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A Continuum Shell Model Including van derWaals Interaction for Free Vibrations of Double-Walled Carbon Nanotubes 被引量:1
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作者 Salvatore Brischetto 《Computer Modeling in Engineering & Sciences》 SCIE EI 2015年第4期305-327,共23页
This paper proposes the free vibration analysis of Double-Walled Carbon NanoTubes(DWCNTs).A continuum elastic three-dimensional shell model is used for natural frequency investigation of simply supported DWCNTs.The 3D... This paper proposes the free vibration analysis of Double-Walled Carbon NanoTubes(DWCNTs).A continuum elastic three-dimensional shell model is used for natural frequency investigation of simply supported DWCNTs.The 3D shell method is compared with beam analyses to show the applicability limits of 1D beam models.The effect of van der Waals interaction between the two cylinders is shown for different Carbon NanoTube(CNT)lengths and vibration modes.Results give the van der Waals interaction effect in terms of frequency values.In order to apply the 3D shell continuum model,DWCNTs are defined as two concentric isotropic cylinders(with an equivalent thickness and Young modulus)which can be linked by means of the interlaminar continuity conditions or by means of an infinitesimal fictitious layer which represents the van der Waals interaction. 展开更多
关键词 Exact solution three-dimensional shell model double-walled carbon NANOTUBE VAN der WAALS INTERACTION free vibration
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基于邻域K-shell分布的关键节点识别方法 被引量:4
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作者 吴亚丽 任远光 +3 位作者 董昂 周傲然 吴学金 郑帅龙 《计算机工程与应用》 CSCD 北大核心 2024年第2期87-95,共9页
复杂网络中关键节点的精准识别对于网络结构稳定和信息传播起着至关重要的作用。传统K-shell方法仅通过节点在网络中所处位置对节点的重要性进行评估,导致区分度不高。基于此,综合考虑了节点的全局信息和局部信息对节点重要性的影响,提... 复杂网络中关键节点的精准识别对于网络结构稳定和信息传播起着至关重要的作用。传统K-shell方法仅通过节点在网络中所处位置对节点的重要性进行评估,导致区分度不高。基于此,综合考虑了节点的全局信息和局部信息对节点重要性的影响,提出一种基于邻域K-shell分布的关键节点识别方法。该方法通过节点邻域Ks值定义节点的熵,从而反映邻居节点的K-shell分布特征。通过11个网络数据集上的仿真实验,验证了所提方法能够更准确地识别并区分复杂网络中的关键节点。 展开更多
关键词 复杂网络 关键节点 K-shell 易感-感染-恢复模型(SIR)
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基于SHELL模型的航空货物运输安全问题研究
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作者 钟波兰 龙海燕 《长沙航空职业技术学院学报》 2024年第3期82-87,共6页
文章阐述了SHELL 模型的基本理论,分析了航空货物运输的基本流程及常见安全问题,应用SHELL模型重点探究航空货物运输中人与硬件(L-H)、人与软件(L-S)、人与环境(L-E)及人与人(L-L)的要素特征与关系界面,梳理引发安全问题导致不安全事件... 文章阐述了SHELL 模型的基本理论,分析了航空货物运输的基本流程及常见安全问题,应用SHELL模型重点探究航空货物运输中人与硬件(L-H)、人与软件(L-S)、人与环境(L-E)及人与人(L-L)的要素特征与关系界面,梳理引发安全问题导致不安全事件的原因,提出缩小关系界面空隙、提高关系匹配度的措施,保障航空货物运输安全,促进航空货运持续稳定发展。 展开更多
关键词 shell模型 航空货物运输 安全
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Natural gas hydrate shell model in gas-slurry pipeline flow 被引量:11
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作者 Jing Gong Bohui Shi Jiankui Zhao 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2010年第3期261-266,共6页
A hydrate shell model coupled with one-dimensional two-fluid pipe flow model was established to study the flow characteristics of gas-hydrate slurry flow system.The hydrate shell model was developed with kinetic limit... A hydrate shell model coupled with one-dimensional two-fluid pipe flow model was established to study the flow characteristics of gas-hydrate slurry flow system.The hydrate shell model was developed with kinetic limitations and mass transfer limitations,and it was solved by Euler method.The analysis of influence factors was performed.It was found that the diffusion coefficient was a key parameter in hydrate forming process.Considering the hydrate kinetics model and the contacting area between gas and water,the hydrate shell model was more close to its practical situations. 展开更多
关键词 natural gas hydrate shell model gas-slurry pipeline flow
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Anomalous scaling in a non-Gaussian random shell model for passive scalars 被引量:1
