It is important to acquire the composition of Si1-xGex layer, especially that with high Ge content, epitaxied on Si substrate. Two nondestructive examination methods, double crystals X-ray diffraction (DCXRD) and mi...It is important to acquire the composition of Si1-xGex layer, especially that with high Ge content, epitaxied on Si substrate. Two nondestructive examination methods, double crystals X-ray diffraction (DCXRD) and micro-Raman measurement, were introduced comparatively to determine x value in Si1-xGex layer, which show that while the two methods are consistent with each other when x is low, the results obtained from double crystals X-ray diffraction are not credible due to the large strain relaxation occurring in Si1-xGex layers when Ge content is higher than about 20%. Micro-Raman measurement is more appropriate for determining high Ge content than DCXRD.展开更多
Although quite a numer of papers can be found up to now dealing with the subject of the measurement ofwood density by using the X-ray exposure methods, direet scanning or radiographic photography, the following two as...Although quite a numer of papers can be found up to now dealing with the subject of the measurement ofwood density by using the X-ray exposure methods, direet scanning or radiographic photography, the following two aspects,which are very important from both theorctical and engineering application points of view, have not yet been properly handled. One is that the elementary analyses or the experimental measurement on the mass attenuation coefficients were notspecified in regard to spectnun energv distridutions [1]. In this connection, the ambiguities in the specification of the coeffiecients and in turn for thc results among studies arise when only one of the two parameters, namely wave length and applied voltage, of detining the energy spectrum of X-ray is given. The oher is that the relationships between the relative intensity and the sample thickness as well the wood moisture content [2], which are the critical factors for the design and theselection of X-ray apparatus, were not sufficiently examined. In addition, the knowledge of the measurelnent of woodmiosture content by using the direct X-ray scanning method is also almost unavaible now. In the study, the direct X-rayscanning method of measuring wood moisture content was at first investigated theoretically with respect to the relationshipbetween the mass attenuation coefficients of wood (beech, Fagus Sylvatica) and the maximum spectrum energy of X-ray.Secondly, the dependence of the relative intensity on the sample thickness and on the wood moisture content was analysed.The main advantage of the method is on-site nondestructive measuring of wood moisture content in the processes such asdrying, impregnation and unsteady mass diffusion. Specifically for the application in the area of biomechanics, the methodcan also bc used for understanding the water pathway within wood, for example, the water around the knots and the relation between the stress distribution and the local moisture content of wood.展开更多
Cardiac coronary angiography is a major technique that assists physicians during interventional heart surgery.Under X-ray irradiation,the physician injects a contrast agent through a catheter and determines the corona...Cardiac coronary angiography is a major technique that assists physicians during interventional heart surgery.Under X-ray irradiation,the physician injects a contrast agent through a catheter and determines the coronary arteries’state in real time.However,to obtain a more accurate state of the coronary arteries,physicians need to increase the fre-quency and intensity of X-ray exposure,which will inevitably increase the potential for harm to both the patient and the surgeon.In the work reported here,we use advanced deep learning algorithms to fi nd a method of frame interpola-tion for coronary angiography videos that reduces the frequency of X-ray exposure by reducing the frame rate of the coronary angiography video,thereby reducing X-ray-induced damage to physicians.We established a new coronary angiography image group dataset containing 95,039 groups of images extracted from 31 videos.Each group includes three consecutive images,which are used to train the video interpolation network model.We apply six popular frame interpolation methods to this dataset to confi rm that the video frame interpolation technology can reduce the video frame rate and reduce exposure of physicians to X-rays.展开更多
N-doped porous carbon has been extensively investigated for broad electrochemical applications.The performance is significantly impacted by the electrochemical double layer(EDL),which is material dependent and hard to...N-doped porous carbon has been extensively investigated for broad electrochemical applications.The performance is significantly impacted by the electrochemical double layer(EDL),which is material dependent and hard to characterize.Limited understanding of doping-derived EDL structure hinders insight into the structure-performance relations and the rational design of high-performance materials.Thus,we analyzed the mass and chemical composition variation of EDL within electrochemical operation by electrochemical quartz crystal microbalance,in-situ X-ray photoelectron spectroscopy,and time-offlight secondary ion mass spectrometry.We found that N-doping triggers specifically adsorbed propylene carbonate solvent in the inner Helmholtz plane(IHP),which prevents ion rearrangement and enhances the migration of cations.However,this specific adsorption accelerated solvent decomposition,rendering rapid performance degradation in practical devices.This work reveals that the surface chemistry of electrodes can cause specific adsorption of solvents and change the EDL structure,which complements the classical EDL theory and provide guidance for practical applications.展开更多
