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Current optimization-based control of dual three-phase PMSM for low-frequency temperature swing reduction
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作者 Linlin Lu Xueqing Wang +3 位作者 Luhan Jin Qiong Liu Yun Zhang Yao Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期238-246,共9页
In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur... In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction. 展开更多
关键词 dual three-phase PMSM Low-frequency temperature swing Copper loss Current optimization Connected neutral points
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Speed Regulation Method Using Genetic Algorithm for Dual Three-phase Permanent Magnet Synchronous Motors 被引量:1
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作者 Xiuhong Jiang Yuying Wang Jiarui Dong 《CES Transactions on Electrical Machines and Systems》 CSCD 2023年第2期171-178,共8页
Dual three-phase Permanent Magnet Synchronous Motor(DTP-PMSM)is a nonlinear,strongly coupled,high-order multivariable system.In today’s application scenarios,it is difficult for traditional PI controllers to meet the... Dual three-phase Permanent Magnet Synchronous Motor(DTP-PMSM)is a nonlinear,strongly coupled,high-order multivariable system.In today’s application scenarios,it is difficult for traditional PI controllers to meet the requirements of fast response,high accuracy and good robustness.In order to improve the performance of DTP-PMSM speed regulation system,a control strategy of PI controller based on genetic algorithm is proposed.Firstly,the basic mathematical model of DTP-PMSM is established,and the PI parameters of DTP-PMSM speed regulation system are optimized by genetic algorithm,and the modeling and simulation experiments of DTP-PMSM control system are carried out by MATLAB/SIMULINK.The simulation results show that,compared with the traditional PI control,the proposed algorithm significantly improves the performance of the control system,and the speed output overshoot of the GA-PI speed control system is smaller.The anti-interference ability is stronger,and the torque and double three-phase current output fluctuations are smaller. 展开更多
关键词 dual three-phase permanent magnet synchronous motor Genetic algorithm PI control Speed regulation
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Zero-sequence Current Suppressing Strategy for Dual Three-phase Permanent Magnet Synchronous Machines Connected with Single Neutral Point 被引量:2
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作者 Zongwang Li Yuxuan Du +2 位作者 Jinghua Ji Tao Tao Wenxiang Zhao 《CES Transactions on Electrical Machines and Systems》 CSCD 2022年第4期465-472,共8页
Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM... Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM)strategy to suppress the ZSC.Five vectors are selected as basic voltage vectors in one switching period.The fundamental and harmonic planes and the zero-sequence plane are taken into consideration to synthesis the reference voltage vector.To suppress the ZSC,a non-zero zero-sequence voltage(ZSV)is generated to compensate the third harmonic back-EMF.Rather than triangular carrier modulation,the sawtooth carrier modulation strategy is used to generate asymmetric PWM signals.The modulation range is investigated to explore the variation of modulation range caused by considering the zero-sequence plane.With the proposed method,the ZSC can be considerably reduced.The simulated and experimental results are presented to validate the effectiveness of the proposed modulation strategy. 展开更多
关键词 Zero-sequence current a single neutral point dual three-phase permanent-magnet synchronous machine third harmonic back-EMF
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Electromagnetic Performance Prediction for the Symmetrical Dual Three-phase Surface-mounted PMSM under Open-phase Faults Based on Accurate Subdomain Model 被引量:1
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作者 Zhe Liang Deliang Liang +1 位作者 Peng Kou Shaofeng Jia 《CES Transactions on Electrical Machines and Systems》 CSCD 2022年第4期422-437,共16页
