The accurate forecasting of tropical cyclones(TCs)is a challenging task.The purpose of this study was to investigate the effects of a dry-mass conserving(DMC)hydrostatic global spectral dynamical core on TC simulation...The accurate forecasting of tropical cyclones(TCs)is a challenging task.The purpose of this study was to investigate the effects of a dry-mass conserving(DMC)hydrostatic global spectral dynamical core on TC simulation.Experiments were conducted with DMC and total(moist)mass conserving(TMC)dynamical cores.The TC forecast performance was first evaluated considering 20 TCs in the West Pacific region observed during the 2020 typhoon season.The impacts of the DMC dynamical core on forecasts of individual TCs were then estimated.The DMC dynamical core improved both the track and intensity forecasts,and the TC intensity forecast improvement was much greater than the TC track forecast improvement.Sensitivity simulations indicated that the DMC dynamical core-simulated TC intensity was stronger regardless of the forecast lead time.In the DMC dynamical core experiments,three-dimensional winds and warm and moist cores were consistently enhanced with the TC intensity.Drier air in the boundary inflow layer was found in the DMC dynamical core experiments at the early simulation times.Water vapor mixing ratio budget analysis indicated that this mainly depended on the simulated vertical velocity.Higher updraft above the boundary layer yielded a drier boundary layer,resulting in surface latent heat flux(SLHF)enhancement,the major energy source of TC intensification.The higher DMC dynamical core-simulated updraft in the inner core caused a higher net surface rain rate,producing higher net internal atmospheric diabatic heating and increasing the TC intensity.These results indicate that the stronger DMC dynamical coresimulated TCs are mainly related to the higher DMC vertical velocity.展开更多
This paper establishes the mathematical model in calculating the effective thermal conductivity and the effective mass diffusivity of dried layer of beef undergoing freeze drying process.First,experimental measurement...This paper establishes the mathematical model in calculating the effective thermal conductivity and the effective mass diffusivity of dried layer of beef undergoing freeze drying process.First,experimental measurements are done on the dehydrated quantity as well as temperature variations at different locations of the beef steak.Then the effective thermal conductivity and the effective mass diffusivity are calculated by applying the above mathematical model on the data of the dehydrated quantity.These two coefficients are further used in the calculation of temperature distribution.The result is in agreement with the measurement,thus confirming the correctness of the model and the values of the coefficients.展开更多
The photosynthetic characteristics of flag leaf and the accumulation and remobilization of pre-anthesis dry mass(DM) and nitrogen(N) in vegetable organs in nine wheat cultivars under different source-sink manipula...The photosynthetic characteristics of flag leaf and the accumulation and remobilization of pre-anthesis dry mass(DM) and nitrogen(N) in vegetable organs in nine wheat cultivars under different source-sink manipulation treatments including defoliation(DF), spike shading(SS) and half spikelets removal(SR) were investigated. Results showed that the SS treatment increased the photosynthetic rate(Pn) of flag leaf in source limited cultivar, but had no significant effect on sink limited cultivar. The SR treatment decreased the Pn of flag leaf. Grain DM accumulation was limited by source in some cultivars, in other cultivars, it was limited by sink. Grain N accumulation was mainly limited by source supply. The contribution of pre-anthesis dry mass to grain yield from high to low was stem, leaf and chaff, while the contribution of pre-anthesis N to grain N from high to low was leaf, stem and chaff. Cultivars S7221 and TA9818 can increase the contribution of remobilization of DM and N to grain at the maximum ratio under reducing source treatments, which may be the major reason for these cultivars having lower decrease in grain yield and N content under reducing source treatments.展开更多
