Assessing the Impact of Petrol Service Stations on Selected Physico-Chemical Water Quality Parameters within Port Harcourt Metropolis, Nigeria

This study assessed the impact of petrol service stations on physico-chemical water quality in Port Harcourt metropolis, Rivers State. This threw light on the extent of damage and alteration of water quality in Port Harcourt metropolis as a result of the proliferation of petrol service stations especially the condition of ground and nearby surface water. This serves as a useful tool to government and regulatory authorities for planning especially due to lack of central water supply system in Port Harcourt metropolis. The parameters studied were sampled, measured and analyzed using in situ and other standard methods. Remarkable results above permissible limits of interest for physicochemical parameter analysis revealed pH values from 4.6 to 6.8, electrical conductivity from 0.002 µS/cm to 0.42 µS/cm, salinity from 3 ppm to 4050 ppm, and temperatures from 19.9˚C to 32.6˚C. Total dissolved solids (TDS) varied from 7 ppm to 1000 ppm, biochemical oxygen demand (BOD) from 0.167 mg/L to 2.167 mg/L, chemical oxygen demand (COD) from 0.257 mg/L to 3.253 mg/L, and dissolved oxygen (DO) concentrations from 1.70 mg/L to 4.30 mg/L. Specifically, water samples from NNPC Filling Station (Choba) and Eneka Pond displayed “Poor” water quality with WQI values of 112.003 and 112.076, respectively. Similarly, ALLTEC Filling Station (Eneka) and TOTAL Filling Station (Rumuomasi) had “Poor” water quality with WQI values of 173.707 and 180.946, respectively. In contrast, Excelsis Filling Station (Akpajo) demonstrated “Good” water quality with a WQI of 85.2072, while Total Filling Stations (Slaughter) and Choba River revealed “unsuitable for drinking” water quality with WQI values of 552.461 and 654.601, respectively. Slaughter River also indicated very poor water quality with a WQI of 442.024. The physicochemical and nutrient analyses of the water samples showed that activities of the filling stations within the study area may have polluted groundwater in the environment posing poor aesthetics and great health risk to consumers of the water bodies. The findings underscore the need for immediate remediation efforts and stricter regulatory measures to protect water quality. The study concluded that surface and groundwater near petrol service stations in Port Harcourt are unfit for drinking and irrigation purposes without adequate treatment.

Corrosion of Basic Refractories for Glass Tanks Using Petrol Coke and Countermeasures

Replacing heavy oil with petrol coke can greatly reduce the cost of glass production,but obviously shorten the service life of refractories used in the regenerator checker body of glass tanks.To prolong the service life of the regenerator checker body,the slag chemical composition and alkali-sulfur ratio of glass tanks after using petrol coke and the damage mechanism of the residual magnesia bricks in the regenerator checker body were studied,as well as the corrosion resistance of three magnesia based bricks(direct bonded magnesia chrome bricks,fused rebonded magnesia chrome bricks,and fused rebonded high-purity magnesium aluminate spinel bricks).On this basis,a series of targeted countermeasures were adopted to optimize the configuration of refractories,significantly improving the service life of checker bricks and meeting the requirements of glass industry development.

The first mitogenome of Lauraceae(Cinnamomum chekiangense)

There are three distinct genetic systems in higher plants,the dominant nuclear genome and the semi-autonomous organelle genomes(plastids and mitochondria).In contrast to the conserved plastid genome(plastome),the plant mitochondrial genome(mitogenome)is characterized by an intriguing“evolutionary paradox”distinguished by a remarkably low mutation rate but with a significantly high rearrangement rate(Palmer and Herbon,1988;Lai et al.,2022).

Morphological comparison and molecular marker screening of three Skeletonema species found in Changjiang(Yangtze)River Basin

In our recent investigations of diatom diversity,we studied three species,namely,Skeletonema costatum,Skeletonema subsalsum,and Skeletonema potamos.Although they have been found frequently in Changjiang(Yangtze)River Basin,their morphological and molecular identification is difficult in taxonomy.Therefore,to integrate morphological and molecular biological approaches,we compared systematically their morphological characters and performed phylogenetic analysis.Twelve strains of Skeletonema were collected and isolated from Shanghai and Jiangsu,China,and their morphological characteristics were examined by light microscopy(LM)and the scanning electron microscopy(SEM).Based on morphological comparison,we determined that S.potamos is easy to distinguish from the other two species.The heavily silicified areolae,undulated or cleft distal ends of terminal fultoportula processes(TFPPs),absence of basal pores of fultoportula processes(FPPs),the rootlike protrusions of FPPs,and no interlocking connection are the stable characteristics that can be used to identify S.potamos.However,there are only two features that can distinguish S.costatum from S.subsalsum,namely the location of terminal rimoportulae(TRPs)and the distal shape of TFPPs.In addition,we amplified and sequenced nine common genetic markers from the strains,from which 101 sequences were obtained,constructed phylogenetic trees based on the nine genes and evaluated that seven genes can be used to identify S.potamos,and revealed that S.subsalsum is the closest known relative of S.costatum,and only ATP synthetase beta-subunit gene(atp B)is able to distinguish them from each other,which strongly support that it is an effective molecular marker for Skeletonema.This work provided a theoretical basis for the taxonomic study of Skeletonema.

