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Brunn-Minkowski inequalities for star duals of intersection bodies and two additions 被引量:1
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作者 刘丽娟 汪卫 何斌吾 《Journal of Shanghai University(English Edition)》 CAS 2010年第3期201-205,共5页
In this paper,we first establish the dual Brunn-Minkowski inequality for the star duals for the Lp radial sum.Furthermore,we give some Brunn-Minkowski inequalities for the star duals of intersection bodies for the Lp ... In this paper,we first establish the dual Brunn-Minkowski inequality for the star duals for the Lp radial sum.Furthermore,we give some Brunn-Minkowski inequalities for the star duals of intersection bodies for the Lp radial sum and the Lp harmonic Blaschke sum. 展开更多
关键词 star dual Brunn-Minkowski inequality intersection body Lp radial sum Lp harmonic Blaschke sum
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Ordered Generalized Sequence Spaces and their Duals
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作者 卜庆营 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1995年第3期7-10,共4页
The main result of this paper is the identification of the sequential order dual [∧(X)]so containing sequentially order continuous linear functionals on the ordered generalized sequence space ∧(X) with its generaliz... The main result of this paper is the identification of the sequential order dual [∧(X)]so containing sequentially order continuous linear functionals on the ordered generalized sequence space ∧(X) with its generalized Kothe dual ∧x(Xso), defined corresponding to the dual pair <X, Xso>. 展开更多
关键词 ss: GENERALIZED SEQUENCE space order DUAL Kothe DUAL
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ON NECESSARY AND SUFFICIENT CONDITIONS FOR DUALS OF WAVELET FRAMES
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作者 张泽银 王建忠 《Acta Mathematica Scientia》 SCIE CSCD 1995年第1期6-14,共9页
This paper is concerned with the characterization of the duals of wavelet frames of L(2)(R). The sufficient and necessary conditions for them are obtained.
关键词 WAVELET ANALYSIS FRAMES DUAL FRAMES AFFINE FRAMES TIGHT FRAMES
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是鸡肋还是利器索尼DualSense Edge上手体验
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作者 Jeffrey 《家庭影院技术》 2023年第3期106-107,共2页
一直以来微软展现了手柄大厂的风范,除了不断出新的配色和游戏限定配色去掏空玩家钱包以外,目标为核(tu)心(hao)玩家的精英手柄系列更是出到了2代.而迟迟未动的索尼这边终于在今年年初发售了第一款精英手柄DualSense Edge!热爱游戏和硬... 一直以来微软展现了手柄大厂的风范,除了不断出新的配色和游戏限定配色去掏空玩家钱包以外,目标为核(tu)心(hao)玩家的精英手柄系列更是出到了2代.而迟迟未动的索尼这边终于在今年年初发售了第一款精英手柄DualSense Edge!热爱游戏和硬件的我立马吃螃蟹.这期就来一探这个最新手柄的方方面面,和自家DualSense以及Xbox Elite 2做一下对比. 展开更多
关键词 Dual 配色 索尼 掏空 玩家 手柄
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双芯IGCT浪涌电流鲁棒性研究 被引量:1
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作者 鲁一苇 姚德贵 +3 位作者 董曼玲 肖超 陈涛 杨武华 《半导体技术》 CAS 北大核心 2024年第3期234-239,245,共7页
作为晶闸管类器件,双芯集成门极换流晶闸管(Dual IGCT)必须具备的抗浪涌电流能力研究鲜见报道。基于多单元集成的器件仿真结构模型,揭示了Dual IGCT在浪涌电流下工作时,总电流在GCT-A部分和GCT-B部分间的分配比例会随晶格温度升高而减... 作为晶闸管类器件,双芯集成门极换流晶闸管(Dual IGCT)必须具备的抗浪涌电流能力研究鲜见报道。基于多单元集成的器件仿真结构模型,揭示了Dual IGCT在浪涌电流下工作时,总电流在GCT-A部分和GCT-B部分间的分配比例会随晶格温度升高而减小。在此基础上,分析了寿命控制技术对Dual IGCT浪涌鲁棒性的影响。结果表明,增大GCT-B的载流子寿命可以提高器件的浪涌鲁棒性,但同时会增大器件的功耗;而在对GCT-B进行载流子寿命控制时,引入具有较大寿命对温度依赖系数的复合中心,可以有效提高Dual IGCT浪涌电流鲁棒性,同时不影响器件的其他性能。最后,提出了一种工艺成本较低的阳极短路Dual IGCT新结构,其在浪涌电流下的晶格温升与传统的Dual IGCT相比大幅减小(约150 K),呈现出极高的抗浪涌能力。 展开更多
关键词 双芯集成门极换流晶闸管(Dual IGCT) 浪涌电流 寿命控制 复合中心 鲁棒性
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Ecological-Based Mining:A Coal-Water-Thermal Collaborative Paradigm in Ecologically Fragile Areas in Western China 被引量:2
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作者 Xiaoxiu Liu Yifan Zeng +3 位作者 Qiang Wu Shihao Meng Jiyue Liang Zhuping Hou 《Engineering》 SCIE EI CAS CSCD 2024年第7期209-222,共14页
