Effect of strain on structure and electronic properties of monolayer C_(4)N_(4)

The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to attenuate shuttle effect in Li–S batteries stemming from its large absorption energy and low diffusion energy barrier.Our results show that the ideal strengths of C_(4)N_(4)under tension and pure shear deformation conditions reach 13.9 GPa and 12.5 GPa when the strains are 0.07 and 0.28,respectively.The folded five-membered rings and diverse bonding modes between carbon and nitrogen atoms enhance the ability to resist plastic deformation of C_(4)N_(4).The orderly bond-rearranging behaviors under the weak tensile loading path along the[100]direction cause the impressive semiconductor–metal transition and inverse semiconductor–metal transition.The present results enrich the knowledge of the structure and electronic properties of C_(4)N_(4)under deformations and shed light on exploring other two-dimensional materials under diverse loading conditions.

Strain effects on Li^(+) diffusion in solid electrolyte interphases:A molecular dynamics study

Dilithium ethylene dicarbonate(Li_(2)EDC) and dilithium butylene dicarbonate(Li_(2)BDC) are the common organic compositions of the solid electrolyte interphase(SEI) layers in rechargeable lithium-ion batteries.The Li^(+) diffusion in the amorphous and ordered phases of Li_(2) EDC and Li_(2) BDC under various strains has been investigated by using molecular dynamics simulations.It is found that different strains lead to diverse changes in Li^(+) diffusivity.The tensile strain makes the Li+diffusion coefficients increase in amorphous and ordered Li_(2)EDC or Li_(2) BDC,and the compressive strain makes the Li+diffusion coefficients decrease in them.The average Li+coordination number calculation,ion conductivity calculation and the calculation of the residence autocorrelation function in amorphous and ordered Li_(2)EDC or Li_(2)BDC are performed to further analyze the strain effects on Li^(+) transport in them.The factors influencing Li^(+) diffusion in amorphous and ordered Li_(2)EDC or Li_(2) BDC under the strain are discussed.

Engineering of Ag@Pd/Al_(2)O_(3)with varied Pd-shell thickness:Dynamic evolution of ligand and strain effects on acetylene selective hydrogenation

Bimetallic nanoparticles exhibit a synergistic effect that critically depends on their surface composition,but such promotion mechanisms become vague with varying surface compositions.Here,alumina supported Ag@Pd core–shell and PdAg alloy structure with controlled size and surface compositions were prepared to demonstrate synergetic mechanisms,particularly,ligand and strain effects on activity and ethylene selectivity for acetylene hydrogenation.The performance evaluation indicates that Ag@Pd catalysts with well-controlled Pd-shell thickness can effectively lower apparent activation energy and improve ethylene selectivity.Hydrogenation activity increases from 0.019 to 0.062 s^(-1) with decreasing Pd-shell thickness under mild conditions,which is 3–6 times higher than their alloyed and monometallic counterparts.Combined characterizations and density functional theory are conducted to reveal such shell-thickness-dependent performance.The ligand effect arising from Ag alloying in the interface of Ag@Pd2ML observes the strongest binding of acetylene,but it diminished sharply and the strain effect gets more prevailing with increasing shell thickness.The competition of ethylene desorption and deephydrogenation were also investigated to understand the selectivity governing factors,and the selectivity descriptor(0.5BE(C_(2)H_(4))–BE(H))was built to match the contribution of ligand and strain effect on the different surfaces of Pd-Ag bimetallic NPs.The exploration of synergetic mechanisms among bimetallic NPs with varied structure and surface compositions in this work can help us to deepen the understanding catalyst structure–activity relationship and provide a feasible way to optimize the overall catalytic performance.

