The transverse cutting mechanism of the checkerboard paving robot, which directly affects the robot's operation, is regarded as the most important part in a transverse pavement system This research aims at designing ...The transverse cutting mechanism of the checkerboard paving robot, which directly affects the robot's operation, is regarded as the most important part in a transverse pavement system This research aims at designing a new system which is appropriate for desert wofidng en- vironments and finishing cutting the rope of straw. In this paper, computer emulating technology is applied, and with three-dimensional modeling by Pro/ENGINEER software, can observe whether or not interference exists. Also, the speed and displacement parameters of the main parts of the cutting system are given by the dynamic emulation by Automatic Dynamic Analysis of Mechanical System (ADAMS), which theoretically assures the feasibility and appropriateness of the cutting mechanisrn~ Finally, results of the experinaent shows that the cutting mechanism can cut the straw strand as designed.展开更多
Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction ...Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction lining and wire rope.Then we carried out a dynamic mechanical analysis(DMA) to explain the change in mechanical properties of the friction lining as function of temperature and load frequency and found that temperature has a stronger effect on the mechanical properties than the frequency.We used multiple regression analysis to obtain the thermoviscoelastic constitutive relations of the friction lining.As well we derived the analytic solution for the thermoviscoelastic contact radius and pressure by combining the theory of viscoelastic contact mechanics with thermoviscoelastic constitutive relations.展开更多
From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion correspon...From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion corresponds to whether the constant term in the equation is equal to zero.If constant term is zero and no dispersive force is considered,the equation represents the traditional Shields initiation curve,and if constant term is zero without the dispersive force being considered,then a new Shields curve which is much lower than the traditional one is got.The fixed point of the equation corresponds to the equilibrium sediment transport of bed load.In the mutation analysis,we have found that the inflection point is the demarcation point of breaking.In theory,the breaking point corresponds to the dividing boundary line,across which the bed form changes from flat bed to sand ripple or sand dune.Compared with the experimental data of Chatou Hydraulic Lab in France,the conclusions are verified.展开更多
Mechanical assembly has its own dynamic quality directly affecting the dynamic quality of whole product and should be considered in quality inspection and estimation of mechanical assembly. Based on functional relatio...Mechanical assembly has its own dynamic quality directly affecting the dynamic quality of whole product and should be considered in quality inspection and estimation of mechanical assembly. Based on functional relations between dynamic characteristics involved in mechanical assembly, the effects of assembling process on dynamic characteristics of substructural components of an assembly system are investigated by substructuring analysis. Assembly-coupling dynamic stiffness is clarified as the dominant factor of the effects and can be used as a quantitative measure of assembly dynamic quality. Two computational schemes using frequency response functions(FRFs) to determine the stiffness are provided and discussed by inverse substructuring analysis, including their applicable conditions and implementation procedure in application. Eigenvalue analysis on matrix-ratios of FRFs before and after assembling is employed and well validates the analytical outcomes and the schemes via both a lumped-parameter model and its analogic experimental counterpart. Applying the two schemes to inspect the dynamic quality provides the message of dynamic performance of the assembly system, and therefore improves conventional quality inspection and estimation of mechanical assembly in completeness.展开更多
The transition behaviour of the blends of isotactic polypropylene (i-PP) with ethylene-propylene terpolymer (EPDM) containing 42 wt% propylene was investigated by dynamic mechanical analysis technique (DMA). Owing to ...The transition behaviour of the blends of isotactic polypropylene (i-PP) with ethylene-propylene terpolymer (EPDM) containing 42 wt% propylene was investigated by dynamic mechanical analysis technique (DMA). Owing to its high propylene content, EPDM is compatible with i-PP to some degree. The interaction between the two components was strengthened. As expected, for partially compatible system the glass transition temperature of i-PP in the blends shifted to lower temperature. It was found that there existed two transitions, αEPDM and βEPDM, for the EPDM used in this work. The former was considered to be the glass transition of the random chain segments of EPDM, while the latter the local motion of the long ethylene sequences in EPDM. The unusual transition behaviour of αEPDM in the blends was explained in terms of the greater thermal expansion of EPDM and the compatibility of the two components. On the other hand, the βEPDM changed with the composition of the blends in a regular manner.展开更多
