P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phas...P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phases remains a necessity.Herein,we design a P2/O3-type Na_(0.76)Ni_(0.31)Zn_(0.07)Mn_(0.50)Ti_(0.12)0_(2)(NNZMT)with high chemical/electrochemical stability by enhancing the coupling between the two phases.For the first time,a unique Na*extraction is observed from a Na-rich O3 phase by a Na-poor P2 phase and systematically investigated.This process is facilitated by Zn^(2+)/Ti^(4+)dual doping and calcination condition regulation,allowing a higher Na*content in the P2 phase with larger Na^(+)transport channels and enhancing Na transport kinetics.Because of reduced Na^(+)in the O3 phase,which increases the difficulty of H^(+)/Na^(+) exchange,the hydrostability of the O3 phase in NNZMT is considerably improved.Furthermore,Zn^(2+)/Ti^(4+)presence in NNZMT synergistically regulates oxygen redox chemistry,which effectively suppresses O_(2)/CO_(2) gas release and electrolyte decomposition,and completely inhibits phase transitions above 4.0 V.As a result,NNZMT achieves a high discharge capacity of 144.8 mA h g^(-1) with a median voltage of 3.42 V at 20 mA g^(-1) and exhibits excellent cycling performance with a capacity retention of 77.3% for 1000 cycles at 2000 mA g^(-1).This study provides an effective strategy and new insights into the design of high-performance layered-oxide cathode materials with enhanced structure/interface stability forSIBs.展开更多
The mechanical characteristics of crystalline rocks are affected by the heterogeneity of the spatial distribution of minerals.In this paper,a novel three-dimensional(3D)grain-based model(GBM)based on particle flow cod...The mechanical characteristics of crystalline rocks are affected by the heterogeneity of the spatial distribution of minerals.In this paper,a novel three-dimensional(3D)grain-based model(GBM)based on particle flow code(PFC),i.e.PFC3D-GBM,is proposed.This model can accomplish the grouping of mineral grains at the 3D scale and then filling them.Then,the effect of the position distribution,geometric size,and volume composite of mineral grains on the cracking behaviour and macroscopic properties of granite are examined by conducting Brazilian splitting tests.The numerical results show that when an external load is applied to a sample,force chains will form around each contact,and the orientation distribution of the force chains is uniform,which is independent of the external load level.Furthermore,the number of high-strength force chains is proportional to the external load level,and the main orientation distribution is consistent with the external loading direction.The main orientation of the cracks is vertical to that of the high-strength force chains.The geometric size of the mineral grains controls the mechanical behaviours.As the average grain size increases,the number of transgranular contacts with higher bonding strength in the region connecting both loading points increases.The number of high-strength force chains increases,leading to an increase in the stress concentration value required for the macroscopic failure of the sample.Due to the highest bonding strength,the generation of transgranular cracks in quartz requires a higher concentrated stress value.With increasing volume composition of quartz,the number of transgranular cracks in quartz distributed in the region connecting both loading points increases,which requires many high-strength force chains.The load level rises,leading to an increase in the tensile strength of the numerical sample.展开更多
目的为了提升生成对抗网络汉字风格迁移的图像生成质量,实现汉字智能生成在字库产业中的实际应用,提出了一种基于直观汉字构形学的条件生成对抗网络字体生成优化方法(Optimizationof Conditional Fonts Generation with Chinese Charact...目的为了提升生成对抗网络汉字风格迁移的图像生成质量,实现汉字智能生成在字库产业中的实际应用,提出了一种基于直观汉字构形学的条件生成对抗网络字体生成优化方法(Optimizationof Conditional Fonts Generation with Chinese Character Configuration GANs,C^(3)-GAN)。方法建构了直观汉字构形模组(C^(3)Module),该模组包含了利于条件生成对抗网络进行汉字构形语义特征学习的全特征汉字字符集。C^(3)-GAN在条件生成对抗网络模型下进行字体生成训练,降低了必要训练样本数量,实现对字体生成效果的优化。结果使用C^(3)-GAN生成汉字图像的清晰度更高、字形更准确。在图像相似性定量评估中,使用C^(3)-GAN的实验组相比于其他模型,获得了更高的相似值和更小的误差值。结论使用C^(3)-GAN可以降低必要训练样本数量、提升汉字图像质量。在实际项目中具有一定的应用性和可操作性。展开更多
