Disinfection Byproducts and Their Precursors in Drinking Water Sources:Origins,Influencing Factors,and Environmental Insights

Tracing the contamination origins in water sources and identifying the impacts of natural and human processes are essential for ecological safety and public health.However,current analysis approaches are not ideal,as they tend to be laborious,time-consuming,or technically difficult.Disinfection byproducts(DBPs)are a family of well-known secondary pollutants formed by the reactions of chemical disinfectants with DBP precursors during water disinfection treatment.Since DBP precursors have various origins(e.g.,natural,domestic,industrial,and agricultural sources),and since the formation of DBPs from different precursors in the presence of specific disinfectants is distinctive,we argue that DBPs and DBP precursors can serve as alternative indicators to assess the contamination in water sources and identify pollution origins.After providing a retrospective of the origins of DBPs and DBP precursors,as well as the specific formation patterns of DBPs from different precursors,this article presents an overview of the impacts of various natural and anthropogenic factors on DBPs and DBP precursors in drinking water sources.In practice,the DBPs(i.e.,their concentration and speciation)originally present in source water and the DBP precursors determined using DBP formation potential tests—in which water samples are dosed with a stoichiometric excess of specific disinfectants in order to maximize DBP formation under certain reaction conditions—can be considered as alternative metrics.When jointly used with other water quality parameters(e.g.,dissolved organic carbon,dissolved organic nitrogen,fluorescence,and molecular weight distribution)and specific contaminants of emerging concern(e.g.,certain pharmaceuticals and personal care products),DBPs and DBP precursors in drinking water sources can provide a more comprehensive picture of water pollution for better managing water resources and ensuring human health.

Application of Ice Pigging in a Drinking Water Distribution System:Impacts on Pipes and Bulk Water Quality

Ice pigging is an emerging technique for pipe cleaning in drinking water distribution systems.However,substantial confusion and controversy exist on the potential impacts of ice pigging on bulk water quality.This study monitored the microstructural features and composition of sediments and microbial community structures in bulk water in eight multimaterial Chinese networks.Chloride concentration analysis demonstrated that separate cleaning of pipes with different materials in complex networks could mitigate the risk of losing ice pigs and degrading water quality.The microstructural and trace element characterization results showed that ice pigs would scarcely disturb the inner surfaces of long-used pipes.The bacterial richness and diversity of bulk water decreased significantly after ice pigging.Furthermore,correlations were established between pipe service age,temperature,and chloride and total iron concentrations,and the 15 most abundant taxa in bulk water,which could be used to guide practical ice pigging operations.

Gross Alpha and Beta Activities and Related Lifetime Risks Assessment Due to Ingestion of Drinking Water from Different Sources in the District of Abidjan, Cote d’Ivoire

Drinking good quality water is essential for better health. It is therefore essential to assess the radiological quality of all water consumed in the District of Abidjan in order to prevent related hazards. Thus, the objective of this study was to assess the risk of cancer due to the ingestion of alpha and beta emitting radionuclides in the different types of water consumed in the region. A total of 63 water samples with 43 tap water samples, 5 bottled mineral water and 15 sachet water samples was collected and taken to GAEC laboratory for analysis. The low background Gas-less Automatic Alpha/Beta counting system (Canberra iMaticTM) was used to determine alpha and beta activity concentrations. Activity concentrations of both gross alpha and gross beta obtained in water sample were respectively lower than the WHO recommended limits of 0.1 Bq/l and 1 Bq/l. Also, the annual effective dose and total equivalent effective dose found in mineral bottled water samples were higher than in other types of water. The assessment of radiological lifetime risk has shown values of cancer risk due to ingestion alpha and beta emitters lower than recommended limit. These results indicate that there is no health hazard associated to consumption of water in the District of Abidjan.

A review of physicochemical and biological contaminants in drinking water and their impacts on human health

Clean drinking water is one of the United Nations Sustainable Development Goals.Despite significant progress in the water purification technology,many regions still lack access to clean water.This paper provides a review of selected water contaminants and their impacts on human health.The World Health Organization(WHO)guidelines and regional standards for key contaminants were used to characterise water quality in the European Union and UK.The concept of safe drinking water was explained based on the non-observed adverse effect level,threshold concentrations for toxic chemicals,and their total daily intake.Various techniques for monitoring water contaminants and the drinking water standards from five different countries,including the UK,USA,Canada,Pakistan and India,were compared to WHO recommended guidelines.The literature on actual water quality in these regions and its potential health impacts was also discussed.Finally,the role of public water suppliers in identifying and monitoring drinking water contaminants in selected developed countries was presented as a potential guideline for developing countries.This review emphasised the need for a comprehensive understanding of water quality and its impacts on human health to ensure access to clean drinking water worldwide.

