An aqueous BiI_(3)-Zn battery with dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox

The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms.

Dual-doping for enhancing chemical stability of functional anionic units in sulfide for high-performance all-solid-state lithium batteries

The sulfide-based solid-state electrolytes(SEs)reactivity toward moisture and Li-metal are huge barriers that impede their large-scale manufactu ring and applications in all-solid-state lithium batteries(ASSLBs).Herein,we proposed an Al and O dual-doped strategy for Li_(3)PS_(4)SE to regulate the chemical/electrochemical stability of anionic PS_(4)^(3-)tetrahedra to mitigate structural hydrolysis and parasitic reactions at the SE/Li interface.The optimized Li_(3.08)A_(10.04)P_(0.96)S_(3.92)O_(0.08)SE presents the highestσLi+of 3.27 mS cm^(-1),which is~6.8 times higher than the pristine Li_(3)PS_(4)and excellently inhibits the structural hydrolysis for~25 min@25%humidity at RT.DFT calculations confirmed that the enhanced chemical stability was revealed to the intrinsically stable entities,e.g.,POS33-units.Moreover,Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE cycled stably in Li//Li symmetric cell over 1000 h@0.1 mA cm^(-2)/0.1 mA h cm^(-2),could be revealed to Li-Al alloy and Li_(2)Oat SE/Li interface impeding the growth of Li-dendrites during cycling.Resultantly,LNO@LCO/Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)/Li-In cell delivered initial discharge capacities of 129.8 mA h g^(-1)and 83.74%capacity retention over 300 cycles@0.2 C at RT.Moreover,the Li_(3.08)Al_(0.04)P_(0.96)S_(3.92)O_(0.08)SE presented>90%capacity retention over 200 and 300 cycles when the cell was tested with LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA)cathode material vs.5 and 10 mg cm^(-2)@RT.

叠层橡胶-可滑动钢弹簧振震双控装置隔震(振)效果研究

为解决传统水平隔震支座难以实现竖向减振的难题,研发叠层橡胶-可滑动钢弹簧振震双控装置,提出新型振震双控装置的设计原理及装配方法,结合振动台试验与有限元分析验证该装置的隔震性能,并通过数值仿真分析讨论其竖向减振效果。结果表明:由钢弹簧、摩擦滑移支座和叠层橡胶组成的新型振震双控装置,具有水平和竖向刚度低,抗倾覆能力强的优点;地震动作用下,水平向加速度峰值降低达80%;地铁竖向振动作用下,减振双控装置上部结构的加速度响应减小90%,分频最大振级减小19.93 dB。

Bis(1-(4-(dimethylamino)benzylidene)-4-phenylthiose micarbaznato)palladium(Ⅱ):Synthesis,Crystal Structure and Its Dual Fluorescence Property

The title compound bis（1-（4-（dimethylamino）benzylidene）-4-phenylthiosemicar-bazato）-palladium（Ⅱ）（PdL2） was obtained by reacting 1-（4-（dimethylamino）benzylidene）-4-phenyl-thiosemicarbazide with dichlorobis（benzonitrile）palladium（Ⅱ） in methanol,and its structure was characterized by single-crystal X-ray diffraction.The crystal of PdL2 was obtained in dimethyl-formamide（DMF） solvent with solvent molecules involved in the cell and crystallizes in the monoclinic system,space group C2 with a = 18.485（15）,b = 7.090（5）,c = 17.595（11） ,β = 121.21（3）o,V = 1972（2） 3,Z = 2,Mr = 847.40,Dc = 1.427 g/cm3,μ = 0.624 mm-1,F（000） = 880,R = 0.0607 and wR = 0.1358.The Pd atom adopts a distorted square planar coordination geometry with two Pd-N and two Pd-S bonds.The ligand loses a proton from its tautomeric thiol form and coordinates to the Pd atom via mercapto sulfur and the imine nitrogen atom,which binds to palladium as bidentate N,S-donors forming five-membered chelate rings.The complex formed hydrogen bonding interaction with solvent DMF molecules from the hydrogen of phenylamine to the oxygen of DMF and several intramolecular hydrogen bonds.Pd（Ⅱ） perturbed ligand π-π＊ transition and metal-to-ligand charge transfer（MLCT） transition are observed in its electronic absorption spectra.The complex exhibits intraligand 1π-π＊（IL） state and MLCT state dual fluorescent emissions in organic solvent at room temperature.

2D Coupled 3D:A New Numerical Model for Dual - Structured - Aquifer System

This paper points out that a successful numerical simulation is to construct a correct conceptional model which is very dose to the natural condition. A new model, two dimensional coupled three dimensional model (2D -3D ) is presented in the Present paper,which is the most suitable one for the dual - structured - aquifer system. An example of Wenyinghu area is shown.By using the 2D-3D model, a satisfied result of the simulated area is achieved.