A compliant tower is modeled as a partially dry, partially tapered, damped Timoshenko beam with the superstructure modeled as an eccentric tip mass, and a non-classical damped boundary at the base. The foundation is m...A compliant tower is modeled as a partially dry, partially tapered, damped Timoshenko beam with the superstructure modeled as an eccentric tip mass, and a non-classical damped boundary at the base. The foundation is modeled as a combination of a linear spring and a torsional spring, along with parallel linear and torsional dampers(Kelvin-Voigt model). The superstructure adds to the kinetic energy of the system without affecting the potential energy, thereby reducing the natural frequencies. The weight of the superstructure acts as an axial compressive load on the beam, reducing its natural frequencies further. The empty space factor due to the truss-type structure of the tower is included. The effect of shear deformation and rotary inertia are included in the vibration analysis; with the non-uniform beam mode-shapes being a weighted sum of the uniform beam mode-shapes satisfying the end condition. The weights are evaluated by the Rayleigh-Ritz(RR) method, and verified using finite element method(FEM). The weight of the superstructure acts as an axial compressive load on the beam. Kelvin-Voigt model of structural damping is included.A part of the structure being underwater, the virtual added inertia is included to calculate the wet natural frequencies. A parametric study is done for various magnitudes of tip mass and various levels of submergence. The computational efficiency and accuracy of the Rayleigh-Ritz method, as compared to the FEA, has been demonstrated. The advantage of using closed-form trial functions is clearly seen in the efficacy of calculating the various energy components in the RR method.展开更多
According to modeling simulation and experiments study, the heat and mass transtfer phenomenon.in wood during dring processes was analyzed. The results indicate: at initial stage of drying, moisture movement in wood i...According to modeling simulation and experiments study, the heat and mass transtfer phenomenon.in wood during dring processes was analyzed. The results indicate: at initial stage of drying, moisture movement in wood is due to capillary force, heat transfer is major effect, at end stage, moisture movement in wood is due to diffusive transport, heat transfer is less展开更多
The presence of grassland biomes and species cannot be predicted by examining bottom up causes such as precipitation and temperature. Top down causes including herbivory and fire seem to be major controlling aspects w...The presence of grassland biomes and species cannot be predicted by examining bottom up causes such as precipitation and temperature. Top down causes including herbivory and fire seem to be major controlling aspects with other factors secondary. We examined soil depth and competitive ability of two North American C4 grasses in a greenhouse experiment. Changes in dry mass were determined and competitive intensity was calculated for both species. Species were grown separately or together in pots 30, 90, or 180 cm deep. When grown in monoculture, Schizachyrium scoparium total and belowground dry mass increased from the 30 to 90 cm depth, with no further significant increase from 90 to 180 cm. Aboveground dry mass did not increase significantly with depth. Total dry mass of Buchloe dactyloides increased significantly with depth when grown in monoculture. Aboveground dry mass increased from 30 to 90 cm depth but not from 90 to 180 cm. Belowground dry mass of B. dactyloides did not increase significantly with depth. In 180 cm pots, 53% of S. scoparium root dry mass was in the top 30 cm;74% of B. dactyloides root dry mass was in the top 30 cm. Roots of B. dactyloides were not found deeper than 90 cm. Aboveground dry mass of S. scoparium was not different in mixture or monoculture at any depth. Buchloe dactyloides aboveground dry mass in mixture was significantly lower than monoculture at the 30 cm depth, but not at 90 or 180 cm. The greatest competitive intensity was in the shallow soil pots. Soil depth could partially explain mosaics found in C4 grasslands where both species were found together with S. scoparium on deeper soils and B. dactyloides on shallower soils.展开更多
Traditional thermal methods of drying food have often led to loss of flavours, nutrients, vitamins, etc., which encourages non-thermal pretreatments such as osmotic dehydration (OD) and/or high electric field (HEF...Traditional thermal methods of drying food have often led to loss of flavours, nutrients, vitamins, etc., which encourages non-thermal pretreatments such as osmotic dehydration (OD) and/or high electric field (HEF) application to improve the overall product quality. The aim of this study was to evaluate the effect of osmotic dehydration (50% sucrose) with high electric field strengths of 0.5 and 1.0 kV/cm as pretreatments on the drying kinetics and mass transfer of green apples during convective drying at 65 ~C and microwave drying at 1 W/g. The added value of the OD and HEF on the drying kinetics, and the effective mass transfer coefficients of the subsequent drying methods were investigated through this research. The efficacy of these pre-treatments was assessed and compared using cell disintegration index, product texture and thus bring forth new correlations between these pre-treatments and the cell disintegration index using dielectric spectroscopy and its effect on the product texture.展开更多
