Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource

Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.

SFC placement and dynamic resource allocation based on VNF performance-resource function and service requirement in cloud-edge environment

With the continuous development of network func-tions virtualization(NFV)and software-defined networking(SDN)technologies and the explosive growth of network traffic,the requirement for computing resources in the network has risen sharply.Due to the high cost of edge computing resources,coordinating the cloud and edge computing resources to improve the utilization efficiency of edge computing resources is still a considerable challenge.In this paper,we focus on optimiz-ing the placement of network services in cloud-edge environ-ments to maximize the efficiency.It is first proved that,in cloud-edge environments,placing one service function chain(SFC)integrally in the cloud or at the edge can improve the utilization efficiency of edge resources.Then a virtual network function(VNF)performance-resource(P-R)function is proposed to repre-sent the relationship between the VNF instance computing per-formance and the allocated computing resource.To select the SFCs that are most suitable to deploy at the edge,a VNF place-ment and resource allocation model is built to configure each VNF with its particular P-R function.Moreover,a heuristic recur-sive algorithm is designed called the recursive algorithm for max edge throughput(RMET)to solve the model.Through simula-tions on two scenarios,it is verified that RMET can improve the utilization efficiency of edge computing resources.

Impact of coupling coordination development of port and city environments on urban economic competitiveness:Evidence from the coastal port cities in eastern China

Promoting the coupling coordination development of port and its hinterland city environments is an important way to improve urban economic competitiveness.Based on relevant data of 13 coastal port cities in eastern China from 2000 to 2018,this study explores the coupling coordination development of port and city environments and its impact on urban economic competitiveness by constructing the coupling coordination degree model and the panel threshold model.The research results show that:(1)In terms of the coupling coordination development of port and city environments,most coastal ports and their hinterland cities are in a state of moderate or serious disorder.Overall,the degree of coupling coordination of port and city environments needs to be further improved;(2)The coupling coordination degree of port and city environments has a significant impact on urban economic competitiveness,and this effect gradually increases with the development of the ports and the urban economy.Among the variables that impact the urban economic competitiveness,fixed assets investment and foreign trade are significant factors that can enhance urban economic competitiveness.(3)At present,there is a“U-shaped”relationship between the coupling coordination degree of port-city environments and the urban economic competitiveness.This relationship lies on the right side of the inflection point of the“U-shaped”curve.Therefore,following the concept of assigning priority to ecological development,expanding fixed assets investment and actively developing foreign trade can further enhance the urban economic competitiveness.

The Application and Effect Evaluation of Corpus Linguistics in English Teaching

This paper explores the application and effect evaluation of corpus linguistics in English teaching.It first introduces the basic concepts and development history of corpus linguistics,then analyzes its connection with language teaching theories,discussing the advantages and challenges of using corpora in language teaching.Next,it delves into the methods and technologies for building and utilizing corpora,as well as their role in developing teaching resources.Lastly,within the framework and methods of teaching effect evaluation,specific application cases of corpus linguistics in teaching design are analyzed,and their effects are assessed.Recommendations for teaching improvement and future development directions are also proposed.

Path of Rural Vitalization Based on Coupling Perspective of Township Construction and Resource Environment in Jiangsu Province,China

Recently,the field of rural vitalization has received extensive research attention.However,only few studies have proposed an approach to rural vitalization from the coupling perspective of township construction and the resource environment.Taking Jiangsu Province of China as the study area,we constructed index systems of township construction function types and resource environments.Based on 875 township study units in Jiangsu,we characterized the township construction function type and resource environment and analyzed the dynamic process of their coupling from 2005 to 2017.The results are as follows:1)the townships of planting and breeding types in Jiangsu were mainly distributed in northern and central Jiangsu;the townships of business travel,industry,and integrated types were mainly distributed in southern Jiangsu;and the townships of ecological type were irregularly distributed throughout Jiangsu.2)Resource environment factors and township construction function types in Jiangsu clustered based on their location with some overlap.3)Spatial variability in the degree of coupling level between township construction and the resource environment in Jiangsu was not apparent,and low coupling levels accounted for most of the study units.The sum of the number of medium and high coupling townships in southern,central,and northern Jiangsu was roughly equal,and the coupling level between township construction and the resource environment in southern Jiangsu evolved remained unchanged,whereas that in the central and northern Jiangsu became imbalanced.4)In Jiangsu,township construction was mainly constrained by water resources,and the constraint parameters gradually increase.Large variability in resource environment constraint was observed in northern,central,and southern Jiangsu for different township construction function types.Based on these findings,we proposed the implementation of targeted rural vitalization strategies.