Fallout volcanic deposits of SommaVesuvius(Campania,southern Italy),characterized by the presence of layers with contrasting textural and hydraulic properties,are frequently affected by shallow landslides during rainw...Fallout volcanic deposits of SommaVesuvius(Campania,southern Italy),characterized by the presence of layers with contrasting textural and hydraulic properties,are frequently affected by shallow landslides during rainwater infiltration.The soils of the stratigraphic sequence present intraparticle pores,originated by the gases escaped during magma decompression in the volcanic conduit,thus are characterized by double porosity(i.e.,intraparticle and interparticle pores),which is expected to affect their hydraulic behaviour,and to play a key role in rainwater infiltration through layered deposits.To understand the effect of double porosity on the hydraulic behaviour of the involved soils,controlled experiments have been carried out in an infiltration column.The experimental apparatus is provided with newly designed non-invasive Time Domain Reflectometry(TDR)probes,not buried in the investigated soil layers so as to minimize disturbance to the flow,allowing water content measurement during vertical flow processes.Specifically,transient flow experiments are carried out through reconstituted specimens of black scoriae and grey pumices,both loose pyroclastic granular soils from fallout deposits of Somma-Vesuvius,featuring double porosity with different pore size distributions,that were estimated by X-ray tomography and Mercury Intrusion Porosimetry.The experimental results highlight the effects of the double porosity and clearly indicate the different behaviour of the two soils during wetting and drying processes,mainly related to the different dimensions of intraparticle pores.展开更多
Layered double hydroxides(LDHs) have attracted considerable attention as a cost effective alternative to the precious iridium-and ruthenium-based electrocatalysts for an oxygen evolution reaction(OER),a bottleneck of ...Layered double hydroxides(LDHs) have attracted considerable attention as a cost effective alternative to the precious iridium-and ruthenium-based electrocatalysts for an oxygen evolution reaction(OER),a bottleneck of water electrolysis for sustainable hydrogen production.Despite their excellent OER performance,the structural and electronic properties of LDHs,particularly during the OER process,remain to be poorly understood.In this study,a series of LDH catalysts is investigated through in situ X-ray absorption fine structure analyses and density functional theory(DFT) calculations.Our experimental results reveal that the LDH catalyst with equal amounts of Ni and Fe(NF-LDH) exhibits the highest OER activity and catalytic life span when compared with its counterparts having equal amounts of Ni and Co(NC-LDH)and Ni only(Ni-LDH).The NF-LDH shows a markedly enhanced OER kinetics compared to the NC-LDH and the Ni-LDH,as proven by the lower overpotentials of 180,240,and 310 mV,respectively,and the Tafel slopes of 35.1,43.4,and 62.7 mV dec^(-1),respectively.The DFT calculations demonstrate that the lowest overpotential of the NF-LDH is associated with the active sites located at the edge planes of NF-LDH in contrast to those located at the basal planes of Ni-LDH and NC-LDH.The current study pinpoints the active sites on various LDHs and presents strategies for optimizing the OER performance of the LDH catalysts.展开更多
The following article has been retracted due to the investigation of complaints received against it. The Editorial Board found that there are conflicts of interests among the authors. The scientific community takes a ...The following article has been retracted due to the investigation of complaints received against it. The Editorial Board found that there are conflicts of interests among the authors. The scientific community takes a very strong view on this matter, and the Advances in Materials Physics and Chemistry treats all unethical behaviors seriously. This paper published in Vol. 4 No. 4 61-74, 2014 has been removed from this site. Title: Jahn–Teller Effect, Crystal Structure and High Temperature Raman Spectroscopy Studies of Ba2-xSrxCuWO6 (0 ≤ x≤ 2) Double Perovskite Oxide. Authors: Amine Ezzahi, Abdellah展开更多
BACKGROUND:Few contemporary studies have assessed physicians’knowledge of radiation exposure associated with common imaging studies,especially in trauma care.The purpose of this study was to assess the knowledge of p...BACKGROUND:Few contemporary studies have assessed physicians’knowledge of radiation exposure associated with common imaging studies,especially in trauma care.The purpose of this study was to assess the knowledge of physicians involved in caring for trauma patients regarding the effective radiation doses of musculoskeletal(MSK)imaging studies routinely utilized in the trauma setting.METHODS:An electronic survey was distributed to United States orthopaedic surgery,general surgery,and emergency medicine(EM)residency programs.Participants were asked to estimate the radiation dose for common imaging modalities of the pelvis,lumbar spine,and lower extremity,in terms of chest X-ray(CXR)equivalents.Physician estimates were compared to the true effective radiation doses.Additionally,participants were asked to report the frequency of discussing radiation risk with patients.RESULTS:A total of 218 physicians completed the survey;102(46.8%)were EM physicians,88(40.4%)wereorthopaedicsurgeons,and28(12.8%)weregeneralsurgeons.Physicians underestimated the effective radiation doses of nearly all imaging modalities,most notably for pelvic computed tomaography(CT)(median 50 CXR estimation vs.162 CXR actual)and lumbar CT(median 50 CXR estimation vs.638 CXR actual).There was no difference between physician specialties regarding estimation accuracy(P=0.133).Physicians who regularly discussed radiation risks with patients more accurately estimated radiation exposure(P=0.007).CONCLUSION:The knowledge among orthopaedic and general surgeons and EM physicians regarding the radiation exposure associated with common MSK trauma imaging is lacking.Further investigation with larger scale studies is warranted,and additional education in this area may improve care.展开更多