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作者 赵英奎 陈式刚 王光瑞 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第10期2848-2854,共7页
In this paper, we have introduced a shell-model of Kraichnan's passive scalar problem. Different from the original problem, the prescribed random velocity field is non-Gaussian and σ correlated in time, and its intr... In this paper, we have introduced a shell-model of Kraichnan's passive scalar problem. Different from the original problem, the prescribed random velocity field is non-Gaussian and σ correlated in time, and its introduction is inspired by She and Levveque (Phys. Rev. Lett. 72, 336 (1994)). For comparison, we also give the passive scalar advected by the Gaussian random velocity field. The anomalous scaling exponents H(p) of passive scalar advected by these two kinds of random velocities above are determined for structure function with values of p up to 15 by Monte Carlo simulations of the random shell model, with Gear methods used to solve the stochastic differential equations. We find that the H(p) advected by the non-Gaussian random velocity is not more anomalous than that advected by the Gaussian random velocity. Whether the advecting velocity is non-Gaussian or Gaussian, similar scaling exponents of passive scalar are obtained with the same molecular diffusivity. 展开更多
关键词 SCALING shell model She and Leveque (SL) model NON-GAUSSIAN passive scalar
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Relativistic Consistent Angular-Momentum Projected Shell-Model:Angular-Momentum Projection 被引量:3
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作者 LIYan-Song LONGGui-Lu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第4期579-582,共4页
The angular-momentum projection part of RECAPS is presented.Application of RECAPS to some deformed nuclei is also presented.
关键词 relativistic consistent angular-momentum projected shell-model angular-momentum projection projected shell model RECAPS-RMF
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Beam Approximation for Dynamic Analysis of Launch Vehicles Modelled as Stiffened Cylindrical Shells 被引量:2
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作者 Siyang Piao Huajiang Ouyang Yahui Zhang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2020年第2期571-591,共21页
A beam approximation method for dynamic analysis of launch vehicles modelled as stiffened cylindrical shells is proposed.Firstly,an initial beam model of the stiffened cylindrical shell is established based on the cro... A beam approximation method for dynamic analysis of launch vehicles modelled as stiffened cylindrical shells is proposed.Firstly,an initial beam model of the stiffened cylindrical shell is established based on the cross-sectional area equivalence principle that represents the shell skin and its longitudinal ribs as a beam with annular cross-section,and the circumferential ribs as lumped masses at the nodes of the beam elements.Then,a fine finite element model(FE model)of the stiffened cylindrical shell is constructed and a modal analysis is carried out.Finally,the initial beam model is improved through model updating against the natural frequencies and mode shapes of the fine FE model of the shell.To facilitate the comparison between the mode shapes of the fine FE model of the stiffened shell and the equivalent beam model,a weighted nodal displacement coupling relationship is introduced.To prevent the design parameters used in model updating from converging to incorrect values,a pre-model updating procedure is added before the proper model updating.The results of two examples demonstrate that the beam approximation method presented in this paper can build equivalent beam models of stiffened cylindrical shells which can reflect the global longitudinal,lateral and torsional vibration characteristics very well in terms of the natural frequencies. 展开更多
关键词 Finite element method model updating stiffened shell beam approximation model reduction.