Existence of Forced Waves and Their Asymptotic for Leslie-Gower Prey-Predator Model with Nonlocal Effects under Shifting Environment

In this paper, we prove the existence of forced waves for Leslie-Gower prey-predator model with nonlocal effects under shifting environment. By constructing a pair of upper and lower solutions with the method of monotone iteration, we can obtain the existence of forced waves for any positive constant shifting speed. Finally, we show the asymptotical behavior of traveling wave fronts in two tails.

The comprehensive evaluation of China＇s urbanization and effects on resources and environment

This paper constructs a comprehensive evaluation index system for the urbanization level in China in terms of four aspects of urbanization connotation： population, economy, society, and land. A comprehensive measurement is carried out for the Chinese urbanization between 1981 and 2006 based on the Entropy method. The results show that the comprehensive level of urbanization in China has a continuous increase with the major features of economic growth and a rapid evolution of the geographical landscape, followed by population urbanization and then social urbanization of health care standard; the distinguished evolutional characteristics can also be found in each of the subsystems. The integrated evolution of urbanization has a profound effect on the resources, energy and the environment, making the land resources and energy security situation under severe pressure. The environment pressure is also increased further.

Strong synergy between physical and chemical properties:Insight into optimization of atomically dispersed oxygen reduction catalysts

Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered.

Purification Effects of Aquatic Vegetations on Lake Wetland Water Environment and Analysis of the Influencing Factors in Hongze Lake

[Objective] To study the purification effect of plant community on wetland water environment in Hongze Lake, and to provide references to the ecological restoration of this area. [Methed] The typical lakeside zone of Hongze Lake Wetland National Nature Reserve was taken as the study area. Through the field survey based on environmental characteristics of aquatic areas and non-aquatic areas, combined with laboratory test, the content changes of nutrients （N and P）, COD （chemical oxygen demand） and SD （transparency） levels in the water body of lake wetland were measured; the purification effect of the lake wetland ecosystem in the growth process of aquatic vegetation was quantitatively analyzed, and possible influ- encing factors were discussed. [Result] Aquatic vegetation could remove the TN, TP, COD, Chla in wetland water environment and had obvious effects on the changes of SD content. Competition between aquatic plants can inhibit the growth of algae and relieve the eutrophication of water body. [Conclusion] This study provided theoretical basis for ecological restoration and enhancement of self-purification capability in the lakeside zone of Hongze Lake.

Hydrocarbon Generation Potential and Organic Matter Enrichment Mechanism of the Cambrian Marine Shale in the Tadong Low Uplift,Tarim Basin

Cambrian shales in China and elsewhere contain abundant oil and gas resources.However,due to its deep burial and limited outcrop,there has been relatively little research conducted on it.The Cambrian shale of the Tadong low uplift in the Tarim Basin of western China,specifically the Xidashan-Xishanbulake Formation(Fm.)and overlying Moheershan Fm.provide a case study through the use of organic petrology,mineralogy,organic and elemental geochemistry,with the aim of analyzing and exploring the hydrocarbon generation potential(PG)and organic matter(OM)enrichment mechanisms within these shale formations.The results indicate that:(1)the Cambrian shale of the Tadong low uplift exhibits relatively dispersed OM that consists of vitrinite-like macerals and solid bitumen.These formations have a higher content of quartz and are primarily composed of silica-based lithology;(2)shale samples from the Xidashan-Xishanbulake and Moheershan formations demonstrate high total organic carbon(TOC)and low pyrolytic hydrocarbon content(S_(2))content.The OM is predominantly typeⅠand typeⅡkerogens,indicating a high level of maturation in the wet gas period.These shales have undergone extensive hydrocarbon generation,showing characteristics of relatively poor PG;(3)the sedimentary environments of the Xidashan-Xishanbulake and Moheershan formations in the Tadong low uplift are similar.They were deposited in warm and humid climatic conditions,in oxygen-deficient environments,with stable terrigenous inputs,high paleoproductivity,high paleosalinity,weak water-holding capacity,and no significant hydrothermal activity;and(4)the relationship between TOC and the paleoproductivity parameter(P/Ti)is most significant in the Lower Cambrian Xidashan-Xishanbulake Fm.,whereas correlation with other indicators is not evident.This suggests a productivity-driven OM enrichment model,where input of landderived material was relatively small during the Middle Cambrian,and the ancient water exhibited lower salinity.A comprehensive pattern was formed under the combined control of paleoproductivity and preservation conditions.This study provides valuable guidance for oil and gas exploration in the Tarim Basin.

