Simultaneous removal of NO and SO_2 from dry gas stream using non-thermal plasma

In order to investigate the feasibility of sequential removal NO and SO2 using non-thermal plasma and adsorbent simultaneously, the removal of NO and SO2 from dry gas stream （NO/SO2/N2/O2） with very little O2 using non-thermal plasma was investigated using a coaxial dielectric barrier discharge. Comparative experiments were carried out in the dry gas stream with and without Ar respectively at O2 concentration of 0.1%. The results showed that NO could be removed remarkably and it would be enhanced in the presence of Ar in the dry gas stream. It seems that SO2 could not be removed unless there is Ar in the dry gas stream. The mechanism of removal of NO and SO2 in the dry gas stream was discussed.

Gas Film Disturbance Characteristics Analysis of High-Speed and High-Pressure Dry Gas Seal

The dry gas seal（DGS） has been widely used in high parameters centrifugal compressor, but the intense vibrations of shafting, especially in high-speed condition, usually result in DGS＇s failure. So the DGS＇s ability of resisting outside interference has become a determining factor of the further development of centrifugal compressor. However, the systematic researches of which about gas film disturbance characteristics of high parameters DGS are very little. In order to study gas film disturbance characteristics of high-speed and high-pressure spiral groove dry gas seal（S-DGS） with a flexibly mounted stator, rotor axial runout and misalignment are taken into consideration, and the finite difference method and analytical method are used to analyze the influence of gas film thickness disturbance on sealing performance parameters, what＇s more, the effects of many key factors on gas film thickness disturbance are systematically investigated. The results show that, when sealed pressure is 10.1MPa and seal face average linear velocity is 107.3 m/s, gas film thickness disturbance has a significant effect on leakage rate, but has relatively litter effect on open force; Excessively large excitation amplitude or excessively high excitation frequency can lead to severe gas film thickness disturbance; And it is beneficial to assure a smaller gas film thickness disturbance when the stator material density is between 3.1 g/cm3 to 8.4 g/cm3; Ensuring sealing performance while minimizing support axial stiffness and support axial damping can help to improve dynamic tracking property of dry gas seal. The proposed research provides the instruction to optimize dynamic tracking property of the DGS.

Effect of acid density of HZSM-5 on the oligomerization of ethylene in FCC dry gas

The oligomerization of ethylene in FCC dry gas over HZSM-5 catalyst with different Si/A12 ratios was studied. The effect of acid density of catalyst on the oligomerization of ethylene was discussed. By increasing the acid density of catalyst, ethylene conversion showed a linear increase, while the yields of olefins decreased when the acid density of catalyst exceeded 0.14mmolNH3/g owing to a promotion of hydrogen transfer reaction. Through comparing the average distance between acid sites on catalyst with kinetic diameters of olefins, it was found that the dimerization of ethylene was not restrained by the sparse distribution of acid sites, while the hydrogen transfer reaction of C3 and C4 olefins was limited. On these bases, a conclusion is proposed that the dimerization of ethylene proceeded via Eley-Rideal mechanism, while the hydrogen transfer reaction of C3 and C4 olefins followed the Langmuir-Hinshelwood mechanism.

Leakage and Stiffness Characteristics of Bionic Cluster Spiral Groove Dry Gas Seal

Spiral groove dry gas seal(S?DGS), the most widely used DGS in the world, encounters the problem of high leakage rate and inferior film stability when used in high?speed machinery equipment, which could not be well solved by optimization of geometrical parameters and molded line of spiral groove. A new type of bionic cluster spiral groove DGS(CS?DGS) is proved to have superior film stability than S?DGS at the condition of high?speed and low?pressure numerically. A bionic CS?DGS is experimentally investigated and compared with common S?DGS in order to provide evidence for theoretical study. The film thickness and leakage rate of both bionic spiral groove and common spiral groove DGS are measured and compared with each other and with theoretical values under different closing force at the condition of static pressure, high?speed and low?pressure, and the film stiffness and stiffness?leakage ratio of these two face seals are derived by the relationship between closing force and film thickness at the steady state. Experimental results agree well with the theory that the leakage and stiffness of bionic CS?DGS are superior to that of common S?DGS under the condition of high?speed and low?pressure, with the decreasing amplitude of 20% to 40% and the growth amplitude of 20%, respectively. The opening performance and stiffness characteristics of bionic CS?DGS are inferior to that of common S?DGS when rotation speed equals to 0 r/min. The proposed research provides a new method to measure the axis film stiffness of DGS, and validates the superior performance of bionic CS?DGS at the condition of high?speed and low?pressure experimentally.