A substantial reduction in groundwater level,exacerbated by coal mining activities,is intensifying water scarcity in western China’s ecologically fragile coal mining areas.China’s national strategic goal of achievin... A substantial reduction in groundwater level,exacerbated by coal mining activities,is intensifying water scarcity in western China’s ecologically fragile coal mining areas.China’s national strategic goal of achieving a carbon peak and carbon neutrality has made eco-friendly mining that prioritizes the protection and efficient use of water resources essential.Based on the resource characteristics of mine water and heat hazards,an intensive coal-water-thermal collaborative co-mining paradigm for the duration of the mining process is proposed.An integrated system for the production,supply,and storage of mining companion resources is achieved through technologies such as roof water inrush prevention and control,hydrothermal quality improvement,and deep-injection geological storage.An active preventive and control system achieved by adjusting the mining technology and a passive system centered on multiobjective drainage and grouting treatment are suggested,in accordance with the original geological characteristics and dynamic process of water inrush.By implementing advanced multi-objective drainage,specifically designed to address the“skylight-type”water inrush mode in the Yulin mining area of Shaanxi Province,a substantial reduction of 50%in water drillings and inflow was achieved,leading to stabilized water conditions that effectively ensure subsequent safe coal mining.An integrated-energy complementary model that incorporates the clean production concept of heat utilization is also proposed.The findings indicate a potential saving of 8419 t of standard coal by using water and air heat as an alternative heating source for the Xiaojihan coalmine,resulting in an impressive energy conservation of 50.2%and a notable 24.2%reduction in carbon emissions.The ultra-deep sustained water injection of 100 m^(3)·h^(-1)in a single well would not rupture the formation or cause water leakage,and 7.87×10^(5)t of mine water could be effectively stored in the Liujiagou Formation,presenting a viable method for mine-water management in the Ordos Basin and providing insights for green and low-carbon mining. 展开更多
关键词 Dual carbon targets Coal-water-thermal co-mining Ecologically fragile areas Mine-water control Resource utilization
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A review of the neurotransmitter system associated with cognitive function of the cerebellum in Parkinson's disease 被引量:2
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作者 Xi Chen Yuhu Zhang 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第2期324-330,共7页
The dichotomized brain system is a concept that was generalized from the‘dual syndrome hypothesis’to explain the heterogeneity of cognitive impairment,in which anterior and posterior brain systems are independent bu... The dichotomized brain system is a concept that was generalized from the‘dual syndrome hypothesis’to explain the heterogeneity of cognitive impairment,in which anterior and posterior brain systems are independent but partially overlap.The dopaminergic system acts on the anterior brain and is responsible for executive function,working memory,and planning.In contrast,the cholinergic system acts on the posterior brain and is responsible for semantic fluency and visuospatial function.Evidence from dopaminergic/cholinergic imaging or functional neuroimaging has shed significant insight relating to the involvement of the cerebellum in the cognitive process of patients with Parkinson’s disease.Previous research has reported evidence that the cerebellum receives both dopaminergic and cholinergic projections.However,whether these two neurotransmitter systems are associated with cognitive function has yet to be fully elucidated.Furthermore,the precise role of the cerebellum in patients with Parkinson’s disease and cognitive impairment remains unclear.Therefore,in this review,we summarize the cerebellar dopaminergic and cholinergic projections and their relationships with cognition,as reported by previous studies,and investigated the role of the cerebellum in patients with Parkinson’s disease and cognitive impairment,as determined by functional neuroimaging.Our findings will help us to understand the role of the cerebellum in the mechanisms underlying cognitive impairment in Parkinson’s disease. 展开更多