The role of strain in oxygen evolution reaction

The oxygen evolution reaction(OER)is a crucial step in metal-air batteries and water splitting technologies,playing a significant role in the efficiency and achievable heights of these two technologies.However,the OER is a four-step,four-electron reaction,and its slow kinetics result in high overpotentials,posing a challenge.To address this issue,numerous strategies involving modified catalysts have been proposed and proven to be highly efficient.In these strategies,the introduction of strain has been widely reported because it is generally believed to effectively regulate the electronic structure of metal sites and alter the adsorption energy of catalyst surfaces with reaction intermediates.However,strain has many other effects that are not well known,making it an important yet unexplored area.Based on this,this review provides a detailed introduction to the various roles of strain in OER.To better explain these roles,the review also presents the definition of strain and elucidates the potential mechanisms of strain in OER based on the d-band center theory and adsorption volcano plot.Additionally,the review showcases various ways of introducing strain in OER through examples reported in the latest literature,aiming to provide a comprehensive perspective for the development of strain engineering.Finally,the review analyzes the appropriate proportion of strain introduction,compares compressive and tensile strain,and examines the impact of strain on stability.And the review offers prospects for future research directions in this emerging field.

Strain-rate effect on initial crush stress of irregular honeycomb under dynamic loading and its deformation mechanism

The seemingly contradictory understandings of the initial crush stress of cellular materials under dynamic loadings exist in the literature, and a comprehensive analysis of this issue is carried out with using direct information of local stress and strain. Local stress/strain calculation methods are applied to determine the initial crush stresses and the strain rates at initial crush from a cell-based finite element model of irregular honeycomb under dynamic loadings. The initial crush stress under constant-velocity compression is identical to the quasi-static one, but less than the one under direct impact, i.e. the initial crush stresses under different dynamic loadings could be very different even though there is no strain-rate effect of matrix material. A power-law relation between the initial crush stress and the strain rate is explored to describe the strain-rate effect on the initial crush stress of irregular honeycomb when the local strain rate exceeds a critical value, below which there is no strain-rate effect of irregular honeycomb. Deformation mechanisms of the initial crush behavior under dynamic loadings are also explored.The deformation modes of the initial crush region in the front of plastic compaction wave are different under different dynamic loadings.

Irradiation effect on strain sensitivity coefficient of strain sensing fiber Bragg gratings

The effect of irradiation on the strain sensitivity coefficient of strain sensing fiber Bragg gratings （FBGs） has been investigated through experiments. FBGs were fabricated in single mode fibers with 3 tool% Ge-concentration in the core and with a H2-1oading treatment. In experiments, the FBGs were subjected to y-radiation exposures using a Co6~ source at a dose-rate of 25 Gy/min up to a total dose of 10.5 kGy. The GeO defect in fiber absorbs photons to form a GeE＇ defect; the interaction with H2 is a probable reason for the y-radiation sensitivity of gratings written in hydrogen loaded fibres, The effect mechanism of radiation on the strain sensitivity coefficient is similar to that of radiation on the temperature sensitivity coefficient. Radiation affects the effective index neff, which results in the change of the thermo-optic coefficient and the strain-optic coefficient. Irradiation can change the strain sensitivity coefficient of FBGs by 1.48%-2.71%, as well as changing the Bragg wavelength shift （BWS） by 22 pm-25 pm under a total dose of 10.5 kGy. Our research demonstrates that the effect of irradiation on the strain sensitivity coefficient of FBG is small and that strain sensing FBGs can work well in the radiation environment.

MODE Ⅰ CRACK TIP FIELD WITH STRAIN GRADIENT EFFECTS

A plane strain mode 1 crack tip field with strain gradient effects is investigated.A new strain gradient theory is used.An elastic-power law hardening strain gradient material is considered and two hardening laws,i.e.a separation law and an integration law are used respectively.As for the material with the separation law hardening,the angular distributions of stresses are consistent with the HRR field,which differs from the stress results;the angular distributions of couple stresses are the same as the couple stress results.For the material with the integration law hardening,the stress field and the couple stress field can not exist simultaneously,which is the same as the conclusion,but for the stress dominated field,the an- gular distributions of stresses are consistent with the HRR field;for the couple stress dominated field,the an- gular distributions of couple stresses are consistent with those in Ref.However,the increase in stresses is not observed in strain gradient plasticity because the present theory is based on the rotation gradient of the deformation only,while the crack tip field of mode 1 is dominated by the tension gradient,which will be shown in another paper.