This paper uses Poincare’s formalism to study . the integral invariants of aconservative holonomic dynamical system Introducing new parameters for theasynchronous variation, a generalization of the poincare and ...This paper uses Poincare’s formalism to study . the integral invariants of aconservative holonomic dynamical system Introducing new parameters for theasynchronous variation, a generalization of the poincare and Poincare-Cartan integralinvariants is presented.展开更多
Conventionally available Polyvinyl acetate (PVAc) wood glues are polyvinyl alcohol (PVA) stabilized, with drawbacks like poor strength at high humidity, poor strength at high temperature and workability at low-tempera...Conventionally available Polyvinyl acetate (PVAc) wood glues are polyvinyl alcohol (PVA) stabilized, with drawbacks like poor strength at high humidity, poor strength at high temperature and workability at low-temperature. PVAc is non-resistant to high humidity, and if such adhesive bonds are exploited in a highly humid environment, its strength substantially decreases. Sufficiently water-resistant adhesive bonds are achieved by modifying PVAc dispersion with special chemicals like acrylic acid (AA) and N-methylol acrylamide (NMA) as a co-monomer, Silanes, and ethylene modified PVA. The Lewis acids like aluminium chloride and aluminium nitrate are used as cross-linkers. So PVAc adhesives are classified as reactive and non-reactive glue. Application of non-reactive D1 (as per EN 204-205) and reactive D2 and D3 (as per EN 204-205) adhesives for bonding laminate on plywood is a regular practice in the Indian market. In summer time, Crack formation was seen in laminate bonded with reactive D2 and D3 adhesives in regions where the room temperature was above 45°C. However, if the same laminate substrates were bonded with non-reactive D1, no cracks were seen. To analyse the above phenomenon, we have done Dynamic mechanical analysis of non-reactive D1, reactive D2 and D3 adhesive.展开更多
Polyethylene octene elastomer (POE) as impact modifier was incorporated into wood/polypropylene composites (WPC) to enhance the impact strength of the composite. Two extruding routes, i.e. direct extruding route and t...Polyethylene octene elastomer (POE) as impact modifier was incorporated into wood/polypropylene composites (WPC) to enhance the impact strength of the composite. Two extruding routes, i.e. direct extruding route and two-stage extruding route, were adopted to produce Wood Powder/PP/POE ternary composites. The mechanical and dynamic mechanical analysis (DMA) properties of the composites were investigated. The results showed that the addition of POE can increase the impact strength of the composites, and the composites produced via two-stage extruding route showed superior mechanical properties. The results of the DMA confirmed the mechanical tests.展开更多
Viscoelastic properties of maleated polypropylene (MAPP)-modified wood flour/polypropylene composites (WPC) were investigated by both a compression stress relaxation method and dynamic mechanical analyses (DMA)....Viscoelastic properties of maleated polypropylene (MAPP)-modified wood flour/polypropylene composites (WPC) were investigated by both a compression stress relaxation method and dynamic mechanical analyses (DMA). Three wood to polymer ratios (40:60, 60:40, and 80:20) and five MAPP loading levels (0, 1, 2, 4 and 8%) were used to study their effects on the viscoelastic prop- erties of MAPP-WPC. The results show that: 1) higher wood to polymer ratio corresponds to higher stress relaxation levels for unmodified WPC. The modification with MAPP has an obvious effect on the stress relaxation of MAPP-WPC at higher wood to polymer ratios (60:40 and 80:20), but almost no effect at the 40:60 wood to polymer ratio. The optimal MAPP loading level for the wood to polymer ratio of 60:40 appears at 1%; 2) the storage modulus reaches its maximum at a MAPP loading level of 1% for wood to polymer ratios of 40:60 and 60:40, while for the 80:20 wood to polymer ratio, a higher storage modulus is observed at higher MAPP loading levels, which is quite consistent with the stress relaxation results. The results suggested that a suitable loading level of MAPP has a positive effect on the viscoelastic properties of WPC at higher wood to polymer ratios. Excessive MAPP loading would have resulted in adverse effects.展开更多
Generalized Kelvin-Voigt and Maxwell models using Prony series are some of the most well-known models to characterize the behavior of polymers.The simulation software for viscoelastic materials generally impleme...Generalized Kelvin-Voigt and Maxwell models using Prony series are some of the most well-known models to characterize the behavior of polymers.The simulation software for viscoelastic materials generally implement only some material models.Therefore,for the practice of the engineer,it is very useful to have formulas that establish the equivalence between different models.Although the existence of these relationships is a well-established fact,moving from one model to another involves a relatively long process.This article presents a development of the relationships between generalized Kelvin-Voigt and Maxwell models using the aforementioned series and their respective relaxation and creep coefficients for one and two summations.The relationship between the singular points(maximums,minimums and inflexion points)is also included.展开更多