Background: Computed radiography has a wider exposure latitude when compared with film-screen imaging system. Consequently, the risk of dose creep is high. A conscientious effort is there-fore, needed by the radiograp...Background: Computed radiography has a wider exposure latitude when compared with film-screen imaging system. Consequently, the risk of dose creep is high. A conscientious effort is there-fore, needed by the radiographer to keep exposure as low as reasonably achievable. Objective: To derive a computed radiography exposure chart for a negroid population using AGFA photostimulable phosphor plates and a GE static X-ray machine. Materials and Method: A static X-ray machine, a digitizer, and photostimulable phosphor plates were used for the X-ray examination. Chest examinations were done at a Focus-Film-Distance (FFD) of 150 - 180 cm while all other examinations were conducted at 90 - 100 cm FFD. The range of exposure factors (kVp, mA and mAs) used by radiog-raphers in the centre was noted and the 90th percentile calculated. Over a three-month period, the patients were examined with the 90th percentile of tube potential (kVp) while keeping other factors constant. The kVp was gradually decreased and halted if radiologists and radiographers uncon-nected with the work expressed misgivings about the quality of the image. A similar procedure was adopted for the tube current (mA). The threshold adopted as low as reasonably achievable was the factor preceding the point of observation by other personnel. Metrics for central tendency from the statistical packages for social sciences, version 17.0 was used to analyze the data. Results: 335 subjects of both gender aged 0 - 92 years were examined by the researchers. Adult exposure factors used by the radiographers (and those derived by the researchers) had a range of 45 - 130 kVp (62 - 94 kVp), 63 - 320 mA (100 - 250 mA) and 4.0 - 25.0 mAs (5.0 - 20.0 mAs) respectively. Pediatric chest (and researchers-derived) factors were 50 - 75 kVp (52 - 65 kVp), 50 - 250 mA (100 - 220 mA) and 3.20 - 10.0 mAs (3.2 - 6.5 mAs) respectively. Conclusion: Upper threshold of adult (and paediatric) exposure factors in computed radiography with comparable equipment and accessories should not exceed 94 kVp (65 kVp), 250 mA (220 mA) and 20.0 mAs (6.5 mAs) respectively. The derived exposure chart is also adequate to address motion unsharpness in chest examinations.展开更多
A special cloth for keeping LiF(Mg,Cu,P)TL dosimetry elements is worn by examinees. The exposures of 128 examinees .received upper G.I.T (gastro-intestinal tram) X-ray examination are measured. The reference point of ...A special cloth for keeping LiF(Mg,Cu,P)TL dosimetry elements is worn by examinees. The exposures of 128 examinees .received upper G.I.T (gastro-intestinal tram) X-ray examination are measured. The reference point of the maximum body surface exposure given is at the middle of stomach. The average of this point is (4.97±1.94) × 10-4C.kg-1 person-1 examination-1 and (1.33±0.28)×10-4C.kg-1.min-1.展开更多
The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA re...The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA repair genes AtKu 70, AtRAD51 and AtRadl, which keeps genome stability in cells of model plant Arabidopsis thaliana, changes differently depending on dose and mode of ionizing radiation exposure had been tested. Gel electrophoresis-based reverse transcription polymerase chain reaction (RT-PCR) method was used for quantifying mRNA transcription levels. The data demonstrated that mode and dose of irradiation affect transcription rate of the genes AtKuTO, AtRAD51 and AtRadI. The fractionated and acute X-ray irradiation may result in adaptive response through the induction of key DNA double-strand break (DSB) repair genes AtKu70 and AtRAD51, as well as in genome instability through transcriptional activation of error-prone AtRadl-mediated DNA DSB repair combined with decreased expression of AtRAD51. In plants at doses within the range of 3-9 Gy, an adaptive influence is prevailed, but at doses of 12-21 Gy an error-prone repair of double-strand DNA damage is activated. Fractionation of dose has a significant effect on the transcription of the genes AtKuTO, AtRAD51 and AtRadl only at doses of 15 Gy and 21 Gy. Acute dose of 15 Gy activates error-prone AtRadl-mediated DSB repair and repressed both AtRAD51-dependent and AtKu70-dependent repair pathways, while fractionated irradiation at the same total dose induces more accurate homologous recombination and canonical non-homologous end joining of the DNA strands. In case of A. thaliana exposed to X-rays at dose 21 Gy, the situation is going reversed because of strong induction of the all three genome caretaker genes in leaves of acutely irradiated plants in contrast to the plants under fractionated exposure.展开更多