In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix wer...In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix were experimentally determined by using infrared (IR) radiation. IR drying of gel coated seeds was carried out at three different temperatures (65℃, 80℃ and 93℃). The shrinkage of the individual particles during drying was quantified by means of the volume and surface area changes evaluated from geometric measurements. The product quality was evaluated in terms of the changes of particle density and percent of cracks in gel coating incurred during drying. Surface area and volume of the gel-seed system decreased about 65% and 80% until the end of the process, respectively, stressing the need to take into account the surface area changes to calculate water flux density as function of moisture content and obtain an accurate interpretation of the drying mechanisms well as to include the volume shrinkage in mass transfer models to determine reliable values of moisture diffusivity. The IR drying behavior of gel-coated seeds was then characterized by the presence of three drying periods: heating up, constant moisture flux and falling moisture flux. Accelerated drying of gel coated seeds was obtained by applying higher IR radiation intensities. The effect of IR source temperature on the particle shrinkage was more pronounced at the constant moisture flux period and practically negligible at the decreasing moisture flux period. Neglecting shrinkage of individual coated-seeds during IR drying led to an erroneous absence of constant flux period and overestimation of the mass transfer by diffusion. Apparent density of the particles was greater at low-temperature IR drying than at high-temperature IR drying. Coated particles keep their original geometry, but a significant cracking of gel coating was observed at rapid drying rate conditions.展开更多
The added mass coefficient and the water level index formulas for the same-phase and anti-phase vibration of rectangular liquid tanks' bulkheads were derived based on dry mode theory. Three fluid-structure interac...The added mass coefficient and the water level index formulas for the same-phase and anti-phase vibration of rectangular liquid tanks' bulkheads were derived based on dry mode theory. Three fluid-structure interaction numerical methods including Fluid FEM and Fluid BEM were used in this case. The comparison of numerical and theoretical results by the present method shows that ANSYS/Fluid80 is more credible, the NASTRAN/Virtual Mass Method is more suitable for engineering calculations and results of the same-phase vibration by the present method is more accurate.展开更多
Requirements of self-compacting concrete (SCC) applied in pre-stressed mass concrete structures include high fluidity, high elastic modulus, low adiabatic temperature rise and low drying shrinkage, which cannot be s...Requirements of self-compacting concrete (SCC) applied in pre-stressed mass concrete structures include high fluidity, high elastic modulus, low adiabatic temperature rise and low drying shrinkage, which cannot be satisfied by ordinary SCC. In this study, in order to solve the problem, a few principles of SCC design were proposed and the effects of binder amount, fly ash (FA) substitution, aggregate content and gradation on the workability, temperature rise, drying shrinkage and elastic modulus of SCC were investigated. The results and analysis indicate that the primary factor influencing the fluidity was paste content, and the main methods improving the elastic modulusof SCC were a lower sand ratio and an optimized coarse aggregate gradation. Lower adiabatic temperature rise and drying shrinkage were beneficial for decreasing the cement content. Further, based on the optimization of mixture, a C50 grade SCC (with binder amount of only 480 kg/ m3, fly ash substitution of 40%, sand ratio of 51% and proper coarse aggregate gradation (Vs.~0 mm: V10-16 ram: V16.20 mm= 30%: 30%:40%)) with superior workability was successfully prepared. The temperature rise and drying shrinkage of the prepared SCC were significantly reduced, and the elastic modulus reached 37.6 GPa at 28 d.展开更多
