Novel ionic liquids with dual acidity, of which the cation contains Brφnsted acidity and anions contain Lewis acidity were synthesized. These ionic liquids obtained were identified by NMR, FF-IR, SDT and FAB-MS. Thei...Novel ionic liquids with dual acidity, of which the cation contains Brφnsted acidity and anions contain Lewis acidity were synthesized. These ionic liquids obtained were identified by NMR, FF-IR, SDT and FAB-MS. Their acidities were determined by pyridine probe on IR spectrography.展开更多
Micro-arc oxidation （MAO） process was cartied out in an optimized dual electrolyte system to fabricate a compact, smooth, and corrosion resistant coating on ZK60 Mg alloy. The microstructural characteristics of coat...Micro-arc oxidation （MAO） process was cartied out in an optimized dual electrolyte system to fabricate a compact, smooth, and corrosion resistant coating on ZK60 Mg alloy. The microstructural characteristics of coating were investigated by scanning electron microscopy （SEM） coupled with an energy dispersive spectrometer （EDS） and X-ray diffraction （XRD）. Test of mass loss was conducted at a 3.5 % NaCl solution to assess the resistance to corrosion. The bonding strength between the coating and ZK60 substrate was evaluated using scratch experiment. The results reveal that MgA1204 and MgO are the main phases of ceramic coating obtained in the dual electrolyte system. The corrosion rate of coating prepared in the optimized dual electrolyte is only 0.0061 g.m-2.h-1, which demonstrates excellent corrosion resistance. This is mainly due to the compact, uniform coating with high bonding strength.展开更多
In this paper, the synchronous concurrent dual-band RF signal is used to drive the RF Power Amplifier (PA). The nonlinear characterization of a concurrent dual-band RF PA is discussed while two band signals in the dua...In this paper, the synchronous concurrent dual-band RF signal is used to drive the RF Power Amplifier (PA). The nonlinear characterization of a concurrent dual-band RF PA is discussed while two band signals in the dual-band are modulated by CDMA2000 and WCDMA signals. When the two band signals in the dual-band of the PA are modulated with the same signals, it is found that the nonlinearity of the PA can be expressed by any of the two corresponding baseband data. On the other hand, when the two band signals in the dual-band of the PA are modulated with two different signals, the PA nonlinearity cannot be characterized by any of the two corresponding baseband data. In this case, its nonlinearity has to be denoted by a composite signals consisting of the two baseband signals. Consequently, the requirements for the speed of the A/D converter can be largely reduced. The experimental results with CDMA2000 and WCDMA signals demonstrate the speed of the A/D converter required is only 30 M Sample Per Second (SaPS), but it will be at least 70 M SaPS for the conventional method.展开更多
Conventional electron and optical microscopy techniques require the sample to be sectioned, polished or etched to expose the internal surfaces for imaging. However, such sample preparation techniques have traditionall...Conventional electron and optical microscopy techniques require the sample to be sectioned, polished or etched to expose the internal surfaces for imaging. However, such sample preparation techniques have traditionally prevented the observation of the same sample over time, under realistic three-dimensional geometries and in an environment representative of real-world operating conditions. X-ray microscopy (XRM) is a rapidly emerging technique that enables non-destructive evaluation of buried structures within hard to soft materials in 3D, requiring little to no sample preparation. Furthermore in situ and 4D quantification of microstructural evolution under controlled environment as a function of time, temperature, chemistry or stress can be done repeatable on the same sample, using practical specimen sizes ranging from tens of microns to several cm diameter, with achievable imaging resolution from submicron to 50 nm. Many of these studies were reported using XRM in synchrotron beamlines. These include crack propagation on composite and construction materials; corrosion studies; microstructural changes during the setting of cement; flow studies within porous media to mention but a few.展开更多
基金the‘973’Program of the Chinese Ministry of Science and Technology(G-2000048002).
文摘Novel ionic liquids with dual acidity, of which the cation contains Brφnsted acidity and anions contain Lewis acidity were synthesized. These ionic liquids obtained were identified by NMR, FF-IR, SDT and FAB-MS. Their acidities were determined by pyridine probe on IR spectrography.
基金supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions and the Key Laboratory of Advanced Welding Technology of Jiangsu Province, China (No. JSAWT-11)
文摘Micro-arc oxidation （MAO） process was cartied out in an optimized dual electrolyte system to fabricate a compact, smooth, and corrosion resistant coating on ZK60 Mg alloy. The microstructural characteristics of coating were investigated by scanning electron microscopy （SEM） coupled with an energy dispersive spectrometer （EDS） and X-ray diffraction （XRD）. Test of mass loss was conducted at a 3.5 % NaCl solution to assess the resistance to corrosion. The bonding strength between the coating and ZK60 substrate was evaluated using scratch experiment. The results reveal that MgA1204 and MgO are the main phases of ceramic coating obtained in the dual electrolyte system. The corrosion rate of coating prepared in the optimized dual electrolyte is only 0.0061 g.m-2.h-1, which demonstrates excellent corrosion resistance. This is mainly due to the compact, uniform coating with high bonding strength.
基金Supported by the National Science and Technology Major Project of China (2010ZX03007-003-04)the National Natural Science Foundation of China (No. 61171040)+4 种基金the Key Project of International Cooperation of the Provincial Science and Technology Major Projects of Zhejiang (2010C14007)the Provincial Natural Science Foundation of Zhejiang (Y1101270)the Natural Science Foundation of Ningbo (2011A610188)Key Project of International Scientific and Technical Cooperation of Yunnan (2009AC010)Excellent Papers Engagement Fund of Ningbo University (PY20100004)
文摘In this paper, the synchronous concurrent dual-band RF signal is used to drive the RF Power Amplifier (PA). The nonlinear characterization of a concurrent dual-band RF PA is discussed while two band signals in the dual-band are modulated by CDMA2000 and WCDMA signals. When the two band signals in the dual-band of the PA are modulated with the same signals, it is found that the nonlinearity of the PA can be expressed by any of the two corresponding baseband data. On the other hand, when the two band signals in the dual-band of the PA are modulated with two different signals, the PA nonlinearity cannot be characterized by any of the two corresponding baseband data. In this case, its nonlinearity has to be denoted by a composite signals consisting of the two baseband signals. Consequently, the requirements for the speed of the A/D converter can be largely reduced. The experimental results with CDMA2000 and WCDMA signals demonstrate the speed of the A/D converter required is only 30 M Sample Per Second (SaPS), but it will be at least 70 M SaPS for the conventional method.
文摘Conventional electron and optical microscopy techniques require the sample to be sectioned, polished or etched to expose the internal surfaces for imaging. However, such sample preparation techniques have traditionally prevented the observation of the same sample over time, under realistic three-dimensional geometries and in an environment representative of real-world operating conditions. X-ray microscopy (XRM) is a rapidly emerging technique that enables non-destructive evaluation of buried structures within hard to soft materials in 3D, requiring little to no sample preparation. Furthermore in situ and 4D quantification of microstructural evolution under controlled environment as a function of time, temperature, chemistry or stress can be done repeatable on the same sample, using practical specimen sizes ranging from tens of microns to several cm diameter, with achievable imaging resolution from submicron to 50 nm. Many of these studies were reported using XRM in synchrotron beamlines. These include crack propagation on composite and construction materials; corrosion studies; microstructural changes during the setting of cement; flow studies within porous media to mention but a few.