Experimental investigation of rigid confinement effects of radial strain on dynamic mechanical properties and failure modes of concrete

In this study,to confirm the effect of confining pressure on dynamic mechanical behavior and failure modes of concrete,a split Hopkinson pressure bar dynamic loading device was utilized to perform dynamic compressive experiments under confined and unconfined conditions.The confining pressure was achieved by applying a lateral metal sleeve on the testing specimen which was loaded in the axial direction.The experimental results prove that dynamic peak axial stress,dynamic peak lateral stress,and peak axial strain of concrete are strongly sensitive to the strain rate under confined conditions.Moreover,the failure patterns are significantly affected by the stress-loading rate and confining pressure.Concrete shows stronger strain rate effects under an unconfined condition than that under a confined condition.More cracks are created in concrete subjected to uniaxial dynamic compression at a higher strain rate,which can be explained by a thermal-activated mechanism.By contrast,crack generation is prevented by confinement.Fitting formulas of the dynamic peak stress and dynamic peak axial strain are established by considering strain rate effects(50–250 s-1)as well as the dynamic confining increase factor(DIFc).

Strain Effect of Manganin Transverse Piezoresistive Gauge and Measurement of Dynamic Transverse Stresses

Manganin piezoresistive gauges have been extensively used in dynamic stress measurement for decades.It is noted,however,that when used to measure transverse stresses,considerable strain effect is caused as the consequence of change of electrical resistance resulted from bending of wires in the longitudinal-strain-experiencing sensing element of the gauge,a phenomenon discussed in this paper theoretically as well as experimentally.This effect yields unwanted signals to blend with output piezoresistive signals and is not negligible,hence decreases measurement accuracy sizably if not properly handled.To overcome this drawback,a new type of manganin transverse piezoresistive gauge has been developed by authors of this paper,which can reduce the resistance increment to acceptable low level so as to effectively bring the adverse effect under control.

MODE Ⅰ AND MODE Ⅱ CRACK TIP ASYMPTOTIC FIELDS WITH STRAIN GRADIENT EFFECTS

The strain gradient effect becomes significant when the size of frac- ture process zone around a crack tip is comparable to the intrinsic material length l, typically of the order of microns. Using the new strain gradient deformation theory given by Chen and Wang, the asymptotic fields near a crack tip in an elastic-plastic material with strain gradient effects are investigated. It is established that the dom- inant strain field is irrotational. For mode Ⅰ plane stress crack tip asymptotic field, the stress asymptotic field and the couple stress asymptotic field can not exist si- multaneously. In the stress dominated asymptotic field, the angular distributions of stresses are consistent with the classical plane stress HRR field; In the couple stress dominated asymptotic field, the angular distributions of couple stresses are consistent with that obtained by Huang et al. For mode Ⅱ plane stress and plane strain crack tip asymptotic fields, only the stress-dominated asymptotic fields exist. The couple stress asymptotic field is less singular than the stress asymptotic fields. The stress asymptotic fields are the same as mode Ⅱ plane stress and plane strain HRR fields, respectively. The increase in stresses is not observed in strain gradient plasticity for mode Ⅰ and mode Ⅱ, because the present theory is based only on the rotational gradi- ent of deformation and the crack tip asymptotic fields are irrotational and dominated by the stretching gradient.

Effects of Temperature and Strain Rate on Dynamic Properties of Concrete

To study the dynamic properties of the concrete subjected to impulsive loading, stress-time curves of concrete in different velocities were measured using split Hopkinson pressure bar (SHPB).Effects of temperature and strain rate on the dynamic yield strength and constitutive relation of the con-crete were analyzed. The dynamic mechanical properties of the reinforced concrete are subjected to high strain rates when it is at a relatively low temperature. But with temperature increasing, the temperature softening effect makes the strength of the concrete weaken and the impact toughness of the concrete is saliently relative to strain rate effect. So, strain rate effect, strain hardening and temperature softening work together on the dynamic mechanical capability of concrete and the relation between them is relatively complex.

