Performance and Application of Double-layered Microcapsule Corrosion Inhibitors

Double-layered microcapsule corrosion inhibitors were developed by sodium monofluorophosphate as the core material,polymethyl methacrylate as the inner wall material,and polyvinyl alcohol as the outer wall material combining the solvent evaporation method and spray drying method.The protection by the outer capsule wall was used to prolong the service life of the corrosion inhibitor.The dispersion,encapsulation,thermal stability of microcapsules,and the degradation rate of capsule wall in concrete pore solution were analyzed by ultra-deep field microscopy,scanning electron microscopy,thermal analyzer,and sodium ion release rate analysis.The microcapsules were incorporated into mortar samples containing steel reinforcement,and the effects of double-layered microcapsule corrosion inhibitors on the performance of the cement matrix and the actual corrosion-inhibiting effect were analyzed.The experimental results show that the double-layered microcapsules have a moderate particle size and uniform distribution,and the capsules were completely wrapped.The microcapsules as a whole have good thermal stability below 230 ℃.The monolayer membrane structure microcapsules completely broke within 1 day in the simulated concrete pore solution,and the double-layer membrane structure prolonged the service life of the microcapsules to 80 days in the simulated concrete pore solution before the core material was completely released.The mortar samples containing steel reinforcement incorporated with the double-layered microcapsule corrosion inhibitors still maintained a higher corrosion potential than the monolayer microcapsule corrosion inhibitors control group at 60 days.The incorporation of double-layered microcapsules into the cement matrix has no significant adverse effect on the setting time and early strength.

Jet formation and penetration performance of a double-layer charge liner with chemically-deposited tungsten as the inner liner

This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.

Time-sequenced damage behavior of reactive projectile impacting double-layer plates

The time-sequenced damage behavior of the reactive projectile impacting double-layer plates is discussed.The analytical model considering the combined effect of kinetic and chemical energy is developed to reveal the damage mechanism.The influences of impact velocity and reactive projectile chemical characteristics on the damage effect are decoupled analyzed based on this model.These analyses indicate that the high energy releasing efficiency and fast reaction propagation velocity of the reactive projectile are conducive to enhancing the damage effect.The experiments with various reactive projectiles impact velocity increasing from 702 to 1385 m/s were conducted to verify this model.The experimental results presented that,the damage hole radius of the rear-plate increases with the increase of impact velocity.At the impact velocity of 1350 m/s,the radius of damage hole formed by PTFE/Al/Bi_(2)O_(3),PTFE/Al/MoO_(3),PTFE/Al/Fe_(2)O_(3)projectile on the rear-plate become smaller in sequence.These results are consistent with the analytical model prediction,demonstrating that this model can predict the damage effect quantitatively.This work is of constructive significance to the application of reactive projectiles.

Gas-and plasma-driven hydrogen permeation behavior of stagnant eutectic-solid GaInSn/Fe double-layer structure

Gas-driven permeation(GDP)and plasma-driven permeation(PDP)of hydrogen gas through Ga In Sn/Fe are systematically investigated in this work.The permeation parameters of hydrogen through Ga In Sn/Fe,including diffusivity,Sieverts'constant,permeability,and surface recombination coefficient are obtained.The permeation flux of hydrogen through Ga In Sn/Fe shows great dependence on external conditions such as temperature,hydrogen pressure,and thickness of liquid Ga In Sn.Furthermore,the hydrogen permeation behavior through Ga In Sn/Fe is well consistent with the multilayer permeation theory.In PDP and GDP experiments,hydrogen through Ga In Sn/Fe satisfies the diffusion-limited regime.In addition,the permeation flux of PDP is greater than that of GDP.The increase of hydrogen plasma density hardly causes the hydrogen PDP flux to change within the test scope of this work,which is due to the dissolution saturation.These findings provide guidance for a comprehensive and systematic understanding of hydrogen isotope recycling,permeation,and retention in plasma-facing components under actual conditions.

Preparation and Microwave Absorbing Properties of Double-layer Fine Iron Tailings Cementitious Materials

To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.

