eastward dominated,while the meridional winds are southward dominated.The variance of GW disturbances in the zonal and meridional directions increases gradually with height,and there is a strong pattern of annual variation.The zonal momentum flux of GW changes little with height,showing weak annual variation.The meridional GW flux varies gradually from northward to southward with height,and the annual periodicity is stronger.For both stations,the maximum values of zonal and meridional wind occur close to the peak heights of GW flux,with opposite directions.This observational evidence is consistent with the filtering theory.The horizontal wind velocity,GW flux,and disturbance variance of the GW at Mohe are overall smaller than those at Zuoling,indicating weaker activities in the MLT at Mohe.The power spectral density(PSD)calculated by the Lomb−Scargle periodogram shows that there are 12-month period and 6-month period in horizontal wind field,GW disturbance variance and GW flux at both stations,and especially there is also a 4-month cycle in the disturbance variance.The PSD of the 12-month and 6-month cycles exhibits maximum values below 88 km and above 94 km.

Experimental and numerical simulation of the attenuation effect of blast shock waves in tunnels at different altitudes

Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid dynamics.The effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical simulation.Based on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was established.The results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude condition.In contrast,an increase in altitude accelerated the propagation speed of the shock wave in the tunnel.The average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.

AI-based Correction of Wave Forecasts Using the Transformer-enhanced UNet Model

Grid forecasting can be used to effectively enhance the spatial and temporal density of forecast products,thereby improving the capability of short-term marine disaster forecasting and warnings in terms of proximity.The traditional method that relies on forecasters'subjective correction of station observation data for forecasting has been unable to meet the practical needs of refined forecasting.To address this problem,this paper proposes a Transformer-enhanced UNet(TransUNet)model for wave forecast AI correction,which fuses wind and wave information.The Transformer structure is integrated into the encoder of the UNet model,and instead of using the traditional upsampling method,the dual-sampling module is employed in the decoder to enhance the feature extraction capability.This paper compares the TransUNet model with the traditional UNet model using wind speed forecast data,wave height forecast data,and significant wave height reanalysis data provided by ECMWF.The experimental results indicate that the TransUNet model yields smaller root-meansquare errors,mean errors,and standard deviations of the corrected results for the next 24-h forecasts than does the UNet model.Specifically,the root-mean-square error decreased by more than 21.55%compared to its precorrection value.According to the statistical analysis,87.81%of the corrected wave height errors for the next 24-h forecast were within±0.2m,with only 4.56%falling beyond±0.3 m.This model effectively limits the error range and enhances the ability to forecast wave heights.

Role of variation coefficient of stone density in determining success of shock wave lithotripsy in urinary calculi

BACKGROUND Various stone factors can affect the net results of shock wave lithotripsy(SWL).Recently a new factor called variation coefficient of stone density(VCSD)is being considered to have an impact on stone free rates.AIM To assess the role of VCSD in determining success of SWL in urinary calculi.METHODS Charts review was utilized for collection of data variables.The patients were subjected to SWL,using an electromagnetic lithotripter.Mean stone density(MSD),stone heterogeneity index(SHI),and VCSD were calculated by generating regions of interest on computed tomography(CT)images.Role of these factors were determined by applying the relevant statistical tests for continuous and categorical variables and a P value of<0.05 was gauged to be statistically significant.RESULTS There were a total of 407 patients included in the analysis.The mean age of the subjects in this study was 38.89±14.61 years.In total,165 out of the 407 patients could not achieve stone free status.The successful group had a significantly lower stone volume as compared to the unsuccessful group(P<0.0001).Skin to stone distance was not dissimilar among the two groups(P=0.47).MSD was significantly lower in the successful group(P<0.0001).SHI and VCSD were both significantly higher in the successful group(P<0.0001).CONCLUSION VCSD,a useful CT based parameter,can be utilized to gauge stone fragility and hence the prediction of SWL outcomes.

A weak formulation of heterogenous viscoacoustic wave propagation in infinite domain

The accurate simulation of wave propagation in real media requires properly taking the attenuation into account,which leads to wave dissipation together with its causal companion,wave dispersion.In this study,to obtain a weak formulation of heterogenous viscoacoustic wave propagation in an infinite domain,the viscoacoustic medium is first characterized by its frequency-dependent complex bulk compliance instead of the classically used complex bulk modulus.Then,a mechanical model using serially connected standard linear solids(SSLS)is built to obtain the rational approximation of the complex bulk compliance whose parameters are calculated via an adapted nonlinear optimization method.Utilizing the obtained bulk compliance-based constitutive relation,a novel second-order viscoacoustic wave equation in the frequency domain is derived,of which the weak formulation can be physically explained as the virtual work equation and can thus be discretized using a continuous spectral element method in space.Additionally,a new method is introduced to address the convolution terms involved in the inverse Fourier transform,whose accurate time integration can then be achieved using an explicit time scheme,which avoids the transient growth that exists in the classical method.The resulting full time-space decoupling scheme can handle wave propagation in arbitrary heterogeneous media.Moreover,to treat the wave propagation in an infinite domain,a perfectly matched layer in weak formulation is derived for the truncation of the infinite domain via complex coordinate stretching of the virtual work equation.With only minor modification,the resulting perfectly matched layer can be implemented using the same time scheme as for the wave equation inside the truncated domain.The accuracy,numerical stability,and versatility of the new proposed scheme are demonstrated with numerical examples.

