To improve surface accuracy of the work-piece and obtain potentially valuable information,a dynamic milling force prediction model was proposed based on data mining.In view of the current dynamic milling force obtaine...To improve surface accuracy of the work-piece and obtain potentially valuable information,a dynamic milling force prediction model was proposed based on data mining.In view of the current dynamic milling force obtained through finite element simulation and analytical calculation,in the finite element modeling,the model built is inevitably different from the actual working conditions,and the analytical calculation is slightly cumbersome and complex,and a dynamic milling force prediction model based on data mining is proposed.The model was established using a combination of regression analysis and Radial Basis Function(RBF) neural network.Using data mining as a means,the internal relationship between milling force,cutting parameters,temperature,vibration and surface quality is deeply analyzed,and the influence of dynamic milling force changes on different situations is extracted and summarized by the methods of cluster analysis and correlation analysis.The results show that the proposed dynamic milling force model has a good prediction effect,ensures the production quality,reduces the occurrence of flutter,improves the surface accuracy of the work-piece,and provides a more accurate basis for the selection of process parameters.展开更多
To improve the hydrogen storage performance of PrMg12-type alloys, Ni was adopted to replace partially Mg in the alloys. The PrMgllNi+x wt.% Ni (x=100, 200) alloys were prepared via mechanical milling. The phase st...To improve the hydrogen storage performance of PrMg12-type alloys, Ni was adopted to replace partially Mg in the alloys. The PrMgllNi+x wt.% Ni (x=100, 200) alloys were prepared via mechanical milling. The phase structures and morphology of the experimental alloys were in vestigated by X-ray diffraction and transmission electron microscopy. The results show that increasing milling time and Ni content accelerate the formation of nanocrystalline and amorphous structure. The gaseous hydrogen storage properties of the experimental alloys were determined by differential scanning calorimetry (DSC) and Sievert apparatus. In addition, increasing milling time makes the hydrogenation rates of the alloys augment firstly and decline subsequently and the dehydrogenation rate always increases. The maximum capacity is 5. 572 wt. % for the x = 100 alloy and 5. 829 wt. % for the x = 200 alloy, respectively. The enthalpy change ( △H ), entropy change (△S) and the dehydrogenation activation energy (Exde) markedly lower with increasing the milling time and the Ni content due to the generation of nanocrystalline and amorphous structure.展开更多
Molecular dynamics (MD) simulations of the consecutive compression-decompression cycles ot hexagonal zinc sulfide (wurtzite) nanoparticles predict an irreversible phase transformation to the cubic polymorph.The ph...Molecular dynamics (MD) simulations of the consecutive compression-decompression cycles ot hexagonal zinc sulfide (wurtzite) nanoparticles predict an irreversible phase transformation to the cubic polymorph.The phase transformation commences at the contact area between the particle and the inden- ter and proceeds with the number of compression cycles. Dislocations are visible for a particle size above 5nm. Results from wet grinding and dry powder compression experiments on a commercial wurtzite pigment agree qualitatively with MD simulation predictions. X-ray diffraction patterns reveal that the amount of cubic polymorph in the compressed samples increases with pressure applied to the powder. In comparison with powder compression, wet milling leads to a more pronounced phase transformation. This occurs because the particles are exposed to a large number of stress events by collision with the grinding media, which leads to the formation of defects and new surface crystallites by particle fracture. According to the MD simulations, phase transformation is expected to occur preferentially in surface crystallites because they experience the highest mechanical load. Because of the phase transformation, the wet ground and compressed samples exhibit a lower photo- luminescence intensity than the feed material. In comparison with powder compression, milling reduces the photoluminescence intensity more substantially. This occurs because a higher defect concentration is formed. The defects contribute to the phase transformation and photoluminescence quenching.展开更多
基金Supported by Gansu Science and Technology Program(21YF5GA080)。
文摘To improve surface accuracy of the work-piece and obtain potentially valuable information,a dynamic milling force prediction model was proposed based on data mining.In view of the current dynamic milling force obtained through finite element simulation and analytical calculation,in the finite element modeling,the model built is inevitably different from the actual working conditions,and the analytical calculation is slightly cumbersome and complex,and a dynamic milling force prediction model based on data mining is proposed.The model was established using a combination of regression analysis and Radial Basis Function(RBF) neural network.Using data mining as a means,the internal relationship between milling force,cutting parameters,temperature,vibration and surface quality is deeply analyzed,and the influence of dynamic milling force changes on different situations is extracted and summarized by the methods of cluster analysis and correlation analysis.The results show that the proposed dynamic milling force model has a good prediction effect,ensures the production quality,reduces the occurrence of flutter,improves the surface accuracy of the work-piece,and provides a more accurate basis for the selection of process parameters.
基金financially sponsored by National Natural Science Foundation of China (51471054)
文摘To improve the hydrogen storage performance of PrMg12-type alloys, Ni was adopted to replace partially Mg in the alloys. The PrMgllNi+x wt.% Ni (x=100, 200) alloys were prepared via mechanical milling. The phase structures and morphology of the experimental alloys were in vestigated by X-ray diffraction and transmission electron microscopy. The results show that increasing milling time and Ni content accelerate the formation of nanocrystalline and amorphous structure. The gaseous hydrogen storage properties of the experimental alloys were determined by differential scanning calorimetry (DSC) and Sievert apparatus. In addition, increasing milling time makes the hydrogenation rates of the alloys augment firstly and decline subsequently and the dehydrogenation rate always increases. The maximum capacity is 5. 572 wt. % for the x = 100 alloy and 5. 829 wt. % for the x = 200 alloy, respectively. The enthalpy change ( △H ), entropy change (△S) and the dehydrogenation activation energy (Exde) markedly lower with increasing the milling time and the Ni content due to the generation of nanocrystalline and amorphous structure.
基金supported financially by Arbeitsgemeinschaft industrieller Forschungsvereinigungen(AiF)(Grant No.:IGF333ZN)
文摘Molecular dynamics (MD) simulations of the consecutive compression-decompression cycles ot hexagonal zinc sulfide (wurtzite) nanoparticles predict an irreversible phase transformation to the cubic polymorph.The phase transformation commences at the contact area between the particle and the inden- ter and proceeds with the number of compression cycles. Dislocations are visible for a particle size above 5nm. Results from wet grinding and dry powder compression experiments on a commercial wurtzite pigment agree qualitatively with MD simulation predictions. X-ray diffraction patterns reveal that the amount of cubic polymorph in the compressed samples increases with pressure applied to the powder. In comparison with powder compression, wet milling leads to a more pronounced phase transformation. This occurs because the particles are exposed to a large number of stress events by collision with the grinding media, which leads to the formation of defects and new surface crystallites by particle fracture. According to the MD simulations, phase transformation is expected to occur preferentially in surface crystallites because they experience the highest mechanical load. Because of the phase transformation, the wet ground and compressed samples exhibit a lower photo- luminescence intensity than the feed material. In comparison with powder compression, milling reduces the photoluminescence intensity more substantially. This occurs because a higher defect concentration is formed. The defects contribute to the phase transformation and photoluminescence quenching.