BACKGROUND Many imaging methods such as ultrasonography,computed tomography(CT),magnetic resonance imaging,and endoscopy are used to identify the problems or complications that occur in the perioperative period and to...BACKGROUND Many imaging methods such as ultrasonography,computed tomography(CT),magnetic resonance imaging,and endoscopy are used to identify the problems or complications that occur in the perioperative period and to determine the appropriate therapeutic approach.Specialists at surgical clinics and intensive care units sometimes need diagnostic procedures that can give quick results or reveal unexpected results.In particular,rapid on-site evaluation of patients followed under intensive care conditions has several advantages.AIM To determine the problems developing in patients in the perioperative period by contrast-enhanced abdominal X-ray(CE-AXR),revealing their current status or defining the effectiveness of CE-AXR.METHODS The files of the patients who underwent hepatopancreatobiliary or upper gastrointestinal surgery,whose CE-AXR film was taken,were reviewed retrospectively.Abdominal X-ray radiographs taken after ingestion of a watersoluble contrast agent(iohexol,300 mg,50 cc vial)and its application in a drain,nasogastric tube,or stent were evaluated.The contribution of the data obtained in patients who underwent CE-AXR to the diagnosis,follow-up,and treatment processes and the effectiveness of the application were investigated.RESULTS CE-AXR was applied to 131 patients in our clinic,most of whom underwent hepatopancreatobiliary or upper gastrointestinal surgery.It was determined that the data obtained from CE-AXR films taken in 98(74.8%)of the patients contributed to the diagnosis,treatment,and follow-up expectations and positively affected the clinical processes.CONCLUSION CE-AXR is a simple procedure that can be applied anywhere,especially in intensive care patients and at bedside,with a portable X-ray device.The simplicity of the procedure,less radiation exposure for the patients,less time wastage,reduction in the CT and endoscopy procedure burden and costs,quick results,rapid assessment of the situation,and enabling the monitoring of processes with repetitive procedures are important advantages.X-rays taken will be useful in terms of being a reference value during the follow-up period of the patient and determining the situation in medicolegal processes.展开更多
Plasma X-ray sources for biological microscopy have been produced by focusing single shots from Nd:glass laser onto carbon rod targets at irradiances between 1 × 1013 W⋅cm−2 and 3 × 1013 W...Plasma X-ray sources for biological microscopy have been produced by focusing single shots from Nd:glass laser onto carbon rod targets at irradiances between 1 × 1013 W⋅cm−2 and 3 × 1013 W⋅cm−2 to expose test objects. The optimum parameters needed for obtaining high accurate information on the samples under test namely: the minimum energies and irradiances at a range of angles between the incoming laser beam and the normal to the resist, the depth of exposure of the photoresist as a function of incident laser energy (and irradiance) were concluded in this work.展开更多
A wide-dynamic-range CMOS image sensor(CIS) based on synthesis of a long-time and a short-time exposure signal in the floating diffusion(FD) of a five-transistor active pixel is proposed.With optimized pixel opera...A wide-dynamic-range CMOS image sensor(CIS) based on synthesis of a long-time and a short-time exposure signal in the floating diffusion(FD) of a five-transistor active pixel is proposed.With optimized pixel operation,the response curve is compressed and a wide dynamic range image is obtained.A prototype wide-dynamic-range CMOS image sensor was developed with a 0.18μm CIS process.With the double exposure time 2.4 ms and 70 ns,the dynamic range of the proposed sensor is 80 dB with 30 frames per second(fps).The proposed CMOS image sensor meets the demands of applications in security surveillance systems.展开更多
A CMOS compatible P+/Nwell/Psub double junction photodiode pixel was proposed, which can effi- ciently detect fluorescence from CsI(T1) scintillation in an X-ray sensor. Photoelectric and spectral responses of P+/...A CMOS compatible P+/Nwell/Psub double junction photodiode pixel was proposed, which can effi- ciently detect fluorescence from CsI(T1) scintillation in an X-ray sensor. Photoelectric and spectral responses of P+/Nwell, NweE1/Psub and P+/Nwell/Psub photodiodes were analyzed and modeled. Simulation results show P+/Nweu/Psub photodiode has larger photocurrent than P+/Nwetl photodiode and Nweu/Psub photodiode, and its spectral response is more in accordance with CsI(T1) fluorescence spectrum. Improved P+/Nweu/Psub photodiode detecting CsI(T1) fluorescence was designed in CSMC 0.5 #m CMOS process, CTIA (capacitive transimpedance amplifier) architecture was used to readout photocurrent signal. CMOS X-ray sensor IC prototype contains 8 × 8 pixel array and pixel pitch is 100 × 100 μm2. Testing results show the dark current of the improved P+/Nwell/Psub photodiode (6.5 pA) is less than that of P+/Nwell and P+/Nwell/Psub photodiodes (13 pA and 11 pA respectively). The sen- sitivity of P+/Nwell/Psub photodiode is about 20 pA/lux under white LED. The spectrum response of P+/Nwell/Psub photodiode ranges from 400 nm to 800 nm with a peak at 532 nm, which is in accordance with the fluorescence spectrum of Csl(T1) in an indirect X-ray sensor. Preliminary testing results show the sensitivity of X-ray sensor IC under Cu target X-ray is about 0.21 V.m^2/W or 5097e-/pixel @ 8.05 keV considering the pixel size, integration time and average energy of X-ray photons.展开更多
基金This work is supported by the National Natural Science Foundation of China (Grant Nos. 60336010 & 90401001)973 Program (Grant No. TG 2000036603)the Student Innovation Program of CAS (No. 1731000500010).