The paper presents an accurate analytical subdomain model for predicting the electromagnetic performance in the symmetrical dual three-phase surface-mounted permanent magnet synchronous machine(PMSM)under open-phase f... The paper presents an accurate analytical subdomain model for predicting the electromagnetic performance in the symmetrical dual three-phase surface-mounted permanent magnet synchronous machine(PMSM)under open-phase faulty conditions.The model derivations are extended from previous accurate subdomain models accounting for slotting effects.Compared with most conventional subdomain models for traditional three-phase machines with nonoverlapping winding arrangement,the subdomain model proposed in this paper applied for the 24-slot/4-pole dual three-phase machine with symmetrical overlapping winding arrangement.In order to investigate the postfault electromagnetic performance,the reconfigured phase currents and then current density distribution in stator slots under different open-circuit conditions are discussed.According to the developed model and postfault current density distribution,the steady-state electromagnetic performance,such as the electromagnetic torque and unbalanced magnetic force,under open-circuit faulty conditions are obtained.For validation purposes,finite element analysis(FEA)is employed to validate the analytical results.The result indicate that the postfault electromagnet performance can be accurately predicted by the proposed subdomain model,which is in good agreement with FEA results. 展开更多
关键词 dual three-phase Permanent magnet synchronous machine Subdomain model Electromagnetic torque Unbalanced magnetic force Open-phase fault
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Steady State Analysis of an Isolated Self-Excited Dual Three-Phase Induction Generator for Renewable Energy
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作者 Mohamed Arbi Khlifi Badr M. Alshammari 《International Journal of Modern Nonlinear Theory and Application》 2014年第5期191-198,共8页
In this paper modelling and analysis in autonomous mode of dual three-phase induction generator (DTPIG) with a new algorithm have been done. We develop the steady state model of a dual three-phase self-excited inducti... In this paper modelling and analysis in autonomous mode of dual three-phase induction generator (DTPIG) with a new algorithm have been done. We develop the steady state model of a dual three-phase self-excited induction generator for stand-alone renewable generation dispensing with the segregating real and imaginary components of the complex impedance of the induction generator. The obtained admittance yields the adequate magnetizing reactance and the frequency. These two key parameters are then used to compute the self-excitation process requirements in terms of the prime mover speed, the capacitance and the load impedance on the one hand and to predict the generator steady state performance parameters on the other. Steady state performances and characteristics of different configurations are clearly examined and compared. The analytical results are found to be in good agreement with experimental results. 展开更多
关键词 dual STATOR WINDINGS Asynchronous Generator Autonomous Mode STEADY State Analysis RENEWABLE Electric Energy Generation
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Fault-tolerant stator flux oriented decoupling control for dual three-phase permanent magnet motor without diagnosis and reconfiguration
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作者 HUANG LinSen ZHAO WenXiang +2 位作者 TAO Tao CUI Jia ZHANG Qiang 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2023年第11期3206-3218,共13页
In this paper,the fault-tolerant capability of the existing stator-flux-oriented decoupling control(SFOC)for the DTP-PM motor is investigated,and a simple fault-tolerant SFOC is further designed to enhance fault toler... In this paper,the fault-tolerant capability of the existing stator-flux-oriented decoupling control(SFOC)for the DTP-PM motor is investigated,and a simple fault-tolerant SFOC is further designed to enhance fault tolerance.Firstly,the mathematical model of the DTP-PM motor in the stator-flux-oriented rotating coordinate system is analyzed.An SFOC is proposed to guarantee healthy operation performance,considering torque,flux linkage,and harmonic currents.Secondly,the coupling relationship under open-phase conditions is assessed.The assessed result shows that the coupling relationship between the harmonic and fundamental components results in conflicts and poor post-fault operation.Thirdly,the proposed SFOC includes an automatic deactivation module to detect conflicts with a variable threshold.The conflicted harmonic current controllers can be excluded automatically.Hence,fault-tolerant control can be remedied without diagnosing the specific fault scenario,and excellent faulttolerant capability can be achieved.Finally,experiments on a DTP-PM motor are carried out to verify the feasibility and effectiveness of the proposed strategy. 展开更多
关键词 dual three-phase motor stator flux orientation decoupling control fault-tolerant control open-phase fault
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Model Predictive Torque Control for a Dual Three-phase PMSM Using Modified Dual Virtual Vector Modulation Method