On the Asymptotic Property of Solutions to Some Nonlinear Dissipative Wave Equations

In this paper the decay of global solutions to some nonlinear dissipative wave equations are discussed, which based on the method of prior estimate technique and a differenece inequality.

ASYMPTOTIC STABILITY OF TRAVELING WAVES FOR A DISSIPATIVE NONLINEAR EVOLUTION SYSTEM

This paper is concerned with the existence and the nonlinear asymptotic stabil- ity of traveling wave solutions to the Cauchy problem for a system of dissipative evolution equations {θt=vζx＋（ζθ）x＋aθxx,ζt=-θx＋βζxx;with initial data and end states （ζθ）（x,0）=（ζ0,θ0）（x）→（ζ±,θ±）as x→∞.We obtain the existence of traveling wave solutions by phase plane analysis and show the asymptotic nonlinear stability of traveling wave solutions without restrictions on the coeffi- cients a and v by the method of energy estimates.

Traveling Wave Solutions and Kind Wave Excitations for the (2 + 1)-Dimensional Dissipative Zabolotskaya-Khokhlov Equation

In this work, with the help of the symbolic computation system Maple and the Riccati mapping approach and a linear variable separation approach, a new family of traveling wave solutions of the (2 + 1)-dimensional dissipative Zabolotskaya-Khokhlov equation (DZK) is derived. Based on the derived solitary wave solution, some novel kind wave excitations are investigated.

Reflection of Plane Waves from a Free Surface of an Initially Stressed Transversely Isotropic Dissipative Medium

The governing equations of a transversely isotropic dissipative medium are solved analytically to obtain the speeds of plane waves. The appropriate solutions satisfy the required boundary conditions at the stress-free surface to obtain the expressions of the reflection coefficients of reflected quasi-P (qP) and quasi-SV (qSV) waves in closed form for the incidence of qP and qSV waves. A particular model is chosen for numerical computation of these reflection coefficients for a certain range of the angle of incidence. The numerical values of these reflection coefficients are shown graphically against the angle of incidence for different values of initial stress parameter. The impact of initial stress parameter on the reflection coefficients is observed significantly.

Diffusion-induced deflection and the effect of two-wave mixing gain on dissipative photovoltaic solitons

In an open-circuit dissipative photovoltaic （PV） crystal, by considering the diffusion effect, the deflection of bright dissipative photovoltaic （DPV） solitons has been investigated by employing numerical technique and perturbational procedure. The relevant results show that the centre of the optical beam moves along a parabolic trajectory, while the central spatial-frequency component shifts linearly with the propagation distance; furthermore, both the spatial deflection and the angular derivation are associated with the photovoltaic field. Such DPV solitons have a fixed deflection degree completely determined by the parameters of the dissipative system. The small bending cannot affect the formation of the DPV soliton via two-wave mixing.

WavewatchⅢ模拟和统计方法在最大波高预报方面的评测分析

为了研究WavewatchⅢ(WWⅢ)海浪模型对最大波高的模拟能力及其与传统统计关系方法的差异,通过对两次台风浪过程的后报模拟和半年的业务化预报,分析了WWⅢ数值模拟的准确度及其与统计关系方法的精度差异。研究结果表明:WWⅢ数值模拟的最大波高(Hmax)的精度略低于有效波高(Hs),但也达到了24 h预报相对误差(H_(max)≥1 m)低于18%、相关系数高于0.94的水平,模拟精度可靠,可以用于业务化预报;与两种统计关系方法(H_(max)和H_(s)分别为1.42和1.52)计算的最大波高相比,数值模拟的精度总体与其相当,但在H_(max)和H_(s)比值大于1.65这种易出现危险的海况下,数值模拟具有更高的准确性,更适合应用于海浪预警报服务。

ON THE NUMERICAL SOLUTION OF QUASILINEAR WAVE EQUATION WITH STRONG DISSIPATIVE TERM

The numerical solution for a type of quasilinear wave equation is studied.The three-level difference scheme for quasi-linear waver equation with strong dissipative term is constructed and the convergence is proved.The error of the difference solution is estimated.The theoretical results are controlled on a numerical example.

Reflection of Plane Waves from Free Surface of an Initially Stressed Rotating Orthotropic Dissipative Solid Half-Space

The governing equations of an initially stressed rotating orthotropic dissipative medium are solved analytically to obtain the velocity equation which indicates the existence of two quasi-planar waves. The appropriate particular solutions in the half-space satisfy the required boundary conditions at the stress-free surface to obtain the expressions of the reflec-tion coefficients of the reflected quasi-P (qP) and reflected quasi-SV (qSV) waves in closed form for the incidence of qP and qSV waves. A particular model is chosen for numerical computation of these reflection coefficients for a certain range of the angle of incidence. The numerical values of these reflection coefficients are shown graphically against the angle of incidence for different values of initial stress parameter and rotation parameter. The impact of initial stress and rotation parameters on the reflection coefficients is observed significantly.