Coordinated contraction of skeletal muscles relies on selective connections between the muscles and multiple classes of the spinal motoneuro ns.Howeve r,current research on the spatial location of the spinal motoneuro...Coordinated contraction of skeletal muscles relies on selective connections between the muscles and multiple classes of the spinal motoneuro ns.Howeve r,current research on the spatial location of the spinal motoneurons innervating differe nt muscles is limited.In this study,we investigated the spatial distribution and relative position of different motoneurons that control the deep muscles of the mouse hindlimbs,which were innervated by the obturator nerve,femoral nerve,inferior gluteal nerve,deep pe roneal nerve,and tibial nerve.Locations were visualized by combining a multiplex retrograde tracking technique compatible with three-dimensional imaging of solvent-cleared o rgans(3DISCO)and 3-D imaging technology based on lightsheet fluorescence microscopy(LSFM).Additionally,we propose the hypothesis that"messenger zones"exist as interlaced areas between the motoneuron pools that dominate the synergistic or antagonist muscle groups.We hypothesize that these interlaced neurons may participate in muscle coordination as messenger neurons.Analysis revealed the precise mutual positional relationships among the many motoneurons that innervate different deep muscles of the mouse.Not only do these findings update and supplement our knowledge regarding the overall spatial layout of spinal motoneurons that control mouse limb muscles,but they also provide insights into the mechanisms through which muscle activity is coordinated and the architecture of motor circuits.展开更多
The Y-cut X propagating LiNbO3 crystals were implanted with a fluence of 5×10^13-5×10^14 C ions/cm^2 at energies from 100 to 200keV,respectively,The implanted LiNbO3 Crystals were analyzed using Rutherford b...The Y-cut X propagating LiNbO3 crystals were implanted with a fluence of 5×10^13-5×10^14 C ions/cm^2 at energies from 100 to 200keV,respectively,The implanted LiNbO3 Crystals were analyzed using Rutherford backscattering/Channeling technique,The result shows that:(1)the damage rages are systematically higher than the projected ranges calculated from TRIM(Transport of Ions in Matter) simulation,and the damage widths are significantly broader than TRIM values;(2) the total disorder induced by carbon ion in LiNbO3 is not linearly increased with the implanted fluence.展开更多
基金supported by the National Natural Science Foundation of China (22169002)the Chongzuo Key Research and Development Program of China (20220603)the Counterpart Aid Project for Discipline Construction from Guangxi University(2023M02)
文摘P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phases remains a necessity.Herein,we design a P2/O3-type Na_(0.76)Ni_(0.31)Zn_(0.07)Mn_(0.50)Ti_(0.12)0_(2)(NNZMT)with high chemical/electrochemical stability by enhancing the coupling between the two phases.For the first time,a unique Na*extraction is observed from a Na-rich O3 phase by a Na-poor P2 phase and systematically investigated.This process is facilitated by Zn^(2+)/Ti^(4+)dual doping and calcination condition regulation,allowing a higher Na*content in the P2 phase with larger Na^(+)transport channels and enhancing Na transport kinetics.Because of reduced Na^(+)in the O3 phase,which increases the difficulty of H^(+)/Na^(+) exchange,the hydrostability of the O3 phase in NNZMT is considerably improved.Furthermore,Zn^(2+)/Ti^(4+)presence in NNZMT synergistically regulates oxygen redox chemistry,which effectively suppresses O_(2)/CO_(2) gas release and electrolyte decomposition,and completely inhibits phase transitions above 4.0 V.As a result,NNZMT achieves a high discharge capacity of 144.8 mA h g^(-1) with a median voltage of 3.42 V at 20 mA g^(-1) and exhibits excellent cycling performance with a capacity retention of 77.3% for 1000 cycles at 2000 mA g^(-1).This study provides an effective strategy and new insights into the design of high-performance layered-oxide cathode materials with enhanced structure/interface stability forSIBs.
基金the financial support of the National Natural Science Foundation of China(Grant No.52179118)the Graduate Innovation Program of China University of Mining and Technology(Grant No.2022WLKXJ032)the Postgraduate Research and Practice Innovation Program of Jiangsu Province,China(Grant No.KYCX22_2581).