文摘It is important to acquire the composition of Si1-xGex layer, especially that with high Ge content, epitaxied on Si substrate. Two nondestructive examination methods, double crystals X-ray diffraction (DCXRD) and micro-Raman measurement, were introduced comparatively to determine x value in Si1-xGex layer, which show that while the two methods are consistent with each other when x is low, the results obtained from double crystals X-ray diffraction are not credible due to the large strain relaxation occurring in Si1-xGex layers when Ge content is higher than about 20%. Micro-Raman measurement is more appropriate for determining high Ge content than DCXRD.
文摘Although quite a numer of papers can be found up to now dealing with the subject of the measurement ofwood density by using the X-ray exposure methods, direet scanning or radiographic photography, the following two aspects,which are very important from both theorctical and engineering application points of view, have not yet been properly handled. One is that the elementary analyses or the experimental measurement on the mass attenuation coefficients were notspecified in regard to spectnun energv distridutions [1]. In this connection, the ambiguities in the specification of the coeffiecients and in turn for thc results among studies arise when only one of the two parameters, namely wave length and applied voltage, of detining the energy spectrum of X-ray is given. The oher is that the relationships between the relative intensity and the sample thickness as well the wood moisture content [2], which are the critical factors for the design and theselection of X-ray apparatus, were not sufficiently examined. In addition, the knowledge of the measurelnent of woodmiosture content by using the direct X-ray scanning method is also almost unavaible now. In the study, the direct X-rayscanning method of measuring wood moisture content was at first investigated theoretically with respect to the relationshipbetween the mass attenuation coefficients of wood (beech, Fagus Sylvatica) and the maximum spectrum energy of X-ray.Secondly, the dependence of the relative intensity on the sample thickness and on the wood moisture content was analysed.The main advantage of the method is on-site nondestructive measuring of wood moisture content in the processes such asdrying, impregnation and unsteady mass diffusion. Specifically for the application in the area of biomechanics, the methodcan also bc used for understanding the water pathway within wood, for example, the water around the knots and the relation between the stress distribution and the local moisture content of wood.
文摘Cardiac coronary angiography is a major technique that assists physicians during interventional heart surgery.Under X-ray irradiation,the physician injects a contrast agent through a catheter and determines the coronary arteries’state in real time.However,to obtain a more accurate state of the coronary arteries,physicians need to increase the fre-quency and intensity of X-ray exposure,which will inevitably increase the potential for harm to both the patient and the surgeon.In the work reported here,we use advanced deep learning algorithms to fi nd a method of frame interpola-tion for coronary angiography videos that reduces the frequency of X-ray exposure by reducing the frame rate of the coronary angiography video,thereby reducing X-ray-induced damage to physicians.We established a new coronary angiography image group dataset containing 95,039 groups of images extracted from 31 videos.Each group includes three consecutive images,which are used to train the video interpolation network model.We apply six popular frame interpolation methods to this dataset to confi rm that the video frame interpolation technology can reduce the video frame rate and reduce exposure of physicians to X-rays.
基金the National Science Foundation for Excellent Young Scholars of China(21922815)the National Natural Science Foundation of China(22179139)+2 种基金the National Key Research and Development Program of China(2020YFB1505800)the Youth Innovation Promotion Association of CAS(2019178)the“Transformational Technologies for Clean Energy and Demonstration”Strategic Priority Research Program of the CAS(XDA21000000)。
文摘N-doped porous carbon has been extensively investigated for broad electrochemical applications.The performance is significantly impacted by the electrochemical double layer(EDL),which is material dependent and hard to characterize.Limited understanding of doping-derived EDL structure hinders insight into the structure-performance relations and the rational design of high-performance materials.Thus,we analyzed the mass and chemical composition variation of EDL within electrochemical operation by electrochemical quartz crystal microbalance,in-situ X-ray photoelectron spectroscopy,and time-offlight secondary ion mass spectrometry.We found that N-doping triggers specifically adsorbed propylene carbonate solvent in the inner Helmholtz plane(IHP),which prevents ion rearrangement and enhances the migration of cations.However,this specific adsorption accelerated solvent decomposition,rendering rapid performance degradation in practical devices.This work reveals that the surface chemistry of electrodes can cause specific adsorption of solvents and change the EDL structure,which complements the classical EDL theory and provide guidance for practical applications.