Groundwater and environmental challenges in Asia

Asia stands out as the most populous and geographically diverse region globally.The pressing issues of water resource development and the resulting ecological impacts are exacerbated by the region's rapid population growth and economic expansion.Groundwater,a vital source of water in Asia,faces significant disparities in distribution and suffers from unsustainable exploitation practices.This study applies groundwater system theory and categorizes Asia into 11 primary groundwater systems and 36 secondary ones,based on intercontinental geological structures,climate,terrain,and hydrogeological characteristics.As of the end of 2010,Asia's assessed groundwater resources totalled 4.677×10^(9) m^(3)/a,with exploitable resources amounting to 3.274×10^(9) m^(3)/a.By considering the geological environmental impacts of groundwater development and the distinctive characteristics of terrain and landforms,six categories of effect zones with varying distribution patterns are identified.The current research on Asia's groundwater resources,environmental dynamics,and human impacts aims to provide a theoretical foundation for sustainable groundwater management and environmental conservation in the region.

Effects of resistant starchⅢon the serum lipids levels and gut microbiota of Kunming mice under high-fat diet

Resistant starch III(RS3),as a prebiotic,provides health benefits.This study aimed to investigate the role of RS3 in lowering serum lipids and regulating gut microbiota by administering Novelose 330 to Kunming(KM)mice.The results demonstrated that RS3 intervention significantly decreased body weight,food intake,levels of serum total cholesterol(TC),triglyceride(TG),low-density lipoprotein cholesterol(LDL-C),and liver fat.RS3 could remarkably improve the quality of the entire cecum,quality of the cecal wall,and wall surface area of mice;enhance the moisture content;and reduce the p H value.Moreover,the decrease in the liver TC content and the increase in the fecal TC content were related to RS3 intervention.The concentrations of total short-chain fatty acids(SCFAs)in the colon and individual levels of acetate,propionate,and butyrate increased with RS3 supplementation.An Illumina-based sequencing approach showed that RS3 notably increased the Bacteroides/Firmicutes ratio in the mice fed a high-fat diet.At the genus level,the relative abundance of Bacteroides,Ruminococcus,and Bifidobacterium and the number of main SCFA producers increased in the mice fed an RS3 diet.These findings provided insights into specific gut microbiota shifts to the hypolipidemic effect of RS3.

The impact of nurses’organizational commitment on their perceptions of the work environment:Strong mediating effect of the psychological contract

Objective:The objective is to assess the direct and indirect effects of nurses’organizational commitment(OC)on their work environment perceptions(WEP)and the role of the psychological contr act(PC).Methods:A cross‑sectional quantitative study of 3047 registered nurses in four Chinese hospitals was conducted.The Essentials of Magnetism II(Chinese version),OC,and PC scales were used in the study,and the structural equation modeling was used to assess the connections among variables.Results:The results showed that OC was positively correlated with WEP(r=0.561,P<0.001),and PC was negatively correlated with the WEP(r=−0.717,P<0.001),and OC(r=−0.739,P<0.001).Nurses’PC played a strong mediating role between OC and WEP,accounting for 87.64%of the total effect.Besides,PC played an important role in creating a healthy work environment.Conclusions:The exploration of the relationships among WEP,PC,and OC provides new insights for hospital managers to build a better work environment for nurses,which is conducive to maintaining a stable nurse team and providing high‑quality nursing services for patients.

Design and Applications of Land Resources and Ecological Environment Information System: A Case Study of Zigui County in the Three Gorges Area of China

The design and applications of a land information system built upon ARC/INFO and ArcView are presented. The proposed system not only maintains all the advantages of the more conventional implementations but also enhances them in the following ways: 1) the application program interfaces (API) are used to transmit data and messages among different parts of the system; 2) the integrated system can support studies on land evaluations and ecological analyses by efficient management of attribute and spatial data and 3) correspondingly, spatial records and attributive records are linked by the same identifiers (ID). A case study application in Zigui County of the Three Gorges Area in China demonstrates that the system could employ land-use maps and land property data to predicate and analyze the land utilization changes in the past, present and future. The ecological environment analysis can be carried out with the data of land, economics and terrain map used, showing that the system can be widely applied, especially to survey land and environment resources in the countryside area.