Layered Structural PBAT Composite Foams for Efficient Electromagnetic Interference Shielding

The utilization of eco-friendly,lightweight,high-efficiency and high-absorbing electromagnetic interference(EMI)shielding composites is imperative in light of the worldwide promotion of sustainable manufacturing.In this work,magnetic poly(butyleneadipate-coterephthalate)(PBAT)microspheres were firstly synthesized via phase separation method,then PBAT composite foams with layered structure was constructed through the supercritical carbon dioxide foaming and scraping techniques.The merits of integrating ferroferric oxideloaded multi-walled carbon nanotubes(Fe3O4@MWCNTs)nanoparticles,a microcellular framework,and a highly conductive silver layer have been judiciously orchestrated within this distinctive layered configuration.Microwaves are consumed throughout the process of“absorption-reflection-reabsorption”as much as possible,which greatly declines the secondary radiation pollution.The biodegradable PBAT composite foams achieved an EMI shielding effectiveness of up to 68 dB and an absorptivity of 77%,and authenticated favorable stabilization after the tape adhesion experiment.

Double-Layer-Optimizing Method of Hybrid Energy Storage Microgrid Based on Improved Grey Wolf Optimization

To reduce the comprehensive costs of the construction and operation of microgrids and to minimize the power fluctuations caused by randomness and intermittency in distributed generation,a double-layer optimizing configuration method of hybrid energy storage microgrid based on improved grey wolf optimization(IGWO)is proposed.Firstly,building a microgrid system containing a wind-solar power station and electric-hydrogen coupling hybrid energy storage system.Secondly,the minimum comprehensive cost of the construction and operation of the microgrid is taken as the outer objective function,and the minimum peak-to-valley of the microgrid’s daily output is taken as the inner objective function.By iterating through the outer and inner layers,the system improves operational stability while achieving economic configuration.Then,using the energy-self-smoothness of the microgrid as the evaluation index,a double-layer optimizing configuration method of the microgrid is constructed.Finally,to improve the disadvantages of grey wolf optimization(GWO),such as slow convergence in the later period and easy falling into local optima,by introducing the convergence factor nonlinear adjustment strategy and Cauchy mutation operator,an IGWO with excellent global performance is proposed.After testing with the typical test functions,the superiority of IGWO is verified.Next,using IGWO to solve the double-layer model.The case analysis shows that compared to GWO and particle swarm optimization(PSO),the IGWO reduced the comprehensive cost by 15.6%and 18.8%,respectively.Therefore,the proposed double-layer optimizationmethod of capacity configuration ofmicrogrid with wind-solar-hybrid energy storage based on IGWO could effectively improve the independence and stability of the microgrid and significantly reduce the comprehensive cost.

Design and implementation of the monochromator shielding for the cold neutron spectrometers XINGZHI and BOYA

An innovative monochromator shielding is designed and implemented for the cold neutron spectrometers XINGZHI and BOYA operated by Renmin University of China at China Advanced Research Reactor.Via Monte Carlo simulations and careful mechanical designs,a shielding configuration has been successfully developed to satisfy safety requirements of below 3μSv/h dose rate at its exterior,meanwhile fulfilling space,floor load and nonmagnetic requirements.Composite materials are utilized to form the sandwich-type shielding walls:the inner layer of boron carbide rubber,the middle layer of steel-encased lead and the outer layer of borated polyethylene.Special-shaped liftable shielding blocks are incorporated to facilitate a continuous adjustment of the neutron energy while preventing radiation leakage.Our work has demonstrated that by utilizing composite shielding materials,along with the sandwich structure and liftable shielding blocks,a compact and lightweight shielding solution can be achieved.This enables the realization of advanced neutron scattering instruments that provide expanded space of measurement,larger energy and momentum coverage,and higher flux on the sample.This shielding represents the first of its kind in neutron scattering instruments in China.Following its successful operation,it has been subsequently employed by other neutron instruments across the country.