Pathogenic effects of O-polysaccharide from Shigella flexneri strain

AIM To investigate the specific pathogenesis ofO-polysaccharide (O--PS) which is on the outermembrane of lipopolysaccharides (LPS) fromShigella fi^eri.METHODS The O--PS was isolated and purifiedfrom Shigella nexneri 5 MgoT by enzymatichydrolysis and gel chromatography. Effects ofO--PS were observed by in vitro experiment,(HeLa cell Culture ), and in vivo experiment(rabbit lieal loop assay).RESULTS ID vitro and in vivo e-cP6riments withthe purified O--PS from Shigells flexnefi revealedthat the O--PS alone was toxic to Hela cells andcaused mucosal inflammation and hemorrhagicexudation in lieal loop of rabbit.DISCUSSION O--PS might b6 one of the factorscausing diarrhea and its mechanism wasdifferent from endotoxin reaction of LPS. Themolecular mechanism of O-PS need furtherstudies.

Mobility enhancement of strained GaSb p-channel metal-oxide-semiconductor field-effect transistors with biaxial compressive strain

Various biaxial compressive strained GaSb p-channel metal-oxide-semiconductor field-effect transistors （MOSFETs） are experimentally and theoretically investigated, The biaxial compressive strained GaSb MOSFETs show a high peak mobility of 638 cm2/V.s, which is 3.86 times of the extracted mobility of the fabricated GaSb MOSFETs without strain. Meanwhile, first principles calculations show that the hole effective mass of GaSb depends on the biaxial compressive strain. The biaxiai compressive strain brings a remarkable enhancement of the hole mobility caused by a significant reduction in the hole effective mass due to the modulation of the valence bands.

Acetic acid-assisted mild dealloying of fine CuPd nanoalloys achieving compressive strain toward high-efficiency oxygen reduction and ethanol oxidation electrocatalysis

Dealloying by which the transition metal is partially or completely leached from an alloy precursor is an effective way to optimize the fundamental effects for further enhancing the electrocatalysis of a catalyst.Herein,to address the deficiencies associated with the commonly used dealloying methods,for example,electrochemical and sulfuric acid/nitric acid treatment,we report an acetic acid-assisted mild strategy to dealloy Cu atoms from the outer surface layers of CuPd alloy nanoparticles to achieve high-efficiency electrocatalysis for oxygen reduction and ethanol oxidation in an alkaline electrolyte.The leaching of Cu atoms by acetic acid exerts an additional compressive strain effect on the surface layers and exposes more active Pd atoms,which is beneficial for boosting the catalytic performance of a dealloyed catalyst for the oxygen reduction reaction(ORR)and the ethanol oxidation reaction(EOR).In particular,for ORR,the CuPd nanoparticles with a Pd/Cu molar ratio of 2:1 after acetic dealloying show a half-wave potential of 0.912 V(vs.RHE)and a mass activity of 0.213 AmgPd^(-1) at 0.9 V,respectively,while for EOR,the same dealloyed sample has a mass activity and a specific activity of 8.4 Amg^(-1) and 8.23 mA cm^(-2),respectively,much better than their dealloyed counterparts at other temperatures and commercial Pd/C as well as a Pt/C catalyst.

Temperature effect on the structural strains of an ancient Tibetan building based on long-term monitoring data

Many studies have indicated that structural strain will be significantly influenced by temperature variations,and a good understanding of the effect of temperature on structural strain is essential.A structural health monitoring system has been installed in a typical Tibetan timber building to measure the structural strains and ambient temperature since 2012.This paper presents the correlation between temperature and strain data from the monitored structure.A method combining singular spectrum analysis and polynomial regression is proposed for modeling the temperature induced strains in the structure.Singular spectrum analysis is applied to smooth the temperature data,and the correlation between the resulting temperature time series and the measured strains is obtained by polynomial regression.Parameters of the singular spectrum analysis and the regression model are selected to have the least regression error.Results show that the proposed method has both good reproduction and prediction capabilities for temperature induced strains,and that the method is accurate and effective for eliminating the effect of temperature from the measured strain.A standardized Novelty Index based on the residual strain is also used for the condition assessment of the structure.