文摘Fallout volcanic deposits of SommaVesuvius(Campania,southern Italy),characterized by the presence of layers with contrasting textural and hydraulic properties,are frequently affected by shallow landslides during rainwater infiltration.The soils of the stratigraphic sequence present intraparticle pores,originated by the gases escaped during magma decompression in the volcanic conduit,thus are characterized by double porosity(i.e.,intraparticle and interparticle pores),which is expected to affect their hydraulic behaviour,and to play a key role in rainwater infiltration through layered deposits.To understand the effect of double porosity on the hydraulic behaviour of the involved soils,controlled experiments have been carried out in an infiltration column.The experimental apparatus is provided with newly designed non-invasive Time Domain Reflectometry(TDR)probes,not buried in the investigated soil layers so as to minimize disturbance to the flow,allowing water content measurement during vertical flow processes.Specifically,transient flow experiments are carried out through reconstituted specimens of black scoriae and grey pumices,both loose pyroclastic granular soils from fallout deposits of Somma-Vesuvius,featuring double porosity with different pore size distributions,that were estimated by X-ray tomography and Mercury Intrusion Porosimetry.The experimental results highlight the effects of the double porosity and clearly indicate the different behaviour of the two soils during wetting and drying processes,mainly related to the different dimensions of intraparticle pores.
基金supported by the National Research Foundation of Korea (NRF-2022R1C1C1004171)supported by the National Science Foundation (Grant number ACI1548562)。
文摘Layered double hydroxides(LDHs) have attracted considerable attention as a cost effective alternative to the precious iridium-and ruthenium-based electrocatalysts for an oxygen evolution reaction(OER),a bottleneck of water electrolysis for sustainable hydrogen production.Despite their excellent OER performance,the structural and electronic properties of LDHs,particularly during the OER process,remain to be poorly understood.In this study,a series of LDH catalysts is investigated through in situ X-ray absorption fine structure analyses and density functional theory(DFT) calculations.Our experimental results reveal that the LDH catalyst with equal amounts of Ni and Fe(NF-LDH) exhibits the highest OER activity and catalytic life span when compared with its counterparts having equal amounts of Ni and Co(NC-LDH)and Ni only(Ni-LDH).The NF-LDH shows a markedly enhanced OER kinetics compared to the NC-LDH and the Ni-LDH,as proven by the lower overpotentials of 180,240,and 310 mV,respectively,and the Tafel slopes of 35.1,43.4,and 62.7 mV dec^(-1),respectively.The DFT calculations demonstrate that the lowest overpotential of the NF-LDH is associated with the active sites located at the edge planes of NF-LDH in contrast to those located at the basal planes of Ni-LDH and NC-LDH.The current study pinpoints the active sites on various LDHs and presents strategies for optimizing the OER performance of the LDH catalysts.
文摘The following article has been retracted due to the investigation of complaints received against it. The Editorial Board found that there are conflicts of interests among the authors. The scientific community takes a very strong view on this matter, and the Advances in Materials Physics and Chemistry treats all unethical behaviors seriously. This paper published in Vol. 4 No. 4 61-74, 2014 has been removed from this site. Title: Jahn–Teller Effect, Crystal Structure and High Temperature Raman Spectroscopy Studies of Ba2-xSrxCuWO6 (0 ≤ x≤ 2) Double Perovskite Oxide. Authors: Amine Ezzahi, Abdellah
文摘BACKGROUND:Few contemporary studies have assessed physicians’knowledge of radiation exposure associated with common imaging studies,especially in trauma care.The purpose of this study was to assess the knowledge of physicians involved in caring for trauma patients regarding the effective radiation doses of musculoskeletal(MSK)imaging studies routinely utilized in the trauma setting.METHODS:An electronic survey was distributed to United States orthopaedic surgery,general surgery,and emergency medicine(EM)residency programs.Participants were asked to estimate the radiation dose for common imaging modalities of the pelvis,lumbar spine,and lower extremity,in terms of chest X-ray(CXR)equivalents.Physician estimates were compared to the true effective radiation doses.Additionally,participants were asked to report the frequency of discussing radiation risk with patients.RESULTS:A total of 218 physicians completed the survey;102(46.8%)were EM physicians,88(40.4%)wereorthopaedicsurgeons,and28(12.8%)weregeneralsurgeons.Physicians underestimated the effective radiation doses of nearly all imaging modalities,most notably for pelvic computed tomaography(CT)(median 50 CXR estimation vs.162 CXR actual)and lumbar CT(median 50 CXR estimation vs.638 CXR actual).There was no difference between physician specialties regarding estimation accuracy(P=0.133).Physicians who regularly discussed radiation risks with patients more accurately estimated radiation exposure(P=0.007).CONCLUSION:The knowledge among orthopaedic and general surgeons and EM physicians regarding the radiation exposure associated with common MSK trauma imaging is lacking.Further investigation with larger scale studies is warranted,and additional education in this area may improve care.