关键词 anterior brain system CEREBELLUM CHOLINERGIC cognitive impairment DOPAMINERGIC dual syndrome hypothesis neuroimage NEUROTRANSMITTER Parkinson’s disease posterior brain system therapeutic targets
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Electron-distribution control via Pt/NC and MoC/NC dual junction:Boosted hydrogen electro-oxidation and theoretical study 被引量:1
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作者 Feng Zhou Xiaofeng Ke +8 位作者 Yihuang Chen Mei Zhao Yun Yang Youqing Dong Chao Zou Xi’an Chen Huile Jin Lijie Zhang Shun Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期513-520,I0011,共9页
The scarcity,high cost and susceptibility to CO of Platinum severely restrict its application in alkaline hydrogen oxidation reaction(HOR).Hybridizing Pt with other transition metals provides an effective strategy to ... The scarcity,high cost and susceptibility to CO of Platinum severely restrict its application in alkaline hydrogen oxidation reaction(HOR).Hybridizing Pt with other transition metals provides an effective strategy to modulate its catalytic HOR performance,but at the cost of mass activity due to the coverage of modifiers on Pt surface.Herein,we constructed dual junctions'Pt/nitrogen-doped carbon(Pt/NC)andδ-MoC/NC to modify electronic structure of Pt via interfacial electron transfer to acquire Pt-MoC@NC catalyst with electron-deficient Pt nanoparticles,simultaneously endowing it with high mass activity and durability of alkaline HOR.Moreover,the unique structure of Pt-MoC@NC endows Pt with a high COtolerance at 1,000 ppm CO/H_(2),a quality that commercial Pt-C catalyst lacks.The theoretical calculations not only confirm the diffusion of electrons from Pt/NC to Mo C/NC could occur,but also demonstrate the negative shift of Pt d-band center for the optimized binding energies of*H,*OH and CO. 展开更多
关键词 Hydrogen oxidation reaction Dual junctions CO-tolerance PLATINUM
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双能量CT扫描技术在胸部疾病诊断中的应用研究进展
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作者 孙萌潞 梁妍 +3 位作者 衣闯 冯艳 李雪 朱军 《中国实验诊断学》 2024年第5期607-610,共4页
双能计算机断层扫描(Dual-EnergyCT,DECT)是在64排CT的基础上,由两套相互垂直的X线球管及探测器系统集成来实现图像采集的,较常规CT相比具备更好的图像分辨率及更快的图像采集速度^([1])。近年来双能CT在临床上的应用越来越广泛。双能C... 双能计算机断层扫描(Dual-EnergyCT,DECT)是在64排CT的基础上,由两套相互垂直的X线球管及探测器系统集成来实现图像采集的,较常规CT相比具备更好的图像分辨率及更快的图像采集速度^([1])。近年来双能CT在临床上的应用越来越广泛。双能CT虚拟去钙技术通过分离算法去除钙离子后能更好的显示骨髓腔体内的出血或水肿情况,是一种新兴的、便捷的检查手段,可用于识别隐匿性骨折^([2])。 展开更多
关键词 计算机断层扫描 图像采集 胸部疾病 图像分辨率 系统集成 分离算法 骨髓腔 Dual
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A strategy for strengthening chaotic mixing of dual shaft eccentric mixers by changing non-Newtonian fluids kinetic energy distribution 被引量:1
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作者 Songsong Wang Tong Meng +4 位作者 Qian Zhang Changyuan Tao Yundong Wang Zequan Li Zuohua Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期122-134,共13页
Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier ... Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier for the existing technologies.Accordingly,this work reports a convenient strategy that changes the kinetic energy to controllably regulate the flow patterns from radial flow to axial flow.Results showed that the desired velocity distribution and flow patterns could be effectively obtained by varying the number and structure of baffles to change kinetic energy,and a more uniform velocity distribution,which could not be reached normally in standard baffle dual shaft mixers,was easily obtained.Furthermore,a comparative analysis of velocity and shear rate distributions is employed to elucidate the mechanism behind the generation of flow patterns in various dual-shaft eccentric mixers.Importantly,there is little difference in the power number of the laminar flow at the same Reynolds number,meaning that the baffle type has no effect on the power consumption,while the power number of both unbaffle and U-shaped baffle mixing systems decreases compared with the standard baffle mixing system in the transition flow.Finally,at the same rotational condition,the dimensionless mixing time of the U-shaped baffle mixing system is 15.3%and 7.9%shorter than that of the standard baffle and the unbaffle mixing system,respectively,which shows the advantage of the U-shaped baffle in stirring rate. 展开更多