建立了一步式QuEChERS自动提取和净化技术结合气相色谱-串联质谱同时测定风干牦牛肉中15种N-亚硝胺的分析方法。样品水化后,经乙腈提取,加入4.0 g MgSO_(4)和1.0 g NaCl除水,经十八烷基硅烷(C_(18))和N-丙基乙二胺(PSA)填料净化,采用DB-...建立了一步式QuEChERS自动提取和净化技术结合气相色谱-串联质谱同时测定风干牦牛肉中15种N-亚硝胺的分析方法。样品水化后,经乙腈提取,加入4.0 g MgSO_(4)和1.0 g NaCl除水,经十八烷基硅烷(C_(18))和N-丙基乙二胺(PSA)填料净化,采用DB-HeavyWAX色谱柱(30 m×0.25 mm×0.25μm)分离15种N-亚硝胺,在多重反应监测(MRM)模式下进行测定,外标法定量。结果表明,15种N-亚硝胺分离性能良好,在0.1~200μg/L范围内线性关系良好,相关系数(r^(2))≥0.999 0;检出限(LOD)为0.05~0.20μg/kg,定量限(LOQ)为0.10~0.50μg/kg;在1倍、2倍和10倍LOQ 3个添加水平下的平均回收率分别为79.4%~102.1%、80.6%~109.5%、83.0%~110.6%,相对标准偏差(RSD)为0.8%~16.0%。应用建立的方法检测2种不同加工工艺的市售样品,其中7种N-亚硝胺类化合物(N-亚硝基二甲胺、N-亚硝基二异丁胺、N-亚硝基二正丁胺、N-亚硝基甲基苯胺、N-亚硝基乙基苯胺、N-亚硝基吡咯烷、N-亚硝基二苯胺)均有不同程度检出,平均含量为0.08~20.18μg/kg,且熟制风干牦牛肉中N-亚硝胺的检出率和平均含量均高于传统生制风干牦牛肉。该方法实现了前处理的自动化,相较于其他传统方法,操作简单,实验效率高,人为影响因素小,检测灵敏度高,适用于风干牦牛肉中15种N-亚硝胺的快速测定,为研究肉制品中N-亚硝胺的测定提供了方法支持。展开更多
基金jointly supported by the National Key Research and Development Program of China (2021YFC3101500)the National Natural Science Foundation of China (Grant Nos. 41830964, 42275062)
文摘The accurate forecasting of tropical cyclones(TCs)is a challenging task.The purpose of this study was to investigate the effects of a dry-mass conserving(DMC)hydrostatic global spectral dynamical core on TC simulation.Experiments were conducted with DMC and total(moist)mass conserving(TMC)dynamical cores.The TC forecast performance was first evaluated considering 20 TCs in the West Pacific region observed during the 2020 typhoon season.The impacts of the DMC dynamical core on forecasts of individual TCs were then estimated.The DMC dynamical core improved both the track and intensity forecasts,and the TC intensity forecast improvement was much greater than the TC track forecast improvement.Sensitivity simulations indicated that the DMC dynamical core-simulated TC intensity was stronger regardless of the forecast lead time.In the DMC dynamical core experiments,three-dimensional winds and warm and moist cores were consistently enhanced with the TC intensity.Drier air in the boundary inflow layer was found in the DMC dynamical core experiments at the early simulation times.Water vapor mixing ratio budget analysis indicated that this mainly depended on the simulated vertical velocity.Higher updraft above the boundary layer yielded a drier boundary layer,resulting in surface latent heat flux(SLHF)enhancement,the major energy source of TC intensification.The higher DMC dynamical core-simulated updraft in the inner core caused a higher net surface rain rate,producing higher net internal atmospheric diabatic heating and increasing the TC intensity.These results indicate that the stronger DMC dynamical coresimulated TCs are mainly related to the higher DMC vertical velocity.
基金the National Natural Science Foundation of China!(No.597760 14 )
文摘This paper establishes the mathematical model in calculating the effective thermal conductivity and the effective mass diffusivity of dried layer of beef undergoing freeze drying process.First,experimental measurements are done on the dehydrated quantity as well as temperature variations at different locations of the beef steak.Then the effective thermal conductivity and the effective mass diffusivity are calculated by applying the above mathematical model on the data of the dehydrated quantity.These two coefficients are further used in the calculation of temperature distribution.The result is in agreement with the measurement,thus confirming the correctness of the model and the values of the coefficients.
基金supported by the Special Fund for Agroscientific Research in the Public Interest in China (201303133, 201203031)the Key Technologies R&D Program of China during the 12th Five-Year Plan period (2011BAD16B14)+1 种基金the Construction of Modern Agricultural Industrial Technology System, Ministry of Agriculture, Chinathe Beijing Higher Education Young Elite Teacher Project, China (YETP0300)
文摘The photosynthetic characteristics of flag leaf and the accumulation and remobilization of pre-anthesis dry mass(DM) and nitrogen(N) in vegetable organs in nine wheat cultivars under different source-sink manipulation treatments including defoliation(DF), spike shading(SS) and half spikelets removal(SR) were investigated. Results showed that the SS treatment increased the photosynthetic rate(Pn) of flag leaf in source limited cultivar, but had no significant effect on sink limited cultivar. The SR treatment decreased the Pn of flag leaf. Grain DM accumulation was limited by source in some cultivars, in other cultivars, it was limited by sink. Grain N accumulation was mainly limited by source supply. The contribution of pre-anthesis dry mass to grain yield from high to low was stem, leaf and chaff, while the contribution of pre-anthesis N to grain N from high to low was leaf, stem and chaff. Cultivars S7221 and TA9818 can increase the contribution of remobilization of DM and N to grain at the maximum ratio under reducing source treatments, which may be the major reason for these cultivars having lower decrease in grain yield and N content under reducing source treatments.
