A starved feed reactor (SFR) is a semi-batch polymerization reactor where initiator and monomer are fed slowly into a fixed amount of solvent. The polymerization is carried out isothermally at elevated temperatures. T...A starved feed reactor (SFR) is a semi-batch polymerization reactor where initiator and monomer are fed slowly into a fixed amount of solvent. The polymerization is carried out isothermally at elevated temperatures. The added initiator decomposes instantaneously and the added monomer polymerizes immediately. The molecular weight (MW) and molecular weight distribution (MWD) of the product polymer can be effectively controlled by the feed ratio of monomer to initiator. This paper presents a study on the MWD of styrene polymerization in a SFR. The MWD model parameters are regressed with experimental data. Although the solids fraction in the SFR is high (higher than 50%), viscosity is not too high and the 'gel effect' is weak due to the low molecular weight of the products. It is found that the termination rate constant is a power function of molecular weight, radicals terminate via 100% combination, the thermal initiation can be neglected even at high reaction temperature studied. And calculated results indicate that in the SFR, the validity of the long chain assumption becomes doubted. It appears that other alterative assumption should be found for an improved model.展开更多
This paper focused on the task of reducing power consumption and improving energy efficiency in the technological process of distribution liquid feeds in a pigsty. The liquid feeds in a pigsty are distributed to the s...This paper focused on the task of reducing power consumption and improving energy efficiency in the technological process of distribution liquid feeds in a pigsty. The liquid feeds in a pigsty are distributed to the stables via pipelines. A centrifugal pump driven by an electric motor is used to supply the liquid feed and to move it through the pipeline. The electric motor is the major electric energy consumer in the process. As shown by experimental data and as following the theory, there is a non-linear relation between the electric motor power, the pump throughput and feed humidity. The purpose of the paper is to calculate such an optimal value of the electric motor power that provides the minimal energy consumption on the process of feed distribution. The problem is solved by the Lagrange multiplier method of nonlinear mathematical programming, taking into account geometrical parameters of the pipeline, humidity and portions volumes of distributed feed. The energy saving effect is estimated and reducing power consumption is shown.展开更多
The machine tool equipped with the dual-drive servo feed system could realize high feed speed as well as sharp precision. Currently, there is no report about the thermal behaviors of the dual-drive machine, and the cu...The machine tool equipped with the dual-drive servo feed system could realize high feed speed as well as sharp precision. Currently, there is no report about the thermal behaviors of the dual-drive machine, and the current research of the thermal characteristics of machines mainly focuses on steady simulation. To explore the influence of thermal characterizations on the precision of a jib boring machine assembled dual-drive feed system, the thermal equilibrium tests and the research on thermal-mechanical transient behaviors are carried out. A laser interferometer, infrared thermography and a temperature-displacement acquisition system are applied to measure the temperature distribution and thermal deformation at different feed speeds. Subsequently, the finite element method （FEM） is used to analyze the transient thermal behaviors of the boring machine. The complex boundary conditions, such as heat sources and convective heat transfer coefficient, are calculated. Finally, transient variances in temperatures and deformations are compared with the measured values, and the errors between the measurement and the simulation of the temperature and the thermal error are 2 ~C and 2.5 pm, respectively. The researching results demonstrate that the FEM model can predict the thermal error and temperature distribution very well under specified operating condition. Moreover, the uneven temperature gradient is due to the asynchronous dual-drive structure that results in thermal deformation. Additionally, the positioning accuracy decreases as the measured point became further away from the motor, and the thermal error and equilibrium period both increase with feed speeds. The research proposes a systematical method to measure and simulate the boring machine transient thermal behaviors.展开更多
The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant difference...The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films, depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.展开更多
The application of the Genetic Algorithm （GA） for the influent flow optimized distribution in the four stage pilot plant of Step-Feed Biological Nutrient Removal （BNR） System was discussed. Under decided process p...The application of the Genetic Algorithm （GA） for the influent flow optimized distribution in the four stage pilot plant of Step-Feed Biological Nutrient Removal （BNR） System was discussed. Under decided process parameter and influent water conditions, the objective function of optimization was designed to minimize the difference between estimated and required effluent concentrations at the four stage pilot plant of Step-Feed BNR System, the optimized parameter for influent distribution ratios of the four stages is 37.2%, 27.4%, 23.2% and 12.2% respectively. According to the optimizations results and raw wastewater pilot-scale experiment, the average removal efficiencies for pollutants are higher.展开更多
The local gas-flow behavior is almost unknown for low pressure plasma systems, except parallel plate reactors for semiconductor purposes. To overcome this lack of knowledge, this study starts with the influence invest...The local gas-flow behavior is almost unknown for low pressure plasma systems, except parallel plate reactors for semiconductor purposes. To overcome this lack of knowledge, this study starts with the influence investigation of the gas feed-in systems technical layout on the homogeneity of the gas supply for large volume plasma enhanced chemical vapor deposition (PECVD) chambers. Computational fluid dynamics (CFD) simulations are used as a tool to determine velocity and pressure distribution inside the gas feed-in pipe as well as in the PECVD-chamber itself. The parameters varied were: flow rate, pipe length, number of holes, hole diameter and aspect ratio of the pipe section. The calculated pressure values are compared with the experimentally measured ones to validate the simulation results. An excellent conformity of the calculated and measured pressures is observed. With the aim to evaluate the homogeneity of gas distribution through the pipe holes the nonuniformity coefficient (Φ) was created. The results show the influence of each layout parameter in the homogeneity of the gas distribution. Hence in future correct technical layouts of gas feed-in systems can easily be applied. With these results construction guidelines has been formulated.展开更多
基金Supported by the State Key Polymerization Reaction Engineering Laboratory of Zhejiang University.