Analysis of the Status and Rational Allocation of Water Resources in China in View of the New Era

This paper examines the current status of water resource management and conservation in China,along with strategies to address the water resource crisis.Given the current situation,the paper highlights issues such as incomplete legal mechanisms,limited environmental awareness among enterprises,and insufficient government investment.To ad-dress these challenges,the paper proposes a series of strategies,including improving the ecological environment,enhanc-ing production techniques,strengthening management systems,rationalizing water resource allocation,and implementing water-saving measures in both industrial and agricultural production.These strategies serve to achieve sustainable water resource management,reduce water pollution,and effectively tackle the pressing water resource issues faced in China currently.

Quantitative evaluation of Tibet’s resource and environmental carrying capacity

This study identifies the carrying state and value of Tibet’s resource and environmental carrying capacity.A new theoretical framework is proposed for exploring the resource and environmental carrying capacity based on two perspectives of“growth limit”and“stability of Human-Earth relationship system”.On this basis,an ideal growth model that accords with the“short board”effect is established to predict the population limitation.Analytical results show that the holistic state of resource and environmental carrying capacity in Tibet is in jeopardy.From 2010 to 2016,Tibet’s carrying state continued to decline,moreover,the negative forces still overwhelm the positive forces.Although the resource reserves still have room for more population,the environmental capacity and ecological capacity have been overloaded.Meanwhile,the Human-Earth relationship system is in an unstable stage.Three scenarios that respond to different socioeconomic developments are implemented to predict the population limitation of resource and environmental carrying capacity in Tibet;thus,authors argue that Tibet should keep its population size within 4 million around 2025.This research will provide reference for sustainable development and resources and environmental conservation in Tibet.

Resource and Environmental Quality Changes and Adjustment Principles for Sustainable Development in Rapidly Developing Coastal Region of Southeastern China

Problems in water-land resources and environmental quality increase with the fast economic development in the coastal region of southeastern China. This region has the highest density in population, industry and towns in China, and the large export-oriented economy makes itself a strategic importance while China enters into international markets. The problems facing to this region include arable land reduction, land degradation aggravation, high percentage of built-up land with high rate of expansion, expanded non-point pollution, deteriorated water quality, decreasing biodiversity, destroyed ecosystems, severe air pollution, frequently occurred acid rain, and multi-pollutants. The important research fields in the near future should include a) influence of high-intensity exploitation of resources on changes of environment quality and its feedback; b) interface processes, key mechanisms and adjustment principles for degradation of water-, land-, and air-resources and environmental quality; c) evolvement processes and nurturing theory of biodiversity and ecological resources; and d) spatio-temporal variation and human-induced effects on regional resources and environment quality. Strategies for sustainable development in the region are as follows: a) controlling to ensure basic cultivated land area; b) enforcing remediation of polluted water environment, and controlling non-point pollution; c) strengthening ecological construction and ecological security; and d) controlling multi-pollution and preventing trace toxic pollutants.

Comprehensive Measurement for Carrying Capacity of Resources and Environment of City Clusters in Central China

Studying the carrying capacity of resources and environment of city clusters in the central China has important practical guidance significance for promoting the healthy, sustainable and stable development of this region. According to their influencing factors and reciprocity mechanism, using system dynamics approaches, this paper built a SD model for measuring the carrying capacity of resources and environment of the city clusters in the central China, and through setting different development models, the comprehensive measurement analysis on the carrying capacity was carried out. The results show that the model of promoting socio-economic development under the protection of resources and environment is the optimal model for promoting the harmony development of resources, environment, society and economy in the city clusters. According to this model, the optimum population scale of the city clusters in 2020 is 42.80×106 persons, and the moderate economic development scale is 22.055×1012 yuan (RMB). In 1996-2020, the carrying capacity of resources and environment in the city clusters took on obvious phase-change characteristics. During the studied period, it is basically at the initial development stage, and will come through the development process from slow development to speedup development.

THE ENVIRONMENTAL PROBLEMS AND COUNTERMEASURES OF MINERAL RESOURCES UTILIZATION IN CHINA

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