A combined computational/experimental study of anode-concerned voltage drop in aqueous primary Mg-air batteries

The voltage drop appearing at Mg anode-electrolyte interface is a critical issue for the battery power and energy density of aqueous primary Mg-air batteries.The respective voltage loss is typically assigned to the deposits layer forming on the anode surface during discharge.In this work,we experimentally and computationally investigate the critical factors affecting the voltage drop at Mg anode towards a deeper understanding of the contribution of deposit and its growth.A two-dimensional(2D)mathematical model is proposed to compute the voltage drop of Mg-0.15Ca wt.%alloy(Mg-0.15Ca)by means of a semi-empirical formulas and experiments-based modification model,considering the effect of discharge current density,the negative difference effect(NDE)and surface deposits layer itself.This model is utilized to simulate the discharge potential of the anode at predefined experimental current densities.The computed voltage drop(half-cell voltage)is in good agreement with the experimental value.The applicability of the mathematical model is successfully validated on the second material(namely high-purity Mg).

Study of main factors influencing unsteady-state temperature drop in oil tank storage under dynamic thermal environment coupling

With the increasing oil demand, the construction of oil energy reserves in China needs to be further strengthened. However, given that there has been no research on the main influencing factors of crude oil temperature drop in storage tanks under actual dynamically changing environments, this paper considers the influence of dynamic thermal environment and internal crude oil physical properties on the fluctuating changes in crude oil temperature. A theoretical model of the unsteady-state temperature drop heat transfer process is developed from a three-dimensional perspective. According to the temperature drop variation law of crude oil storage tank under the coupling effect of various heat transfer modes such as external forced convection, thermal radiation, and internal natural convection, the external dynamic thermal environment influence zone, the internal crude oil physical property influence zone, and the intermediate transition zone of the tank are proposed. And the multiple non-linear regression method is used to quantitatively characterize the influence of external ambient temperature, solar radiation, wind speed, internal crude oil density, viscosity, and specific heat capacity on the temperature drop of crude oil in each influencing zone. The results of this paper not only quantitatively explain the main influencing factors of the oil temperature drop in the top, wall, and bottom regions of the tank, but also provide a theoretical reference for oil security reserves under a dynamic thermal environment.

In Tube Condensation:Changing the Pressure Drop into a Temperature Difference for a Wire-on-Tube Heat Exchanger

A theoretical study based on the Penalty factor(PF)method by Cavallini et al.is conducted to show that the pressure drop occurring in a wire-on-tube heat exchanger can be converted into a temperature difference for two types of refrigerants R-134a and R-600a typically used for charging refrigerators and freezers.The following conditions are considered:stratified or stratified-wavyflow condensation occurring inside the smooth tube of a wire-on-tube condenser with diameter 3.25,4.83,and 6.299 mm,condensation temperatures 35℃,45℃,and 54.4℃ and cover refrigerant massflow rate spanning the interval from 1 to 7 kg/hr.The results show that the PF variation is not linear with vapor quality and attains a maximum when the vapor quality is 0.2 and 0.18 for the R-134a and R-600a refrigerants,respectively.The PF increases with the refrigerant massflow rate if the inner diameter and saturation temperature constant,and it decreases on increasing the inner diameter to 6.299 mm for constant refrigerant massflow rate and saturation temperature.The PF for R-600a is higher than that for R-134a due to the lower saturation pressure in thefirst case.Furthermore,a stratifiedflow produces higher PF in comparison to the annularflow due to the effect of the surface tension.

Rear-Surface Deformation of a Water Drop in Aero-Breakup of Shear Mode

Deformation of water drops in shock-induced high-speed flows is investigated with a focus to the influence of primitive flow parameters on the rear-surface deformation features. Two typical deformation patterns are discovered through high-speed photography. A simple equation to evaluate the radial acceleration of the drop surface is derived. The combined use of this equation and outer flow simulation makes it possible for us to reconstruct the profiles of the early deformed drops. The results agree well with the experiments. Further analysis shows that the duration of flow establishment with respect to the overall breakup time shapes the rear side profile of the drop. Thereby the ratio of the two times, expressed as the square root of the density ratio, appears to be an effective indicator of the deformation features.

