Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Rational architecture design of yolk/double-shells Si-based anode material with double buffering carbon layers for high performance lithium-ion battery

Among the many strategies to fabricate the silicon/carbon composite,yolk/double-shells structure can be regarded as an effective strategy to overcome the intrinsic defects of Si-based anode materials for Li-ion batteries(LIBs).Hereon,a facile and inexpensive technology to prepare silicon/carbon composite with yolk/double-shells structure is proposed,in which the double buffering carbon shells are fabricated.The silicon/carbon nanoparticles with core-shell structure are encapsulated by SiO_(2)and external carbon layer,and it shows the yolk/double-shells structure via etching the SiO_(2)sacrificial layer.The multiply shells structure not only significantly improves the electrical conductivity of composite,but also effectively prevents the exposure of Si particles from the electrolyte composition.Meanwhile,the yolk/double-shells structure can provide enough space to accommodate the volume change of the electrode during charge/discharge process and avoid the pulverization of Si particles.Moreover,the as-prepared YDS-Si/C shows excellent performance as anode of LIBs,the reversible capacity is as high as 1066 mA h g^(-1) at the current density of 0.5 A g^(-1) after 200 cycles.At the same time,the YDS-Si/C has high capacity retention and good cyclic stability.Therefore,the unique architecture design of yolk/double-shells for Si/C composite provides an instructive exploration for the development of next generation anode materials of LIBs with high electrochemical performances and structural stability.

Double设计在对称化L_2-偏差下的均匀性

二水平部分因子设计在工农业生产、科学实验等领域得到广泛应用,因此有关二水平部分因子设计的研究一直是热点问题.最近,一种称为doubling的方法被用来构造二水平部分因子设计,特别是在构造分辨度为Ⅳ的设计时,这种方法是非常简单但很实用的方法,本文从均匀性的角度来研究double设计,进一步讨论doubling方法的实用性,利用对称化L_2-偏差作为均匀性的测度,发现double设计D(X)的均匀性与初始设计X的均匀性有着密切的联系,给出了double设计在对称化L_2-偏差下的下界.

Double设计在对称化L_2-偏差下两个下界的比较

从列平衡的角度出发,将设计的中心化L2-偏差、对称化L2-偏差、可卷L2-偏差分别用二次型和均衡模式表示,可分别得到两个下界,它们都适合用来评价正交设计的均匀性。以double设计的对称化L2-偏差为例,证明了这两种方法算出的下界是相等的。

Double设计在对称化L_2-偏差下的广义字长型

在工农业生产、科学实验等领域都广泛应用到二水平部分因子设计.最近,在构造二水平部分因子设计时一种称为doubling的方法被使用.特别是在构造分辨度为IV的设计时,doubling是非常简单但很实用的方法.本文利用对称化L2-偏差作为均匀性的测度,得到了double设计D(X)的对称化L2-偏差值与初始设计X的广义字长型之间的关系.利用上述关系,我们断定对于具有广义较小低阶混杂的初始设计X,其对应的double设计D(X)也应该具有较小的对称化L2-偏差值,也就是说,D(X)应该具有较好的均匀性.

Increase of brightness and transmission efficiency in fiat panel display through serial synchronous scanning mode with double buffers

This paper presents a serial synchronous scanning mode in fiat panel display （FPD） by adding a latch buffer between the serializer and the driving buffer. Comparing with conventional techniques, the proposed structure can efficiently reduce the brightness loss and improve the transmission performance. Theoretical analysis and experimental results show that the ratio between the lightest weight display time and the relative transmission time is a tradeoff between brightness loss and transmission efficiency.

Double perovskite oxides Sr_2Mg_(1-x)Fe_xMoO(6-δ) for catalytic oxidation of methane

The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.

Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment

The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.

Desorption of Cl^(-) from Mg-Al layered double hydroxide intercalated with Cl^(-) using CO_(2) gas and water

Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).

Promoting surface reconstruction of NiFe layered double hydroxides via intercalating[Cr(C_(2)O_(4))_(3)]^(3-)for enhanced oxygen evolution

Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.

Study on the Technique of Double-faced Embroidery on Chinese Palace Fans

Double - faced iso - object embroidery is carried out byusing the uneven intercalated stitch crafts of the parallel- lines stitch as a main body, being accompanied by oth-er stitch crafts and miscellaneous stitches, done on thesame textile material. This paper deals with the flower -bird double - faced embroidery fan of the Qing Dynasty,from pattern design, stitching formation and techniqueof color arrangement, describes the possible way of mak-ing double - faced embroidery with iso - object effectboth in the front and in the back.

New Pyrometer with Double Y-type Optical Fibers

Abstract: A new pyrometer, which can solve the affection of emissivity change in temperature measuring, has been developed by double Y - type optical fibers. The mathematical model of the new pyrometer is presented and the errors of the new pyrometer are analyzed.

Optical, Mechanical and Laser-induced Damage Threshold Properties of 1064 nm, 532 nm Frequency-doubled Antireflection Coating for LBO

1 064 nm, 532 nm frequency-doubled antireflection （AR） coatings with buffer layer of SiO2 between the coating and the substrate were fabricated by the electron beam evaporation technology on the substrate of lithium triborate （LiB3O5 or LBO） crystals. The residual reflectance of the sample is 0.07% and 0.11% at 1 064 nm and 532 nm, respectively. The adhesion and the laser-induced damage threshold （LIDT） of the sample are greater than 200 mN and 18.6 J/cm2. The strengthening mechanism of adhesion and LIDT of the buffer layer of SiO2 were discussed by considering full plastic indentation and shear theory, and spallation of a plated film induced by thermal shock stress, respectively.