This research focused on the dynamic mechanical and thermal properties of woven mat jute/kenaf/jute(J/K/J)and kenaf/jute/kenaf(K/J/K)hybrid composites.Dynamic mechanical analysis(DMA)and Thermo-gravimetric Analysis(TG...This research focused on the dynamic mechanical and thermal properties of woven mat jute/kenaf/jute(J/K/J)and kenaf/jute/kenaf(K/J/K)hybrid composites.Dynamic mechanical analysis(DMA)and Thermo-gravimetric Analysis(TGA)were used to study the effect of layering sequence on the thermal properties of kenaf/jute hybrid composites.The DMA results;it was found that the differences in the stacking sequence between the kenaf/jute composites do not affect their storage modulus,loss modulus and damping factor.From the TGA and DMA results,it has been shown that stacking sequence has given positive effect to the kenaf/jute hybrid composite compared to pure epoxy composite.This is because kenaf and jute fibre has increased the Tg values of the composites,thus affect the thermal degradation.Results showed that the storage modulus for kenaf/jute hybrid composites increased compared with pure epoxy composites with increasing temperature and the values of remained almost the same at glass transition temperature(Tg),the hybrid composite perhaps due to the improved fibre/matrix interface bonding.The preliminary analysis could provide a new direction for the creation of a novel hybrid composite which offers unique properties which cannot be accomplished in a single material system.展开更多
We investigated the temperature dependency of the dynamic mechanical properties of cement asphalt paste by the dynamic mechanical thermal analysis(DMTA) method. The experimental results show that the dynamic mechani...We investigated the temperature dependency of the dynamic mechanical properties of cement asphalt paste by the dynamic mechanical thermal analysis(DMTA) method. The experimental results show that the dynamic mechanical properties of cement asphalt pastes are sensitive to temperature due to the inclusion of asphalt, and may go through different states within a temperature range of-40 ℃ to 60 ℃, which is different from that of pure cement and asphalt. As the temperature of the cement asphalt paste increases, a considerable change of dynamic mechanical properties, including storage modulus(E'), loss modulus(E'') and loss factor(tand) is observed. Moreover, the influence of asphalt to cement(A/C) ratio on the temperature sensitivity of the dynamic mechanical properties of cement asphalt composites was investigated. The temperature dependency of cement asphalt composites is ascribed to the temperature dependency of the asphalt and its interaction with cement paste. A simple fractional model is proposed to describe the viscoelastic behavior of cement asphalt composites.展开更多
Cross-linked polystyrene/glass fiber composites were fabricated using cross-linked polystyrene (CLPS) as matrix and E-glass fiber as the reinforcement. Surfaces of E-glass fibers were modified by vinyl triethoxysila...Cross-linked polystyrene/glass fiber composites were fabricated using cross-linked polystyrene (CLPS) as matrix and E-glass fiber as the reinforcement. Surfaces of E-glass fibers were modified by vinyl triethoxysilane (VTES), vinyl trimethoxysilane (VTMS) and γ-methacryloylpropyl trimethoxysilane (MPS). The treated glass fibers were analyzed by fourier transform infrared spectroscopy (FTIR). Dynamic mechanical thermal analysis (DMTA) and thermo-gravimetric analysis (TGA) were employed to investigate the effect of glass fibers surface modification on viscoelastic behavior and thermal properties. The morphology of fracture surfaces of various composites was observed by scanning electron microscopy (SEM). The results revealed that these coupling agents were connected to the surfaces of the fibers by chemical bonding. Dynamic mechanical properties as well as thermal stability of the composites were improved considerablely, but to varying degrees depending on the fiber modification. The diversities of improvement of properties were attributed to the different interfacial adhesion between CLPS matrix and the glass fibers.展开更多
The aging properties of advanced composite T300/5405 which soaked in 15# hydraulic oil, 4010 lubricating oil, RP-3 kerosene and AHC-1 cleaner were studied. The absorption and mechanical properties of the composites we...The aging properties of advanced composite T300/5405 which soaked in 15# hydraulic oil, 4010 lubricating oil, RP-3 kerosene and AHC-1 cleaner were studied. The absorption and mechanical properties of the composites were measured, and the scanning electron microscopy (SEIVO, dynamic mechanical analysis (DMA) and the infrared analysis (IR) were used to investigate the properties' changes of the composite. The aging mechanism of composite T300/5405 was also discussed. The experimental results show that the absorption of the composite in AHC-1 was the biggest, and the other three mediums had little effect on the composites. The mechanical properties declined in the aging. The composites have undergone chemical change in the test; Tg rose or declined atter the aging, and the AHC-1 cleaner and 4010 lubricating oil had the greatest influence on the Tg.展开更多
In addition to being used for pattern transfer,the negative photoresist SU-8 iswidely used as a structural material in microelectromechanical systems(MEMS).Due to its good photopatternability,SU-8 has lower manufactur...In addition to being used for pattern transfer,the negative photoresist SU-8 iswidely used as a structural material in microelectromechanical systems(MEMS).Due to its good photopatternability,SU-8 has lower manufacturing costs than many other materials,but its mechanical properties are relatively weak to some extent,which limits its performance.The mechanical properties of epoxy-like SU-8 can be enhanced by addingmicro-or nano-fillers such as carbon nanotube,clay,and SiC nanowire,which have superior elastic modulus.In this study,SiC nanowires were used to improve the mechanical properties of SU-8 while the SU-8 retains its photopatternability.The SiC nanowires were uniformly dispersed in SU-8 by stirring and ultrasonication.SU-8 materials with different SiC nanowire contents were fabricated into dog bone samples by lithography.The elastic modulus,storage modulus,and damping factor of the samples were measured by the Dynamic mechanical analysis(DMA)Q800.The experiment result shows that the rigidity and toughness increased,and the damping reduced.The 2 wt%SiC nanowires-reinforced SU-8 had a 73.88%increase in elastic modulus and a 103.4%increase in elongation at break.Furthermore,a spring component made by SiC-doped SU-8 could withstand greater acceleration.The SiC nanowires-reinforced SU-8 has the potential tomeet higher requirements in the design andmanufacture of MEMS and greatly reduce the manufacturing costs of MEMS devices.展开更多