On the excavation-induced stress drop in damaged coal considering a coupled yield and failure criterion

Investigating the stress drop of abutment pressure is the key to a deep quantitative analysis of the discontinuous stress redistribution under mining.In the present study,uniaxial and triaxial compression tests are carried out separately to determine the bulk and shear moduli,the cohesion,and the internal friction angle of the coal samples.By extending the meaning of Mohr’s circle referring to yield stress instead of the maximum principal stress,a yield line is introduced to illustrate the stress drop of Mohr’s circle referring to yield stress instead of the maximum principal stress at the elastoplastic boundary.Furthermore,a theoretical solution of the stress drop as a function of the damage is proposed to investigate how the abutment pressure differs considering the yield line and failure line.In addition,applying the stress drop at the yield line in non-pillar mining,top coal mining,and protective coal mining shows that the damage has a nonlinearly positive influence on the stress drop.The results shows that the bulk modulus and internal friction angle have a more sensitive influence on the stress drop than do the shear modulus and cohesion.Finally,the stress drop is divided into a discontinuous stress drop at the yield line and a structural stress drop at the failure line.The stress drop is effective in describing the discontinuous stress redistribution and shows a clear difference in the movement direction of Mohr’s circle considering the unloading pressure.

Analysis of MHD Pressure Drop in Liquid LiPb Flow in Chinese ITER DFLL-TBM with Insulating Coating

Magnetohydrodynamic （MHD） pressure drop in the Chinese Dual Functional Liquid Lithium-lead Test Blanket Module （DFLL-TBM） proposed for ITER is discussed in this paper. Electrical insulation between the coolant channel surfaces and the liquid metal is required to reduce the MHD pressure drop to a manageable level. Insulation can be provided by a thin insulating coating, such as Al2O3, which can also serve as a tritium barrier layer, at the channel surfaces in contact with LiPb. The coating＇s effectiveness for reducing the MHD pressure drop is analysed through three-dimensional numerical simulation. A MHD-based commercial computational fluid dynamic （CFD） software FLUENT is used to simulate the LiPb flow. The effect on the MHD pressure drop due to cracks or faults in the coating layer is also considered. The insulating performance requirement for the coating material in DFLL-TBM design is proposed according to the analysis.

Effect of nozzle geometry on pressure drop in submerged gas injection

Submerged gas injection into liquid leads to complex multiphase flow, in which nozzle geometries are crucial important for the operational expenditure in terms of pressure drop. The influence of the nozzle geometry on pressure drop between nozzle inlet and outlet has been experimentally studied for different gas flow rates and bath depths. Nozzles with circular, gear-like and four-leaf cross-sectional shape have been studied. The results indicate that, besides the hydraulic diameter of the outlet, the orifice area and the perimeter of the nozzle tip also play significant roles. For the same superficial gas velocity, the average pressure drop from the four-leaf-shaped geometry is the least. The influence of bath depth was found negligible. A correlation for the modified Euler number considering the pressure drop is proposed depending on nozzle geometric parameter and on the modified Froude number with the hydraulic diameter of the nozzle do as characteristic length.

Spreading of a Multicomponent Drop in Water: Solutions and Suspensions

The distribution of material resulting from the impact of a freely falling drop with a target liquid has been studied by photo and video registration methods.Different cases have been investigated by considering drops made of aqueous solutions(ink,salt,acid)and including fine solid particles(i.e.,suspensions).New features have been observed in terms of flow dynamics and thin components produced as a result of the impact(such as banded elements,ligaments,and vortices at the surface of the liquid).In particular,the characteristics of emerging netlike structures have been found to depend on the size of the suspension clusters.For the case of acetic acid,a different patterning behavior has been obtained:sequences of concentric arcs are produced in that case.However,linear scaling laws and the discrete nature of the distribution of the droplet material seem to be features common to all the cases considered.

A Model for Predicting Holdup and Pressure Drop in Gas- Liquid Stratified Flow

The time-dependent liquid film thickness and pressure drop were measured by using parallel-wire conductance probes and capacitance differential-pressure transducers. Applying the eddy viscosity theory and an appropriate correlation of interfacial sear stress,a new two-dimensional separated model of holdup and pressure drop of turbulent/turbulent gas-liquid stratified flow was presented. Prediction results agreed well with experimental data.