Study on the Possibility of Raw Seawater into Drinking Water—A Religious Water Literacy

This paper explores the conversion of raw seawater into drinking water from a religious water literacy (RWL) perspective. RWL is here defined as a socially just water literacy that is based on the respect for the dignity of life of all living beings on the Earth. It discusses the importance of sustainable water sources and proposes purification methods. That is, the study aims to show a brief outline of the drinking water source (inland waters;mainly river water) and their purification technologies in recent times and today and propose the purification method (Freezing-Thawing-UV method) in case of taking the seawater as the source. And, it emphasizes the need for dialogue and cooperation between countries in order to proceed. The paper also discusses the relationship among religion, culture, and civilization, and highlights the similarities between Marx’s historical materialism and Umesao’s ecological view. It further discusses the importance of water purification technology, separation methods, and the potential for seawater as an energy source. The paper concludes by discussing the importance of dialogue, communication and understanding environmental decision-making. In order to carry them forward, it is convinced that citizens in the world are nothing but people with self-awareness of “Bodhisattvas of the Earth” as identities. As a result, the new findings that suggest the possibility of raw seawater into drinking water from a religious water literacy perspective through the lens of Kawakatsu’s maritime view have been obtained.

Impact of the Condition of Drinking Water Supply Networks on the Quality of Water Intended for Consumption: The Case of the Network in the Commune of Daloa (Central West of Côte d’Ivoire)

The potability of drinking water depends not only on the source and the treatment system, but also on the quality of the waterworks. In fact, the quality of drinking water is considerably degraded by the dilapidated state and lack of maintenance of drinking water networks. In Côte d’Ivoire, the majority of drinking water networks in the various towns are ageing. In Daloa, despite the efforts made by the company in charge of water treatment and distribution to make the water drinkable, the water at consumers’ taps is often colored, has an unpleasant aftertaste and settles after collection. As a result, people are concerned about the potability of tap water, and some are turning to alternative sources of drinking water of unknown quality. In order to determine the factors responsible for the deterioration in water color and taste, as well as the sectors of the network most affected, a diagnosis of the network’s equipment was carried out. Water samples taken from the network were analyzed for color and turbidity. The diagnosis revealed that most of the equipment (suction pads, valves, drains and fire hydrants) is outdated and irregularly maintained. Analyses show that the water is more colored in cast-iron and PVC pipes than in asbestos cement pipes. Coloration values in the network range from 0 to 27 UVC for asbestos cement pipes, from 15 to 56 UCV for ductile iron pipes, and from 11 to 102 UCV for PVC pipes. On the over hand, turbidity values vary from 8.02 to 3.32 NTU for ductile cast iron pipes, 8.51 to 16.98 NTU for asbestos cement pipes and 0.9 to 6.98 NTU for PVC pipes. Old cast-iron pipes release ferric ions on contact with water, degrading their color. Old cast-iron pipes release ferric ions into the water, degrading its color. The high color values observed in the vicinity of drains are thought to be due to irregular maintenance of the network. In fact, after network maintenance, a reduction rate ranging from 2% to 73% is observed for turbidity, while for color, the rate varies from 5% to 72%. In short, the network’s obsolescence and irregular maintenance contribute significantly to the deterioration of water quality.

Legislation on protection of drinking water sources and local management practices in the Pearl River Delta region of China

The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.

Drinking water and liver cancer *

AIM To study the relationship between mutagenicity of drinking water and incidence of liver cancer in high liver cancer incidence areas in Guangxi.

Drinking water production by uitrafiltration of Songhuajiang River with PAC adsorption

In recent years, membrane ultrafiltration （UF） of surface water for drinking water treatment has become a more attractive technology worldwide as a possible alternative treatment to conventional clarification. To evaluate the performance of ultrafiltration membranes for treatment of surface water in North China, a 48-m^2 low pressure hollow fiber membrane ultrafiltration pilot plant was constructed. Ultrafiltration was operated in cross-flow and with powdered activated carbon （PAC） adsorption. Turbidity was almost completely removed to less than 0.2 NTU （below Chinese standard 1 NTU）. It was found that PAC addition enhanced organic matter removal. The combined process of PAC/UF allowed to 41% removal of CODMn, 46% removal of DOC and 57% decrease in UV254 absorbance. The elimination of particles, from average 12000/ml in the raw water to approximately 15/ml in the permeated, was observed. When PAC concentration was below 30 mg/L, backwashing could recovery the membrane flux with backwash interval/backwashing duration of 1/30.

