Imaging through dynamic scattering media with stitched speckle patterns

Imaging through scattering media via speckle autocorrelation is a popular method based on the optical memory effect.However,it fails if the amount of valid information acquired is insufficient due to a limited sensor size.In this Letter,we reveal a relationship between the detector and object sizes for the minimum requirement to ensure image reconstruction by defining a sampling ratio R,and propose a method to enhance the image quality at a small R by capturing multiple frames of speckle patterns and piecing them together.This method will be helpful in expanding applications of speckle autocorrelation to remote sensing,underwater probing,and so on.

Seeing through dynamics scattering media:Suppressing diffused reflection based on decorrelation time difference

We observed a phenomenon that different scattering components have different decorrelation time.Based on decorrelation time difference,we proposed a method to image an object hidden behind a turbid medium in a reflection mode.In order to suppress the big disturbance calused by reflection and back scattering,two framnes of speckles are recorded in sequence,and their difference is used for image reconstruction.Our method is immune to both medium motions and object movements.

Thermal Transport in Methane Hydrate by Molecular Dynamics and Phonon Inelastic Scattering

The heat conduction and thermal conductivity for methane hydrate are simulated from equilibrium molecular dynamics. The thermal conductivity and temperature dependence trend agree well with the experimental results. The nonmonotonic temperature dependence is attributed to the phonon inelastic scattering at higher temperature and to the confinement of the optic phonon modes and low frequency phonons at low temperature. The thermal conductivity scales proportionally with the van der Waals interaction strength, The conversion of a crystal-like nature into an amorphous one oecurs at higher strength. Both the temperature dependence and interaction strength dependence are explained by phonon inelastic scattering.

Dynamic Behavior and Mass Transport in Polyacrylic Acid Gel by Dynamic Light Scattering

Dynamic behaviors on polyacrylic acid (PAA) gels and mass (small molecules) transports in the gels have been studied mainly by dynamic light scattering (DLS). The cross-linking degree (fc), monomer concentration (Cm) and temperature of the gels have significant influences on its dynamic behavior and mass transport in the gels. The increase of fc leads to decrease of the mesh sizes of the gels, thus the obstacle of the gels for mass transport is increased. As a result, small molecular diffusion Dk in the gels is decreased. So even if for small molecules, the Dk also is influenced.

DYNAMIC LIGHT SCATTERING STUDY ON TRANSLATION DIFFUSION OF 8-ARM STAR POLYSTYRENE IN GOOD AND THETA SOLVENTS

The technique of dynamic light scattering has been used to investigate the translation diffusion behavior of 8-arm star polystyrene (SPS)in a good solvent, tetrahydrofuran (THF) or benzene (BZ) and a theta solvent, cyclohexane (CH), by homodyne photon correlation spectroscopy .The intensityintensity autocorrelation function was analyzed by the method of cumulant. The translation diffusion coefficients have been obtained as a function of temperature and concentration. Under theta condition ,the non-concentration dependence of diffusion coefficient showed the unperturbed Gaussian state o the SPS molecular chain. The different hydrodynamic radii estimated from Stokes- Einstein equation reflected the stretch extent of the arm chain for regular star polymer. The data of diffusion activation energy of SPS in THF, BZ and CH were also obtained respectively.

EARLY CATARACT DETECTION BY DYNAMIC LIGHT SCATTERING WITH SPARSE BAYESIAN LEARNING

Dynamic light scattering(DLS)is a promising technique for early cataract detection and for studying cataractogenesis.A novel probabilistic analysis tool,the sparse Bayesian learning(SBL)algorithm,is described for reconstructing the most-probable size distribution ofα-crystallin and their aggregates in an ocular lens from the DLS data.The performance of the algorithm is evaluated by analyzing simulated correlation data from known distributions and DLS data from the ocular lenses of a fetal calf,a Rhesus monkey,and a man,so as to establish the required efficiency of the SBL algorithm for clinical studies.

Using Refined Theory to Studied Elastic Wave Scattering and Dynamic Stress Concentrations in Plates with Two Cutouts

In this paper, based on complex variables and conformal mapping methods, using the refined dynamic equation of plates, elastic wave scattering and dynamic stress concentrations in plates with two cutouts were studied. Applying the orthogonal function expansion method, the problem to be solved can be reduced into the solution of a set of infinite algebraic equations. According to free boundary conditions, numerical results of dynamic moment concentration factors in thick plates with two circular cutouts analyze that: there will be more complex interaction changes between two-cutout situation than single cutout situation. In the case of low frequency or high frequency and thin plate, the hole-spacing in the absence of coupling interactions was larger or smaller. The numerical results and method can be used to analyze the dynamics and strength of plate-like structures.

