Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Promoting surface reconstruction of NiFe layered double hydroxides via intercalating[Cr(C_(2)O_(4))_(3)]^(3-)for enhanced oxygen evolution

Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.

Study on the Technique of Double-faced Embroidery on Chinese Palace Fans

Double - faced iso - object embroidery is carried out byusing the uneven intercalated stitch crafts of the parallel- lines stitch as a main body, being accompanied by oth-er stitch crafts and miscellaneous stitches, done on thesame textile material. This paper deals with the flower -bird double - faced embroidery fan of the Qing Dynasty,from pattern design, stitching formation and techniqueof color arrangement, describes the possible way of mak-ing double - faced embroidery with iso - object effectboth in the front and in the back.

Double设计在对称化L_2-偏差下的均匀性

二水平部分因子设计在工农业生产、科学实验等领域得到广泛应用,因此有关二水平部分因子设计的研究一直是热点问题.最近,一种称为doubling的方法被用来构造二水平部分因子设计,特别是在构造分辨度为Ⅳ的设计时,这种方法是非常简单但很实用的方法,本文从均匀性的角度来研究double设计,进一步讨论doubling方法的实用性,利用对称化L_2-偏差作为均匀性的测度,发现double设计D(X)的均匀性与初始设计X的均匀性有着密切的联系,给出了double设计在对称化L_2-偏差下的下界.

Double设计在对称化L_2-偏差下两个下界的比较

从列平衡的角度出发,将设计的中心化L2-偏差、对称化L2-偏差、可卷L2-偏差分别用二次型和均衡模式表示,可分别得到两个下界,它们都适合用来评价正交设计的均匀性。以double设计的对称化L2-偏差为例,证明了这两种方法算出的下界是相等的。

Double设计在对称化L_2-偏差下的广义字长型

在工农业生产、科学实验等领域都广泛应用到二水平部分因子设计.最近,在构造二水平部分因子设计时一种称为doubling的方法被使用.特别是在构造分辨度为IV的设计时,doubling是非常简单但很实用的方法.本文利用对称化L2-偏差作为均匀性的测度,得到了double设计D(X)的对称化L2-偏差值与初始设计X的广义字长型之间的关系.利用上述关系,我们断定对于具有广义较小低阶混杂的初始设计X,其对应的double设计D(X)也应该具有较小的对称化L2-偏差值,也就是说,D(X)应该具有较好的均匀性.

Double perovskite oxides Sr_2Mg_(1-x)Fe_xMoO(6-δ) for catalytic oxidation of methane

The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.

Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment

The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.

The adjusting mining technology of combining fully mechanized with individual prop,rotating,hilt,irregular form,and double unit face on thin coal seam of Tianchen Mine

Analyzed the situations and characteristics of thin coal seam mining and its mining technologies,and introduced the mining innovation technology used by Tianchen Coal Mine of Zhaozhuang Coal Company of China.This innovation technology combined the fully mechanized mining with individual props,and the working face of mining is over length,irregular form and double units.The rotational adjusting mining technology on thin coal seam is also practiced in this new mining technology.The detail technologies,such as outlays of working face and ways,mining methods,equipments of cutting,transporting and sporting,have been introduced.So that,using the synthetic and creative mining tech- nologies,Tianchen Coal Mine solves the mining problems of thin coal seam successfully.

Desorption of Cl^(-) from Mg-Al layered double hydroxide intercalated with Cl^(-) using CO_(2) gas and water

Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).

Simulation Analysis on Quasistatic Characteristics of Multistage Face Gears with Double Crown Surfac

The multistage face gears are the core component of the planetary gear train,which is symmetrically meshed by multiple single-stage face gear and multiple cylindrical gears.However,it is difficult to synchronize the contact between face gears and cylindrical gear due to the tooth number differences.Thus,the interference problems between two stages and big stress concentration are obvious.The crown surface configuration technology and structure design were introduced to optimize the meshing condition.To improve the double crown design feasibility and meshing stability,it is necessary to establish a reasonable multistage face gears pair simulation model to evaluate various influence factors on the contact condition and quasi-static characteristics of multistage face gears structure.The relevant scatter plots are fitted by comparing the contact results with different crown quantities and friction coefficients to intuitively obtain the variation regularity of maximum deformation,maximum strain,maximum stress and maximum strain energy.The natural frequency and mode coefficient are also determined by modal analysis under these two conditions.All the above mentioned studies verified the contact conjugate properties of double crown surface configuration were suitable.The results can provide a foundation for structure optimization and transmission reliability of multistage face gears.

New Pyrometer with Double Y-type Optical Fibers

Abstract: A new pyrometer, which can solve the affection of emissivity change in temperature measuring, has been developed by double Y - type optical fibers. The mathematical model of the new pyrometer is presented and the errors of the new pyrometer are analyzed.

Constraints on Estimation of Radius of Double Pulsar PSR J0737-3039A and Its Neutron Star Nuclear Matter Composition

The aspect of formation and evolution of the recycled pulsar（PSR J0737-3039 A/B） is investigated, taking into account the contributions of accretion rate, radius and spin-evolution diagram（- diagram） in the double pulsar system. Accepting the spin-down age as a rough estimate（or often an upper limit） of the true age of the neutron star, we also impose the restrictions on the radius of this system. We calculate the radius of the recycled pulsar PSR J0737-3039 A ranges approximately from 8.14 to 25.74 km, and the composition of its neutron star nuclear matters is discussed in the mass-radius diagram.