Surface effects on mechanical behavior of elastic nanoporous materials under high strain

This paper studies surface effects on the mechanical behavior of nanoporous materials under high strains with an improved anisotropic Kelvin model. The stress-strain relations are derived by the theories of Euler-Bernoulli beam and surface elasticity. Mean- while, the influence of strut （or ligament） size on the mechanical properties of nanoporous materials is discussed, which becomes a key factor with consideration of the residual sur- face stress and the surface elasticity. The results show that the decrease in the strut diameter and the increase in the residual surface stress or the surface elasticity can both lead to an increase in the carrying capacity of nanoporous materials. F^lrthermore, me- chanical behaviors of anisotropic nanoporous materials in different directions （the rise direction and the transverse direction） are investigated. The results indicate that the sur- face effects in the transverse direction are more obvious than those in the rise direction for anisotropic nanoporous materials. In addition, the present results can be reduced to the cases of conventional foams as the strut size increases to micron-scale, which confirms validity of the model to a certain extent.

EFFECTIVE STRESS AND STRAIN IN FINITE DEFORMATION

Whether the concept of effective stress and strain in elastic-plastic theory is still valid under the condition of finite deformation was mainly discussed. The uni-axial compression experiments in plane stress and plane strain states were chosen for study. In the two kinds of stress states, the stress-strain curve described by logarithm strain and rotated Kirchhoff stress matches the experiments data better than the curves defined by other stress-strain description.

Modeling Strain Rate Effect for Heterogeneous Brittle Materials

Rocks are heterogeneous from the point of microstructure which is of significance to their dynamic failure behavior. Both the compressive and tensile strength of rock-like materials is regarded different from the static strength. The present study adopts smoothed particle hydrodynamics (SPH) which is a virtual particle based meshfree method to investigate strain rate effect for heterogeneous brittle materials. The SPH method is capable of simulating rock fracture, free of the mesh constraint of the traditional FEM and FDM models. A pressure dependent J-H constitutive model involving heterogeneity is employed in the numerical modeling. The results show the compressive strength increases with the increase of strain rate as well as the tensile strength, which is important to the engineering design.

Effect of height of rock specimen on strain localization, precursor to failure and entire deformational characteristics

Patterns of shear band,precursors to shear failure occurring instrain-softening stage,axial,lateral and volumetric strains as well as Poisson's ratio ofplane strain rock specimens in compression for different heights were investigated byuse of Fast Lagrangian Analysis of Continua(FLAC).A material imperfection closer tothe lower-left comer of the specimen was prescribed.For finer mesh,the imperfectionwas modeled by four null elements,while it was modeled by a null element for coarsermesh.FISH functions were written to calculate the entire deformational characteristics ofthe specimen.In elastic stage,the adopted constitutive relation was linear elastic;instrain-softening stage,a composite Mohr-Coulomb criterion with tension cut-off and apost-peak linear constitutive relation were adopted.Height of rock specimen does not in-fluence shear band's pattern(including the thickness and inclination angle of shearband).The slopes of the post-peak stress-axial strain curve,stress-lateral strain curve,lateral strain-axial strain curve,Poisson's ratio-axial strain curve and volumetricstrain-axial strain curve depend on the height.Hence,the slopes of these curves cannotbe considered as material properties.Nonlinear deformation prior to the peak stress is akind of precursors to shear failure,which is less apparent for shorter specimen.For thesame axial strain,lower lateral expansion is reached for shorter specimen,leading tolower Poisson's ratio and higher volumetric strain.The maximum volumetric strain oflonger specimen is less than that of shorter specimen.The conclusions drawn from nu-merical results using finer mesh qualitatively agree with those using coarser mesh.

Numerical Derivation of Strain Rate Effects on Material Properties of Masonry with Solid Clay Bricks

In this paper, numerical method is used to study the strain rate effect on masonry materials. A typical unit of masonry is selected to serve as a representative volume element (RVE). Numerical model of RVE is established with detailed distinctive modeling of brick and mortar with their respective dynamic material properties obtained from laboratory tests. The behavior of brick and mortar are characterized by a dynamic damage model that accounts for rate-sensitive and pressuredependent properties of masonry materials. Dynamic loads of different loading rates are applied to RVE. The equivalent homogenized uniaxial compressive strength, threshold strain and elastic modulus in three directions of the masonry are derived from the simulated responses of the RVE. The strain rate effect on the masonry material with clay brick and mortar, such as the dynamic increase factor (DIF) of the ultimate strength and elastic modulus as a function of strain rate are derived from the numerical results.