PRESSURE DROP IN THE VERTICAL PNEUMATIC PIPE FOR POWDER CONVEYING

Based on the former research work of the authors,the resistance of differentsolid particle suspension flow in a vertical pipe is analysed,and investigatedexperimentally.The applicable formulas of pressure drop are presented.Two types of par-ticles,talcum powder and glass beads,are convcyed in the test which has been carried outat various air vclocities of 10 to 28 m/s and at the ratio of solids-air mass flow rateranged from 0 to 2.The experimental results show a good agreement with the calculatedones.

MOTION AND DEFORMATION OF VISCOUS DROP IN STOKES FLOW NEAR RIGID WALL

A boundary integral method was developed for simulating the motion and deformation of a viscous drop in an axisymmetric ambient Stokes flow near a rigid wall and for direct calculating the stress on the wall. Numerical experiments by the method were performed for different initial stand-off distances of the drop to the wall, viscosity ratios, combined surface tension and buoyancy parameters and ambient flow parameters. Numerical results show that due to the action of ambient flow and buoyancy the drop is compressed and stretched respectively in axial and radial directions when time goes. When the ambient flow action is weaker than that of the buoyancy the drop raises and bends upward and the stress on the wall induced by drop motion decreases when time advances. When the ambient flow action is stronger than that of the buoyancy the drop descends and becomes flatter and flatter as time goes. In this case when the initial stand-off distance is large the stress on the wall increases as the drop evolutes but when the stand-off distance is small the stress on the wall decreases as a result of combined effects of ambient flow, buoyancy and the stronger wall action to the flow. The action of the stress on the wall induced by drop motion is restricted in an area near the symmetric axis, which increases when the initial stand-off distance increases. When the initial stand-off distance increases the stress induced by drop motion decreases substantially. The surface tension effects resist the deformation and smooth the profile of the drop surfaces. The drop viscosity will reduce the deformation and migration of the drop.

Topological structure bifurcation of temperature field of deformable drop in Marangoni migration

The unsteady processes of the Marangoni migration of deformable liquid drops are simulated numerically in a wider range of Marangoni number(up to Ma = 500) in the present work.A steady terminal state can always be reached,and the scaled terminal velocity is a monotonic function decreasing with increasing Marangoni number,which is generally in agreement with corresponding experimental data.The topological structure of flow field in the steady terminal state does not change as the Marangoni number increases,while bifurcation of the topological structure of temperature field occurs twice at two corresponding critical Marangoni numbers.A third critical value of Marangoni number also exists,beyond which the coldest point jumps from the rear stagnation to inside the drop though the topological structure of the temperature field does not change.It is found that the inner and outer thermal boundary layers may exist along the interface both inside and outside the drop if Ma>70.But the thickness decreases with increasing Marangoni number more slowly than the prediction of potential flow at large Marangoni and Reynolds numbers.

Heat Transfer Characteristics and Pressure Drop in a Horizontal Circulating Fluidized Bed Evaporator

A vapor-liquid-solid horizontal circulating fluidized bed evaporation setup was constructed to study the thermal-exchange properties and pressure change.The influences of the operating variables,including the amount of added particles,heat flux,and circulating flow velocity,were systematically inspected using resistance temperature detectors and pressure sensors.The results showed that the heat transfer eff ect was improved with the increase in the amount of added particles,circulating flow velocity,and particle diameter,but decreased with increasing heat flux.The pressure drop fluctuated with the increase in operating parameters,except circulating flow velocity.The enhancing factor reached up to 71.5%.The enhancing fac-tor initially increased and then decreased with the increase in the amount of added particles and circulating flow velocity,fluctuated with increasing particle diameter,and decreased with increasing heat flux.Phase diagrams showing the variation ranges of the operation variables for the enhancing factor were constructed.

A data-driven model of drop size prediction based on artificial neural networks using small-scale data sets

An artificial neural network(ANN)method is introduced to predict drop size in two kinds of pulsed columns with small-scale data sets.After training,the deviation between calculate and experimental results are 3.8%and 9.3%,respectively.Through ANN model,the influence of interfacial tension and pulsation intensity on the droplet diameter has been developed.Droplet size gradually increases with the increase of interfacial tension,and decreases with the increase of pulse intensity.It can be seen that the accuracy of ANN model in predicting droplet size outside the training set range is reach the same level as the accuracy of correlation obtained based on experiments within this range.For two kinds of columns,the drop size prediction deviations of ANN model are 9.6%and 18.5%and the deviations in correlations are 11%and 15%.