Double设计的几个结果

讨论了Double设计在对称化L2-偏差下的均匀性,给出了Double设计为均匀设计的充要条件,同时得到了Double设计的对称化L2-偏差的下界,来评价Double设计的均匀性,最后通过一个例子来验证理论结果。

基于强化学习的高层建筑施工进度-成本优化研究

为解决高层建筑施工进度-成本目标智能优化管控问题,提出了一种基于强化学习算法并考虑工序工期不确定性的高层建筑施工进度-成本综合优化算法框架方法,该方法融合PERT原理引入不确定性,基于DoubleDQN算法架构开发了进度-成本优化决策模型。并在某高层建筑工程案例项目中进行了验证和应用,经过模型优化后,案例项目工序施工总工期、总成本优化提升明显,实现了项目的降本增效,有助于施工过程科学规划决策与风险管理。这种基于强化学习所开发的优化算法框架克服了传统方法的局限性,有效提升了高层建筑施工管控的智能化水平,为科学施工管理赋能。

复杂光照与背景下的Double肤色模型人脸检测算法

针对复杂光照与背景的图像中难以准确检测出人脸的情况,提出一种复杂光照与背景下的Double肤色模型人脸检测算法。采用一种改进的光照补偿方法对图像进行光照预处理,融合改进的高斯肤色模型和非线性肤色模型,通过对融合算法进行收敛性验证与实例检验,证明了其可行性。实验结果表明,该算法能够对复杂背景及光照下多人脸、多姿态、遮挡、动态视频图像等情况的人脸检测有较好的检测效果。

A New Inversion Method of Sedimentary Strata For Deriving Double Parameters and Its Applications

The inverse problem of wave equation is the importance of study not only in seismic prospecting but also in applied mathematics. With the development of the research, the inverse methods of 1 - D wave equations have been trending towards the multiple parameters inversion . We have obtained an inverse method with double -parameter, in which medium density and wave velocity can be derived simultaneously. In this paper, to increase the inverse accuracy, the method is improved as follows. Firstly, the formula in which the Green Function is omitted are derived and used. Secondly, the regularizing method is reasonable used by choosing the stable function. With the new method, we may derive elastic parameter and medium density or medium density and wave velocity. Thus, lithology parameters for seismic prospecting may be obtained.After comparing the derived values from the new method with that from previous method, we obtain the new method through which substantially improve the derived accuracy . The new method has been applied to real depths inversion for sedimentary strata and volcanic rock strata in Chaoyanggou Terrace of Songliao Basin in eastern China. According to the inverse results,the gas - bearing beds are determlned.

Dislocation stability in three-phase nanocomposites with imperfect interface

Interface imperfection can significantly affect the mechanical properties and failure mechanisms as well as the strength and toughness of nanocomposites. The elastic behavior of a screw dislocation in nanoscale coating with imperfect interface is studied in the three-phase composite cylinder model. The interface between inner nanoin- homogeneity and intermediate coating is assumed as perfectly bonded. The bonding between intermediate coating and outer matrix is considered to be imperfect with the assumption that interface imperfection is uniform, and a linear spring model is adopted to describe the weakness of imperfect interface. The explicit expression for image force acting on dislocation is obtained by means of a complex variable method. The analytic results indicate that inner interface effect and outer interface imperfection, simultaneously taken into account, would influence greatly image force, equilibrium position and stability of dislocation, and various critical parameters that would change dislocation stability. The weaker interface is a very strong trap for glide dislocation and, thus, a more effective barrier for slip transmission.

皮革产品碳足迹核算--以皮毛一体鞋面革为例

皮革行业是我国出口创汇的重要产业。国际上以产品碳足迹为供应链核心的形势越来越紧迫,行业应当尽快对皮革产品开展碳足迹核算的相关工作。本文以辛集市梅花皮业有限公司的经典产品——皮毛一体鞋面革为研究对象,通过实地调研与数据采集,在轻工(皮革)行业用化学品碳排放因子数据集的支持下,建模核算得到皮革产品碳足迹值。本文建立的碳足迹核算方法可实现对皮革产品制造过程各工序碳足迹的核算,为绿色制革提供可靠的数据支撑,助力行业绿色低碳转型与高质量发展。

径向双端面机械密封端面热-力耦合变形研究

针对鱼雷涡轮机径向双端面机械密封在高速、高温、高压等复杂极端工况下,内层密封发生泄漏的问题,基于热流固耦合仿真方法研究了其端面变形情况,结果表明,内、外层密封端面均产生沿半径增长方向逐渐变大的端面间隙,内层密封端面间隙大于外层,最大为0.04 mm。针对内层机械密封,比较动、静环端面单一热、力、热力耦合变形结果,并研究冷却水压力、密封端面宽度对其端面温度及变形的影响。结果表明,静环端面变形受温度影响较大,且力变形会抑制热变形,动环端面变形主要受温度影响;随冷却水压力增高,密封端面温度逐渐升高,静环端面变形略有减小,动环端面变形几乎不变;随密封端面宽度减小,端面温度逐渐升高,动环端面变形增大,最佳密封端面宽度为3.5 mm,静环端面变形随端面宽度减小而减小。