Dynamic mechanical analysis was used to study the mechanical properties and microstructureof crazes in polystyrene produced in air or in methanol at different temperatures. A new loss peakwas found at about 82℃,which...Dynamic mechanical analysis was used to study the mechanical properties and microstructureof crazes in polystyrene produced in air or in methanol at different temperatures. A new loss peakwas found at about 82℃,which is assigned to glass transition peak of craze fibrils. The decreaseof glass transition temperature of polymer in craze fibrils is due to the high values of surface tovolume ratio. The glass transition temperature ratio of craze fibrils to bulk material (T;/Tg) hasbeen expressed as a function of the fibrils diameter (d). From T;of craze fibrils,the value of fibrildiameter can be calculated. Annealing the crazed specimen at room temperature makes the fibrilsplastically deform and cause the fibrils to thin slightly,whereas annealing the crazed specimen atthe temperature near T;of the craze fibrils makes the fibrils bundle together.展开更多
The crystallization behavior,crystal morphology and form,and viscoelastic behavior of poly(butylene succinate)(PBS)and coir fiber/PBS composites(CPB)were investigated by differential scanning calorimetry(DSC),polarize...The crystallization behavior,crystal morphology and form,and viscoelastic behavior of poly(butylene succinate)(PBS)and coir fiber/PBS composites(CPB)were investigated by differential scanning calorimetry(DSC),polarized optical microscopy(POM),X-ray diffraction(XRD)and dynamic mechanical analysis(DMA).The results of DSC measurement show that the crystallization temperature increases with the filling of coir fibers.POM images reveal that the spherulitic size and crystallization behavior of PBS are influenced by the coir fibers in the composites.XRD curves show that the crystal form of pure PBS and CPB are remaining almost identical.In addition,the storage modulus of CPB significantly increases comparing with the pure PBS.This predicted the dimensional stability and improved load-deformation temperature.In conclusion,the addition of coir fibers has a significant effect on the thermal properties of the matrix.展开更多
Two aromatic polyimides were prepared by two- step way. Firstly, the poly(amic acid)s were synthesized from 1, 3 - bis(4 - aminophenoxy)benzene and two different aromatic dianhydrides. Secondly, polyimides were pr...Two aromatic polyimides were prepared by two- step way. Firstly, the poly(amic acid)s were synthesized from 1, 3 - bis(4 - aminophenoxy)benzene and two different aromatic dianhydrides. Secondly, polyimides were prepared via thermal imidization of poly(amic acid) precursors. The polyimides prepared were insoluble in common organic solvents such as tetrahydrofuran, chloroform and N, N- dimethyiformamide. The inherent viscosities of poly(amic acid)s were 1.82 dL/g and 2.67 dL/g. The high inherent viscosities were due to the strong intra- or intermolecular hydrogen interaction. The polyimides were characterized by mechanical and thermal analysis. It was found that the samples are of excellent thermal stability, higher glass-transition temperature and excellent dynamic mechanical and thermal properties.展开更多
Wood composites glued with thermosetting synthetic resins tend to show inadequate damping performance caused by the cured resinous matrix.Waste rubber maintains prominent elasticity and is feasible to be an optional m...Wood composites glued with thermosetting synthetic resins tend to show inadequate damping performance caused by the cured resinous matrix.Waste rubber maintains prominent elasticity and is feasible to be an optional modifier.To that end,composite panels of granulated tire rub-ber(GTR)powders and thermal-mechanically pulped wood fibers were fabricated in this study.Urea formaldehyde(UF)resin was applied as the bonding agent(10%based on wood/rubber total weight).Dynamical mechanical analysis(DMA)was conducted to disclose the thermo-mechanical behaviors of the rubber-filled wood fiber composites.Influence of two technical pa-rameters,i.e.,GTR powder size(0.55-1.09 mm)and addition content(10%,20%and 30%based on wood/rubber total weight),was specifically discussed.The results showed that storage modu-lus(E’)of the rubber-filled composite decreased while loss factor(tan𝛿)increased monotonously along with elevated temperature.A steady“plateau”region among 110-170°C was found where both E’and tan𝛿keep constant.Accordingly,tan𝛿showed two peak values at 103-108 and 231-233°C due to glass transition of lignin and thermal degradation of hemicellulose,respectively.Addition of rubber fillers resulted in lower bending and internal bonding strengths as well as stor-age modulus values.When the temperature was above 183°C,all the rubber-filled composites showed higher tan𝛿values than the control.The findings above fully demonstrate the improved damping performance of the UF-bonded wood fiber composites on account of rubber component.Further work is still needed to optimize the rubber/fiber interfacial bonding strength.展开更多