关键词 Dual shaft “U-shaped”baffle Flow pattern Mixing time Power demand
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Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries 被引量:1
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作者 Baolin Wu Chunguang Chen +4 位作者 Dmitri L.Danilov Zhiqiang Chen Ming Jiang Rüdiger-A.Eichel Peter H.L.Notten 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期84-92,共9页
Anode-free Li-metal batteries are of significant interest to energy storage industries due to their intrinsically high energy.However,the accumulative Li dendrites and dead Li continuously consume active Li during cyc... Anode-free Li-metal batteries are of significant interest to energy storage industries due to their intrinsically high energy.However,the accumulative Li dendrites and dead Li continuously consume active Li during cycling.That results in a short lifetime and low Coulombic efficiency of anode-free Li-metal batteries.Introducing effective electrolyte additives can improve the Li deposition homogeneity and solid electrolyte interphase(SEI)stability for anode-free Li-metal batteries.Herein,we reveal that introducing dual additives,composed of LiAsF6 and fluoroethylene carbonate,into a low-cost commercial carbonate electrolyte will boost the cycle life and average Coulombic efficiency of NMC‖Cu anode-free Li-metal batteries.The NMC‖Cu anode-free Li-metal batteries with the dual additives exhibit a capacity retention of about 75%after 50 cycles,much higher than those with bare electrolytes(35%).The average Coulombic efficiency of the NMC‖Cu anode-free Li-metal batteries with additives can maintain 98.3%over 100 cycles.In contrast,the average Coulombic efficiency without additives rapidly decline to 97%after only 50 cycles.In situ Raman measurements reveal that the prepared dual additives facilitate denser and smoother Li morphology during Li deposition.The dual additives significantly suppress the Li dendrite growth,enabling stable SEI formation on anode and cathode surfaces.Our results provide a broad view of developing low-cost and high-effective functional electrolytes for high-energy and long-life anode-free Li-metal batteries. 展开更多
关键词 anode-free lithium metal battery dual additives in situ Raman Li growth SEI formation
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A dual-RPA based lateral flow strip for sensitive,on-site detection of CP4-EPSPS and Cry1Ab/Ac genes in genetically modified crops 被引量:1
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作者 Jinbin Wang Yu Wang +7 位作者 Xiuwen Hu Yifan Chen Wei Jiang Xiaofeng Liu Juan Liu Lemei Zhu Haijuan Zeng Hua Liu 《Food Science and Human Wellness》 SCIE CSCD 2024年第1期183-190,共8页
Traditional transgenic detection methods require high test conditions and struggle to be both sensitive and efficient.In this study,a one-tube dual recombinase polymerase amplification(RPA)reaction system for CP4-EPSP... Traditional transgenic detection methods require high test conditions and struggle to be both sensitive and efficient.In this study,a one-tube dual recombinase polymerase amplification(RPA)reaction system for CP4-EPSPS and Cry1Ab/Ac was proposed and combined with a lateral flow immunochromatographic assay,named“Dual-RPA-LFD”,to visualize the dual detection of genetically modified(GM)crops.In which,the herbicide tolerance gene CP4-EPSPS and the insect resistance gene Cry1Ab/Ac were selected as targets taking into account the current status of the most widespread application of insect resistance and herbicide