Hollow Metal-Organic Framework/MXene/Nanocellulose Composite Films for Giga/Terahertz Electromagnetic Shielding and Photothermal Conversion

With the continuous advancement of communication technology,the escalating demand for electromagnetic shielding interference(EMI)materials with multifunctional and wideband EMI performance has become urgent.Controlling the electrical and magnetic components and designing the EMI material structure have attracted extensive interest,but remain a huge challenge.Herein,we reported the alternating electromagnetic structure composite films composed of hollow metal-organic frameworks/layered MXene/nanocellulose(HMN)by alternating vacuum-assisted filtration process.The HMN composite films exhibit excellent EMI shielding effectiveness performance in the GHz frequency(66.8 dB at Kaband)and THz frequency(114.6 dB at 0.1-4.0 THz).Besides,the HMN composite films also exhibit a high reflection loss of 39.7 dB at 0.7 THz with an effective absorption bandwidth up to 2.1 THz.Moreover,HMN composite films show remarkable photothermal conversion performance,which can reach 104.6℃under 2.0 Sun and 235.4℃under 0.8 W cm^(−2),respectively.The unique micro-and macrostructural design structures will absorb more incident electromagnetic waves via interfacial polarization/multiple scattering and produce more heat energy via the local surface plasmon resonance effect.These features make the HMN composite film a promising candidate for advanced EMI devices for future 6G communication and the protection of electronic equipment in cold environments.

Stretchable,Transparent,and Ultra-Broadband Terahertz Shielding Thin Films Based on Wrinkled MXene Architectures

With the increasing demand for terahertz(THz)technology in security inspection,medical imaging,and flexible electronics,there is a significant need for stretchable and transparent THz electromagnetic interference(EMI)shielding materials.Existing EMI shielding materials,like opaque metals and carbon-based films,face challenges in achieving both high transparency and high shielding efficiency(SE).Here,a wrinkled structure strategy was proposed to construct ultra-thin,stretchable,and transparent terahertz shielding MXene films,which possesses both isotropous wrinkles(height about 50 nm)and periodic wrinkles(height about 500 nm).Compared to flat film,the wrinkled MXene film(8 nm)demonstrates a remarkable 36.5%increase in SE within the THz band.The wrinkled MXene film exhibits an EMI SE of 21.1 dB at the thickness of 100 nm,and an average EMI SE/t of 700 dBμm^(−1)over the 0.1-10 THz.Theoretical calculations suggest that the wrinkled structure enhances the film’s conductivity and surface plasmon resonances,resulting in an improved THz wave absorption.Additionally,the wrinkled structure enhances the MXene films’stretchability and stability.After bending and stretching(at 30%strain)cycles,the average THz transmittance of the wrinkled film is only 0.5%and 2.4%,respectively.The outstanding performances of the wrinkled MXene film make it a promising THz electromagnetic shielding materials for future smart windows and wearable electronics.

Research on the design method for uniform wear of shield cutters in sand-pebble strata

During shield tunneling in highly abrasive formations such as sand–pebble strata,nonuniform wear of shield cutters is inevitable due to the different cutting distances.Frequent downtimes and cutter replacements have become major obstacles to long-distance shield driving in sand–pebble strata.Based on the cutter wear characteristics in sand–pebble strata in Beijing,a design methodology for the cutterhead and cutters was established in this study to achieve uniform wear of all cutters by the principle of frictional wear.The applicability of the design method was verified through three-dimensional simulations using the engineering discrete element method.The results show that uniform wear of all cutters on the cutterhead could be achieved by installing different numbers of cutters on each trajectory radius and designing a curved spoke with a certain arch height according to the shield diameter.Under the uniform wear scheme,the cutter wear coefficient is greatly reduced,and the largest shield driving distance is increased by approximately 47%over the engineering scheme.The research results indicate that the problem of nonuniform cutter wear in shield excavation could be overcome,thereby providing guiding significance for theoretical innovation and construction of long-distance shield excavation in highly abrasive strata.

An origami shield with supporting frame structures optimized by a feature-driven topology optimization method

In this paper,the design,manufacture and testing of an origami protective shield with a supporting frame structure are presented.It consists of an origami shield surface and a deployable supporting frame structure that needs to be portable and sufficiently stiff.First,for the design of the shield surface,a threestage origami crease pattern is developed to reduce the shield size in the folded state.The shield surface consists of several stiff modular panels and layered with flexible fabric.The modular panels are made of a multi-layer composite where a ceramic layer is made of small pieces to improve durability as those small pieces enable restriction of crack propagation.Then,the supporting frame structure is designed as a chain-of-bars structure in order to fold into a highly compact state as a bundle of bars and deploy in sequence.Thus,a feature-driven topology structural optimization method preserving component sequence is developed where the inter-dependence of sub-structures is taken into account.A bar with semi-circular ends is used as a basic design feature.The positions of the bar’s end points are treated as design variables and the width of the bars is kept constant.Then,a constraint on the total length of the chain of bars is introduced.Finally,the modular panels made of multi-layer composite and the full-scale prototype of the origami shield are fabricated and tested to verify the bullet-proof performance.