The Application of Genetic Algorithms and Multidimensional Distinguishing Model in Forecasting and Evaluating Credits for Mobile Clients

To solve the arrearage problem that puzzled most of the mobile corporations, we propose an approach to forecast and evaluate the credits for mobile clients, devising a method that is of the coalescence of genetic algorithm and multidimensional distinguishing model. In the end of this paper, a result of a testing application in Zhuhai Branch, GMCC was provided. The precision of the forecasting and evaluation of the client’s credit is near 90%. This study is very significant to the mobile communication corporation at all levels. The popularization of the techniques and the result would produce great benefits of both society and economy.

A Distinguishing Method and Distribution Characteristics of Fog and Haze Days in Fuzhou

For data of atmospheric composition missing, fog and haze days were distinguished based on the standard of meteorological industry Observation and Forecasting Levels of Haze （QX/T113-2010） and four user-defined standards, and using data of surface meteorological factors in Fuzhou City, China from 2005 to 2011, temporal distributions of fog and haze days were analyzed respectively to provide methods for fog and haze forecast. The results showed that there were 28.9 fog days and 89.7 haze days per year in Fuzhou. Both fog and haze days were variable, and there might be a day difference of twice to thrice among the years. They were the most in 2007, and then decreased in recent years. Both fog and haze days were more in winter and spring, accounted for 94.1% and 70.1% respectively, while in summer and autumn, they only accounted for 5.9% and 29.9% respectively. In a day, fog mainly occurred from night to early morning, while haze occurred mainly at about noon, which demonstrated that fog and haze are different synoptic phenomena. The mass concentration of PM2.5 in fog days was 34 μg/m^3, while it was 61 μg/m^3 in haze days, and in 22% of haze days it was larger than 75 μg/m3, which was above the national second-grade ambient air quality standard.

Modelling of modern automotive petrol engine performance using Support Vector Machines

Modern automotive petrol engine performance is significantly affected by effective tune-up. Current practice of engine tune-up relies on the experience of the automotive engineer, and tune-up is usually done by trial-and-error method and then the vehicle engine is run on the dynamometer to show the actual engine performance. Obviously the current practice involves a large amount of time and money, and then may even fail to tune up the engine optimally because a formal performance model of the engine has not been determined yet. With an emerging technique, Support Vector Machines (SVM), the approximate per- formance model of a petrol vehicle engine can be determined by training the sample engine performance data acquired from the dynamometer. The number of dynamometer tests for an engine tune-up can therefore be reduced because the estimated engine performance model can replace the dynamometer tests to a certain extent. In this paper, the construction, validation and accuracy of the model are discussed. The study showed that the predicted results agree well with the actual test results. To illustrate the significance of the SVM methodology, the results were also compared with that regressed using multilayer feedforward neural networks.

Effect of Petroleum Products on Soil Catalase and Dehydrogenase Activities

The effect of refined petroleum products on the activities of selected enzymes (catalase and dehydrogenase) was studied. There was a significant decrease (p kerosene > diesel > engine oil. However, a significant increase (p diesel > petrol > engine oil. On the whole the results reveal that refined petroleum products alter soil biochemistry.

Design of intelligent distinguishing system for slot machine based on PLC

Due to the emergence of a large number of counterfeit notes and incomplete coins in the slot machine of self-service bus, to improve the automization of intelligent slot machine, based on multi-sensor testing technology, using programming log- ic controller （PLC） as the core of the whole system, the PLC hardware design and software design are accomplished for the first time to detect the counterfeit notes and coins. The system was tested by many groups of experiments. The results show that the system has reliable recognition rate, good flexibility and stability, reaching the accuracy of 97%.