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Relativistic Consistent Angular-Momentum Projected Shell-Model: Relativistic Mean Field 被引量:3
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作者 LIYan-Song LONGGui-Lu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2004年第3期429-434,共6页
We develop a relativistic nuclear structure model, relativistic consistent angular-momentum projected shell-model (RECAPS), which combines the relativistic mean-field theory with the angular-momentum projection method... We develop a relativistic nuclear structure model, relativistic consistent angular-momentum projected shell-model (RECAPS), which combines the relativistic mean-field theory with the angular-momentum projection method. In this new model, nuclear ground-state properties are first calculated consistently using relativistic mean-field (RMF) theory. Then angular momentum projection method is used to project out states with good angular momentum from a few important configurations. By diagonalizing the hamiltonian, the energy levels and wave functions are obtained. This model is a new attempt for the understanding of nuclear structure of normal nuclei and for the prediction of nuclear properties of nuclei far from stability. In this paper, we will describe the treatment of the relativistic mean field. A computer code, RECAPS-RMF, is developed. It solves the relativistic mean field with axial-symmetric deformation in the spherical harmonic oscillator basis. Comparisons between our calculations and existing relativistic mean-field calculations are made to test the model. These include the ground-state properties of spherical nuclei <SUP>16</SUP>O and <SUP>208</SUP>Pb, the deformed nucleus <SUP>20</SUP>Ne. Good agreement is obtained. 展开更多
关键词 relativistic consistent angular-momentum projected shell-model relativistic mean field projected shell model PECAPS-RMF
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Elastic Constants of Superconducting MgB2 from Molecular Dynamics Simulations with Shell Model 被引量:1
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作者 GUO Yun-Dong CHEN Xiang-Rong +1 位作者 YANG Xiang-Dong GOU Qing-Quan 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第5X期936-940,共5页
The elastic constants of superconducting MgB2 are calculated using a molecular dynamics method (MD)with shell model. The lattice parameters, five independent elastic constants, equations of state (EOS), Debye temperat... The elastic constants of superconducting MgB2 are calculated using a molecular dynamics method (MD)with shell model. The lattice parameters, five independent elastic constants, equations of state (EOS), Debye temperature, and bulk modulus of MgB2 are obtained. Meanwhile, the dependence of the bulk modulus B, the lattice parameters a and c, and the unit cell volume V on the applied pressure are presented. It is demonstrated that the method introduced here can well reproduce the experimental results with a reasonable accuracy. 展开更多
关键词 MGB2 elastic constants shell model molecular dynamics
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Astrophysics: Macroobject Shell Model 被引量:3
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作者 Vladimir S. Netchitailo 《Journal of High Energy Physics, Gravitation and Cosmology》 2017年第4期776-790,共15页
The model proposes that Nuclei of all macroobjects (Galaxy clusters, Galaxies, Star clusters, Extrasolar systems) are made up of Dark Matter Particles (DMP). These Nuclei are surrounded by Shells composed of both Dark... The model proposes that Nuclei of all macroobjects (Galaxy clusters, Galaxies, Star clusters, Extrasolar systems) are made up of Dark Matter Particles (DMP). These Nuclei are surrounded by Shells composed of both Dark and Baryonic matter. This model is used to explain various astrophysical phenomena: Multi-wavelength Pulsars;Binary Millisecond Pulsars;Gamma-Ray Bursts;Fast Radio Bursts;Young Stellar Object Dippers;Starburst Galaxies;Gravitational Waves. New types of Fermi Compact Stars made of DMP are introduced: Neutralino star, WIMP star, and DIRAC star. Gamma-Ray Pulsars are rotating Neutralino and WIMP stars. Merger of binary DIRAC stars can be a source of Gravitational waves. 展开更多
关键词 HYPERSPHERE World-Universe model Medium of the World Macroobject shell model Dark Matter Particles Gamma-Ray BURSTS Fast Radio BURSTS Multiwavelength PULSARS Binary MILLISECOND PULSARS Young Stellar Object Dippers STARBURST Galaxies Gravitational Waves
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Nucleon—Pair Shell Model:Magnetic Excitations for Ba Isotopes 被引量:1
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作者 LUOYan-An NINGPing-Zhi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2002年第3期331-334,共4页
Magnetic excitations for Ba isotopes are discussed within the nucleon-pair shell model truncated in the SD subspace. With the SD pair determined by a surface- interaction, M1 transitions for are well fitted. The M1 a... Magnetic excitations for Ba isotopes are discussed within the nucleon-pair shell model truncated in the SD subspace. With the SD pair determined by a surface- interaction, M1 transitions for are well fitted. The M1 and M3 transitions for and are also predicted. It is shown that the statement, the collective magnetic properties are due to the orbital motion of nucleons, is approximately valid. 展开更多