tolerance traits and their stacked traits.Gradient diluted plasmids,transgenic standards,and actual samples were used as templates to conduct sensitivity,specificity,and practicality assays,respectively.The constructed method achieved the visual detection of plasmid at levels as low as 100 copies,demonstrating its high sensitivity.In addition,good applicability to transgenic samples was observed,with no cross-interference between two test lines and no influence from other genes.In conclusion,this strategy achieved the expected purpose of simultaneous detection of the two popular targets in GM crops within 20 min at 37°C in a rapid,equipmentfree field manner,providing a new alternative for rapid screening for transgenic assays in the field. 展开更多
关键词 Genetically modifi ed crops On-site detection Lateral fl ow test strips Dual recombinase polymerase amplification (RPA)
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Hybrid treatment of varied orthodontic appliances for a patient with skeletal class II and temporomandibular joint disorders:A case report and review of literature 被引量:1
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作者 Tong Lu Li Mei +2 位作者 Bao-Chao Li Zi-Wei Huang Huang Li 《World Journal of Clinical Cases》 SCIE 2024年第2期431-442,共12页
BACKGROUND The relation between orthodontic treatment and temporomandibular disorders(TMDs)is under debate;the management of TMD during orthodontic treatment has always been a challenge.If TMD symptoms occur during or... BACKGROUND The relation between orthodontic treatment and temporomandibular disorders(TMDs)is under debate;the management of TMD during orthodontic treatment has always been a challenge.If TMD symptoms occur during orthodontic treatment,an immediate pause of orthodontic adjustments is recommended;the treatment can resume when the symptoms are managed and stabilized.CASE SUMMARY This case report presents a patient(26-year-old,female)with angle class I,skeletal class II and TMDs.The treatment was a hybrid of clear aligners,fixed appliances and temporary anchorage devices(TADs).After 3 mo resting and treatment on her TMD,the patient’s TMD symptom alleviated,but her anterior occlusion displayed deep overbite.Therefore,the fixed appliances with TAD were used to correct the anterior deep-bite and level maxillary and mandibular deep curves.After the levelling,the patient showed dual bite with centric relation and maximum intercuspation discrepancy on her occlusion.After careful examination of temporomandibular joints(TMJ)position,the stable bite splint and Invisible Mandibular Advancement appliance were used to reconstruct her occlusion.Eventually,the improved facial appearance and relatively stable occlusion were achieved.The 1-year follow-up records showed there was no obvious change in TMJ morphology,and her occlusion was stable.CONCLUSION TMD screening and monitoring is of great clinical importance in the TMD susceptible patients.Hybrid treatment with clear aligners and fixed appliances and TADs is an effective treatment modality for the complex cases. 展开更多
关键词 Temporomandibular disorder Skeletal class II Deep overbite Dual bite Invisible mandibular advancement appliance Case report
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Characteristic tilting modules and Ringel duals 被引量:4
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作者 惠昌常 《Science China Mathematics》 SCIE 2000年第11期1121-1130,共10页
The characteristic tilting modules of quasi-hereditary algebras which are dual extensions of directed monomial algebras are explicitly constructed; and it is shown that the Ringel dual of the dual extension of an arbi... The characteristic tilting modules of quasi-hereditary algebras which are dual extensions of directed monomial algebras are explicitly constructed; and it is shown that the Ringel dual of the dual extension of an arbitrary hereditary algebra has triangular decomposition and bipartite quiver. 展开更多
关键词 quasi-hereditary ALGEBRAS CHARACTERISTIC MODULES DUAL EXTENSIONS Ringel duals.
