Construction of multi-channels of photo-carrier migration in photocatalysts is favor to boost conversion efficiency of solar energy by promoting the charge separation and transfer.Herein,a ternary ZnIn_(2)S_(4)/g-C_(3...Construction of multi-channels of photo-carrier migration in photocatalysts is favor to boost conversion efficiency of solar energy by promoting the charge separation and transfer.Herein,a ternary ZnIn_(2)S_(4)/g-C_(3)N_(4)/Ti_(3)C_(2) MXene hybrid composed of S-scheme junction integrated Schottky-junction was fabricated using a simple hydrothermal approach.All the components(g-C_(3)N_(4),ZnIn_(2)S_(4) and Ti_(3)C_(2) MXene)demonstrated two-dimensional(2D)nanosheets structure,leading to the formation of a 2D/2D/2D sandwich-like structure with intimate large interface for carrier migration.Furthermore,the photogenerated carriers on the g-C_(3)N_(4) possessed dual transfer channels,including one route in S-scheme transfer mode between the g-C_(3)N_(4) and ZnIn_(2)S_(4) and the other route in Schottky-junction between g-C_(3)N_(4) and Ti_(3)C_(2) MXene.Consequently,a highly efficient carrier separation and transport was realized in the ZnIn_(2)S_(4)/g-C_(3)N_(4)/Ti_(3)C_(2) MXene heterojunction.This ternary sample exhibited wide light response from 200 to 1400 nm and excellent photocatalytic H_(2) evolution of 2452.1μmol∙g^(–1)∙h^(–1),which was 200,3,1.5 and 1.6 times of g-C_(3)N_(4),ZnIn_(2)S_(4),ZnIn_(2)S_(4)/Ti_(3)C_(2) MXene and g-C_(3)N_(4)/ZnIn_(2)S_(4) binary composites.This work offers a paradigm for the rational construction of multi-electron pathways to regulate the charge separation and migration via the introduction of dual-junctions in catalytic system.展开更多
移动式无线电能传输(wireless power transfer, WPT)需根据车辆的实时位置,切换不同的发射线圈,确定车辆的位置是实现移动式WPT的关键。为实现车辆位置的实时检测,设计了一种移动式双通道WPT系统,其中能量传输通道用于传输主能量,位置...移动式无线电能传输(wireless power transfer, WPT)需根据车辆的实时位置,切换不同的发射线圈,确定车辆的位置是实现移动式WPT的关键。为实现车辆位置的实时检测,设计了一种移动式双通道WPT系统,其中能量传输通道用于传输主能量,位置检测通道用于实时检测车辆位置。为研究WPT系统双通道间的相互干扰的问题,建立了四线圈耦合模型,解耦双通道四线圈间的干扰,确定位置检测通道频率,提出弱感性微失谐补偿方案,在不影响系统性能的条件下,降低发射端空载电流。通过理论推导、仿真分析等手段,对相关内容开展研究,并通过实验验证该频率下双通道间的干扰处于可接受范围,弱感性微失谐补偿方案可行有效。展开更多
文摘Construction of multi-channels of photo-carrier migration in photocatalysts is favor to boost conversion efficiency of solar energy by promoting the charge separation and transfer.Herein,a ternary ZnIn_(2)S_(4)/g-C_(3)N_(4)/Ti_(3)C_(2) MXene hybrid composed of S-scheme junction integrated Schottky-junction was fabricated using a simple hydrothermal approach.All the components(g-C_(3)N_(4),ZnIn_(2)S_(4) and Ti_(3)C_(2) MXene)demonstrated two-dimensional(2D)nanosheets structure,leading to the formation of a 2D/2D/2D sandwich-like structure with intimate large interface for carrier migration.Furthermore,the photogenerated carriers on the g-C_(3)N_(4) possessed dual transfer channels,including one route in S-scheme transfer mode between the g-C_(3)N_(4) and ZnIn_(2)S_(4) and the other route in Schottky-junction between g-C_(3)N_(4) and Ti_(3)C_(2) MXene.Consequently,a highly efficient carrier separation and transport was realized in the ZnIn_(2)S_(4)/g-C_(3)N_(4)/Ti_(3)C_(2) MXene heterojunction.This ternary sample exhibited wide light response from 200 to 1400 nm and excellent photocatalytic H_(2) evolution of 2452.1μmol∙g^(–1)∙h^(–1),which was 200,3,1.5 and 1.6 times of g-C_(3)N_(4),ZnIn_(2)S_(4),ZnIn_(2)S_(4)/Ti_(3)C_(2) MXene and g-C_(3)N_(4)/ZnIn_(2)S_(4) binary composites.This work offers a paradigm for the rational construction of multi-electron pathways to regulate the charge separation and migration via the introduction of dual-junctions in catalytic system.
文摘移动式无线电能传输(wireless power transfer, WPT)需根据车辆的实时位置,切换不同的发射线圈,确定车辆的位置是实现移动式WPT的关键。为实现车辆位置的实时检测,设计了一种移动式双通道WPT系统,其中能量传输通道用于传输主能量,位置检测通道用于实时检测车辆位置。为研究WPT系统双通道间的相互干扰的问题,建立了四线圈耦合模型,解耦双通道四线圈间的干扰,确定位置检测通道频率,提出弱感性微失谐补偿方案,在不影响系统性能的条件下,降低发射端空载电流。通过理论推导、仿真分析等手段,对相关内容开展研究,并通过实验验证该频率下双通道间的干扰处于可接受范围,弱感性微失谐补偿方案可行有效。