关键词 the nucleon-pair shell model magnetic excitation Ba isotopes
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Thermodynamic Consistency of Plate and Shell Mathematical Models in the Context of Classical and Non-Classical Continuum Mechanics and a Thermodynamically Consistent New Thermoelastic Formulation 被引量:3
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作者 Karan S. Surana Sri Sai Charan Mathi 《American Journal of Computational Mathematics》 2020年第2期167-220,共54页
Inclusion of dissipation and memory mechanisms, non-classical elasticity and thermal effects in the currently used plate/shell mathematical models require that we establish if these mathematical models can be derived ... Inclusion of dissipation and memory mechanisms, non-classical elasticity and thermal effects in the currently used plate/shell mathematical models require that we establish if these mathematical models can be derived using the conservation and balance laws of continuum mechanics in conjunction with the corresponding kinematic assumptions. This is referred to as thermodynamic consistency of the mathematical models. Thermodynamic consistency ensures thermodynamic equilibrium during the evolution of the deformation. When the mathematical models are thermodynamically consistent, the second law of thermodynamics facilitates consistent derivations of constitutive theories in the presence of dissipation and memory mechanisms. This is the main motivation for the work presented in this paper. In the currently used mathematical models for plates/shells based on the assumed kinematic relations, energy functional is constructed over the volume consisting of kinetic energy, strain energy and the potential energy of the loads. The Euler’s equations derived from the first variation of the energy functional for arbitrary length when set to zero yield the mathematical model(s) for the deforming plates/shells. Alternatively, principle of virtual work can also be used to derive the same mathematical model(s). For linear elastic reversible deformation physics with small deformation and small strain, these two approaches, based on energy functional and the principle of virtual work, yield the same mathematical models. These mathematical models hold for reversible mechanical deformation. In this paper, we examine whether the currently used plate/shell mathematical models with the corresponding kinematic assumptions can be derived using the conservation and balance laws of classical or non-classical continuum mechanics. The mathematical models based on Kirchhoff hypothesis (classical plate theory, CPT) and first order shear deformation theory (FSDT) that are representative of most mathematical models for plates/shells are investigated in this paper for their thermodynamic consistency. This is followed by the details of a general and higher order thermodynamically consistent plate/shell thermoelastic mathematical model that is free of a priori consideration of kinematic assumptions and remains valid for very thin as well as thick plates/shells with comprehensive nonlinear constitutive theories based on integrity. Model problem studies are presented for small deformation behavior of linear elastic plates in the absence of thermal effects and the results are compared with CPT and FSDT mathematical models. 展开更多
关键词 Plate and shell Mathematical models Energy Functional Thermodynamic Consistency Classical Continuum Mechanics Non-Classical Continuum Mechanics Internal Rotations Cosserat Rotations Principle of Virtual Work
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Nonlinear free vibration of piezoelectric semiconductor doubly-curved shells based on nonlinear drift-diffusion model 被引量:1
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作者 Changsong ZHU Xueqian FANG Jinxi LIU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第10期1761-1776,共16页
In this paper, the nonlinear free vibration behaviors of the piezoelectric semiconductor(PS) doubly-curved shell resting on the Pasternak foundation are studied within the framework of the nonlinear drift-diffusion(NL... In this paper, the nonlinear free vibration behaviors of the piezoelectric semiconductor(PS) doubly-curved shell resting on the Pasternak foundation are studied within the framework of the nonlinear drift-diffusion(NLDD) model and the first-order shear deformation theory. The nonlinear constitutive relations are presented, and the strain energy, kinetic energy, and virtual work of the PS doubly-curved shell are derived.Based on Hamilton's principle as well as the condition of charge continuity, the nonlinear governing equations are achieved, and then these equations are solved by means of an efficient iteration method. Several numerical examples are given to show the effect of the nonlinear drift current, elastic foundation parameters as well as geometric parameters on the nonlinear vibration frequency, and the damping characteristic of the PS doublycurved shell. The main innovations of the manuscript are that the difference between the linearized drift-diffusion(LDD) model and the NLDD model is revealed, and an effective method is proposed to select a proper initial electron concentration for the LDD model. 展开更多
关键词 nonlinear free vibration piezoelectric semiconductor(PS)doubly-curved shell nonlinear drift-diffusion(NLDD)model linearized drift-diffusion(LDD)model