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应对可转移多黏菌素耐药性--饲料添加剂来源的白屈菜红碱具有双重效应
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作者 Huangwei Song Xueyang Wang +12 位作者 Muchen Zhang Zhiyu Zou Siyuan Yang Tian Yi Jianfeng Wang Dejun Liu Yingbo Shen Chongshan Dai Zhihai Liu Timothy R.Walsh Jianzhong Shen Congming Wu Yang Wang 《Engineering》 SCIE EI CAS CSCD 2024年第1期163-173,共11页
The emergence and spread of the mobile colistin-resistance gene,mcr-1,and its variants pose achallenge to the use of colistin,a last-resort antibiotic used to treat severe infections caused by extensively drug-resista... The emergence and spread of the mobile colistin-resistance gene,mcr-1,and its variants pose achallenge to the use of colistin,a last-resort antibiotic used to treat severe infections caused by extensively drug-resistant(XDR)Gram-negative pathogens.Antibiotic adjuvants are a promising strategy to enhance the efficacy of colistin against colistin-resistant pathogens;however,few studies have considered the effects of adjuvants on limiting resistance-gene transmission.We found that chelerythrine(4 mg·L^(-1))derived from Macleaya cordata extract,which is used as an animal feed additive,reduced the minimal inhibitory concentration(MIC)of colistin against an mcr-1 positive Escherichia coli(E.coli)strain by 16-fold(from 2.000 to 0.125 mg·L^(-1)).eliminated approximately 10^(4) colony-forming units(CFUs)of an mcr-1-carrying strain in a murine intestinal infection model,and inhibited the conjugation of an mcr-1-bearing plasmid in vitro(by>100-fold)and in a mouse model(by up to 5-fold).A detailed analysis revealed that chelery-thrine binds to phospholipids on bacterial membranes and increases cytoplasmic membrane fluidity,thereby impairing respiration,disrupting proton motive force(PMF),generating reactive oxygen species(ROS),and decreasing intracellular adenosine triphosphate(ATP)levels,which subsequently downregu-lates mcr-1 and conjugation-associated genes.These dual effects of chelerythrine can expand the use of antibiotic adjuvants and may provide a new strategy for circumventing mobile colistin resistance. 展开更多
关键词 CHELERYTHRINE Antibiotic adjuvant Conjugation inhibitor COLISTIN mcr-1 Dual effects
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Enhanced Precision Therapy of Multiple Myeloma Through Engineered Biomimetic Nanoparticles with Dual Targeting
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作者 Ruogu Qi Shanshan Wang +8 位作者 Jiayi Yu Tianming Lu Zhiqiang Bi Weibo Liu Yuanyuan Guo Yong Bian Jianliang Shen Xuesong Zhang Wenhao Hu 《Engineering》 SCIE EI CAS CSCD 2024年第5期178-192,共15页
Multiple myeloma(MM)is the second most prevalent hematological malignancy.Current MM treatment strategies are hampered by systemic toxicity and suboptimal therapeutic efficacy.This study addressed these limitations th... Multiple myeloma(MM)is the second most prevalent hematological malignancy.Current MM treatment strategies are hampered by systemic toxicity and suboptimal therapeutic efficacy.This study addressed these limitations through the development of a potent MM-targeting chemotherapy strategy,which capitalized on the high binding affinity of alendronate for hydroxyapatite in the bone matrix and the homologous targeting of myeloma cell membranes,termed T-PB@M.The results from our investigations highlight the considerable bone affinity of T-PB@M,both in vitro and in vivo.Additionally,this material demonstrated a capability for drug release triggered by low pH conditions.Moreover,T-PB@M induced the generation of reactive oxygen species and triggered cell apoptosis through the poly(ADP-ribose)polymerase 1(PARP1)-Caspase-3-B-cell lymphoma-2(Bcl-2)pathway in MM cells.Notably,T-PB@M preferentially targeted bone-involved sites,thereby circumventing systemic toxic side effects and leading to prolonged survival of MM orthotopic mice.Therefore,this designed target-MM nanocarrier presents a promising and potentially effective platform for the precise treatment of MM. 展开更多
关键词 Multiple myeloma BORTEZOMIB Drug delivery Dual targeting Controlled release