Buckling Properties of Water-Drop-Shaped Pressure Hulls with Various Shape Indices Under Hydrostatic External Pressure

The water-drop-shaped pressure hull has a good streamline,which has good application prospect in the underwater observatory.Therefore,this study conducted analytical,experimental and numerical investigation of the buckling properties of water-drop-shaped pressure hulls under hydrostatic pressure.A water-drop experiment was conducted to design water-drop-shaped pressure hulls with various shape indices.The critical loads for the water-drop-shaped pressure hulls were resolved by using Mushtari’s formula.Several numerical simulations including linear buckling analysis and nonlinear buckling analysis including eigenmode imperfections were performed.The results indicated that the critical loads resolved by Mushtari's formula were in good agreement with the linear buckling loads from the numerical simulations.This formula can be extended to estimate the buckling capacity of water-drop-shaped pressure hulls.In addition,three groups of pressure hulls were fabricated by using stereolithography,a rapid prototyping technique.Subsequently,three groups of the pressure hulls were subjected to ultrasonic measurements,optical scanning,hydrostatic testing and numerical analysis.The experimental results were consistent with the numerical results.The results indicate that the sharp end of the water-drop-shaped pressure hulls exhibited instability compared with the blunt end.This paper provides a new solution to the limitations of experimental studies on the water-drop-shaped pressure hulls as well as a new configuration and evaluation method for underwater observatories.

Evaluation of frictional pressure drop correlations for air-water and air-oil two-phase flow in pipeline-riser system

Accurate prediction of the frictional pressure drop is important for the design and operation of subsea oil and gas transporting system considering the length of the pipeline. The applicability of the correlations to pipeline-riser flow needs evaluation since the flow condition in pipeline-riser is quite different from the original data where they were derived from. In the present study, a comprehensive evaluation of 24prevailing correlation in predicting frictional pressure drop is carried out based on experimentally measured data of air-water and air-oil two-phase flows in pipeline-riser. Experiments are performed in a system having different configuration of pipeline-riser with the inclination of the downcomer varied from-2°to-5°to investigated the effect of the elbow on the frictional pressure drop in the riser. The inlet gas velocity ranges from 0.03 to 6.2 m/s, and liquid velocity varies from 0.02 to 1.3 m/s. A total of885 experimental data points including 782 on air-water flows and 103 on air-oil flows are obtained and used to access the prediction ability of the correlations. Comparison of the predicted results with the measured data indicate that a majority of the investigated correlations under-predict the pressure drop on severe slugging. The result of this study highlights the requirement of new method considering the effect of pipe layout on the frictional pressure drop.

Ladder Time Stepwise Inertia Coordinated Control Method of Multiple Wind Farms to Suppress System Frequency Secondary Drop

Currently,both regulated and deregulated power trading exist in China’s power system,which has caused imbalanced funds in the electricity market.In this paper,a simulation analysis of the electricity market with wind energy resources is conducted,and the calculation methods of unbalanced funds are investigated systematically.In detail,the calculation formulas of unbalanced funds are illustrated based on their definition,and a two-track electricity market clearing model is established.Firstly,the concept of the dual-track system is explained,and the specific calculation formulas of various types of unbalanced funds are provided.Next,considering the renewable energy consumption,the market clearing model based on DC power flow is constructed and solved;by combining fitting methods of mid-and long-term curves,the unbalanced funds are calculated based on clearing results and formulas.