文摘The mechanical characteristics of crystalline rocks are affected by the heterogeneity of the spatial distribution of minerals.In this paper,a novel three-dimensional(3D)grain-based model(GBM)based on particle flow code(PFC),i.e.PFC3D-GBM,is proposed.This model can accomplish the grouping of mineral grains at the 3D scale and then filling them.Then,the effect of the position distribution,geometric size,and volume composite of mineral grains on the cracking behaviour and macroscopic properties of granite are examined by conducting Brazilian splitting tests.The numerical results show that when an external load is applied to a sample,force chains will form around each contact,and the orientation distribution of the force chains is uniform,which is independent of the external load level.Furthermore,the number of high-strength force chains is proportional to the external load level,and the main orientation distribution is consistent with the external loading direction.The main orientation of the cracks is vertical to that of the high-strength force chains.The geometric size of the mineral grains controls the mechanical behaviours.As the average grain size increases,the number of transgranular contacts with higher bonding strength in the region connecting both loading points increases.The number of high-strength force chains increases,leading to an increase in the stress concentration value required for the macroscopic failure of the sample.Due to the highest bonding strength,the generation of transgranular cracks in quartz requires a higher concentrated stress value.With increasing volume composition of quartz,the number of transgranular cracks in quartz distributed in the region connecting both loading points increases,which requires many high-strength force chains.The load level rises,leading to an increase in the tensile strength of the numerical sample.
文摘目的为了提升生成对抗网络汉字风格迁移的图像生成质量,实现汉字智能生成在字库产业中的实际应用,提出了一种基于直观汉字构形学的条件生成对抗网络字体生成优化方法(Optimizationof Conditional Fonts Generation with Chinese Character Configuration GANs,C^(3)-GAN)。方法建构了直观汉字构形模组(C^(3)Module),该模组包含了利于条件生成对抗网络进行汉字构形语义特征学习的全特征汉字字符集。C^(3)-GAN在条件生成对抗网络模型下进行字体生成训练,降低了必要训练样本数量,实现对字体生成效果的优化。结果使用C^(3)-GAN生成汉字图像的清晰度更高、字形更准确。在图像相似性定量评估中,使用C^(3)-GAN的实验组相比于其他模型,获得了更高的相似值和更小的误差值。结论使用C^(3)-GAN可以降低必要训练样本数量、提升汉字图像质量。在实际项目中具有一定的应用性和可操作性。
基金supported by the Chinese National General Program of the National Natural Science Foundation of China,No.82072162(to XY)。
文摘Coordinated contraction of skeletal muscles relies on selective connections between the muscles and multiple classes of the spinal motoneuro ns.Howeve r,current research on the spatial location of the spinal motoneurons innervating differe nt muscles is limited.In this study,we investigated the spatial distribution and relative position of different motoneurons that control the deep muscles of the mouse hindlimbs,which were innervated by the obturator nerve,femoral nerve,inferior gluteal nerve,deep pe roneal nerve,and tibial nerve.Locations were visualized by combining a multiplex retrograde tracking technique compatible with three-dimensional imaging of solvent-cleared o rgans(3DISCO)and 3-D imaging technology based on lightsheet fluorescence microscopy(LSFM).Additionally,we propose the hypothesis that"messenger zones"exist as interlaced areas between the motoneuron pools that dominate the synergistic or antagonist muscle groups.We hypothesize that these interlaced neurons may participate in muscle coordination as messenger neurons.Analysis revealed the precise mutual positional relationships among the many motoneurons that innervate different deep muscles of the mouse.Not only do these findings update and supplement our knowledge regarding the overall spatial layout of spinal motoneurons that control mouse limb muscles,but they also provide insights into the mechanisms through which muscle activity is coordinated and the architecture of motor circuits.
文摘The Y-cut X propagating LiNbO3 crystals were implanted with a fluence of 5×10^13-5×10^14 C ions/cm^2 at energies from 100 to 200keV,respectively,The implanted LiNbO3 Crystals were analyzed using Rutherford backscattering/Channeling technique,The result shows that:(1)the damage rages are systematically higher than the projected ranges calculated from TRIM(Transport of Ions in Matter) simulation,and the damage widths are significantly broader than TRIM values;(2) the total disorder induced by carbon ion in LiNbO3 is not linearly increased with the implanted fluence.