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Optimizing the sulfur-resistance and activity of perovskite oxygen carrier for chemical looping dry reforming of methane
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作者 Yuelun Li Dong Tian +6 位作者 Lei jiang Huicong Zuo LiNan Huang Mingyi Chen Jianchun Zuo Hua Wang Kongzhai Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期259-271,共13页
Perovskite oxides has been attracted much attention as high-performance oxygen carriers for chemical looping reforming of methane,but they are easily inactivated by the presence of trace H_(2)S.Here,we propose to modu... Perovskite oxides has been attracted much attention as high-performance oxygen carriers for chemical looping reforming of methane,but they are easily inactivated by the presence of trace H_(2)S.Here,we propose to modulate both the activity and resistance to sulfur poisoning by dual substitution of Mo and Ni ions with the Fe-sites of LaFeO_(3)perovskite.It is found that partial substitution of Ni for Fe substantially improves the activity of LaFeO_(3)perovskite,while Ni particles prefer to grow and react with H_(2)S during the long-term successive redox process,resulting in the deactivation of oxygen carriers.With the presence of Mo in LaNi_(0.05)Fe_(0.95)O_(3−σ)perovskite,H_(2)S preferentially reacts with Mo to generate MoS_(2),and then the CO_(2)oxidation can regenerate Mo via removing sulfur.In addition,Mo can inhibit the accumulation and growth of Ni,which helps to improve the redox stability of oxygen carriers.The LaNi_(0.05)Mo_(0.07)Fe_(0.88)O_(3−σ)oxygen carrier exhibits stable and excellent performance,with the CH_(4)conversion higher than 90%during the 50 redox cycles in the presence of 50 ppm H_(2)S at 800℃.This work highlights a synergistic effect in the perovskite oxides induced by dual substitution of different cations for the development of high-performance oxygen carriers with excellent sulfur tolerance. 展开更多
关键词 Perovskite oxygen carriers Chemical looping reforming Sulfur-resistance Dual substitution SYNGAS
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Mg/Fe site-specific dual-doping to boost the performance of cobalt-free nickle-rich layered oxide cathode for high-energy lithium-ion batteries
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作者 Yunting Wang Gaohui Du +7 位作者 Di Han Wenhao Shi Jiahao Deng Huayu Li Wenqi Zhao Shukai Ding Qingmei Su Bingshe Xu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期670-679,共10页
Layer-type LiNi0.9Mn0.1O2is promising to be the primary cathode material for lithium-ion batteries(LIBs)due to its excellent electrochemical performance.Unfortunately,the cathode with high nickel content suffers from ... Layer-type LiNi0.9Mn0.1O2is promising to be the primary cathode material for lithium-ion batteries(LIBs)due to its excellent electrochemical performance.Unfortunately,the cathode with high nickel content suffers from severely detrimental structural transformation that causes rapid capacity attenuation.Herein,site-specific dual-doping with Fe and Mg ions is proposed to enhance the structural stability of LiNi0.9Mn0.1O2.The Fe3+dopants are inserted into transition metal sites(3b)and can favorably provide additional redox potential to compensate for charge and enhance the reversibility of anionic redox.The Mg ions are doped into the Li sites(3a)and serve as O_(2)^(-)-Mg^(2+)-O_(2)^(-)pillar to reinforce the electrostatic cohesion between the two adjacent transition-metal layers,which further suppress the cracking and the generation of harmful phase transitions,ultimately improving the cyclability.The theoretical calculations,including Bader charge and crystal orbital Hamilton populations(COHP)analyses,confirm that the doped Fe and Mg can form stable bonds with oxygen and the electrostatic repulsion of O_(2)^(-)-O_(2)^(-)can be effectively suppressed,which effectively mitigates oxygen anion loss at the high delithiation state.This dual-site doping strategy offers new avenues for understanding and regulating the crystalline oxygen redox and demonstrates significant potential for designing high-performance cobalt-free nickel-rich cathodes. 展开更多