Efficacy of recombinant human epidermal growth factor plus sodium hyaluronate eye drops in diabetic dry eye post-cataract surgery

BACKGROUND Dry eye syndrome(DES)after diabetic cataract surgery can seriously affect the patient’s quality of life.Therefore,effective alleviation of symptoms in patients with this disease has important clinical significance.AIM To explore the clinical effect of recombinant human epidermal growth factor(rhEGF)plus sodium hyaluronate(SH)eye drops on DES after cataract surgery in patients with diabetes.METHODS We retrospectively evaluated 82 patients with diabetes who experienced DES after cataract surgery at Tianjin Beichen Hospital,Affiliated Hospital of Nankai University between April 2021 and April 2023.They were classified into an observation group(42 cases,rhEGF+SH eye drops)and a control group(40 cases,SH eye drops alone),depending on the different treatment schemes.The therapeutic efficacy,dry eye symptom score,tear film breakup time(TFBUT),basic tear secretion score[assessed using Schirmer I test(SIt)],corneal fluorescein staining(FL)score,tear inflammatory markers,adverse reactions during treat-ment,and treatment satisfaction were compared between the two groups.RESULTS Therapeutic efficacy was higher in the observation group compared with the control group.Both groups showed improved TFBUT and dry eye,as well as improved SIt and FL scores after treatment,with a more pronounced improvement in the observation group.Although no marked differences in adverse reactions were observed between the two groups,treatment satisfaction was higher in the observation group.CONCLUSION rhEGF+SH eye drops rendered clinical benefits to patients by effectively ameliorating dry eye and visual impairment with favorable efficacy,fewer adverse reactions,and high safety levels.Thus,this treatment should be promoted in clinical practice.

Flow Rate Measurement of Gravity Infusion Set and Functional Evaluation of Drop Counter: A Pilot Study

Developing a novel drop counter by introducing the Internet of Things concept has been vigorously conducted in recent years. Understanding the newly introduced drop counter’s flow rate control accuracy and flow rate count feature is essential for improving safety in infusion management. This study aimed to verify if the new drop counters could secure accurate flow rate and drip count by conducting actual flow rate measurements using gravimetry and functional evaluation. A drop counter was attached to each drip chamber of the infusion set, and an IV drip was conducted at the 100 ml/h flow rate. The weight of discharged physiological saline was measured to plot trumpet curves. Next, three different types of drop counters were evaluated to determine if they maintained drip count accuracy according to the changes in their position angles. The flow rate errors in all conditions indicated trumpet-like curves, exhibiting an overall error range within ±10% in all observation windows. Although every drop counter successfully detected and measured dripping, it was challenging in some counters to detect dripping when the drip chamber was tilted. In comparing adult and pediatric IV sets, the adult IV set was found to be less likely to detect dripping in the angled position. No significant differences in results were confirmed between high and low flow rates, suggesting that the drop count function would not be affected by the flow rate in the ranges of typical infusion practices. Doppler sensors have a wide range of measurements and high sensitivity;the dripping was detected successfully even when the drip chamber was tilted, probably due to the advantages of these sensors. In contrast, miscounts occurred in those equipped with infrared sensors, which could not detect light intensity changes in tilted positions. Understanding the tendencies in flow rate errors in infusion can be valuable information for infusion management.

Prevalence and Factors Associated with Dry Eyes Syndrome in Glaucomatous Patients on Anti-Glaucoma Eye Drops Followed up at the Garoua Regional Hospital-Northern Cameroon

Background: Dry eye and glaucoma are two common pathologies in the elderly, and are very often associated. This association suggests a link between them and between their treatments. Our purpose for this study is to determine the prevalence of dry eye in our glaucoma patients treated with eye drops and deduce the factors associated with it. Patients and Methods: We conducted a cross-sectional, analytical study from October 2022 to September 2023 in the ophthalmology department of Garoua Regional Hospital in glaucoma patients aged over 15 years able to answer the Ocular Surface Disease Index (OSDI) questionnaires and treated with antiglaucoma eye drops for more than 3 months. These patients underwent a complete ophthalmological examination and a tear film break-up time test. Results: A total of 73 patients (146 eyes) were examined. The average age of the patients was 47.2 ± 16.5 years, with a male predominance of 54.8%. The prevalence of dry eye syndrome in our patients according to the OSDI score was 56.2% (95% CI) (44.8;67.6). The prevalence of dry eye syndrome on clinical examination of the BUT in the right eye was 83.7% (95% CI) (75.1;92.1) and 79.4% (70.2;88.7) in the left eye. The duration of antiglaucoma treatment was the factor associated with dry eye syndrome (p < 0.05) in glaucoma patients in our setting. Conclusion: Dry Eye Syndrome is common in glaucoma patients on drops in our setting. Treatment duration of more than 1 year seems to be associated with dry eyes.