基金supported by National High Technology Research and Development Program 863(Grant No.2002AA422170)the grant of Educational Commission of Heilongjiang Province of China(Grant No.10541042)
文摘The transverse cutting mechanism of the checkerboard paving robot, which directly affects the robot's operation, is regarded as the most important part in a transverse pavement system This research aims at designing a new system which is appropriate for desert wofidng en- vironments and finishing cutting the rope of straw. In this paper, computer emulating technology is applied, and with three-dimensional modeling by Pro/ENGINEER software, can observe whether or not interference exists. Also, the speed and displacement parameters of the main parts of the cutting system are given by the dynamic emulation by Automatic Dynamic Analysis of Mechanical System (ADAMS), which theoretically assures the feasibility and appropriateness of the cutting mechanisrn~ Finally, results of the experinaent shows that the cutting mechanism can cut the straw strand as designed.
基金Projects 50875253 supported by the National Natural Science Foundation of China20060290505 by the Research Fund for the Doctoral Program of Higher Education of China+2 种基金107054 by the Key Project of Ministry of Education of ChinaBK2008127 by the Natural Science Foundation of Jiangsu ProvinceCX08B_042Z by the Scientific Innovation Program for Postgraduates in Colleges and Universities of Jiangsu Province
文摘Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction lining and wire rope.Then we carried out a dynamic mechanical analysis(DMA) to explain the change in mechanical properties of the friction lining as function of temperature and load frequency and found that temperature has a stronger effect on the mechanical properties than the frequency.We used multiple regression analysis to obtain the thermoviscoelastic constitutive relations of the friction lining.As well we derived the analytic solution for the thermoviscoelastic contact radius and pressure by combining the theory of viscoelastic contact mechanics with thermoviscoelastic constitutive relations.
基金Supported by National Natural Science Foundation of China (No.50809045 and No.40776045)National Basic Research Program of China ("973" Program)(No.2007CB714101)Ministry of Education’s New Century Elitist Project of China
文摘From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion corresponds to whether the constant term in the equation is equal to zero.If constant term is zero and no dispersive force is considered,the equation represents the traditional Shields initiation curve,and if constant term is zero without the dispersive force being considered,then a new Shields curve which is much lower than the traditional one is got.The fixed point of the equation corresponds to the equilibrium sediment transport of bed load.In the mutation analysis,we have found that the inflection point is the demarcation point of breaking.In theory,the breaking point corresponds to the dividing boundary line,across which the bed form changes from flat bed to sand ripple or sand dune.Compared with the experimental data of Chatou Hydraulic Lab in France,the conclusions are verified.
基金Supported by National Natural Science Foundation of China(Grant No.51475211)
文摘Mechanical assembly has its own dynamic quality directly affecting the dynamic quality of whole product and should be considered in quality inspection and estimation of mechanical assembly. Based on functional relations between dynamic characteristics involved in mechanical assembly, the effects of assembling process on dynamic characteristics of substructural components of an assembly system are investigated by substructuring analysis. Assembly-coupling dynamic stiffness is clarified as the dominant factor of the effects and can be used as a quantitative measure of assembly dynamic quality. Two computational schemes using frequency response functions(FRFs) to determine the stiffness are provided and discussed by inverse substructuring analysis, including their applicable conditions and implementation procedure in application. Eigenvalue analysis on matrix-ratios of FRFs before and after assembling is employed and well validates the analytical outcomes and the schemes via both a lumped-parameter model and its analogic experimental counterpart. Applying the two schemes to inspect the dynamic quality provides the message of dynamic performance of the assembly system, and therefore improves conventional quality inspection and estimation of mechanical assembly in completeness.
基金This Paper was presented before the Symposium on Polymers,Chengdu,P.R.China.Nov,14-18,1989
文摘The transition behaviour of the blends of isotactic polypropylene (i-PP) with ethylene-propylene terpolymer (EPDM) containing 42 wt% propylene was investigated by dynamic mechanical analysis technique (DMA). Owing to its high propylene content, EPDM is compatible with i-PP to some degree. The interaction between the two components was strengthened. As expected, for partially compatible system the glass transition temperature of i-PP in the blends shifted to lower temperature. It was found that there existed two transitions, αEPDM and βEPDM, for the EPDM used in this work. The former was considered to be the glass transition of the random chain segments of EPDM, while the latter the local motion of the long ethylene sequences in EPDM. The unusual transition behaviour of αEPDM in the blends was explained in terms of the greater thermal expansion of EPDM and the compatibility of the two components. On the other hand, the βEPDM changed with the composition of the blends in a regular manner.