关键词 Cobalt-free Layered oxide Cathode Dual dopants Density functional theory calculation
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Anion storing,oxygen vacancy incorporated perovskite oxide composites for high-performance aqueous dual ion hybrid supercapacitors
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作者 Taehun Kang Puritut Nakhanivej +3 位作者 Kyung Jae Wang Yu Chen Yongchul G Chung Ho Seok Park 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期646-655,共10页
Dual ion storage hybrid supercapacitors(HsCs)are considered as a promising device to overcome the limited energy density of existing supercapacitors while preserving high power and long cyclability.However,the develop... Dual ion storage hybrid supercapacitors(HsCs)are considered as a promising device to overcome the limited energy density of existing supercapacitors while preserving high power and long cyclability.However,the development of high-capacity anion-storing materials,which can be paired with fast charg-ing capacitive electrodes,lags behind cation-storing counterparts.Herein,we demonstrate the surface faradaic OH-storage mechanism of anion storing perovskite oxide composites and their application in high-performance dual ion HsCs.The oxygen vacancy and nanoparticle size of the reduced LaMnO_(3)(r-LaMnO_(3))were controlled,while r-LaMnO_(3) was chemically coupled with ozonated carbon nanotubes(oCNTs)for the improved anion storing capacity and cycle performance.As taken by in-situ and ex-situ spectroscopic and computational analyses,OH-ions are inserted into the oxygen vacancies coordi-nating with octahedral Mn with the increase in the oxidation state of Mn during the charging process or vice versa.Configuring OH-storing r-LaMnO_(3)/oCNT composite with Na*storing MXene,the as-fabricated aqueous dual ion HSCs achieved the cycle performance of 73.3%over 10,000 cycles,delivering the max-imum energy and power densities of 47.5 w h kg^(-1) and 8 kw kg^(-1),respectively,far exceeding those of previously reported aqueous anion and dual ion storage cells.This research establishes a foundation for the unique anion storage mechanism of the defect engineered perovskite oxides and the advancement of dual ion hybrid energy storage devices with high energy and power densities. 展开更多
关键词 Anion storage Dual ion storage Defect engineered perovskites Hybrid supercapacitors NANOCOMPOSITES
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A Sustainable Dual Cross‑Linked Cellulose Hydrogel Electrolyte for High‑Performance Zinc‑Metal Batteries
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作者 Haodong Zhang Xiaotang Gan +1 位作者 Yuyang Yan Jinping Zhou 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期63-75,共13页
Aqueous rechargeable Zn-metal batteries(ARZBs)are considered one of the most promising candidates for grid-scale energy storage.However,their widespread commercial application is largely plagued by three major challen... Aqueous rechargeable Zn-metal batteries(ARZBs)are considered one of the most promising candidates for grid-scale energy storage.However,their widespread commercial application is largely plagued by three major challenges:The uncontrollable Zn dendrites,notorious parasitic side reactions,and sluggish Zn^(2+) ion transfer.To address these issues,we design a sustainable dual crosslinked cellulose hydrogel electrolyte,which has excellent mechanical strength to inhibit dendrite formation,high Zn^(2+) ions binding capacity to suppress side reaction,and abundant porous structure to facilitate Zn^(2+) ions migration.Consequently,the Zn||Zn cell with the hydrogel electrolyte can cycle stably for more than 400 h under a high current density of 10 mA cm^(−2).Moreover,the hydrogel electrolyte also enables the Zn||polyaniline cell to achieve high-rate and long-term cycling performance(>2000 cycles at 2000 mA g^(−1)).Remarkably,the hydrogel electrolyte is easily accessible and biodegradable,making the ARZBs attractive in terms of scalability and sustainability. 展开更多
关键词 CELLULOSE Dual cross-linked Aqueous rechargeable Zn-metal batteries Hydrogel electrolyte
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