1 Introduction In recent years porous carbons have been widely used in many fields such as energy storage(Mc Creery,2008;Liu et al,2009;Ho et al,2014;Yang et al,2015),adsorption,wastewater treatment,air purification
Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surf...Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.展开更多
Mercaptopropionic acid monolayer protected gold nanoclusters (MPA MPCs) were synthesized and characterized by transmission electron microscopy, UV Vis spectroscopy, X ray photoelectron spectroscopy and Fourier tran...Mercaptopropionic acid monolayer protected gold nanoclusters (MPA MPCs) were synthesized and characterized by transmission electron microscopy, UV Vis spectroscopy, X ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The exact value of quantized double layer capacitance of MPCs in aqueous media was obtained by differential pulse voltammograms.展开更多
基金financial support from the National Natural Science Foundation of China (51274015)National Program on Key Basic Research Project (973 Program) (2014CB846000)Test Fund of Peking University
文摘1 Introduction In recent years porous carbons have been widely used in many fields such as energy storage(Mc Creery,2008;Liu et al,2009;Ho et al,2014;Yang et al,2015),adsorption,wastewater treatment,air purification
文摘Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.
文摘Mercaptopropionic acid monolayer protected gold nanoclusters (MPA MPCs) were synthesized and characterized by transmission electron microscopy, UV Vis spectroscopy, X ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The exact value of quantized double layer capacitance of MPCs in aqueous media was obtained by differential pulse voltammograms.