文摘This paper uses Poincare’s formalism to study . the integral invariants of aconservative holonomic dynamical system Introducing new parameters for theasynchronous variation, a generalization of the poincare and Poincare-Cartan integralinvariants is presented.
文摘Conventionally available Polyvinyl acetate (PVAc) wood glues are polyvinyl alcohol (PVA) stabilized, with drawbacks like poor strength at high humidity, poor strength at high temperature and workability at low-temperature. PVAc is non-resistant to high humidity, and if such adhesive bonds are exploited in a highly humid environment, its strength substantially decreases. Sufficiently water-resistant adhesive bonds are achieved by modifying PVAc dispersion with special chemicals like acrylic acid (AA) and N-methylol acrylamide (NMA) as a co-monomer, Silanes, and ethylene modified PVA. The Lewis acids like aluminium chloride and aluminium nitrate are used as cross-linkers. So PVAc adhesives are classified as reactive and non-reactive glue. Application of non-reactive D1 (as per EN 204-205) and reactive D2 and D3 (as per EN 204-205) adhesives for bonding laminate on plywood is a regular practice in the Indian market. In summer time, Crack formation was seen in laminate bonded with reactive D2 and D3 adhesives in regions where the room temperature was above 45°C. However, if the same laminate substrates were bonded with non-reactive D1, no cracks were seen. To analyse the above phenomenon, we have done Dynamic mechanical analysis of non-reactive D1, reactive D2 and D3 adhesive.
基金This study was supported by Introducing Foreign Advanced Technology Project (2001-1).
文摘Polyethylene octene elastomer (POE) as impact modifier was incorporated into wood/polypropylene composites (WPC) to enhance the impact strength of the composite. Two extruding routes, i.e. direct extruding route and two-stage extruding route, were adopted to produce Wood Powder/PP/POE ternary composites. The mechanical and dynamic mechanical analysis (DMA) properties of the composites were investigated. The results showed that the addition of POE can increase the impact strength of the composites, and the composites produced via two-stage extruding route showed superior mechanical properties. The results of the DMA confirmed the mechanical tests.
基金supported by the National Natural Science Foundation of China (Grant No. 30871966)
文摘Viscoelastic properties of maleated polypropylene (MAPP)-modified wood flour/polypropylene composites (WPC) were investigated by both a compression stress relaxation method and dynamic mechanical analyses (DMA). Three wood to polymer ratios (40:60, 60:40, and 80:20) and five MAPP loading levels (0, 1, 2, 4 and 8%) were used to study their effects on the viscoelastic prop- erties of MAPP-WPC. The results show that: 1) higher wood to polymer ratio corresponds to higher stress relaxation levels for unmodified WPC. The modification with MAPP has an obvious effect on the stress relaxation of MAPP-WPC at higher wood to polymer ratios (60:40 and 80:20), but almost no effect at the 40:60 wood to polymer ratio. The optimal MAPP loading level for the wood to polymer ratio of 60:40 appears at 1%; 2) the storage modulus reaches its maximum at a MAPP loading level of 1% for wood to polymer ratios of 40:60 and 60:40, while for the 80:20 wood to polymer ratio, a higher storage modulus is observed at higher MAPP loading levels, which is quite consistent with the stress relaxation results. The results suggested that a suitable loading level of MAPP has a positive effect on the viscoelastic properties of WPC at higher wood to polymer ratios. Excessive MAPP loading would have resulted in adverse effects.
文摘Generalized Kelvin-Voigt and Maxwell models using Prony series are some of the most well-known models to characterize the behavior of polymers.The simulation software for viscoelastic materials generally implement only some material models.Therefore,for the practice of the engineer,it is very useful to have formulas that establish the equivalence between different models.Although the existence of these relationships is a well-established fact,moving from one model to another involves a relatively long process.This article presents a development of the relationships between generalized Kelvin-Voigt and Maxwell models using the aforementioned series and their respective relaxation and creep coefficients for one and two summations.The relationship between the singular points(maximums,minimums and inflexion points)is also included.
基金This work is supported by UPM under GP-IPS Grant 9486400.
