Solid base catalysts for the direct synthesis of dimethyl carbonate(DMC)from carbon dioxide,methanol,and propylene oxide were prepared by loading KCl and K_(2)CO_(3) on the surface of La_(2)O_(3),Y_(2)O_(3),CeO2 and N...Solid base catalysts for the direct synthesis of dimethyl carbonate(DMC)from carbon dioxide,methanol,and propylene oxide were prepared by loading KCl and K_(2)CO_(3) on the surface of La_(2)O_(3),Y_(2)O_(3),CeO2 and Nd_(2)O_(3).The catalysts were characterized by thermogravimetric analysis(TGA)and X-ray diffraction(XRD)techniques.The catalytic activities were efficiently influenced by the preparation conditions.The optimal loading amount of K_(2)CO_(3) is 17.6%(mass)for KCl-K_(2)CO_(3)/Y_(2)O_(3) and 22.2%for other catalysts.Supports affected the activity of catalyst.KCl-K_(2)CO_(3)/Nd_(2)O_(3) exhibited the highest activity.The activity of KCl-K_(2)CO_(3)/Y_(2)O_(3) increased with the increase of calcination temperature in the range of 800℃–900℃.The formation of KYO2,Y_(3)O_(4)Cl or YOX species probably promoted the catalysts.展开更多
文摘Solid base catalysts for the direct synthesis of dimethyl carbonate(DMC)from carbon dioxide,methanol,and propylene oxide were prepared by loading KCl and K_(2)CO_(3) on the surface of La_(2)O_(3),Y_(2)O_(3),CeO2 and Nd_(2)O_(3).The catalysts were characterized by thermogravimetric analysis(TGA)and X-ray diffraction(XRD)techniques.The catalytic activities were efficiently influenced by the preparation conditions.The optimal loading amount of K_(2)CO_(3) is 17.6%(mass)for KCl-K_(2)CO_(3)/Y_(2)O_(3) and 22.2%for other catalysts.Supports affected the activity of catalyst.KCl-K_(2)CO_(3)/Nd_(2)O_(3) exhibited the highest activity.The activity of KCl-K_(2)CO_(3)/Y_(2)O_(3) increased with the increase of calcination temperature in the range of 800℃–900℃.The formation of KYO2,Y_(3)O_(4)Cl or YOX species probably promoted the catalysts.