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作者 Zhujin Ren Jinghua Ji +3 位作者 Hongyu Tang Tao Tao Linsen Huang Wenxiang Zhao 《Chinese Journal of Electrical Engineering》 CSCD 2022年第4期91-103,共13页
Single voltage vectors applied in the conventional model predictive torque control(MPTC)for multiphase motors do not only suffer from serious torque and stator flux ripples but also cause the large harmonic current.To... Single voltage vectors applied in the conventional model predictive torque control(MPTC)for multiphase motors do not only suffer from serious torque and stator flux ripples but also cause the large harmonic current.To address the aforementioned challenges,an MPTC using a modified dual virtual vector modulation method is proposed to improve the operational performance of a dual three-phase permanent magnet synchronous motor.Virtual voltage vectors are synthesized as the candidate control set to restrain the harmonic current.A transformation method is introduced to consider both the stator flux and torque in the duty cycle modulation.The torque and stator flux ripples are simultaneously reduced by addressing the limitations of nonuniform units.Furthermore,the null voltage vector is then inserted to expand the modulation range and improve the steady-state performance.Moreover,the sawtooth carrier is adopted to address the challenge of the asymmetric switch sequence caused by the modified modulation.Finally,the experimental results are presented to verify the effectiveness and superiority of the proposed MPTC method. 展开更多
关键词 Model predictive torque control dual three-phase motor permanent magnet synchronous motor dual virtual vector modulation
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Dual-Path Vision Transformer用于急性缺血性脑卒中辅助诊断
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作者 张桃红 郭学强 +4 位作者 郑瀚 罗继昌 王韬 焦力群 唐安莹 《电子科技大学学报》 EI CAS CSCD 北大核心 2024年第2期307-314,共8页
急性缺血性脑卒中是由于脑组织血液供应障碍导致的脑功能障碍,数字减影脑血管造影(DSA)是诊断脑血管疾病的金标准。基于患者的正面和侧面DSA图像,对急性缺血性脑卒中的治疗效果进行分级评估,构建基于Vision Transformer的双路径图像分... 急性缺血性脑卒中是由于脑组织血液供应障碍导致的脑功能障碍,数字减影脑血管造影(DSA)是诊断脑血管疾病的金标准。基于患者的正面和侧面DSA图像,对急性缺血性脑卒中的治疗效果进行分级评估,构建基于Vision Transformer的双路径图像分类智能模型DPVF。为了提高辅助诊断速度,基于EdgeViT的轻量化设计思想进行了模型的构建;为了使模型保持轻量化的同时具有较高的精度,提出空间-通道自注意力模块,促进Transformer模型捕获更全面的特征信息,提高模型的表达能力;此外,对于DPVF的两分支的特征融合,构建交叉注意力模块对两分支输出进行交叉融合,促使模型提取更丰富的特征,从而提高模型表现。实验结果显示DPVF在测试集上的准确率达98.5%,满足实际需求。 展开更多
关键词 急性缺血性脑卒中 视觉Transformer 双分支网络 特征融合
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Deciphering engineering principle of three-phase interface for advanced gas-involved electrochemical reactions 被引量:2
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作者 Yanzheng He Sisi Liu +3 位作者 Mengfan Wang Qiyang Cheng Tao Qian Chenglin Yan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期302-323,I0008,共23页
As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen e... As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions. 展开更多
关键词 three-phase reaction Surface reactions Mass diffusion Electron transfer Gas-involved electrochemical reactions
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Electrical characteristics of new three-phase traction power supply system for rail transit 被引量:1
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作者 Xiaohong Huang Hanlin Wang +4 位作者 Qunzhan Li Naiqi Yang Tao Ren You Peng Haoyang Li 《Railway Engineering Science》 2023年第1期75-88,共14页
A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.... A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%. 展开更多
关键词 three-phase AC power supply Two-stage power supply structure Electrical characteristics Current distribution Voltage losses Regenerative energy
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Electron-distribution control via Pt/NC and MoC/NC dual junction:Boosted hydrogen electro-oxidation and theoretical study 被引量:1
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作者 Feng Zhou Xiaofeng Ke +8 位作者 Yihuang Chen Mei Zhao Yun Yang Youqing Dong Chao Zou Xi’an Chen Huile Jin Lijie Zhang Shun Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期513-520,I0011,共9页
The scarcity,high cost and susceptibility to CO of Platinum severely restrict its application in alkaline hydrogen oxidation reaction(HOR).Hybridizing Pt with other transition metals provides an effective strategy to ... The scarcity,high cost and susceptibility to CO of Platinum severely restrict its application in alkaline hydrogen oxidation reaction(HOR).Hybridizing Pt with other transition metals provides an effective strategy to modulate its catalytic HOR performance,but at the cost of mass activity due to the coverage of modifiers on Pt surface.Herein,we constructed dual junctions'Pt/nitrogen-doped carbon(Pt/NC)andδ-MoC/NC to modify electronic structure of Pt via interfacial electron transfer to acquire Pt-MoC@NC catalyst with electron-deficient Pt nanoparticles,simultaneously endowing it with high mass activity and durability of alkaline HOR.Moreover,the unique structure of Pt-MoC@NC endows Pt with a high COtolerance at 1,000 ppm CO/H_(2),a quality that commercial Pt-C catalyst lacks.The theoretical calculations not only confirm the diffusion of electrons from Pt/NC to Mo C/NC could occur,but also demonstrate the negative shift of Pt d-band center for the optimized binding energies of*H,*OH and CO. 展开更多