文摘Background: Computed radiography has a wider exposure latitude when compared with film-screen imaging system. Consequently, the risk of dose creep is high. A conscientious effort is there-fore, needed by the radiographer to keep exposure as low as reasonably achievable. Objective: To derive a computed radiography exposure chart for a negroid population using AGFA photostimulable phosphor plates and a GE static X-ray machine. Materials and Method: A static X-ray machine, a digitizer, and photostimulable phosphor plates were used for the X-ray examination. Chest examinations were done at a Focus-Film-Distance (FFD) of 150 - 180 cm while all other examinations were conducted at 90 - 100 cm FFD. The range of exposure factors (kVp, mA and mAs) used by radiog-raphers in the centre was noted and the 90th percentile calculated. Over a three-month period, the patients were examined with the 90th percentile of tube potential (kVp) while keeping other factors constant. The kVp was gradually decreased and halted if radiologists and radiographers uncon-nected with the work expressed misgivings about the quality of the image. A similar procedure was adopted for the tube current (mA). The threshold adopted as low as reasonably achievable was the factor preceding the point of observation by other personnel. Metrics for central tendency from the statistical packages for social sciences, version 17.0 was used to analyze the data. Results: 335 subjects of both gender aged 0 - 92 years were examined by the researchers. Adult exposure factors used by the radiographers (and those derived by the researchers) had a range of 45 - 130 kVp (62 - 94 kVp), 63 - 320 mA (100 - 250 mA) and 4.0 - 25.0 mAs (5.0 - 20.0 mAs) respectively. Pediatric chest (and researchers-derived) factors were 50 - 75 kVp (52 - 65 kVp), 50 - 250 mA (100 - 220 mA) and 3.20 - 10.0 mAs (3.2 - 6.5 mAs) respectively. Conclusion: Upper threshold of adult (and paediatric) exposure factors in computed radiography with comparable equipment and accessories should not exceed 94 kVp (65 kVp), 250 mA (220 mA) and 20.0 mAs (6.5 mAs) respectively. The derived exposure chart is also adequate to address motion unsharpness in chest examinations.
文摘A special cloth for keeping LiF(Mg,Cu,P)TL dosimetry elements is worn by examinees. The exposures of 128 examinees .received upper G.I.T (gastro-intestinal tram) X-ray examination are measured. The reference point of the maximum body surface exposure given is at the middle of stomach. The average of this point is (4.97±1.94) × 10-4C.kg-1 person-1 examination-1 and (1.33±0.28)×10-4C.kg-1.min-1.
文摘The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA repair genes AtKu 70, AtRAD51 and AtRadl, which keeps genome stability in cells of model plant Arabidopsis thaliana, changes differently depending on dose and mode of ionizing radiation exposure had been tested. Gel electrophoresis-based reverse transcription polymerase chain reaction (RT-PCR) method was used for quantifying mRNA transcription levels. The data demonstrated that mode and dose of irradiation affect transcription rate of the genes AtKuTO, AtRAD51 and AtRadI. The fractionated and acute X-ray irradiation may result in adaptive response through the induction of key DNA double-strand break (DSB) repair genes AtKu70 and AtRAD51, as well as in genome instability through transcriptional activation of error-prone AtRadl-mediated DNA DSB repair combined with decreased expression of AtRAD51. In plants at doses within the range of 3-9 Gy, an adaptive influence is prevailed, but at doses of 12-21 Gy an error-prone repair of double-strand DNA damage is activated. Fractionation of dose has a significant effect on the transcription of the genes AtKuTO, AtRAD51 and AtRadl only at doses of 15 Gy and 21 Gy. Acute dose of 15 Gy activates error-prone AtRadl-mediated DSB repair and repressed both AtRAD51-dependent and AtKu70-dependent repair pathways, while fractionated irradiation at the same total dose induces more accurate homologous recombination and canonical non-homologous end joining of the DNA strands. In case of A. thaliana exposed to X-rays at dose 21 Gy, the situation is going reversed because of strong induction of the all three genome caretaker genes in leaves of acutely irradiated plants in contrast to the plants under fractionated exposure.