文摘This research focused on the dynamic mechanical and thermal properties of woven mat jute/kenaf/jute(J/K/J)and kenaf/jute/kenaf(K/J/K)hybrid composites.Dynamic mechanical analysis(DMA)and Thermo-gravimetric Analysis(TGA)were used to study the effect of layering sequence on the thermal properties of kenaf/jute hybrid composites.The DMA results;it was found that the differences in the stacking sequence between the kenaf/jute composites do not affect their storage modulus,loss modulus and damping factor.From the TGA and DMA results,it has been shown that stacking sequence has given positive effect to the kenaf/jute hybrid composite compared to pure epoxy composite.This is because kenaf and jute fibre has increased the Tg values of the composites,thus affect the thermal degradation.Results showed that the storage modulus for kenaf/jute hybrid composites increased compared with pure epoxy composites with increasing temperature and the values of remained almost the same at glass transition temperature(Tg),the hybrid composite perhaps due to the improved fibre/matrix interface bonding.The preliminary analysis could provide a new direction for the creation of a novel hybrid composite which offers unique properties which cannot be accomplished in a single material system.
基金Funded by the National Natural Science Foundation of China(50878209 and 51208515)the National Basic Research Program of China(“973”Program)(2013CB036201)
文摘We investigated the temperature dependency of the dynamic mechanical properties of cement asphalt paste by the dynamic mechanical thermal analysis(DMTA) method. The experimental results show that the dynamic mechanical properties of cement asphalt pastes are sensitive to temperature due to the inclusion of asphalt, and may go through different states within a temperature range of-40 ℃ to 60 ℃, which is different from that of pure cement and asphalt. As the temperature of the cement asphalt paste increases, a considerable change of dynamic mechanical properties, including storage modulus(E'), loss modulus(E'') and loss factor(tand) is observed. Moreover, the influence of asphalt to cement(A/C) ratio on the temperature sensitivity of the dynamic mechanical properties of cement asphalt composites was investigated. The temperature dependency of cement asphalt composites is ascribed to the temperature dependency of the asphalt and its interaction with cement paste. A simple fractional model is proposed to describe the viscoelastic behavior of cement asphalt composites.
基金Supported by National Natural Science Foundation of China (No.50872101,A3 Foresight Program-50821140308)National Basic Research Program of China (No.2009CB939704)a joint project of National Nature Science Foundation of China and Russian Foundation for Basic Research(No.NSFC-RFBR 51011120252)
文摘Cross-linked polystyrene/glass fiber composites were fabricated using cross-linked polystyrene (CLPS) as matrix and E-glass fiber as the reinforcement. Surfaces of E-glass fibers were modified by vinyl triethoxysilane (VTES), vinyl trimethoxysilane (VTMS) and γ-methacryloylpropyl trimethoxysilane (MPS). The treated glass fibers were analyzed by fourier transform infrared spectroscopy (FTIR). Dynamic mechanical thermal analysis (DMTA) and thermo-gravimetric analysis (TGA) were employed to investigate the effect of glass fibers surface modification on viscoelastic behavior and thermal properties. The morphology of fracture surfaces of various composites was observed by scanning electron microscopy (SEM). The results revealed that these coupling agents were connected to the surfaces of the fibers by chemical bonding. Dynamic mechanical properties as well as thermal stability of the composites were improved considerablely, but to varying degrees depending on the fiber modification. The diversities of improvement of properties were attributed to the different interfacial adhesion between CLPS matrix and the glass fibers.
基金Funded by the Commission of Science Technology and Industry for National Defense Technology Base Environmental Test and Observation Program(No.H052007A001)
文摘The aging properties of advanced composite T300/5405 which soaked in 15# hydraulic oil, 4010 lubricating oil, RP-3 kerosene and AHC-1 cleaner were studied. The absorption and mechanical properties of the composites were measured, and the scanning electron microscopy (SEIVO, dynamic mechanical analysis (DMA) and the infrared analysis (IR) were used to investigate the properties' changes of the composite. The aging mechanism of composite T300/5405 was also discussed. The experimental results show that the absorption of the composite in AHC-1 was the biggest, and the other three mediums had little effect on the composites. The mechanical properties declined in the aging. The composites have undergone chemical change in the test; Tg rose or declined atter the aging, and the AHC-1 cleaner and 4010 lubricating oil had the greatest influence on the Tg.
基金supports from the Shanghai Professional Technical Service Platform for Non-Silicon Micro-Nano Integrated ManufacturingProject funded by China Postdoctoral Science Foundation (No. 2018M630440)
文摘In addition to being used for pattern transfer,the negative photoresist SU-8 iswidely used as a structural material in microelectromechanical systems(MEMS).Due to its good photopatternability,SU-8 has lower manufacturing costs than many other materials,but its mechanical properties are relatively weak to some extent,which limits its performance.The mechanical properties of epoxy-like SU-8 can be enhanced by addingmicro-or nano-fillers such as carbon nanotube,clay,and SiC nanowire,which have superior elastic modulus.In this study,SiC nanowires were used to improve the mechanical properties of SU-8 while the SU-8 retains its photopatternability.The SiC nanowires were uniformly dispersed in SU-8 by stirring and ultrasonication.SU-8 materials with different SiC nanowire contents were fabricated into dog bone samples by lithography.The elastic modulus,storage modulus,and damping factor of the samples were measured by the Dynamic mechanical analysis(DMA)Q800.The experiment result shows that the rigidity and toughness increased,and the damping reduced.The 2 wt%SiC nanowires-reinforced SU-8 had a 73.88%increase in elastic modulus and a 103.4%increase in elongation at break.Furthermore,a spring component made by SiC-doped SU-8 could withstand greater acceleration.The SiC nanowires-reinforced SU-8 has the potential tomeet higher requirements in the design andmanufacture of MEMS and greatly reduce the manufacturing costs of MEMS devices.