UV-B与重金属Cd双重胁迫对麦长管蚜种群生长发育和繁殖的影响

【目的】为探究UV-B和重金属Cd双重胁迫对麦长管蚜Sitobion avenae(Fabricius)生长发育和繁殖的影响,以及UV-B和重金属Cd两因素间的交互作用。【方法】在室内,不同辐射强度UV-B(0,0.1,0.2和0.7 m W/cm^2)与不同浓度重金属Cd(0,20,40,80和160 mg/kg)处理后,采用特定年龄生命表方法,统计麦长管蚜种群参数、繁殖参数、存活率和繁殖力的变化。【结果】麦长管蚜种群的生命表各参数受UV-B与重金属Cd双重胁迫影响显著,且UV-B对麦长管蚜的生命表各参数影响要大于重金属Cd;UV-B和重金属Cd两因素间存在交互作用。同一重金属Cd浓度时,随着UV-B辐射强度的增加,麦长管蚜种群的内禀增长率r、周限增长率λ、净增殖率R_0、繁殖力F、产仔天数和成虫寿命均呈现先下降后上升的趋势,且均在UV-B辐射强度为0.2 m W/cm^2时下降至最低点;而麦长管蚜种群的平均世代周期T则呈现先升高后下降的趋势,且在UV-B辐射强度为0.1m W/cm^2时上升至最高点。同一UV-B辐射强度下,随着重金属Cd浓度的增加,麦长管蚜种群生命表各参数均呈现波动变化;双重胁迫处理组麦长管蚜种群内禀增长率r、周限增长率λ、净增殖率R_0、繁殖力F、产仔天数和成虫寿命均显著低于单一重金属Cd处理组,而其平均世代周期T显著高于单一重金属Cd处理组,且双重胁迫处理组生命表各参数的峰值点较单一因素重金属Cd处理组均呈现不同程度的提前。【结论】UV-B与重金属Cd影响麦长管蚜种群的生长发育和繁殖,且由于这两因素间存在交互作用,二者双重胁迫对麦长管蚜种群的生长发育和繁殖影响更加严重。

旱区湿地周边盐渍化农田生态水位阈值与“水位-水量”双控技术

西北旱区湿地周边农田易盐渍化,合理实时控制和降低地下水水位是实现湿地保护及其周边农田盐渍化防控“双赢”的有效途径。选取西北石羊河流域邓马营湖湿地与农田之间过渡带为示范研究区,通过分析地下水埋深变化特征及其与表层土壤盐分的协同关系,确定生态水位阈值,并基于该阈值研发了由虹吸辐射井群为支撑的地下水“水位-水量”智能双控技术,其关键点是:采用一井虹吸联通多个辐射井,用于增大弱透水层区单井涌水量,实现水位面状控制;利用电系统、信号系统和控制器集成智能控制子系统,实现地下水水位和水量的实时控制。该技术示范应用结果表明:随地下水埋深增大,农田盐渍化风险和湿地植被芦苇覆盖率均降低,农田盐渍化防控和湿地保护的地下水埋深阈值为1.9~3.0 m;每年7—8月的潜水蒸发阶段是表层土壤主要积盐时段,期间智能双控系统可将地下水埋深调控在水位阈限范围;该双控作用不仅能够控降灌溉引起的表层土壤电导率的增大幅度,而且还能有效降低表层土壤的积盐速率;相对微咸水,淡水灌溉条件下智能双控技术的淋盐和控盐效果更明显。因此,这项技术能够实现地下水水位精准调控,对旱区湿地保护及其周边农田盐渍化防控具有重要的现实意义。

A-C双转台五轴机床数控加工安全性研究

针对A-C双转台五轴机床加工中的干涉、加工盲区问题,通过对数控加工中实际情况进行分析,从其产生原因入手,首先从CAM软件编程设置控制刀轴、计算夹具的安全高度抬升工件这两个方面避免刀具、刀柄或主轴部件与非加工部位发生干涉;然后通过A、C旋转角的优化规定A角度的取值为零或负值,解决了加工盲区问题;最后通过VERICUT软件仿真及实例加工验证了这3种方法对A-C双转台五轴机床加工中安全性的提升具有重要的实用价值。

舰艇会议桌-手术床两用装置设计研究

目的:设计能够同时满足舰艇日常会议、急救手术需求的两用装置。方法:会议桌-手术床两用结构主要由面板机构、支撑机构、面板展收机构、手术体位调节机构、手术器械盘托架机构等部分组成,对各部分设计通过三维建模来实现。结果:设计了一种全机械结构的会议桌-手术床两用装置,平时处于会议桌状态,需要手术时可快速转换为手术床状态,在此状态下能够实现的手术体位包括平躺、头部放低和腿部放低。结论:较好地解决了舰艇会议室开展紧急救治手术时存在的诸多问题,对提高舰艇伤员急救效率、减少伤死率具有重大意义。