Lead Concentration in Hong Kong Roadside Dust after Reduction of Lead Level in Petrol

Samples of roadside dust were collected from 30 sites in Hong Kong.The total concentrations of 10 metals in the samples were analyzed,and the correlation coefficients among the metal contents and the annual average daily traffic(AADT)in 1986 were determined.Pb was found to have a significant correlation(P<0.01)with AADT.No correlation was found between Al, Ba,Cd,Cr,Cu,Fe,Mn,Ni,and Zn with respect to AADT.A general decrease in the level of Pb in roadside dust in the past few years has been observed since the reduction in the level of lead in petrol.1989 Academic Press,Inc.

Vertex-distinguishing IE-total Colorings of Cycles and Wheels

Let G be a simple graph. An IE-total coloring f of G refers to a coloring of the vertices and edges of G so that no two adjacent vertices receive the same color. Let C（u） be the set of colors of vertex u and edges incident to u under f. For an IE-total coloring f of G using k colors, if C（u）=C（v） for any two different vertices u and v of V （G）, then f is called a k-vertex-distinguishing IE-total-coloring of G, or a k-VDIET coloring of G for short. The minimum number of colors required for a VDIET coloring of G is denoted by χievt（G）, and is called the VDIET chromatic number of G. We get the VDIET chromatic numbers of cycles and wheels, and propose related conjectures in this paper.

Distinguishing the Effects of Cryosphere Change in the Background of Climate Change in China

Climate change has major impacts directly on the natural ecosystem and human society, of which the cryosphere is most easily affected be-cause of its frangibility and sensitivity. Similarly, cryosphere change has numerous impacts on the natural ecosystem and human society, which may resemble an indirect influence of climate change. These two types of impacts, in shared fields, are distinguished in space and time by effective mechanisms and processes. Climate change has positive and negative impacts on some systems, which may be adjusted by cryosphere change. These indirect and direct impacts may be distinguished, and then correct policies and measures can be made against these changes.

Vertex-distinguishing IE-total Colorings of Complete Bipartite Graphs K8,n

Let G be a simple graph. An IE-total coloring f of G is a coloring of the vertices and edges of G so that no two adjacent vertices receive the same color. For each vertex x of G, let C(x) be the set of colors of vertex x and edges incident to x under f. For an IE-total coloring f of G using k colors, if C(u) ≠ C(v) for any two different vertices u and v of G, then f is called a k-vertex-distinguishing IE-total-coloring of G or a k-VDIET coloring of G for short. The minimum number of colors required for a VDIET coloring of G is denoted by χ_(vt)^(ie) (G) and is called vertex-distinguishing IE-total chromatic number or the VDIET chromatic number of G for short. The VDIET colorings of complete bipartite graphs K_(8,n)are discussed in this paper. Particularly, the VDIET chromatic number of K_(8,n) are obtained.

On the adjacent vertex-distinguishing acyclic edge coloring of some graphs

A proper edge coloring of a graph G is called adjacent vertex-distinguishing acyclic edge coloring if there is no 2-colored cycle in G and the coloring set of edges incident with u is not equal to the coloring set of edges incident with v, where uv∈ E（G）. The adjacent vertex distinguishing acyclic edge chromatic number of G, denoted by X＇Aa（G）, is the minimal number of colors in an adjacent vertex distinguishing acyclic edge coloring of G. If a graph G has an adjacent vertex distinguishing acyclic edge coloring, then G is called adjacent vertex distinguishing acyclic. In this paper, we obtain adjacent vertex-distinguishing acyclic edge coloring of some graphs and put forward some conjectures.

ON EQUITABLE VERTEX DISTINGUISHING EDGE COLORINGS OF TREES

It has been known that determining the exact value of vertex distinguishing edge index X ＇8（G） of a graph G is difficult, even for simple classes of graphs such as paths, cycles, bipartite complete graphs, complete, graphs, and graphs with maximum degree 2. Let rid（G） denote the number of vertices of degree d in G, and let X＇es（G） be the equitable vertex distinguishing edge index of G. We show that a tree T holds nl （T） ≤ X ＇s （T） ≤ n1 （T） ＋ 1 and X＇s（T） = X＇es（T） if T satisfies one of the following conditions （i） n2（T） ≤△（T） or （ii） there exists a constant c with respect to 0 〈 c 〈 1 such that n2（T） △ cn1（T） and ∑3 ≤d≤△（T）nd（T） ≤ （1 - c）n1（T） ＋ 1.