关键词 Hydrogen oxidation reaction dual junctions CO-tolerance PLATINUM
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Optimization of Control Loops and Operating Parameters for Three-Phase Separators Used in Oilfield Central Processing Facilities
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作者 Zhenfeng Li Yaqiao Li Guangjun Wei 《Fluid Dynamics & Materials Processing》 EI 2023年第3期635-649,共15页
In this study,the Stokes formula is used to analyze the separation effect of three-phase separators used in a Oilfield Central Processing Facility.The considered main influencing factors include(but are not limited to... In this study,the Stokes formula is used to analyze the separation effect of three-phase separators used in a Oilfield Central Processing Facility.The considered main influencing factors include(but are not limited to)the typical size of oil and water droplets,the residence time and temperature of fluid and the dosage of demulsifier.Using the“Specification for Oil and Gas Separators”as a basis,the control loops and operating parameters of each separator are optimized Considering the Halfaya Oilfield as a testbed,it is shown that the proposed approach can lead to good results in the production stage. 展开更多
关键词 Distributed control system(DCS) three-phase separator control loop operating parameter
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A strategy for strengthening chaotic mixing of dual shaft eccentric mixers by changing non-Newtonian fluids kinetic energy distribution 被引量:1
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作者 Songsong Wang Tong Meng +4 位作者 Qian Zhang Changyuan Tao Yundong Wang Zequan Li Zuohua Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期122-134,共13页
Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier ... Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier for the existing technologies.Accordingly,this work reports a convenient strategy that changes the kinetic energy to controllably regulate the flow patterns from radial flow to axial flow.Results showed that the desired velocity distribution and flow patterns could be effectively obtained by varying the number and structure of baffles to change kinetic energy,and a more uniform velocity distribution,which could not be reached normally in standard baffle dual shaft mixers,was easily obtained.Furthermore,a comparative analysis of velocity and shear rate distributions is employed to elucidate the mechanism behind the generation of flow patterns in various dual-shaft eccentric mixers.Importantly,there is little difference in the power number of the laminar flow at the same Reynolds number,meaning that the baffle type has no effect on the power consumption,while the power number of both unbaffle and U-shaped baffle mixing systems decreases compared with the standard baffle mixing system in the transition flow.Finally,at the same rotational condition,the dimensionless mixing time of the U-shaped baffle mixing system is 15.3%and 7.9%shorter than that of the standard baffle and the unbaffle mixing system,respectively,which shows the advantage of the U-shaped baffle in stirring rate. 展开更多
关键词 dual shaft “U-shaped”baffle Flow pattern Mixing time Power demand
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Purification of Moringa oleifera Leaves Protease by Three-Phase Partitioning and Investigation of Its Potential Antibacterial Activity
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作者 Adam Abdoulaye Agossou D. P. Noumavo +6 位作者 Durand Dah-Nouvlessounon Messan A. B. Ohin Hasan Bayraktar Farid T. Bade Honoré S. Bankole Lamine Baba-Moussa Farid Baba-Moussa 《American Journal of Plant Sciences》 CAS 2023年第1期64-76,共13页