文摘A compliant tower is modeled as a partially dry, partially tapered, damped Timoshenko beam with the superstructure modeled as an eccentric tip mass, and a non-classical damped boundary at the base. The foundation is modeled as a combination of a linear spring and a torsional spring, along with parallel linear and torsional dampers(Kelvin-Voigt model). The superstructure adds to the kinetic energy of the system without affecting the potential energy, thereby reducing the natural frequencies. The weight of the superstructure acts as an axial compressive load on the beam, reducing its natural frequencies further. The empty space factor due to the truss-type structure of the tower is included. The effect of shear deformation and rotary inertia are included in the vibration analysis; with the non-uniform beam mode-shapes being a weighted sum of the uniform beam mode-shapes satisfying the end condition. The weights are evaluated by the Rayleigh-Ritz(RR) method, and verified using finite element method(FEM). The weight of the superstructure acts as an axial compressive load on the beam. Kelvin-Voigt model of structural damping is included.A part of the structure being underwater, the virtual added inertia is included to calculate the wet natural frequencies. A parametric study is done for various magnitudes of tip mass and various levels of submergence. The computational efficiency and accuracy of the Rayleigh-Ritz method, as compared to the FEA, has been demonstrated. The advantage of using closed-form trial functions is clearly seen in the efficacy of calculating the various energy components in the RR method.
文摘According to modeling simulation and experiments study, the heat and mass transtfer phenomenon.in wood during dring processes was analyzed. The results indicate: at initial stage of drying, moisture movement in wood is due to capillary force, heat transfer is major effect, at end stage, moisture movement in wood is due to diffusive transport, heat transfer is less
文摘The presence of grassland biomes and species cannot be predicted by examining bottom up causes such as precipitation and temperature. Top down causes including herbivory and fire seem to be major controlling aspects with other factors secondary. We examined soil depth and competitive ability of two North American C4 grasses in a greenhouse experiment. Changes in dry mass were determined and competitive intensity was calculated for both species. Species were grown separately or together in pots 30, 90, or 180 cm deep. When grown in monoculture, Schizachyrium scoparium total and belowground dry mass increased from the 30 to 90 cm depth, with no further significant increase from 90 to 180 cm. Aboveground dry mass did not increase significantly with depth. Total dry mass of Buchloe dactyloides increased significantly with depth when grown in monoculture. Aboveground dry mass increased from 30 to 90 cm depth but not from 90 to 180 cm. Belowground dry mass of B. dactyloides did not increase significantly with depth. In 180 cm pots, 53% of S. scoparium root dry mass was in the top 30 cm;74% of B. dactyloides root dry mass was in the top 30 cm. Roots of B. dactyloides were not found deeper than 90 cm. Aboveground dry mass of S. scoparium was not different in mixture or monoculture at any depth. Buchloe dactyloides aboveground dry mass in mixture was significantly lower than monoculture at the 30 cm depth, but not at 90 or 180 cm. The greatest competitive intensity was in the shallow soil pots. Soil depth could partially explain mosaics found in C4 grasslands where both species were found together with S. scoparium on deeper soils and B. dactyloides on shallower soils.
文摘Traditional thermal methods of drying food have often led to loss of flavours, nutrients, vitamins, etc., which encourages non-thermal pretreatments such as osmotic dehydration (OD) and/or high electric field (HEF) application to improve the overall product quality. The aim of this study was to evaluate the effect of osmotic dehydration (50% sucrose) with high electric field strengths of 0.5 and 1.0 kV/cm as pretreatments on the drying kinetics and mass transfer of green apples during convective drying at 65 ~C and microwave drying at 1 W/g. The added value of the OD and HEF on the drying kinetics, and the effective mass transfer coefficients of the subsequent drying methods were investigated through this research. The efficacy of these pre-treatments was assessed and compared using cell disintegration index, product texture and thus bring forth new correlations between these pre-treatments and the cell disintegration index using dielectric spectroscopy and its effect on the product texture.
基金The authors are grateful to CNPq(National Council for Research)and FAPITEC(Foundation for Research Support of Sergipe State)for the financial support received.