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Analytical modeling and vibration analysis of fiber reinforced composite hexagon honeycomb sandwich cylindrical-spherical combined shells 被引量:1
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作者 Hui LI Bocheng DONG +4 位作者 Zhijiang GAO Jing ZHAO Haiyang ZHANG Xiangping WANG Qingkai HAN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第9期1307-1322,共16页
This study analyzes and predicts the vibration characteristics of fiberreinforced composite sandwich(FRCS)cylindrical-spherical(CS)combined shells with hexagon honeycomb core(HHC)for the first time based on an analyti... This study analyzes and predicts the vibration characteristics of fiberreinforced composite sandwich(FRCS)cylindrical-spherical(CS)combined shells with hexagon honeycomb core(HHC)for the first time based on an analytical model developed,which makes good use of the advantage of the first-order shear deformation theory(FSDT),the multi-segment decomposition technique,the virtual spring technology,the Jacobi-Ritz approach,and the transfer function method.The equivalent material properties of HHC are firstly determined by the modified Gibson’s formula,and the related energy equations are derived for the HHC-FRCS-CS combined shells,from which the fundamental frequencies,the mode shapes,and the forced vibration responses are solved.The current model is verified through the discussion of convergence and comparative analysis with the associated published literature and finite element(FE)results.The effects of geometric parameters of HHC on the dynamic property of the structure are further investigated with the verified model.It reveals that the vibration suppression capability can be greatly enhanced by reducing the ratio of HHC thickness to total thickness and the ratio of wall thickness of honeycomb cell to overall radius,and by increasing the ratio of length of honeycomb cell to overall radius and honeycomb characteristic angle of HHC. 展开更多
关键词 analytical modeling cylindrical-spherical(CS)combined shell hexagonal honeycomb core(HHC) fiber reinforced composite(FRC) modified equivalent elastic modulus
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Simulation and model design of pipe-shell reactor for the direct synthesis of dimethyl ether from syngas 被引量:3
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作者 Yanfang Hu Zhaoguang Nie Dingye Fang 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第2期195-200,共6页
The simulation was made based on the model of pipe-shell reactor that was established by the model of global kinetics of synthesis of dimethyl ether from syngas over a bifunctional catalyst. The results of simulation ... The simulation was made based on the model of pipe-shell reactor that was established by the model of global kinetics of synthesis of dimethyl ether from syngas over a bifunctional catalyst. The results of simulation showed that the selectivity for dimethyl ether (DME) and the conversion of CO were higher but the hot spot was kept below the temperature limit of the pipe-shell reactor. The suitable diameter of the pipe was φ38×2 mm, and the length of the pipe was 5.8 m. The optimal process conditions of the reactor were that the pressure was 5 MPa, the temperature of the cooling water was 240 ℃, and the temperature of the raw gas at inlet of the reactor was 220 ℃. The production of this reactor was 102800 t/y (ton per year) under these conditions. 展开更多
关键词 SIMULATION model dimethyl ether pipe-shell reactor SYNGAS
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Finite element modeling of power spinning of thin-walled shell with hoop inner rib 被引量:15
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作者 白倩 杨合 詹梅 《中国有色金属学会会刊:英文版》 EI CSCD 2008年第1期6-13,共8页
A 3D elasto-plastic finite element(FE)model of power spinning of thin-walled aluminum alloy shell with hoop inner rib was established under software ABAQUS.Key technologies were dealt with reasonably.The reliability o... A 3D elasto-plastic finite element(FE)model of power spinning of thin-walled aluminum alloy shell with hoop inner rib was established under software ABAQUS.Key technologies were dealt with reasonably.The reliability of the FE model was verified theoretically and experimentally.The forming process was simulated and studied.The distribution of the thickness and stress,and the variations of spinning force were obtained.The workpiece springback was analyzed with ABAQUS/Standard.The results show that the FE model considering elastic deformation can not only be used to analyze the workpiece springback in the complex spinning process,but also serve as a significant guide to study the local deformation mechanism and choose the reasonable parameters. 展开更多
关键词 铝合金 有限元素模型化 稀有金属 处理方法
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Attractive fixed-point solution study of shell model for homogeneous isotropic turbulence
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作者 郭昊 李超 +1 位作者 屈秋林 刘沛清 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2013年第3期259-268,共10页