Constraints on Estimation of Radius of Double Pulsar PSR J0737-3039A and Its Neutron Star Nuclear Matter Composition

The aspect of formation and evolution of the recycled pulsar（PSR J0737-3039 A/B） is investigated, taking into account the contributions of accretion rate, radius and spin-evolution diagram（- diagram） in the double pulsar system. Accepting the spin-down age as a rough estimate（or often an upper limit） of the true age of the neutron star, we also impose the restrictions on the radius of this system. We calculate the radius of the recycled pulsar PSR J0737-3039 A ranges approximately from 8.14 to 25.74 km, and the composition of its neutron star nuclear matters is discussed in the mass-radius diagram.

Double设计的几个结果

讨论了Double设计在对称化L2-偏差下的均匀性,给出了Double设计为均匀设计的充要条件,同时得到了Double设计的对称化L2-偏差的下界,来评价Double设计的均匀性,最后通过一个例子来验证理论结果。

基于强化学习的高层建筑施工进度-成本优化研究

为解决高层建筑施工进度-成本目标智能优化管控问题,提出了一种基于强化学习算法并考虑工序工期不确定性的高层建筑施工进度-成本综合优化算法框架方法,该方法融合PERT原理引入不确定性,基于DoubleDQN算法架构开发了进度-成本优化决策模型。并在某高层建筑工程案例项目中进行了验证和应用,经过模型优化后,案例项目工序施工总工期、总成本优化提升明显,实现了项目的降本增效,有助于施工过程科学规划决策与风险管理。这种基于强化学习所开发的优化算法框架克服了传统方法的局限性,有效提升了高层建筑施工管控的智能化水平,为科学施工管理赋能。

A New Inversion Method of Sedimentary Strata For Deriving Double Parameters and Its Applications

The inverse problem of wave equation is the importance of study not only in seismic prospecting but also in applied mathematics. With the development of the research, the inverse methods of 1 - D wave equations have been trending towards the multiple parameters inversion . We have obtained an inverse method with double -parameter, in which medium density and wave velocity can be derived simultaneously. In this paper, to increase the inverse accuracy, the method is improved as follows. Firstly, the formula in which the Green Function is omitted are derived and used. Secondly, the regularizing method is reasonable used by choosing the stable function. With the new method, we may derive elastic parameter and medium density or medium density and wave velocity. Thus, lithology parameters for seismic prospecting may be obtained.After comparing the derived values from the new method with that from previous method, we obtain the new method through which substantially improve the derived accuracy . The new method has been applied to real depths inversion for sedimentary strata and volcanic rock strata in Chaoyanggou Terrace of Songliao Basin in eastern China. According to the inverse results,the gas - bearing beds are determlned.

Dual-function protective layer for highly reversible Zn anode

The thermodynamic instability of zinc anodes in aqueous electrolytes leads to issues such as corrosion,hydrogen evolution reactions(HER), and dendrite growth, severely hindering the practical application of zinc-based aqueous energy storage devices. To address these challenges, this work proposes a dualfunction zinc anode protective layer, composed of Zn-Al-In layered double oxides(ILDO) by rationally designing Zn-Al layered double hydroxides(Zn-Al LDHs) for the first time. Differing from previous works on the LDHs coatings, firstly, the ILDO layer accelerates zinc-ion desolvation and also captures and anchors SO_(4)^(2-). Secondly, the in-situ formation of the Zn-In alloy phase effectively lowers the nucleation energy barrier, thereby regulating zinc nucleation. Consequently, the zinc anode with the ILDO protective layer demonstrates long-term stability exceeding 1900 h and low voltage hysteresis of 7.5 m V at 0.5 m A cm^(-2) and 0.5 m A h cm^(-2). Additionally, it significantly enhances the rate capability and cycling performance of Zn@ILDO//MnO_(2) full batteries and Zn@ILDO//activated carbon zinc-ion hybrid capacitors.This simple and effective dual-function protective layer strategy offers a promising approach for achieving high-performance zinc-ion batteries.

Growth of High-Quality InP-on-GaAs Quasi-Substrates Using Double Low-Temperature Buffers and Strained Layer Surperlattices by MOCVD

We investigate the growth of InP-on-GaAs combined with the advantages of double low-temperature （LT） buffers and strained layer surperlattices （SLSs）. It is found that LT-InP/LT-GaAs double LT buffers are more effective for strain accommodation than a LT-InP single buffer in InP-on-GaAs. On the other hand, there is an optimal thickness for LT-GaAs for a given thickness of the LT-InP layer,at which the double LT buffers can reach the best state for strain ad- justment. Furthermore,the position of insertion of SLSs should be carefully designed because the distance above the InP/ buffer interface plays an important role in threading dislocation interactions for dislocation reduction. As a result, the density of threading dislocations in the InP epilayer is markedly reduced. X-ray diffraction measurements show that the full width at half maximum of the ω/2θ rocking curve for the 2μm-thick InP epilayer is less than 200.

一种使用BU-65170内部RAM实现双缓冲的星载1553B总线数据传输技术

星载1553B总线数据传输通常需要使用外部RAM缓存待发送数据,使用外部RAM带来系统功耗和面积的增加,也增加了系统的复杂性。提出了一种使用1553B芯片内部RAM实现双缓冲的数据传输方案。此方案采用FPGA作为主控芯片,BU-65170作为1553B总线控制芯片,利用BU-65170内部RAM的两个地址空间段构成双缓冲,避免使用外部RAM,简化了系统硬件设计,提高了系统的可靠性。对双缓冲区采取交替更新访问方式,实现了1553B总线数据的可靠传输。此方案已成功应用于星载GNOS掩星探测仪。