One of plant-based products for dental care is plant-based proteolytic enzymes which are principally proteases. In order not to damage the protein and bioactive content, an efficient method should be employed for thei... One of plant-based products for dental care is plant-based proteolytic enzymes which are principally proteases. In order not to damage the protein and bioactive content, an efficient method should be employed for their purifications. As such, three-phase partitioning (TPP) was used to purify protease from moringa (Moringa oleifera). TPP is an emerging, promising, non-chromatographic and economical technology which is simple, quick, efficient and often one-step process for the separation and purification of bioactive molecules from natural sources. It involves the addition of salt (ammonium sulphate) to the crude extract followed by the addition of an organic solvent (butanol). The protein appears as an interfacial precipitate between upper organic solvent and lower aqueous phases. The various conditions such as ammonium sulphate, ratio of crude extract to t-butanol and pH which are required for attaining efficient purification of the protease fractions were optimized. Under optimized conditions, it was seen that, 35% of ammonium sulphate saturation with 1:0.75 ratio of crude extract to t-butanol at pH 7 gave 4.94-fold purification with 96.20% activity yield of protease in the middle phase of the TPP system. The purified enzyme from Moringa oleifera has no antimicrobial effect on the pathogenic bacteria tested. However, this purified enzyme, can be considered as a promising agent, cheap, and safe source which is suitable for using in various industries. 展开更多
关键词 three-phase Partitioning Moringa oleifera PROTEASE Protein Purification ANTIMICROBIAL
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Vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers under blast load
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作者 Quoc-Hoa Pham Van Ke Tran Trung Thanh Tran 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第6期148-163,共16页
In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order... In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order shear deformation theory(HSDT)to achieve the governing equations.The sandwich plates with the ultra-light feature of the auxetic honeycomb core layer(negative Poisson’s ratio)and reinforced by two laminated three-phase skin layers.The obtained results in our work are compared with other previously published to confirm accuracy and reliability.In addition,the effects of parameters such as geometrical and material parameters on the vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers are fully investigated. 展开更多
关键词 Laminated three-phase Sandwich plate Auxetic honeycomb ES-MITC3 element High-order shear deformation theory
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Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries 被引量:1
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作者 Baolin Wu Chunguang Chen +4 位作者 Dmitri L.Danilov Zhiqiang Chen Ming Jiang Rüdiger-A.Eichel Peter H.L.Notten 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期84-92,共9页
Anode-free Li-metal batteries are of significant interest to energy storage industries due to their intrinsically high energy.However,the accumulative Li dendrites and dead Li continuously consume active Li during cyc... Anode-free Li-metal batteries are of significant interest to energy storage industries due to their intrinsically high energy.However,the accumulative Li dendrites and dead Li continuously consume active Li during cycling.That results in a short lifetime and low Coulombic efficiency of anode-free Li-metal batteries.Introducing effective electrolyte additives can improve the Li deposition homogeneity and solid electrolyte interphase(SEI)stability for anode-free Li-metal batteries.Herein,we reveal that introducing dual additives,composed of LiAsF6 and fluoroethylene carbonate,into a low-cost commercial carbonate electrolyte will boost the cycle life and average Coulombic efficiency of NMC‖Cu anode-free Li-metal batteries.The NMC‖Cu anode-free Li-metal batteries with the dual additives exhibit a capacity retention of about 75%after 50 cycles,much higher than those with bare electrolytes(35%).The average Coulombic efficiency of the NMC‖Cu anode-free Li-metal batteries with additives can maintain 98.3%over 100 cycles.In contrast,the average Coulombic efficiency without additives rapidly decline to 97%after only 50 cycles.In situ Raman measurements reveal that the prepared dual additives facilitate denser and smoother Li morphology during Li deposition.The dual additives significantly suppress the Li dendrite growth,enabling stable SEI formation on anode and cathode surfaces.Our results provide a broad view of developing low-cost and high-effective functional electrolytes for high-energy and long-life anode-free Li-metal batteries. 展开更多
关键词 anode-free lithium metal battery dual additives in situ Raman Li growth SEI formation