文摘A starved feed reactor (SFR) is a semi-batch polymerization reactor where initiator and monomer are fed slowly into a fixed amount of solvent. The polymerization is carried out isothermally at elevated temperatures. The added initiator decomposes instantaneously and the added monomer polymerizes immediately. The molecular weight (MW) and molecular weight distribution (MWD) of the product polymer can be effectively controlled by the feed ratio of monomer to initiator. This paper presents a study on the MWD of styrene polymerization in a SFR. The MWD model parameters are regressed with experimental data. Although the solids fraction in the SFR is high (higher than 50%), viscosity is not too high and the 'gel effect' is weak due to the low molecular weight of the products. It is found that the termination rate constant is a power function of molecular weight, radicals terminate via 100% combination, the thermal initiation can be neglected even at high reaction temperature studied. And calculated results indicate that in the SFR, the validity of the long chain assumption becomes doubted. It appears that other alterative assumption should be found for an improved model.
文摘This paper focused on the task of reducing power consumption and improving energy efficiency in the technological process of distribution liquid feeds in a pigsty. The liquid feeds in a pigsty are distributed to the stables via pipelines. A centrifugal pump driven by an electric motor is used to supply the liquid feed and to move it through the pipeline. The electric motor is the major electric energy consumer in the process. As shown by experimental data and as following the theory, there is a non-linear relation between the electric motor power, the pump throughput and feed humidity. The purpose of the paper is to calculate such an optimal value of the electric motor power that provides the minimal energy consumption on the process of feed distribution. The problem is solved by the Lagrange multiplier method of nonlinear mathematical programming, taking into account geometrical parameters of the pipeline, humidity and portions volumes of distributed feed. The energy saving effect is estimated and reducing power consumption is shown.
基金Supported by National Hi-tech Research and Development Program of China(863 Program,Grant No.2012AA040701)
文摘The machine tool equipped with the dual-drive servo feed system could realize high feed speed as well as sharp precision. Currently, there is no report about the thermal behaviors of the dual-drive machine, and the current research of the thermal characteristics of machines mainly focuses on steady simulation. To explore the influence of thermal characterizations on the precision of a jib boring machine assembled dual-drive feed system, the thermal equilibrium tests and the research on thermal-mechanical transient behaviors are carried out. A laser interferometer, infrared thermography and a temperature-displacement acquisition system are applied to measure the temperature distribution and thermal deformation at different feed speeds. Subsequently, the finite element method （FEM） is used to analyze the transient thermal behaviors of the boring machine. The complex boundary conditions, such as heat sources and convective heat transfer coefficient, are calculated. Finally, transient variances in temperatures and deformations are compared with the measured values, and the errors between the measurement and the simulation of the temperature and the thermal error are 2 ~C and 2.5 pm, respectively. The researching results demonstrate that the FEM model can predict the thermal error and temperature distribution very well under specified operating condition. Moreover, the uneven temperature gradient is due to the asynchronous dual-drive structure that results in thermal deformation. Additionally, the positioning accuracy decreases as the measured point became further away from the motor, and the thermal error and equilibrium period both increase with feed speeds. The research proposes a systematical method to measure and simulate the boring machine transient thermal behaviors.
基金The project is supported by Beijing Natural Science Fund.
文摘The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch, seeded batch and semicontinuous pro-cesses,respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films, depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.
文摘The application of the Genetic Algorithm （GA） for the influent flow optimized distribution in the four stage pilot plant of Step-Feed Biological Nutrient Removal （BNR） System was discussed. Under decided process parameter and influent water conditions, the objective function of optimization was designed to minimize the difference between estimated and required effluent concentrations at the four stage pilot plant of Step-Feed BNR System, the optimized parameter for influent distribution ratios of the four stages is 37.2%, 27.4%, 23.2% and 12.2% respectively. According to the optimizations results and raw wastewater pilot-scale experiment, the average removal efficiencies for pollutants are higher.
文摘The local gas-flow behavior is almost unknown for low pressure plasma systems, except parallel plate reactors for semiconductor purposes. To overcome this lack of knowledge, this study starts with the influence investigation of the gas feed-in systems technical layout on the homogeneity of the gas supply for large volume plasma enhanced chemical vapor deposition (PECVD) chambers. Computational fluid dynamics (CFD) simulations are used as a tool to determine velocity and pressure distribution inside the gas feed-in pipe as well as in the PECVD-chamber itself. The parameters varied were: flow rate, pipe length, number of holes, hole diameter and aspect ratio of the pipe section. The calculated pressure values are compared with the experimentally measured ones to validate the simulation results. An excellent conformity of the calculated and measured pressures is observed. With the aim to evaluate the homogeneity of gas distribution through the pipe holes the nonuniformity coefficient (Φ) was created. The results show the influence of each layout parameter in the homogeneity of the gas distribution. Hence in future correct technical layouts of gas feed-in systems can easily be applied. With these results construction guidelines has been formulated.