The attractive fixed-point solution of a nonlinear cascade model is stud- ied for the homogeneous isotropic turbulence containing a parameter C, introduced by Desnyansky and Novikov. With a traditional constant positi... The attractive fixed-point solution of a nonlinear cascade model is stud- ied for the homogeneous isotropic turbulence containing a parameter C, introduced by Desnyansky and Novikov. With a traditional constant positive external force added on the first shell equation, it can be found that the attractive fixed-point solution of the model depends on both the parameter C and the external force. Thus, an explicit force is introduced to remove the effects of the external force on the attractive fixed-point solu- tion. F^arthermore, two groups of attractive fixed-point solutions are derived theoretically and studied numerically. One of the groups has the same scaling behavior of the velocity in the whole inertial range and agrees well with those observed by Bell and Nelkin for the nonnegative parameters. The other is found to have different scaling behaviors of the velocity at the odd and even number shells for the negative parameters. This special characteristic may be used to study the anomalous scaling behavior of the turbulence. 展开更多
关键词 TURBULENCE shell model attractive fixed-point SCALING
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Physical model of acoustic forward scattering by cylindrical shell and its experimental validation
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作者 雷波 杨坤德 马远良 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第5期369-377,共9页
Research on the underwater target scattering can provide important theoretical support for target detection. The scattering model of cylindrical shell is established in this paper. It is found that the forward target ... Research on the underwater target scattering can provide important theoretical support for target detection. The scattering model of cylindrical shell is established in this paper. It is found that the forward target strength is much stronger and varies with angles of incident wave less significantly than backward target strength. The received forward signal strength fluctuates with the target moving due to the interference between direct signal and scattering signal, which is most significant when the target approaches the baseline. An experiment is carried out in an anechoic tank to validate the scattering model. The method of acquisiting forward scattering in the tank is proposed. The forward and the backward target strengths are achieved by using the pulse compression technology, and they axe about 3dB less than the modeling results. The forward scattering phenomena of quiescent and moving targets are measured, which are similar to modeling results with different target types. 展开更多
关键词 scattering model forward scattering target strength shell
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Analysis of Error Caused by Replacing Spherical Shell with an Elastic Plate Model in Studying Bending Deformation of the Lithosphere
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作者 Wu Hongling Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081 Wang Ren Center for Geodynamics Research, Peking University, Beijing 100871 《Journal of Earth Science》 SCIE CAS CSCD 1998年第2期3-7,共5页
To study the bending deformation of the lithosphere, the simplification of replacing a spherical shell by a plate model is usually made. Based on the differential equations for the bending of plates and shallow spheri... To study the bending deformation of the lithosphere, the simplification of replacing a spherical shell by a plate model is usually made. Based on the differential equations for the bending of plates and shallow spherical shells, an expression for the error caused by such a simplification is derived in this paper. The effect of model sizes on the error is discussed. It is proved that if we replace the shallow spherical shell by a plate model to solve the bending deformation of lithospheric plate, a large error will be caused. In contrast, if we use a plate on an elastic foundation instead, an approximate solution closer to that of spherical shell can be obtained. In such a way, the error can be reduced effectively and the actual geological condition can be modeled more closely. 展开更多
关键词 plate model spherical shell model earth curvature bending deformation of lithosphere.
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Shell and shrinking core kinetics model of Mg-based hydrogen storage alloys
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作者 于振兴 王尔德 +3 位作者 张文丛 房文斌 孙宏飞 梁吉 《中国有色金属学会会刊:英文版》 CSCD 2005年第S2期178-182,共5页
The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption... The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption process with shell diffusion as the controlling step were determined by semi-empirical and semi-theoretical methods, and the apparent activation energy of the hydrogen absorption process was obtained. The calculation results can well accord with the experimental data, and can well forecast the hydrogen storage capacity and absorption rate at different times. By using the kinetics equation, the effects of temperature and pressure on the hydrogen storage process can also be well understood. The kinetics equation is helpful for the design of the hydrogen storage container. 展开更多
关键词 Mg-based ALLOYS hydrogen storage shell and CORE SHRINKING model KINETICS EQUATION
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