文摘BACKGROUND Many imaging methods such as ultrasonography,computed tomography(CT),magnetic resonance imaging,and endoscopy are used to identify the problems or complications that occur in the perioperative period and to determine the appropriate therapeutic approach.Specialists at surgical clinics and intensive care units sometimes need diagnostic procedures that can give quick results or reveal unexpected results.In particular,rapid on-site evaluation of patients followed under intensive care conditions has several advantages.AIM To determine the problems developing in patients in the perioperative period by contrast-enhanced abdominal X-ray(CE-AXR),revealing their current status or defining the effectiveness of CE-AXR.METHODS The files of the patients who underwent hepatopancreatobiliary or upper gastrointestinal surgery,whose CE-AXR film was taken,were reviewed retrospectively.Abdominal X-ray radiographs taken after ingestion of a watersoluble contrast agent(iohexol,300 mg,50 cc vial)and its application in a drain,nasogastric tube,or stent were evaluated.The contribution of the data obtained in patients who underwent CE-AXR to the diagnosis,follow-up,and treatment processes and the effectiveness of the application were investigated.RESULTS CE-AXR was applied to 131 patients in our clinic,most of whom underwent hepatopancreatobiliary or upper gastrointestinal surgery.It was determined that the data obtained from CE-AXR films taken in 98(74.8%)of the patients contributed to the diagnosis,treatment,and follow-up expectations and positively affected the clinical processes.CONCLUSION CE-AXR is a simple procedure that can be applied anywhere,especially in intensive care patients and at bedside,with a portable X-ray device.The simplicity of the procedure,less radiation exposure for the patients,less time wastage,reduction in the CT and endoscopy procedure burden and costs,quick results,rapid assessment of the situation,and enabling the monitoring of processes with repetitive procedures are important advantages.X-rays taken will be useful in terms of being a reference value during the follow-up period of the patient and determining the situation in medicolegal processes.
文摘Plasma X-ray sources for biological microscopy have been produced by focusing single shots from Nd:glass laser onto carbon rod targets at irradiances between 1 × 1013 W⋅cm−2 and 3 × 1013 W⋅cm−2 to expose test objects. The optimum parameters needed for obtaining high accurate information on the samples under test namely: the minimum energies and irradiances at a range of angles between the incoming laser beam and the normal to the resist, the depth of exposure of the photoresist as a function of incident laser energy (and irradiance) were concluded in this work.
基金supported by the National Natural Science Foundation of China(Nos.60806010,60976030)the Tianjin Innovation Special Funds for Science and Technology,China(No.05FZZDGX00200).
文摘A wide-dynamic-range CMOS image sensor(CIS) based on synthesis of a long-time and a short-time exposure signal in the floating diffusion(FD) of a five-transistor active pixel is proposed.With optimized pixel operation,the response curve is compressed and a wide dynamic range image is obtained.A prototype wide-dynamic-range CMOS image sensor was developed with a 0.18μm CIS process.With the double exposure time 2.4 ms and 70 ns,the dynamic range of the proposed sensor is 80 dB with 30 frames per second(fps).The proposed CMOS image sensor meets the demands of applications in security surveillance systems.
基金supported by the National Natural Science Foundation of China(No.61076075)the Natural Science Foundation of Zhejiang Province(No.Y1100287)
文摘A CMOS compatible P+/Nwell/Psub double junction photodiode pixel was proposed, which can effi- ciently detect fluorescence from CsI(T1) scintillation in an X-ray sensor. Photoelectric and spectral responses of P+/Nwell, NweE1/Psub and P+/Nwell/Psub photodiodes were analyzed and modeled. Simulation results show P+/Nweu/Psub photodiode has larger photocurrent than P+/Nwetl photodiode and Nweu/Psub photodiode, and its spectral response is more in accordance with CsI(T1) fluorescence spectrum. Improved P+/Nweu/Psub photodiode detecting CsI(T1) fluorescence was designed in CSMC 0.5 #m CMOS process, CTIA (capacitive transimpedance amplifier) architecture was used to readout photocurrent signal. CMOS X-ray sensor IC prototype contains 8 × 8 pixel array and pixel pitch is 100 × 100 μm2. Testing results show the dark current of the improved P+/Nwell/Psub photodiode (6.5 pA) is less than that of P+/Nwell and P+/Nwell/Psub photodiodes (13 pA and 11 pA respectively). The sen- sitivity of P+/Nwell/Psub photodiode is about 20 pA/lux under white LED. The spectrum response of P+/Nwell/Psub photodiode ranges from 400 nm to 800 nm with a peak at 532 nm, which is in accordance with the fluorescence spectrum of Csl(T1) in an indirect X-ray sensor. Preliminary testing results show the sensitivity of X-ray sensor IC under Cu target X-ray is about 0.21 V.m^2/W or 5097e-/pixel @ 8.05 keV considering the pixel size, integration time and average energy of X-ray photons.