Sparsity-based efficient simulation of cluster targets electromagnetic scattering

An efficient and real-time simulation method is proposed for the dynamic electromagnetic characteristics of cluster targets to meet the requirements of engineering practical applications.First,the coordinate transformation method is used to establish a geometric model of the observation scene,which is described by the azimuth angles and elevation angles of the radar in the target reference frame and the attitude angles of the target in the radar reference frame.Then,an approach for dynamic electromagnetic scattering simulation is proposed.Finally,a fast-computing method based on sparsity in the time domain,space domain,and frequency domain is proposed.The method analyzes the sparsity-based dynamic scattering characteristic of the typical cluster targets.The error between the sparsity-based method and the benchmark is small,proving the effectiveness of the proposed method.

Polarized imaging dynamic light scattering for simultaneous measurement of nanoparticle size and morphology

The performance of nanoparticles is often affected by particle size and morphology.Currently,electron microscopy or atomic force microscopy is typically utilized to determine the size and morphology of nanoparticles.However,there are issues such as difficult sample preparation,long processing times,and challenges in quantitative characterization.Therefore,it is of great significance to develop a fast,accu-rate,and statistical method to measure the size and morphology of nanoparticles.In this study,a new method,called polarized imaging dynamic light scattering(PIDLS),is proposed.The nanoparticles are irradiated with a vertical linearly polarized laser beam,and a polarization camera collected the dynamic light scattering images of particles at four different polarization directions(0°,45°,90°,and 135°)at a scattering angle of 90°.The average particle size and distribution are obtained using the imaging dy-namic light scattering method at 0°polarization direction,and the morphology of the particles is ob-tained based on the depolarization patterns of the scattered light.The optical sphericityΦis defined based on the degree of linear polarization(DoLP).It is also implemented for the quantitative evaluation of the sphericity of the nanoparticles,including spherical,octahedral,nanoplate,nanorod,and linear ones.Together with the Poincarésphere parameterψ,the morphology of the nanoparticles can be roughly identified.In addition,PIDLS enables the measurement of particle size and morphology distributions simultaneously for evaluating the uniformity of particles.The effectiveness of PIDLS is verified by the measurement of five kinds of industrial titanium dioxide as well.

Applying dynamic light scattering to investigate the self-assembly process of DNA nanostructures

Understanding the dynamic assembly process of DNA nanostructures is important for developing novel strategy to design and construct functional devices.In this work,temperature-controlled dynamic light scattering(DLS)strategy has been applied to study the global assembly process of DNA origami and DNA bricks.Through the temperature dependent size and intensity profiles,the self-assembly process of various DNA nanostructures with different morphologies have been well-studied and the temperature transition ranges could be observed.Taking advantage of the DLS information,rapid preparation of the DNA origami and the brick assembly has been realized through a constant temperature annealing.Our results demonstrate that the DLS-based strategy provides a convenient and robust tool to study the dynamic process of forming hieratical DNA structures,which will benefit understanding the mechanism of self-assembly of DNA nanostructures.

A regularization algorithm of dynamic light scattering for estimating the particle size distribution of dual-substance mixture in water

Dynamic light scattering(DLS)is a nondestructive,well-established technique for the size characterization of proteins,nanoparticles,polymers,and colloidal dispersions.However,current DLS techniques are only applied to particle groups of single composition due to the limitation of their inversion algorithm.In this study,we propose a particle size distribution inversion algorithm based on the Tikhnonov regularization method that can be applied to the dual-substance particle mixture.The algorithm retrieves the particle size distributions of two substances,respectively,by taking advantage of their refractive index differences.The simulation results reveal that the algorithm has excellent accuracy and stability when the scattering angle is 30°.Instead of the original identity matrix,the first-order difference matrix and second-order difference matrix are used as the regular matrix when utilizing the Tikhnonov algorithm,which obviously improves the anti-interference,accuracy,and stability of the algorithm.Furthermore,the inversion of particle size distribution is carried out at a 0.01%–1%noise level,which shows that the algorithm has an available antinoise ability.Finally,experimental particle size measurements for a mixture of polystyrene beads and toner particles demonstrate that the proposed algorithm is superior to the traditional Tikhnonov algorithm in applicability and accuracy.

Study of asphaltene reaggregation in toluene/heptane mixture by dynamic and static light scattering

This paper presents the study of the effect of multiple ultrasonic impacts on submicron asphaltene aggregates in a toluene/heptane solution,conducted with dynamic light scattering technique.The objects of the study were four samples of asphaltenes obtained from four different oils.For all samples,the change in the average size of the asphaltene submicron aggregates with time was measured after the addition of a precipitant(heptane)to a solution of asphaltenes in toluene at an amount above the threshold concentration.Asphaltene aggregates formed in solution after the addition of the precipitant and were subjected to ultrasonic treatment,which led to the destruction of the asphaltene aggregates.Aggregation of destroyed asphaltenes was observed.The kinetics of this aggregation were similar to the kinetics of aggregation of asphaltenes after the addition of a precipitant.Multiple iterations of asphaltene aggregate destruction in the sample led to a significant change in the kinetics of aggregation:the growth of aggregates slowed and stabilized at a size of approximately 200 nm and 30 nm for the different studied samples.