Dynamic Coupling Correlation of Gas Film in Dry Gas Seal with Spiral Groove

In working state, the dynamic performance of dry gas seal, generated by the rotating end face with spiral grooves, is determined by the open force of gas film and leakage flow rate. Generally, the open force and the leakage flow rate can be obtained by finite element method, computational fluid dynamics method and experimental measurement method. However, it will take much time to carry out the above measurements and calculations. In this paper, the approximate model of parallel grooves based on the narrow groove theory is used to establish the dynamic equations of the gas film for the purpose of obtaining the dynamic parameters of gas film. The nonlinear differential equations of gas film model are solved by Runge-Kutta method and shooting method. The numerical values of the pressure profiles, leakage flux and opening force on the seal surface are integrated, and then compared to experimental data for the reliability of the numerical simulation. The results show that the numerical simulation curves are in good agreement with experimental values. Furthermore, the opening force and the leakage flux are proved to be strongly correlated with the operating parameters. Then, the function-coupling method is introduced to analyze the numerical results to obtain the correlation formulae of the opening force and leakage flux respectively with the operating parameters, i.e., the inlet pressure and the rotating speed. This study intends to provide an effective way to predict the aerodynamic performance for designing and optimizing the groove styles in dry gas seal rapidly and accurately.

Recent progresses in dry gas polymeric filters

Filtration and membrane separation are popular methods in gas separation since they are cost and energy efficient. Despite to air filters, there are comparatively few studies on dry gas filters, particularly at industrial scale. In fact, major unsolved challenges such as high efficiency, low pressure drop, long-term stability, high-thermal and chemical stability and advanced physiochemical properties, are still remained. The aim of this review is to scrutinize the advanced scientific and technological practices (such as selection of appropriate polymeric materials and additives, nanotechnology, modification techniques and preparation methods) towards design and fabrication of an efficient filter media for solid particles removal from the natural gas flow. Recent progresses in solid particle separation mechanisms, modeling and simulation techniques and the effect of membrane fabrication methods on its performance, strategies for modification of filter media, current challenges and future perspective are discussed.

A Comparative Study on the Performance of Typical Types of Bionic Groove Dry Gas Seal based on Bird Wing

A series of bionic grooves based on bird wing, such as cluster spiral groove, multi-array spiral groove and flow-split spiral groove, are introduced to improve the film stiffness and sealing properties of dry gas seal. A theoretical model solved with Finite Difference Method （FMD） is developed to study the static sealing performance, such as film stiffness and leakage rate of these bionic groove dry gas seals. Then, a performance comparative study between the bionic groove dry gas seals and common spiral groove dry gas seal with different groove geometry parameters such as groove depth ratio, spiral angle and micro groove number under different average linear velocity at seal ring face and seal pressure is carried out. The closing force, film thickness and leakage rate of dry gas seals with bionic grooves and common spiral groove are measured experimentally. Results show that cluster spiral groove and multi-array spiral groove dry gas seals have superiority in the film stiffness and stiffness-leakage ratio compared with common spiral groove under the condition of high-speed and low-pressure, while flow-split spiral groove dry gas seal has no obvious advantages of performance. Film stiffness of cluster spiral groove dry gas seal and stiffness-leakage ratio of multi-array spiral groove dry gas are 20% and 50% larger than that of common spiral groove dry gas seal, respectively, which are verified by the experimental results.

The Application of Cold Banding Technology for Dust Removed From BOF Gas Using Dry Dedusting Technology

Firstly, physical and chemical properties of dust removed from BOF gas are analyzed, and then the cold banding technology of dust removed from BOF gas and its application are introduced. Tests have proved that using cooled agglomerated pellets made of the dust removed from BOF gas and small amounts of modified starch as a coolant and slagging agent in steel production can bring about considerable economic, social and environmental benefits.

Haier developes new standard for dry burning-resistant gas stove

The world’s first standard for dry burning-resistant gas stove developed by Haier,China’s giant of household appliance and China Association of Standardization was released in Wuhan and simultaneously in America,Australia,Europe and Asia.It clearly defines such safety properties and technical requirements as dry burning-resistance and automatic stove shut-off,promoting the industry upgrading.In the past five years,after surveying the kitchen environments and cooking habits of 2 million users in 20 countries worldwide,

Experiment on Wear Behavior of High Pressure Gas Seal Faces

Current researches show that mechanical deformation of seal ring face makes fluid film clearance decrease at high pressure side, thus a divergent clearance is formed and face wear occurs more seriously at the high pressure side than that on the low pressure side. However, there is still lack of published experimental works enough to prove the theoretical results. In this paper, a spiral groove dry gas seal at high pressures is experimentally investigated so as to prove the face wear happened at the high pressure side of seal faces due to the face mechanical deformation, and the wear behavior affected by seal ring structure is also studied. The experimental results show that face wear would occur at the high pressure side of seal faces due to the deformation, thus the leakage and face temperature increase, which all satisfies the theoretical predictions. When sealed pressure is not less than 5 MPa, the pressure can provide enough opening force to separate the seal faces. The seal ring sizes have obvious influence on face wear. Face wear, leakage and face temperature of a dry gas seal with the smaller cross sectional area of seal ring are less than that of a dry gas seal with bigger one, and the difference of leakage rate between these two sizes of seal face width is in the range of 24%–25%. Compared with the effect of seal ring sizes, the effect of secondary O-ring seal position on face deformation and face wear is less. The differences between these two types of dry gas seals with different secondary O-ring seal positions are less than 5.9% when the rotational speed varies from 0 to 600 r/min. By linking face wear and sealing performance changes to the shift in mechanical deformation of seal ring, this research presents an important experimental method to study face deformation of a dry gas seal at high pressures.