文摘Dynamic mechanical analysis was used to study the mechanical properties and microstructureof crazes in polystyrene produced in air or in methanol at different temperatures. A new loss peakwas found at about 82℃,which is assigned to glass transition peak of craze fibrils. The decreaseof glass transition temperature of polymer in craze fibrils is due to the high values of surface tovolume ratio. The glass transition temperature ratio of craze fibrils to bulk material (T;/Tg) hasbeen expressed as a function of the fibrils diameter (d). From T;of craze fibrils,the value of fibrildiameter can be calculated. Annealing the crazed specimen at room temperature makes the fibrilsplastically deform and cause the fibrils to thin slightly,whereas annealing the crazed specimen atthe temperature near T;of the craze fibrils makes the fibrils bundle together.
基金The Natural Science Foundation of Shandong Province,China(Grant No.ZR2020QE075).
文摘The crystallization behavior,crystal morphology and form,and viscoelastic behavior of poly(butylene succinate)(PBS)and coir fiber/PBS composites(CPB)were investigated by differential scanning calorimetry(DSC),polarized optical microscopy(POM),X-ray diffraction(XRD)and dynamic mechanical analysis(DMA).The results of DSC measurement show that the crystallization temperature increases with the filling of coir fibers.POM images reveal that the spherulitic size and crystallization behavior of PBS are influenced by the coir fibers in the composites.XRD curves show that the crystal form of pure PBS and CPB are remaining almost identical.In addition,the storage modulus of CPB significantly increases comparing with the pure PBS.This predicted the dimensional stability and improved load-deformation temperature.In conclusion,the addition of coir fibers has a significant effect on the thermal properties of the matrix.
基金the Key Natural Science Foundation of Shanghai (No.02ZA14004)
文摘Two aromatic polyimides were prepared by two- step way. Firstly, the poly(amic acid)s were synthesized from 1, 3 - bis(4 - aminophenoxy)benzene and two different aromatic dianhydrides. Secondly, polyimides were prepared via thermal imidization of poly(amic acid) precursors. The polyimides prepared were insoluble in common organic solvents such as tetrahydrofuran, chloroform and N, N- dimethyiformamide. The inherent viscosities of poly(amic acid)s were 1.82 dL/g and 2.67 dL/g. The high inherent viscosities were due to the strong intra- or intermolecular hydrogen interaction. The polyimides were characterized by mechanical and thermal analysis. It was found that the samples are of excellent thermal stability, higher glass-transition temperature and excellent dynamic mechanical and thermal properties.
基金supported by Innovation Center of Forestry Resources Utilization,Jiangsu Province(No.KY202200174).
文摘Wood composites glued with thermosetting synthetic resins tend to show inadequate damping performance caused by the cured resinous matrix.Waste rubber maintains prominent elasticity and is feasible to be an optional modifier.To that end,composite panels of granulated tire rub-ber(GTR)powders and thermal-mechanically pulped wood fibers were fabricated in this study.Urea formaldehyde(UF)resin was applied as the bonding agent(10%based on wood/rubber total weight).Dynamical mechanical analysis(DMA)was conducted to disclose the thermo-mechanical behaviors of the rubber-filled wood fiber composites.Influence of two technical pa-rameters,i.e.,GTR powder size(0.55-1.09 mm)and addition content(10%,20%and 30%based on wood/rubber total weight),was specifically discussed.The results showed that storage modu-lus(E’)of the rubber-filled composite decreased while loss factor(tan𝛿)increased monotonously along with elevated temperature.A steady“plateau”region among 110-170°C was found where both E’and tan𝛿keep constant.Accordingly,tan𝛿showed two peak values at 103-108 and 231-233°C due to glass transition of lignin and thermal degradation of hemicellulose,respectively.Addition of rubber fillers resulted in lower bending and internal bonding strengths as well as stor-age modulus values.When the temperature was above 183°C,all the rubber-filled composites showed higher tan𝛿values than the control.The findings above fully demonstrate the improved damping performance of the UF-bonded wood fiber composites on account of rubber component.Further work is still needed to optimize the rubber/fiber interfacial bonding strength.