Non-enzymatic electrochemical sensors for the determination of hydrogen peroxide(H_(2)O_(2))have attracted more and more concerns.A series of nickel and cobalt double oxides(Ni_(x)Co_(y)-DO)with the different ratios o...Non-enzymatic electrochemical sensors for the determination of hydrogen peroxide(H_(2)O_(2))have attracted more and more concerns.A series of nickel and cobalt double oxides(Ni_(x)Co_(y)-DO)with the different ratios of Ni/Co have been prepared by a polyol-mediated solvothermal method for H_(2)O_(2)detection.The obtained products exhibit honeycomb-like open porous microtubes constituted with the low-dimensional nanostructured Ni_(x)Co_(y)-DO blocks after the calcination treatment.Compared with nickel oxides,the introduced Co ions in Ni_(x)Co_(y)-DO can induce the production of surficial oxygen vacancies,and further enhance the electrode surface activity.In particular,the NiCo-DO sample(with an atomic ratio of Ni/Co=4:3)shows the richest surficial oxygen vacancies and presents the highest H_(2)O_(2)detection activity among all the as-prepared samples,demonstrating an excellent sensitivity of698.60μAL mmol^(-1)cm^(-2)(0~0.4 mmol/L),low detection limit(0.28μmol/L,S/N=3),as well as long stability,high selectivity and good reproducibility.This work lends a new impetus to the potential application of double metal oxides for the next generation of non-enzymatic sensors.展开更多
基金supported by the National Natural Science Foundation of China(Nos.51432003,51802011 and 51125007)the Start-Up Fund for Talent Introduction of Beijing University of Chemical Technology(No.buctrc201806)the Fundamental Research Funds for the Central Universities(No.JD2010)。
文摘Non-enzymatic electrochemical sensors for the determination of hydrogen peroxide(H_(2)O_(2))have attracted more and more concerns.A series of nickel and cobalt double oxides(Ni_(x)Co_(y)-DO)with the different ratios of Ni/Co have been prepared by a polyol-mediated solvothermal method for H_(2)O_(2)detection.The obtained products exhibit honeycomb-like open porous microtubes constituted with the low-dimensional nanostructured Ni_(x)Co_(y)-DO blocks after the calcination treatment.Compared with nickel oxides,the introduced Co ions in Ni_(x)Co_(y)-DO can induce the production of surficial oxygen vacancies,and further enhance the electrode surface activity.In particular,the NiCo-DO sample(with an atomic ratio of Ni/Co=4:3)shows the richest surficial oxygen vacancies and presents the highest H_(2)O_(2)detection activity among all the as-prepared samples,demonstrating an excellent sensitivity of698.60μAL mmol^(-1)cm^(-2)(0~0.4 mmol/L),low detection limit(0.28μmol/L,S/N=3),as well as long stability,high selectivity and good reproducibility.This work lends a new impetus to the potential application of double metal oxides for the next generation of non-enzymatic sensors.