Stick–slip behavior of Indian gabbro as studied using a NIED large-scale biaxial friction apparatus

This paper reports stick-slip behaviors of Indian gabbro as studied using a new large-scale biaxial friction apparatus, built in the National Research Institute for Earth Science and Disaster Prevention （NIED）, Tsukuba, Japan. The apparatus consists of the existing shaking table as the shear-loading device up to 3,600 kN, the main frame for holding two large rectangular prismatic specimens with a sliding area of 0.75 m^2 and for applying normal stresses an up to 1.33 MPa, and a reaction force unit holding the stationary specimen to the ground. The shaking table can produce loading rates v up to 1.0 m/s, accelerations up to 9.4 m/s^2, and displacements d up to 0.44 m, using four servocontrolled actuators. We report results from eight preliminary experiments conducted with room humidity on the same gabbro specimens at v = 0.1-100 mm/s and an = 0.66-1.33 MPa, and with d of about 0.39 m. The peak and steady-state friction coefficients were about 0.8 and 0.6, respectively, consistent with the Byerlee friction. The axial force drop or shear stress drop during an abrupt slip is linearly proportional to the amount of displacement, and the slope of this rela- tionship determines the stiffness of the apparatus as 1.15 × 10^8 N/m or 153 MPa/m for the specimens we used. This low stiffness makes fault motion very unstable and the overshooting of shear stress to a negative value was recognized in some violent stick-slip events. An abrupt slip occurred in a constant rise time of 16-18 ms despite wide variation of the stress drop, and an average velocity during an abrupt slip is linearly proportional to the stress drop. The use of a large-scale shaking table has a great potential in increasing the slip rate and total displacement in biaxial friction experiments with large specimens.

飞利浦MX4000 Dual型CT机故障维修2例

0引言飞利浦MX4000 Dual型CT机又称为＂MX荣耀CT＂,是飞利浦医疗2005年推出的最新型双排CT产品。飞利浦MX4000 Dual型CT机在各项硬件指标上均处于领先地位,并在综合性能上基本能够满足临床需求。我院自2008年安装至今,机器运转良好,年开机率可达95%以上。但有时也会出现故障,现将该设备出现的2例故障分析和处理方法介绍如下,供同行参考。

Stroke optimization of a novel multi-station rotary polishing robot based on workspace analysis

In order to meet the polishing requirement of faucets and other products,a novel multi-station rotary polishing robot is designed,which is a PPPR + RR type of degree of freedom( DOF) distribution structure,and is similar to dual-arm robot. Forward and inverse kinematic analysis is carried out by robot modeling. In order to make this robot structure more compact,first of all,X,Y and Z three moving degrees of freedom( DOF) limit stroke polishing need is calculated by using an artificial fish swarm algorithm,which analyzes dexterous workspace of this robot. Then,on the basis of the above analysis,the three DOF stroke is optimized. Simulation and polishing experimental results verify that this polishing robot with optimized stroke parameters can meet the polishing needs of faucets and other bathroom pieces.

数控X-Y平台伺服控制系统的双内模控制研究

基于先进的内模控制理论,针对数控X-Y平台伺服控制系统的位置速度双闭环系统提出了一种双内模控制结构,并进行了伺服控制系统的控制器设计。所设计的速度控制器为PI结构,具有对控制对象参数变化的鲁棒性能;设计的伺服位置控制器为PID结构,只有一个可调参数,调整方便。仿真实验验证了内模控制方法设计的系统性能优于工程设计方法设计的性能。

DUAL CS505—4 LP唱盘

自1994年推出大受LP发烧友欢迎的Orbe唱盘之后,设计师JohnMichel 1已经很久没有推出新产品了,眼前所见这款GyroDec唱盘其实也不能算是全新品。

双循环新发展格局下中国科技服务业参与全球生产网络研究

科技服务业作为现代服务业的重要组成部分,加快科技服务业发展,对于推动经济提质增效升级具有重要意义。运用社会网络法分析2000-2014年世界投入产出表,分析国际科技服务业发展趋势及我国内外循环中科技服务业发展现状。研究表明,我国科技服务业正处于高速发展阶段,在全球生产网络中影响力逐渐扩大,并逐渐向全球生产网络中心迁移。对于内循环,国内科技服务业生产网络变化不大,其前后向联系部门呈分散化,科技服务部门发展不均衡。