Vertex-distinguishing E-total Coloring of Complete Bipartite Graph K 7,n when7≤n≤95

Let G be a simple graph. A total coloring f of G is called an E-total coloring if no two adjacent vertices of G receive the same color, and no edge of G receives the same color as one of its endpoints. For an E-total coloring f of a graph G and any vertex x of G, let C（x） denote the set of colors of vertex x and of the edges incident with x, we call C（x） the color set of x. If C（u） ≠ C（v） for any two different vertices u and v of V （G）, then we say that f is a vertex-distinguishing E-total coloring of G or a VDET coloring of G for short. The minimum number of colors required for a VDET coloring of G is denoted by Хvt^e（G） and is called the VDE T chromatic number of G. The VDET coloring of complete bipartite graph K7,n （7 ≤ n ≤ 95） is discussed in this paper and the VDET chromatic number of K7,n （7 ≤ n ≤ 95） has been obtained.

Upper bounds on vertex distinguishing chromatic index of some Halin graphs

A vertex distinguishing edge coloring of a graph G is a proper edge coloring of G such that any pair of vertices has the distinct sets of colors. The minimum number of colors required for a vertex distinguishing edge coloring of a graph C is denoted by Xs＇8（G）. In this paper, we obtained upper bounds on the vertex distinguishing chromatic index of 3-regular Halin graphs and Halin graphs with △（G） ≥ 4, respectively.

Vertex-distinguishing VE-total Colorings of Cycles and Complete Graphs

Let G be a simple graph of order at least 2.A VE-total-coloring using k colors of a graph G is a mapping f from V (G) E(G) into {1,2,···,k} such that no edge receives the same color as one of its endpoints.Let C(u)={f(u)} {f(uv) | uv ∈ E(G)} be the color-set of u.If C(u)=C(v) for any two vertices u and v of V (G),then f is called a k-vertex-distinguishing VE-total coloring of G or a k-VDVET coloring of G for short.The minimum number of colors required for a VDVET coloring of G is denoted by χ ve vt (G) and it is called the VDVET chromatic number of G.In this paper we get cycle C n,path P n and complete graph K n of their VDVET chromatic numbers and propose a related conjecture.

Adjacent Vertex Distinguishing I-total Coloring of Outerplanar Graphs

Let G be a simple graph with no isolated edge. An Ⅰ-total coloring of a graph G is a mapping φ : V(G) ∪ E(G) → {1, 2, · · ·, k} such that no adjacent vertices receive the same color and no adjacent edges receive the same color. An Ⅰ-total coloring of a graph G is said to be adjacent vertex distinguishing if for any pair of adjacent vertices u and v of G, we have C_φ(u) = C_φ(v), where C_φ(u) denotes the set of colors of u and its incident edges. The minimum number of colors required for an adjacent vertex distinguishing Ⅰ-total coloring of G is called the adjacent vertex distinguishing Ⅰ-total chromatic number, denoted by χ_at^i(G).In this paper, we characterize the adjacent vertex distinguishing Ⅰ-total chromatic number of outerplanar graphs.

Finite Element Analysis of In-Plane Displacements and Von-Mises Stresses in Ellipsoidal and Circular Cylinderical Petroleum Tankers

Road tankers are the most used means of transporting petroleum product to end users due to its cost effectiveness and energy-efficiency. The cylindrical tank has been well designed for by ASME VIII divisions 1 and 2 using analytical equations. Petrol tankers are not circular but elliptical probably for stability during transportation. This paper has used the finite element method to investigate in-plane displacements and Von-Mises stresses in both circular and elliptical cylindrical tanks under full loading. An elliptical OANDO? tanker of 66.78 m3volume and shell thickness of0.2 mmand an equivalent volume circular cylindrical tank was used for the simulation. MATLAB? was used to generate geometrical mesh model of the petroleum tankers, extract element coordinates and conduct the finite element analysis. Plane strain condition was used in analyzing a section of the petroleum tanker. It was observed that an equivalent volume circular cylindrical tank was under a higher internal pressure (16,858 N/m2) compared to the elliptical cylinder (14,480 N/m2). Von-Mises stress and in-plane displacements showed direct linear relationships with internal fluid pressure. Von-Mises stress in the elliptical tank was found to be lower (5.7 × 106 N/m2) than for the circular tank (8 × 106 N/m2). In plane displacements was zero in the longitudinal direction for both tanks and of the order of 10-4 mm in the y-direction for both tanks with the circular larger by about 2.5 × 10-3 cm. So in addition to tank stability on the lorry, the Von-Mises stresses were lower as well for the elliptical tank. It was also observed that Von-Mises stresses were far below the yield stress of the steel plate. However, the effect of weldment area on lowering of yield stress was not studied. Stress values were validated using analytical method and found to be insignificantly different (P > 0.05).