Dynamic stress concentrations in thick plates with two holes based on refined theory

Based on complex variables and conformal mapping, the elastic wave scat- tering and dynamic stress concentrations in the plates with two holes are studied by the refined dynamic equation of plate bending. The problem to be solved is changed to a set of infinite algebraic equations by an orthogonM function expansion method. As examples, under free boundary conditions, the numerical results of the dynamic moment concen- tration factors in the plates with two circular holes are computed. The results indicate that the parameters such as the incident wave number, the thickness of plates, and the spacing between holes have great effects on the dynamic stress distributions. The results are accurate because the refined equation is derived without any engineering hypothese.

Electromagnetic scattering characteristics of coaxial helicopter based on dynamic transformation method

With the development of coaxial rotors and high-speed helicopters, the electromagnetic scattering characteristics of coaxial helicopters have gradually become a research hotspot. In order to deal with the Radar Cross-Section(RCS) of high-speed rotating rotors or coaxial main rotors, a Dynamic Scattering Method(DSM) based on dynamic process simulation and grid coordinate transformation is presented. Instantaneous electromagnetic scattering from rotors and helicopters is solved using Physical Optics(PO) and Physical Theory of Diffraction(PTD). Important factors are analyzed and discussed in detail, including individual rotor rotation, azimuth, elevation angle,fuselage, pitch angle, and roll angle. The results show that the electromagnetic scattering characteristics of rotor-type components are dynamic and periodic. The dynamic RCS period of a single rotor is related to the dynamic RCS period of the coaxial main rotor. Choosing different observation angles and attitude angles has a great impact on the static and dynamic RCS of the helicopter.The presented DSM is effective and efficient to analyze and determine the dynamic electromagnetic scattering characteristics of conventional helicopters or coaxial helicopters.

Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants

Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering. A monodisperse vesicle system is obtained with a polydispersity of 0.082. Ultrasonication can promote the vesicle formation. Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.

Fast nanoparticle sizing by image dynamic light scattering

In this paper, an image dynamic light scattering method for nanoparticle sizing is introduced. The spatial distribution of the scattered lights from nanoparticles undergoing Brownian motion was captured at a high frame rate by a digital camera within one second, which is considerably faster than the conven- tional photon correlation spectroscopy method. The captured series of photographs were meshed into thousands of small units for calculating the intensity autocorrelation functions in parallel. Experimental results from the measurements of three reference nanoparticle samples （27, 80, and 352 nm in diameters） demonstrated the feasibility of this method.

Spectroscopic and dynamic light scattering studies of the interaction between pterodontic acid and bovine serum albumin

Pterodontic acid(PA)has been isolated from Laggera pterodonta,a Chinese herbal medicine,and shown to possess antibacterial activity in vitro.To facilitate its preclinical development,the interaction between PA and bovine serum albumin(BSA)was studied using a fluorescence quenching technique,ultraviolet–visible spectrophotometry and dynamic light scattering(DLS).At temperatures of 297 K and 310 K and an excitation wavelength of 282 nm,the fluorescence intensity of BSA decreased significantly with increasing concentration of PA attributed to the formation of a PA–BSA complex.The apparent binding constant,number of binding sites and corresponding thermodynamic parameters were calculated and the main intermolecular attraction shown to result from hydrogen bonding and van der Waals forces.Synchronous fluorescence spectrometry revealed that the binding site in the complex approached the microenvironment of Trp and three-dimensional fluorescence spectroscopy showed the binding induced conformational changes in BSA.Using DLS,increasing PA concentration was shown to cause a gradual increase in hydrodynamic diameter and significant aggregation of the complex.

A HYBRID POLYMER GEL AND ITS STATIC NONERGODICITY

We used a thermally reversible hybrid gel made of billions of physically jam-packed swollen thermally sensitivepoly(N-isopropyl-acrylamide) chemical microgels. Laser light scattering study on a series of such hybrid gels formed atdifferent gelling rates and temperatures revealed that the position-dependence of the scattering speckle pattern(staticnonergodicity) came from large voids formed during the sol-gel transition. With a proper preparation, such a nonergodicitycould be completely removed, indicating that the static nonergodicity generally observed in a gel is not indinsic, but comesfrom the clustering "island" structure formed during the gelation process.

Spectroscopic Evaluation of Effects of Heat Treatments on the Structures and Emulsifying Properties of Caseins

The effects of heat treatment(heating temperature and pH) on the structures and emulsifying properties of caseins were systematically studied by spectroscopy.Heat treatment from 60to 100℃resulted in an increase in their fluorescence intensity,hydrodynamic diameter,turbidity and emulsifying activity index,but decreased the size polydispersity of caseins.In the pH range of 5.5to 7.0,the fluorescence intensity,hydrodynamic diameter,turbidity and emulsifying properties decreased with increased heating pH,but the size polydispersity of caseins increased with increased pH.The relationship between the surface fluorescence intensity and emulsifying activity was also investigated,revealing a correlation coefficient of 0.90.These results suggested that heat treatment could be used to modify the structures and emulsifying properties of caseins by appropriately selecting heating conditions.