Relationship Between Microcystin in Drinking Water and Colorectal Cancer

Objective To investigate the association of microcystin (MC) in drinking water with the incidence of colorectal cancer. Methods The study was designed as a retrospective cohort. Eight townships or towns were randomly selected as the study sites in Haining City of Zhejiang Province, China. 408 cases of colon and rectum carcinomas diagnosed from 1977 to 1996 in the study sites were included, and a survey on types of drinking water of these patients was conducted. Samples of different water sources (well, tap, river and pond) were collected separately and microcystin concentrations were determined by indirect competitive ELISA method. Results The incidence rate of colorectal cancer was significantly higher in population who drank river and pond water than those who drank well and tap water. Compared to well water, the relative risk (RR) for colorectal cancer was 1.88 (tap), 7.94 (river) and 7.70 (pond) respectively. The positive rate (>50 pg/mL) of microcystin in samples of well, tap, river and pond water was 0, 0, 36.23% and 17.14% respectively. The concentration of microcystin in river and pond water was significantly higher than that in well and tap water (P<0.01). Spearman rank correlation analysis showed that in the study sites, the microcystin concentration of river and pond water was positively associated with the incidence of colorectal cancer (rs= 0.881, P<0.01). Conclusions The types of drinking water are positively associated with the incidence of colorectal cancer in the study sites, and this may be related to microcystin contamination of drinking water. Further biological study is needed to support the possible causative role of mycrocystin in carcinogenesis of colon and rectum.

Genotoxicity evaluation and a primary risk assessment of organic pollutants in the drinking water sources of Nanjing, China

An increasing number of industrial, agricultural, and commercial chemicals in the aquatic environment leads to various deleterious effects on organisms, which is becoming an increasingly serious problem in China. In this study, the comet assay was conducted to investigate the genotoxicity to human body caused by organic concentrates in the drinking water sources of Nanjing City from Yangtze River of China, and health and ecology risk due to expose to these organic pollutants were evaluated with the multimedia environmental assessment system （MEAS）. For all the water samples, they were collected from four different locations in the drinking water sourcr samples, es of Nanjing City. The results of the comet assay showed that all the organic concentrates from the water samples could induce different levels DNA damages on human peripheral blood lymphocytes, and a statistically significant difference （p〈0.01） was observed compared with the solvent control, which demonstrated the genotoxicity was in existence. According to the ambient severity （AS） of individual compound, we had sorted out the main organic pollutants in the drinking water source of the four waterworks, and the results showed that there was some potential hazard to human body for all the source water, namely the total ambient severity （TAS） of health for each water source was more than 1. However, the TAS of ecology for each water source was less than 1, which indicated that it was safe to ecology. The results of this investigation demonstrate the application of the comet assay and the MEAS in aquatic environmental monitoring studies, and the comet assay found to be fast, sensitive, and suitable for genotoxicity monitoring programs of drinking water source.

Effects of fulvic acid and humic acid on aluminum speciation in drinking water

This article focused on the influences of fulvic acid and humic acid on aluminum speciation in drinking water. Factors including the concentration of residual chlorine and pH value had been concerned. Aluminum species investigated in the experiments included inorganic mononuclear, organic mononuclear, mononuclear, polymer, soluble, and suspended forms. It was found that the effects of fulvic acid and humic acid on aluminum speciation depended mainly on their molecular weight. Fulvic acid with molecular weight less than 5000 Dalton had little influence on aluminum speciation; while fulvic acid with molecular weight larger than 5000 Dalton and humic acid would increase the concentration of soluble aluminum significantly even at concentration below 0.5 mg/L （calculated as TOC）. Aluminum species, in the present of fulvic acid with molecular weight larger than 5000 Dalton and humic acid, were more stable than that in the present of fluvic acid with molecular mass less than 5000 Dalton, and varied little with reaction time. Within pH range 6.5-7.5, soluble aluminum increased notably in water with organic matter. As the concentration of residual chlorine increased, the effects of fulvic acid and humic acid became weak. The reactions between humic acid, fulvic acid with large molecular weight, and aluminum were considered to be a multi-dentate coordination process. With the consideration of aluminum bioavailability, reducing the concentration of fulvic acid and humic acid and keeping the pH value among 6.5-7.5 were recommended during drinking water treatment.

