Indoor dusffall samples were collected in Pit 1 and Pit 2 of Emperor Qin＇s Terra-cotta Warriors and Horses Museum in Xi＇an, Shaanxi Province, China. The morphological and elemental analysis for long-term （〉10 year...Indoor dusffall samples were collected in Pit 1 and Pit 2 of Emperor Qin＇s Terra-cotta Warriors and Horses Museum in Xi＇an, Shaanxi Province, China. The morphological and elemental analysis for long-term （〉10 years） and short-term （～0.5 year） dusffall particles and lacquer pieces on the faces of partly assembled warriors were performed with scanning electron microscopy with energy dispersive X-ray spectrometer （SEM/EDX）. The results showed that the majority of dusffall samples appeared to be composed of mineral dust particles, fly ash, and biological particles with different elemental compositions. Most of the mineral particles had irregular shapes with smooth edges. Small floccules of calcium sulfate were more frequently observed in long-term dusffall samples than in short-term samples, implying a progressive chemical reaction between continuous dusffall particles and atmospheric sulfur dioxide. Crystals of calcium sulfate were also found near pits on both inner and outer surfaces of lacquer pieces, revealing an acid chemical reaction between sulfur dioxide and lacquer material as the cause of the formation of erosion pits and cracks on surface of lacquer pieces.展开更多
基金This research was supported by the National Science Foundation of China （No. 40121303） was supported by the National Basic Research Program of China （G2004CB720200）.
文摘Indoor dusffall samples were collected in Pit 1 and Pit 2 of Emperor Qin＇s Terra-cotta Warriors and Horses Museum in Xi＇an, Shaanxi Province, China. The morphological and elemental analysis for long-term （〉10 years） and short-term （～0.5 year） dusffall particles and lacquer pieces on the faces of partly assembled warriors were performed with scanning electron microscopy with energy dispersive X-ray spectrometer （SEM/EDX）. The results showed that the majority of dusffall samples appeared to be composed of mineral dust particles, fly ash, and biological particles with different elemental compositions. Most of the mineral particles had irregular shapes with smooth edges. Small floccules of calcium sulfate were more frequently observed in long-term dusffall samples than in short-term samples, implying a progressive chemical reaction between continuous dusffall particles and atmospheric sulfur dioxide. Crystals of calcium sulfate were also found near pits on both inner and outer surfaces of lacquer pieces, revealing an acid chemical reaction between sulfur dioxide and lacquer material as the cause of the formation of erosion pits and cracks on surface of lacquer pieces.