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Enhancing ammonia production rates from electrochemical nitrogen reduction by engineering three-phase boundary with phosphorus-activated Cu catalysts
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作者 Jeehye Kim Cho Hee Lee +5 位作者 Yong Hyun Moon Min Hee Lee Eun Hyup Kim Sun Hee Choi Youn Jeong Jang Jae Sung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期394-401,共8页
Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to i... Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to its low solubility in aqueous electrolytes.Herein,we propose phosphorus-activated Cu electrocatalysts to generate electron-deficient Cu sites on the catalyst surface to promote the adsorption of N_(2) molecules.The eNRR system is further modified using a gas diffusion electrode(GDE) coated with polytetrafluoroethylene(PTFE) to form an effective three-phase boundary of liquid water-gas N_(2)-solid catalyst to facilitate easy access of N_(2) to the catalytic sites.As a result,the new catalyst in the flow-type cell records a Faradaic efficiency of 13.15% and an NH_(3) production rate of 7.69 μg h^(-1) cm^(-2) at-0.2 V_(RHE),which represent 3.56 and 59.2 times increases from those obtained with a pristine Cu electrode in a typical electrolytic cell.This work represents a successful demonstration of dual modification strategies;catalyst modification and N_(2) supplying system engineering,and the results would provide a useful platform for further developments of electrocatalysts and reaction systems. 展开更多
关键词 Electrochemical nitrogen reduction reaction Ammonia production Phosphorous modified copper electrodes Gas diffusion electrodes three-phase boundary PTFE coating
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Automatic measurement of three-phase contact angles in pore throats based on digital images
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作者 ZANG Chuanzhen WANG Lida +3 位作者 ZHOU Kaihu YU Fuwei JIANG Hanqiao LI Junjian 《Petroleum Exploration and Development》 SCIE 2023年第2期442-449,共8页
With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flood... With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flooding experiment videos as the data source. The results of the new method were verified through comparing with the manual measurement data.On this basis, the dynamic changes of the three-phase contact angles under flow conditions were clarified by the contact angles probability density curve and mean value change curve. The results show that, for water-wetting rocks, the mean value of the contact angles is acute angle during the early stage of the water flooding process, and it increases with the displacement time and becomes obtuse angle in the middle-late stage of displacement as the dominant force of oil phase gradually changes from viscous force to capillary force. The droplet flow in the remaining oil occurs in the central part of the pore throats, without three-phase contact angle. The contact angles for the porous flow and the columnar flow change slightly during the displacement and present as obtuse angles in view of mean values, which makes the remaining oil poorly movable and thus hard to be recovered. The mean value of the contact angle for the cluster flow tends to increase in the flooding process, which makes the remaining oil more difficult to be recovered. The contact angles for the membrane flow are mainly obtuse angles and reach the highest mean value in the late stage of displacement, which makes the remaining oil most difficult to be recovered. After displacement, the remaining oils under different flow regimes are just subjected to capillary force, with obtuse contact angles, and the wettability of the pore throat walls in the microfluidic model tends to be oil-wet under the action of crude oil. 展开更多
关键词 microfluidic model water flooding experiment digital image processing three-phase contact angle measure-ment method flow regime of the remaining oil
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Application of CD34 expression combined with three-phase dynamic contrast-enhanced computed tomography scanning in preoperative staging of gastric cancer
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作者 Hua Liu Kang-Yan Zhao 《World Journal of Gastrointestinal Surgery》 SCIE 2023年第11期2513-2524,共12页