Particle properties in granular activated carbon filter during drinking water treatment

The elemental composition and bacteria attached in particles were investigated during granular activated carbon （GAC） filtration.The experimental results showed that trapped influent particles could form new,larger particles on GAC surface.The sloughing of individuals off GAC surface caused an increase in effluent particles in the size range from 5 to 25 μm.The selectivity for element removal in GAC filters caused an increasing proportion of metallic elements in the effluent particles.The distribution of molar ratio indicated a complicated composition for large particles,involving organic and inorganic substances.The organic proportion accounted for 40% of total carbon attached to the particles.Compared with dissolved carbon,there was potential for the formation of trihalomethanes by organic carbon attached to particles,especially for those with size larger than 10 μm.The pure carbon energy spectrum was found only in the GAC effluent and the size distribution of carbon fines was mainly above 10 μm.The larger carbon fines provided more space for bacterial colonization and stronger protection for attached bacteria against disinfection.The residual attached bacteria after chorine disinfection was increased to 10 2-10 3 CFU/mL within 24 hours at 25°C.

Occurrence of Haloacetic Acids in Drinking Water in Certain Cities of China

Objective Since haloacetic acids (HAAs), which are nonvolatile and of high carcinogenic risk, are common species of chlorinated disinfection by-products(DBPs) in drinking water, and little has been known in China, it is necessary to make a survey about the kinds and levels of HAAs in drinking water of the nation. Method HAAs were analyzed using gas chromatography with electron capture detector(GC/ECD) and relatively complex pretreatment process of sample was applied. Five main cities in different areas of China were chosen in the survey. Results Studies showed that the main species of HAAs in drinking water in China were DCAA and TCAA, ranging from 0.4 礸/L to 12.85 礸/L and from 0.56 礸/L to 10.98 礸/L, respectively. MBAA and DBAA were also detected in one city, ranging from 2.20 礸/L to 4.95 礸/L and 1.10 礸/L to 2.81 礸/L, respectively. Therefore, the contents of HAAs varied, usually no more than 25 礸/L. Based on the acquired data to date, it is known that the concentrations of HAAs in drinking water in China were surely under the limits of Sanitary Standard for Drinking Water Quality (China, 2001). Conclusion A wider survey of HAAs in drinking water should be conducted throughout the nation to get adequate data and information, the ultimate aim of which is to control HAAs pollution and keep the balance between microbiological safety insurance and chemical risk control, minimize the formation of DBPs and ensure the safety of water supply at the same time.

Application of PCR-DGGE in Research of Bacterial Diversity in Drinking Water

Objective To analyze the structure of bacteria in drinking water by molecular biological techniques, Methods DNA of bacteria in drinking water was directly extracted without culture. 16S ribosomal DNA fragments, including V-6, -7, and -8 regions, were amplified with universal primers （EUBf933CJC and EUBr1387） and analyzed by DGGE. Results DGGE indicated that amplification products could be separated, The results showed that DGGE could be used in the separation of different microbial 16SrRNA genes extracted from drinkng water. Though there were special bacteria in different water samples, the predominant bacteria were essentially the same. Three sequences of the reclaimed specific bands were obtained, and phylogenetic tree of these bands was made. Conclusion Bacterial diversity in drinking water is identified by molecular biological techniques.

Performance of microbiological control by a point-of-use filter system for drinking water purification

Purification capacity of a faucet mounted type water filter for home use was evaluated, particularly with regard to microbiological performance under different running conditions. Biofilms were formed inside the filter, affecting the bacterial quality of the effluent water. Low flow rate, long stagnation period and high filter temperature were found favorable for bacterial growth inside. By commercial analytical profile index （API） kits, ten different bacterial species were identified in drinking water, four of which were probably contributed to the biofilm formation since they were also present in the biofilm. Fluorescence in situ hybridization （FISH） was used to confirm the API identification results, and direct viable count （DVC） method was employed to improve the sensitivity of FISH for the isolated Acinetobacter spp. and Pseudomonas putida as models. Relationship between the filter operating condition and the bacterial community alteration was partly revealed, which could provide the basic knowledge for the filter design and its practical use.

