On the basis of investigation of molecular structure characteristics of model ferrocene derivatives, the correlation between stability and molecular structure of double-core ferrocene derivatives （DFDs） was studied....On the basis of investigation of molecular structure characteristics of model ferrocene derivatives, the correlation between stability and molecular structure of double-core ferrocene derivatives （DFDs） was studied. Then, the relation of stability of DFDs and impact sensitivity of fine-AP/DFD mixtures was investigated. The results showed that the DFDs with methylene bridge group were more stable than those with methylethylidene bridge group. The stability order of the five DFDs was DEFM〉EDFM≈BDFM〉GFP〉TBPF. The impact sensitivities of the fine-AP/DFD mixtures were in inverse proportion to the stabilities of the DFDs.展开更多
基金We are grateful for the financial support from the joint fund of the National Natural Science Foundation Committee of China Academy of Engineering Physics （NSAF） （No. U1230102）.
文摘On the basis of investigation of molecular structure characteristics of model ferrocene derivatives, the correlation between stability and molecular structure of double-core ferrocene derivatives （DFDs） was studied. Then, the relation of stability of DFDs and impact sensitivity of fine-AP/DFD mixtures was investigated. The results showed that the DFDs with methylene bridge group were more stable than those with methylethylidene bridge group. The stability order of the five DFDs was DEFM〉EDFM≈BDFM〉GFP〉TBPF. The impact sensitivities of the fine-AP/DFD mixtures were in inverse proportion to the stabilities of the DFDs.