BACKGROUND Accurate preoperative staging of gastric cancer(GC),a common malignant tumor worldwide,is critical for appropriate treatment plans and prognosis.Dynamic three-phase enhanced computed tomography(CT)scanning ... BACKGROUND Accurate preoperative staging of gastric cancer(GC),a common malignant tumor worldwide,is critical for appropriate treatment plans and prognosis.Dynamic three-phase enhanced computed tomography(CT)scanning for preoperative staging of GC has limitations in evaluating tumor angiogenesis.CD34,a marker on vascular endothelial cell surfaces,is promising in evaluating tumor angiogenesis.We explored the value of their combination for preoperative staging of GC to improve the efficacy and prognosis of patients with GC.Medical records of 106 patients with GC treated at the First People's Hospital of Lianyungang between February 2021 and January 2023 were retrospectively studied.All patients underwent three-phase dynamic contrast-enhanced CT scanning before surgery,and CD34 was detected in gastroscopic biopsy specimens.Using surgical and pathological results as the gold standard,the diagnostic results of three-phase dynamic contrast-enhanced CT scanning at different T and N stages were analyzed,and the expression of CD34-marked microvessel density(MVD)at different T and N stages was determined.The specificity and sensitivity of three-phase dynamic contrast-enhanced CT and CD34 in T and N staging were calculated;those of the combined diagnosis of the two were evaluated in parallel.Independent factors affecting lymph node metastasis were analyzed using multiple logistic regression.RESULTS The accuracy of three-phase dynamic contrast-enhanced CT scanning in diagnosing stages T1,T2,T3 and T4 were 68.00%,75.00%,79.41%,and 73.68%,respectively,and for diagnosing stages N0,N1,N2,and N3 were 75.68%,74.07%,85.00%,and 77.27%,respectively.CD34-marked MVD expression increased with increasing T and N stages.Specificity and sensitivity of three-phase dynamic contrast-enhanced CT in T staging were 86.79%and 88.68%;for N staging,89.06%and 92.86%;for CD34 in T staging,64.15%and 88.68%;and for CD34 in N staging,84.38%and 78.57%,respectively.Specificity and sensitivity of joint diagnosis in T staging were 55.68%and 98.72%,and N staging were 75.15%and 98.47%,respectively,with the area under the curve for diagnosis improving accordingly.According to multivariate analysis,a longer tumor diameter,higher pathological T stage,lower differ-entiation degree,and higher expression of CD34-marked MVD were independent risk factors for lymph node metastasis in patients with GC.CONCLUSION With high accuracy in preoperatively determining the invasion depth and lymph node metastasis of GC,CD34 expression and three-phase dynamic contrast-enhanced CT can provide a reliable basis for surgical resection. 展开更多
关键词 CD34 three-phase dynamic contrast-enhanced computed tomography scanning Gastric cancer Preoperative staging INVASION Lymph node metastasis
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A dual-RPA based lateral flow strip for sensitive,on-site detection of CP4-EPSPS and Cry1Ab/Ac genes in genetically modified crops 被引量:1
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作者 Jinbin Wang Yu Wang +7 位作者 Xiuwen Hu Yifan Chen Wei Jiang Xiaofeng Liu Juan Liu Lemei Zhu Haijuan Zeng Hua Liu 《Food Science and Human Wellness》 SCIE CSCD 2024年第1期183-190,共8页
Traditional transgenic detection methods require high test conditions and struggle to be both sensitive and efficient.In this study,a one-tube dual recombinase polymerase amplification(RPA)reaction system for CP4-EPSP... Traditional transgenic detection methods require high test conditions and struggle to be both sensitive and efficient.In this study,a one-tube dual recombinase polymerase amplification(RPA)reaction system for CP4-EPSPS and Cry1Ab/Ac was proposed and combined with a lateral flow immunochromatographic assay,named“Dual-RPA-LFD”,to visualize the dual detection of genetically modified(GM)crops.In which,the herbicide tolerance gene CP4-EPSPS and the insect resistance gene Cry1Ab/Ac were selected as targets taking into account the current status of the most widespread application of insect resistance and herbicide tolerance traits and their stacked traits.Gradient diluted plasmids,transgenic standards,and actual samples were used as templates to conduct sensitivity,specificity,and practicality assays,respectively.The constructed method achieved the visual detection of plasmid at levels as low as 100 copies,demonstrating its high sensitivity.In addition,good applicability to transgenic samples was observed,with no cross-interference between two test lines and no influence from other genes.In conclusion,this strategy achieved the expected purpose of simultaneous detection of the two popular targets in GM crops within 20 min at 37°C in a rapid,equipmentfree field manner,providing a new alternative for rapid screening for transgenic assays in the field. 展开更多
关键词 Genetically modifi ed crops On-site detection Lateral fl ow test strips dual recombinase polymerase amplification (RPA)
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