文摘In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix were experimentally determined by using infrared (IR) radiation. IR drying of gel coated seeds was carried out at three different temperatures (65℃, 80℃ and 93℃). The shrinkage of the individual particles during drying was quantified by means of the volume and surface area changes evaluated from geometric measurements. The product quality was evaluated in terms of the changes of particle density and percent of cracks in gel coating incurred during drying. Surface area and volume of the gel-seed system decreased about 65% and 80% until the end of the process, respectively, stressing the need to take into account the surface area changes to calculate water flux density as function of moisture content and obtain an accurate interpretation of the drying mechanisms well as to include the volume shrinkage in mass transfer models to determine reliable values of moisture diffusivity. The IR drying behavior of gel-coated seeds was then characterized by the presence of three drying periods: heating up, constant moisture flux and falling moisture flux. Accelerated drying of gel coated seeds was obtained by applying higher IR radiation intensities. The effect of IR source temperature on the particle shrinkage was more pronounced at the constant moisture flux period and practically negligible at the decreasing moisture flux period. Neglecting shrinkage of individual coated-seeds during IR drying led to an erroneous absence of constant flux period and overestimation of the mass transfer by diffusion. Apparent density of the particles was greater at low-temperature IR drying than at high-temperature IR drying. Coated particles keep their original geometry, but a significant cracking of gel coating was observed at rapid drying rate conditions.
基金supported by the Dalian Shipbuilding Industry Co., Ltd
文摘The added mass coefficient and the water level index formulas for the same-phase and anti-phase vibration of rectangular liquid tanks' bulkheads were derived based on dry mode theory. Three fluid-structure interaction numerical methods including Fluid FEM and Fluid BEM were used in this case. The comparison of numerical and theoretical results by the present method shows that ANSYS/Fluid80 is more credible, the NASTRAN/Virtual Mass Method is more suitable for engineering calculations and results of the same-phase vibration by the present method is more accurate.
基金Funded by National Natural Science Foundation of China(Nos.U1134008 and 51302090)the Fundamental Research Funds for the Central Universities(No.2015ZJ0005)
文摘Requirements of self-compacting concrete (SCC) applied in pre-stressed mass concrete structures include high fluidity, high elastic modulus, low adiabatic temperature rise and low drying shrinkage, which cannot be satisfied by ordinary SCC. In this study, in order to solve the problem, a few principles of SCC design were proposed and the effects of binder amount, fly ash (FA) substitution, aggregate content and gradation on the workability, temperature rise, drying shrinkage and elastic modulus of SCC were investigated. The results and analysis indicate that the primary factor influencing the fluidity was paste content, and the main methods improving the elastic modulusof SCC were a lower sand ratio and an optimized coarse aggregate gradation. Lower adiabatic temperature rise and drying shrinkage were beneficial for decreasing the cement content. Further, based on the optimization of mixture, a C50 grade SCC (with binder amount of only 480 kg/ m3, fly ash substitution of 40%, sand ratio of 51% and proper coarse aggregate gradation (Vs.~0 mm: V10-16 ram: V16.20 mm= 30%: 30%:40%)) with superior workability was successfully prepared. The temperature rise and drying shrinkage of the prepared SCC were significantly reduced, and the elastic modulus reached 37.6 GPa at 28 d.
文摘建立了一步式QuEChERS自动提取和净化技术结合气相色谱-串联质谱同时测定风干牦牛肉中15种N-亚硝胺的分析方法。样品水化后,经乙腈提取,加入4.0 g MgSO_(4)和1.0 g NaCl除水,经十八烷基硅烷(C_(18))和N-丙基乙二胺(PSA)填料净化,采用DB-HeavyWAX色谱柱(30 m×0.25 mm×0.25μm)分离15种N-亚硝胺,在多重反应监测(MRM)模式下进行测定,外标法定量。结果表明,15种N-亚硝胺分离性能良好,在0.1~200μg/L范围内线性关系良好,相关系数(r^(2))≥0.999 0;检出限(LOD)为0.05~0.20μg/kg,定量限(LOQ)为0.10~0.50μg/kg;在1倍、2倍和10倍LOQ 3个添加水平下的平均回收率分别为79.4%~102.1%、80.6%~109.5%、83.0%~110.6%,相对标准偏差(RSD)为0.8%~16.0%。应用建立的方法检测2种不同加工工艺的市售样品,其中7种N-亚硝胺类化合物(N-亚硝基二甲胺、N-亚硝基二异丁胺、N-亚硝基二正丁胺、N-亚硝基甲基苯胺、N-亚硝基乙基苯胺、N-亚硝基吡咯烷、N-亚硝基二苯胺)均有不同程度检出,平均含量为0.08~20.18μg/kg,且熟制风干牦牛肉中N-亚硝胺的检出率和平均含量均高于传统生制风干牦牛肉。该方法实现了前处理的自动化,相较于其他传统方法,操作简单,实验效率高,人为影响因素小,检测灵敏度高,适用于风干牦牛肉中15种N-亚硝胺的快速测定,为研究肉制品中N-亚硝胺的测定提供了方法支持。