Enhancing the Interaction of Carbon Nanotubes by Metal-Organic Decomposition with Improved Mechanical Strength and Ultra-Broadband EMI Shielding Performance

The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.

Experimental study on the influences of cutter geometry and material on scraper wear during shield TBM tunnelling in abrasive sandy ground

When shield TBM tunnelling in abrasive sandy ground,the rational design of cutter parameters is critical to reduce tool wear and improve tunnelling efficiency.However,the influence mechanism of cutter parameters on scraper wear remains unclear due to the lack of a reliable test method.Geometry and material optimisation are often based on subjective experience,which is unfavourable for improving scraper geological adaptability.In the present study,the newly developed WHU-SAT soil abrasion test was used to evaluate the variation in scraper wear with cutter geometry,material and hardness.The influence mechanism of cutter parameters on scraper wear has been revealed according to the scratch characteristics of the scraper surface.Cutter geometry and material parameters have been optimised to reduce scraper wear.The results indicate that the variation in scraper wear with cutter geometry is related to the cutting resistance,frictional resistance and stress distribution.An appropriate increase in the front angle(or back angle)reduces the cutting resistance(or frictional resistance),while an excessive increase in the front angle(or back angle)reduces the edge angle and causes stress concentration.The optimal front angle,back angle and edge angle for quartz sand samples areα=25°,β=10°andγ=55°,respectively.The wear resistance of the modelled scrapers made of different metal materials is related to the chemical elements and microstructure.The wear resistances of the modelled scrapers made of 45#,06Cr19Ni10,42CrMo4 and 40CrNiMoA are 0.569,0.661,0.691 and 0.728 times those made of WC-Co,respectively.When the alloy hardness is less than 47 HRC(or greater than 58 HRC),scraper wear decreases slowly with increasing alloy hardness as the scratch depth of the particle asperity on the metal surface stabilizes at a high(or low)level.However,when the alloy hardness is between 47 HRC and 58 HRC,scraper wear decreases rapidly with increasing alloy hardness as the scratch depth transitions from high to low levels.The sensitive hardness interval and recommended hardness interval for quartz sand are[47,58]and[58,62],respectively.The present study provides a reference for optimising scraper parameters and improving cutterhead adaptability in abrasive sandy ground tunnelling.

A shield of defense:Developing ballistic composite panels with effective electromagnetic interference shielding absorption

The primary goal of this study is to develop cost-effective shield materials that offer effective protection against high-velocity ballistic impact and electromagnetic interference(EMI)shielding capabilities through absorption.Six fiber-reinforced epoxy composite panels,each with a different fabric material and stacking sequence,have been fabricated using a hand-layup vacuum bagging process.Two panels made of Kevlar and glass fibers,referred to as(K-NIJ)and(G-NIJ),have been tested according to the National Institute of Justice ballistic resistance protective materials test NIJ 0108.01 Standard-Level IIIA(9 mm×19 mm FMJ 124 g)test.Three panels,namely,a hybrid of Kevlar and glass(H-S),glass with ceramic particles(C-S),and glass with recycled rubber(R-S)have been impacted by the bullet at the center,while the fourth panel made of glass fiber(G-S)has been impacted at the side.EMI shielding properties have been measured in the X-band frequency range via the reflection-transmission method.Results indicate that four panels(K-NIJ,G-NIJ,H-S,and G-S)are capable of withstanding high-velocity impact by stopping the bullet from penetrating through the panels while maintaining their structural integrity.However,under such conditions,these panels may experience localized delamination with variable severity.The EMI measurements reveal that the highest absorptivity observed is 88% for the KNIJ panel at 10.8 GHz,while all panels maintain an average absorptivity above 65%.All panels act as a lossy medium with a peak absorptivity at different frequencies,with K-NIJ and H-S panels demonstrating the highest absorptivity.In summary,the study results in the development of a novel,costeffective,multifunctional glass fiber epoxy composite that combines ballistic and electromagnetic interference shielding properties.The material has been developed using a simple manufacturing method and exhibits remarkable ballistic protection that outperforms Kevlar in terms of shielding efficiency;no bullet penetration or back face signature is observed,and it also demonstrates high EMI shielding absorption.Overall,the materials developed show great promise for various applications,including the military and defense.