Factors effecting aluminum speciation in drinking waterby laboratory research

Effects of aluminum on water distribution system and human health mainly attribute to its speciation in drinking water. Laboratory experiments were performed to investigate factors that may influence aluminum speciation in water supply system. The concentration of soluble aluminum and its transformation among other aluminum species were mainly controlled by kinetics processes of related reactions. Total aluminum concentration had a notable effect on the concentrations of mononuclear and soluble aluminum in the first 4 day; then its effect became weak. At pH above 7.50, both fluoride and orthophosphate had little effect on aluminum speciation; while, when the solution pH was below 7.50, the concentrations of mononuclear and soluble aluminum were proportional to the concentration of fluoride and inversely proportional to the concentration of orthophosphate. Both mononuclear and polynuclear silicic acids could complex with mononuclear aluminum by forming soluble aluminosilicates. In addition, the adding sequence of orthophosphate and aluminum into drinking water would also affect the distribution of aluminum species in the first 4 day. In order to minimize aluminum bioavailability in drinking water, it was suggested that orthophosphate should be added prior to coagulant process, and that the concentrations of fluoride and silicic acids should be controlled below 2.0 and 25 mg/L, respectively, prior to the treatment. The solution pH in coagulation and filtration processes should be controlled in the range of 6.50-7.50.

Spatial variation of health risk of groundwater for drinking water supply in Mingshan County,Ya'an City,China

Rural drinking water safety is a growing concern in China. This study investigated the health risk of pollution of groundwater for the drinking water supply in Mingshan County, Ya＇an City, in Sichuan Province, China, using 46 samples from the years 1991 to 2010. Carcinogenic, non-carcinogenic, and total risks were assessed by the model recommended by the United States Environmental Protection Agency （U.S. EPA）. Thematic maps of the risks caused by single and multiple factors were generated from inverse distance weighting interpolation （IDW） and the geostatistical analysis functions of ArcGIS. The results show that the carcinogenic risks caused by chemicals in groundwater for drinking water supply are low, within the acceptable interval for risk management. However, non-carcinogenic risks are high and the number of sampling sites with risk values exceeding the standards amounted to 29. Non-carcinogenic risks of Cr6＋, nitrate, fluoride, and Fe at sites 43, 46, 50, 64, 67, and 74 were the sources that caused high total health risk. This study reveals the risk level of groundwater quality and orders of treatment of pollutants, and provides a scientific basis for groundwater management in this area.

Particle size distribution and property of bacteria attached to carbon fines in drinking water treatment

The quantitative change and size distribution of particles in the effluents from a sand filter and a granular activated carbon （GAC） filter in a drinking water treatment plant were investigated. The average total concentration of particles in the sand filter effluent during a filter cycle was 148 particles/mL, 27 of which were larger than 2 μm in size. The concentration in the GAC effluent （561 particles/mL） was significantly greater than that in the sand filter effluent. The concentration of particles larger than 2 μm in the GAC filter effluent reached 201 particles/mL, with the amount of particles with sizes between 2 μm and 15 μm increasing. The most probable number （MPN） of carbon fines reached 43 unit/L after six hours and fines between 0.45 μm and 8.0 μm accounted for more than 50%. The total concentration of outflowing bacteria in the GAC filter effluent, 350 CFU （colony-forming units） /mL, was greater than that in the sand filter effluent, 210 CFU/mL. The desorbed bacteria concentration reached an average of 310 CFU/mg fines. The disinfection efficiency of desorbed bacteria was lower than 40% with 1.5 mg/L of chlorine. The disinfection effect showed that the inactivation rate with 2.0 mg/L of chloramine （90%） was higher than that with chlorine （70%）. Experimental results indicated that the high particle concentration in raw water and sedimentation effluent led to high levels of outflowing particles in the sand filter effluent. The activated carbon fines in the effluent accounted for a small proportion of the total particle amount, but the existing bacteria attached to carbon fines may influence the drinking water safety. The disinfection efficiency of desorbed bacteria was lower than that of free bacteria with chlorine, and the disinfection effect on bacteria attached to carbon fines with chloramine was better than that with only chlorine.

Researches on Formation of Haloacetic Acids in Chlorination of Drinking Water by a Novel Technique

Haloacetic acids(HAAs) are formed during the chlorination of drinking water,which are harmful to people′s health due to their carcinogenic and mutagenic effects. In the present study,a detection method combining methyl tert -butyl ether(MtBE) extraction with acid catalysis and gas chromatography coupled with an electron capture detector(GC/ECD) was developed for determining HAAs. The detection limit of this method(MDL) and relative standard deviation(RSD) were below 0.37 μg/L and 6.2%,respectively. The laboratory chlorination experiments were conducted with the purpose of investigating the influences of reaction time,temperature,UV_ 254 ,bromide and ammonia-nitrogen on the formation of HAAs. The results show that the formation amount of HAAs increases with increasing reaction time and temperature,respectively;and there exists a linear relationship between the formation of HAAs and UV_ 254 . The formation amount of HAAs decreases first and then increases as the bromide ion concentration increases,and adding NH +_4 is a possible way to control the formation of HAAs.