To realize potential cost savings in coastal monitoring programs and provide timely advice for marine management, there is an urgent need for efficient evaluation tools based on easily measured variables for the rapid...To realize potential cost savings in coastal monitoring programs and provide timely advice for marine management, there is an urgent need for efficient evaluation tools based on easily measured variables for the rapid and timely assessment of estuarine and offshore eutrophication. In this study, using parallel factor analysis(PARAFAC), principal component analysis(PCA), and discriminant function analysis(DFA) with the trophic index(TRIX) for reference, we developed an approach for rapidly assessing the eutrophication status of coastal waters using easy-to-measure parameters, including chromophoric dissolved organic matter(CDOM), fluorescence excitation–emission matrices, CDOM UV-Vis absorbance, and other water-quality parameters(turbidity, chlorophyll a, and dissolved oxygen). First, we decomposed CDOM excitation-emission matrices(EEMs) by PARAFAC to identify three components. Then, we applied PCA to simplify the complexity of the relationships between the water-quality parameters. Finally, we used the PCA score values as independent variables in DFA to develop a eutrophication assessment model. The developed model yielded classification accuracy rates of 97.1%, 80.5%, 90.3%, and 89.1% for good, moderate, and poor water qualities, and for the overall data sets, respectively. Our results suggest that these easy-to-measure parameters could be used to develop a simple approach for rapid in-situ assessment and monitoring of the eutrophication of estuarine and offshore areas.展开更多
Sequencing biofilm batch reactor(SBBR) under micro-aerobic condition was applied to the treatment of aniline-contaminated wastewater in this study.Hydraulic retention time(HRT) of 12—36 h and dissolved oxygen(DO) con...Sequencing biofilm batch reactor(SBBR) under micro-aerobic condition was applied to the treatment of aniline-contaminated wastewater in this study.Hydraulic retention time(HRT) of 12—36 h and dissolved oxygen(DO) concentration of 0.1—0.5 mg/L were selected as the operating variables to model,analyze and optimize the process.Five dependent parameters,aniline(AN),chemical oxygen demand(COD),ammonium,total nitrogen(TN) and total phosphorus(TP) removal efficiencies as the process responses,were studied.From the results,increase in DO concentration could promote the AN,COD and ammonium removal;increase in HRT could also lead to increase of the AN and ammonium removal,but might decrease COD removal due to endogenous respiration and soluble microbial products.In the SBBR system,24 h for HRT and 0.5 mg/L for DO concentration were chosen as the optimum operating condition.The actual removal efficiencies of COD,AN and ammonium under the optimum operating condition were 98.37%,100%and 89.29%,respectively.The experimental findings were in close agreement with the model prediction.The presence of glucose could promote bacterial growth and has positive influence on AN degradation and ammonium removal.展开更多
基金the National Natural Science Foundation of China (No. 41376106)the Shandong Provincial Natural Science Foundation of China (No. ZR2013DM017)
文摘To realize potential cost savings in coastal monitoring programs and provide timely advice for marine management, there is an urgent need for efficient evaluation tools based on easily measured variables for the rapid and timely assessment of estuarine and offshore eutrophication. In this study, using parallel factor analysis(PARAFAC), principal component analysis(PCA), and discriminant function analysis(DFA) with the trophic index(TRIX) for reference, we developed an approach for rapidly assessing the eutrophication status of coastal waters using easy-to-measure parameters, including chromophoric dissolved organic matter(CDOM), fluorescence excitation–emission matrices, CDOM UV-Vis absorbance, and other water-quality parameters(turbidity, chlorophyll a, and dissolved oxygen). First, we decomposed CDOM excitation-emission matrices(EEMs) by PARAFAC to identify three components. Then, we applied PCA to simplify the complexity of the relationships between the water-quality parameters. Finally, we used the PCA score values as independent variables in DFA to develop a eutrophication assessment model. The developed model yielded classification accuracy rates of 97.1%, 80.5%, 90.3%, and 89.1% for good, moderate, and poor water qualities, and for the overall data sets, respectively. Our results suggest that these easy-to-measure parameters could be used to develop a simple approach for rapid in-situ assessment and monitoring of the eutrophication of estuarine and offshore areas.
基金the National Major Water Project of China(No.2013ZX07201007)the Fund supported by State Key Laboratory of Urban Water Resource and Environment(Harbin Institute of Technology)(No.2013DX06)
文摘Sequencing biofilm batch reactor(SBBR) under micro-aerobic condition was applied to the treatment of aniline-contaminated wastewater in this study.Hydraulic retention time(HRT) of 12—36 h and dissolved oxygen(DO) concentration of 0.1—0.5 mg/L were selected as the operating variables to model,analyze and optimize the process.Five dependent parameters,aniline(AN),chemical oxygen demand(COD),ammonium,total nitrogen(TN) and total phosphorus(TP) removal efficiencies as the process responses,were studied.From the results,increase in DO concentration could promote the AN,COD and ammonium removal;increase in HRT could also lead to increase of the AN and ammonium removal,but might decrease COD removal due to endogenous respiration and soluble microbial products.In the SBBR system,24 h for HRT and 0.5 mg/L for DO concentration were chosen as the optimum operating condition.The actual removal efficiencies of COD,AN and ammonium under the optimum operating condition were 98.37%,100%and 89.29%,respectively.The experimental findings were in close agreement with the model prediction.The presence of glucose could promote bacterial growth and has positive influence on AN degradation and ammonium removal.