Gradient coil design with enhanced shielding constraint for a cryogen-free superconducting MRI system

The relatively fragile low-temperature stability of cryogen-free superconducting magnetic resonance imaging(MRI)magnets requires the careful management of exogenous heat sources.A strongly shielded gradient magnetic field is important for the optimal operation of cryogen-free MRI systems.In this study,we present an enhanced shielding method incorporating a regionalized stray field constraining strategy.By optimizing the constraint parameters,we could develop engineering-feasible gradient coil schemes without increasing system complexity but with the stray field intensity reduced by half.In real measurement in an integrated MRI system,the developed gradient assembly demonstrated good performance and supported to output images of excellent quality.Our findings suggested that the proposed method could potentially form a useful design paradigm for cryogen-free MRI magnets.

Self‑Assembly of Binderless MXene Aerogel for Multiple‑Scenario and Responsive Phase Change Composites with Ultrahigh Thermal Energy Storage Density and Exceptional Electromagnetic Interference Shielding

The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs.

Flexible, Transparent and Conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding

Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant challenge.Herein,a flexible,transparent,and conductive copper(Cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating technique.The Cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending cycles.As a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°C within 60 s at 1.00 V applied voltage.Moreover,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μm.As a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic waves.Therefore,the flexible and transparent conductive Cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications.

Determination of the critical rainfall of runoff-initiated debris flows by the perspective of physical mechanics and Shields stress

The critical rainfall of runoff-initiated debris flows is utmost importance for local early hazard forecasting.This paper presents research on the critical rainfall of runoff-initiated debris flows through comparisons between slope gradients and three key factors,including topographic contributing area,dimensionless discharge,and Shields stress.The rainfall amount was estimated by utilizing in-situ rainfall records and a slope-dependent Shields stress model was created.The created model can predict critical Shields stress more accurately than the other two models.Furthermore,a new dimensionless discharge equation was proposed based on the corresponding discharge-gradient datasets.The new equation,along with factors such as contributing area above bed failure sites,channel width,and mean diameter of debris flow deposits,predicts a smaller rainfall amount than the in-situ measured records.Although the slope-dependent Shields stress model performs well and the estimated rainfall amount is lower than the in-situ records,the sediment initiation in the experiments falls within sheet flow regime due to a large Shields stress.Therefore,further sediment initiation experiments at a steeper slope range are expected in the future to ensure that the sediment transport belongs to mass failure regime characterized by a low level of Shields stress.Finally,a more accurate hazard forecast on the runoff-initiated debris flow holds promise when the corresponding critical slope-dependent dimensionless discharge of no motion,fluvial sediment transport,mass flow regime,and sheet flow regime are considered.

3D‑Printed Carbon‑Based Conformal Electromagnetic Interference Shielding Module for Integrated Electronics

Electromagnetic interference shielding(EMI SE)modules are the core com-ponent of modern electronics.However,the tra-ditional metal-based SE modules always take up indispensable three-dimensional space inside electronics,posing a major obstacle to the integra-tion of electronics.The innovation of integrating 3D-printed conformal shielding(c-SE)modules with packaging materials onto core electronics offers infinite possibilities to satisfy ideal SE func-tion without occupying additional space.Herein,the 3D printable carbon-based inks with various proportions of graphene and carbon nanotube nanoparticles are well-formulated by manipulating their rheological peculiarity.Accordingly,the free-constructed architectures with arbitrarily-customized structure and multifunctionality are created via 3D printing.In particular,the SE performance of 3D-printed frame is up to 61.4 dB,simultaneously accompanied with an ultralight architecture of 0.076 g cm^(-3) and a superhigh specific shielding of 802.4 dB cm3 g^(-1).Moreover,as a proof-of-concept,the 3D-printed c-SE module is in situ integrated into core electronics,successfully replacing the traditional metal-based module to afford multiple functions for electromagnetic compatibility and thermal dissipa-tion.Thus,this scientific innovation completely makes up the blank for assembling carbon-based c-SE modules and sheds a brilliant light on developing the next generation of high-performance shielding materials with arbitrarily-customized structure for integrated electronics.