The Controversial Genesis of Thermogenic Gas-A Polemical Article

The article contains a critique of the biogenic theory of natural gas,which incorrectly combines the phenomenon of methane formation in the anaerobic process of decomposition of organic matter with the phenomenon of methane expulsion in the process of pyrolysis and cracking.The view of the organic origin of methane is treated as a paradigm,despite the lack of thermal conditions to induce expulsion.The mineralized organic substance for which the name“kerogen”was created undergoes the process of carbonization and this process,under the conditions of the deposit,is a one-way process.The paradox of the petroleum geology methodology is the determination of the oil potential from the TOC(Total Organic Carbon)in the rock.In reservoir conditions,methane is produced by chemical reactions of igneous gases,mainly hydrogen,carbon and oxygen.These elements are formed in the process of hot plasma recombination in zone D and the formation of basalt magma.The change in the structure of matter causes stresses in the rock mass and the formation of igneous intrusions.After lowering the temperature of post-igneous solutions,the release of igneous gases and a rapid increase in pressure occurs.In the created dislocation zones tectonic pressure in natural gas deposits is more than twice the hydrostatic pressure.The process of the evolution of igneous gases and reactions between them are,among others,methane explosions in hard coal mines.The inorganic origin of methane also has a positive aspect,the conclusion is that natural gas resources are renewable and that they are ubiquitous.

Study on the supercritical phase behavior of Yaha condensate gas reservoir in Tarim Basin

Yaha condensate gas reservoir is condensate gas reservoir developed by gas injection in the Tarim Basin.The practice of gas injection in condensate gas reservoir shows that the key to improve gas injection effect is to control gas channeling.Dynamic monitoring shows that there is no instantaneous miscibility between dry gas and condensate gas during gas injection.Based on the principle of entropy increase and mass transfer kinetics,the phase behavior of condensate gas and dry gas in reservoir is analyzed theoretically.The new technique to improve condensate recovery is adopted for condensate gas field.By using the density difference and seepage characteristics of dry gas and condensate gas,the injected dry gas cap is formed at the top of the gas reservoir,and the three-dimensional displacement is realized by the expansion of dry gas cap.Gas injection gravity assisted flooding technology is to realize vertical displacement of injected gas through the expansion of dry gas cap by using gravity differentiation caused by gas density difference.This technology can keep the front edge of gas injection advance evenly and solve the problem of gas channeling in the process of cyclic gas injection.

Methyl chloride dehydration with ionic liquid based on COSMO-RS model

A suitable ionic liquid for methyl chloride drying experiment was screened out from 210 ionic liquids by COSMO-RS model.Moreover,the experimental mechanism of ionic liquids drying is further explained by the COSMO-RS model,and it is further confirmed by analyzing the binding energy.The solubility of methyl chloride in[EMIM][BF4]and TEG and[EMIM][BF4]+H2O was completed,and the experimental results well proved the reliability of the UNIFAC-Lei model.The unknown interaction parameters were obtained through the solubility data of this work and the experimental data in the literatures.The methyl chloride drying experiment was completed in the laboratory,and the water content of the methyl chloride can be reduced to below 200 ppm.The simulation of the methyl chloride drying process using[EMIM][BF4]or TEG as absorbents was carried out by ASPEN software on an industrial scale.The final simulation results show that the[EMIM][BF4]drying process has lower energy consumption and better drying effect.

CO_(2) storage in depleted gas reservoirs:A study on the effect of residual gas saturation

Depleted gas reservoirs are recognized as the most promising candidate for carbon dioxide storage.Primary gas production followed by injection of carbon dioxide after depletion is the strategy adopted for secondary gas recovery and storage practices.This strategy,however,depends on the injection strategy,reservoir characteristics and operational parameters.There have been many studies to-date discussing critical factors influencing the storage performance in depleted gas reservoirs while little attention was given to the effect of residual gas.In this paper,an attempt was made to highlight the importance of residual gas on the capacity,injectivity,reservoir pressurization,and trapping mechanisms of storage sites through the use of numerical simulation.The results obtained indicated that the storage performance is proportionally linked to the amount of residual gas in the medium and reservoirs with low residual fluids are a better choice for storage purposes.Therefore,it would be wise to perform the secondary recovery before storage in order to have the least amount of residual gas in the medium.Although the results of this study are useful to screen depleted gas reservoirs for the storage purpose,more studies are required to confirm the finding presented in this paper.