Phase-field simulations of the effect of temperature and interface for zirconiumδ-hydrides

Hydride precipitation in zirconium cladding materials can damage their integrity and durability.Service temperature and material defects have a significant effect on the dynamic growth of hydrides.In this study,we have developed a phasefield model based on the assumption of elastic behaviour within a specific temperature range(613 K-653 K).This model allows us to study the influence of temperature and interfacial effects on the morphology,stress,and average growth rate of zirconium hydride.The results suggest that changes in temperature and interfacial energy influence the length-to-thickness ratio and average growth rate of the hydride morphology.The ultimate determinant of hydride orientation is the loss of interfacial coherency,primarily induced by interfacial dislocation defects and quantifiable by the mismatch degree q.An escalation in interfacial coherency loss leads to a transition of hydride growth from horizontal to vertical,accompanied by the onset of redirection behaviour.Interestingly,redirection occurs at a critical mismatch level,denoted as qc,and remains unaffected by variations in temperature and interfacial energy.However,this redirection leads to an increase in the maximum stress,which may influence the direction of hydride crack propagation.This research highlights the importance of interfacial coherency and provides valuable insights into the morphology and growth kinetics of hydrides in zirconium alloys.

Calculation of effective temperature for pavement rutting using numerical simulation methods

In order to predict the long-term rutting of asphalt pavement, the effective temperature for pavement rutting is calculated using the numerical simulation method. The transient temperature field of asphalt pavement was simulated based on actual meteorological data of Nanjing. 24-hour rutting development under a transient temperature field was calculated in each month. The rutting depth accumulated under the static temperature field was also estimated and the relationship between constant temperature parameters was analyzed. Then the effective temperature for pavement rutting was determined based on the rutting equivalence principle. The results show that the monthly effective temperature is above 40 t in July and August, while in June and September it ranges from 30 to 40 Rutting development can be ignored when the monthly effective temperature is less than 30 t. The yearly effective temperature for rutting in Nanjing is around 38. 5 t. The long-term rutting prediction model based on the effective temperature can reflect the influences of meteorological factors and traffic time distribution.

Kinetic Implication from Temperature Effect on Hydrogen Evolution Reaction at Ag Electrode

Hydrogen evolution reaction （HER） at polycrystalline silver electrode in 0.1 mol/L HClO4 solution is investigated by cyclic voltammetry in the temperature range of 278-333 K. We found that at electrode potential φa,app decreases with φ, while pre-exponential factor A remains nearly unchanged,which conforms well the prediction from Butler-Volmer equation. In contrast, with φ nega-tive shifts from the onset potential for HER to the potential of zero charge （PZC≈-0.4 V）, both Ea,app and A for HER increase （e.g., Ea,app increases from 24 kJ/mol to 32 kJ/mol）. The increase in Ea,app and A with negative shift in φ from -0.25 V to PZC is explained by the increases of both internal energy change and entropy change from reactants to the transition states, which is correlated with the change in the hydrogen bond network during HER. The positive entropy effects overcompensate the adverse effect from the increase in the activation energy, which leads to a net increase in HER current with the activation energy negative shift from the onset potential of HER to PZC. It is pointed out that entropy change may contribute greatly to the kinetics for electrode reaction which involves the transfer of electron and proton, such as HER.

Temperature Effect on Hydrogen Evolution Reaction at Au Electrode

The temperature dependence of hydrogen evolution reaction （HER） at a quasi-single crystalline gold electrode in both 0.1 mol/L HCl04 and 0.1 mol/L KOH solutions was investigated by cyclic voltammetry. HER current displays a clear increase with reaction overpotential （η） and temperature from 278-333 K. In 0.1 mol/L HClO4 the Tafel slopes are found to increases slightly with temperature from 118 mV/dec to 146 mV/dec, while in 0.1 mol/L KOH it is ca. 153±15 mV/dec without clear temperature-dependent trend. The apparent activation energy （Ea） for HER at equilibrium potential is ca. 48 and 34 kJ/mol in 0.1 mol/L HC104 and 0.1 mol/L KOH, respectively. In acid solution, Ea decreases with increase in η, from Ea-37 kJ/mol （η=0.2 V） to 30 kJ/mol （η=0.35 V）. In contrast, in 0.1 mol/L KOH, Ea does not show obvious change with U. The pre-exponential factor （A） in 0.1 mol/L HC104 is ca. 1 order higher than that in 0.1 mol/L KOH. Toward more negative potential, in 0.1 mol/L HC104 A changes little with potential, while in 0.1 mol/L KOH it displays a monotonic increase with U. The change trends of the potential-dependent kinetic parameters for HER at Au electrode in 0.1 mol/L HClO4 and that in 0.1 mol/L KOH are discussed.

Temperature effect on aerobic denitrification and nitrification

Nitrogen loss without organic removal in biofilter was observed and its possible reason was explained. A lower hydraulic loading could improve aerobic denitrification rate. Aerobic denitrification was seriously affected by low temperature(below 10℃). However, nitrification rate remained high when the temperature dropped from 15℃ to 5℃. It seemed the autotrophic biofilm in BAF could alleviate the adverse effect of low temperature.

Effects of temperatures on the development and reproduction of the armyworm, Mythimna roseilinea: Analysis using an age-stage, two-sex life table

The armyworm Mythimna roseilinea（Walker） is a major pest of grain crops in South China. So far little is known about its basic biology and ecology, making prediction of population dynamics difficult. This study examined the relationships of individual development and population growth with temperature based on an age-stage, two-sex life table of M. roseilinea reared on maize in the laboratory at 18, 21, 24, 27 and 30℃. The highest values of net reproductive rate（R_0） and fecundity were observed at 21 and 24℃, respectively. Both the intrinsic rate of increase（r） and finite rate of increase（λ） increased significantly and mean generation time（T） decreased significantly with increasing temperature. M. roseilinea was able to develop, survive and lay eggs at all temperature regimes tested. Development rates of the egg, larval, pupal, as well as the whole pre-oviposition stages had a positive linear relationship with temperature. The calculated development threshold temperatures of egg, larval, pupal, pre-oviposition and total pre-oviposition stages were 13.29, 8.39, 14.35, 7.42, and 12.24℃, respectively, and their effective accumulated temperatures were 63.59, 445.00, 211.11, 89.02, and 698.95 degree-days, respectively. These results provide insight into temperature-based phenology and population ecology of this insect pest and will allow population prediction and management available in the field.

Effect of Temperature on Gas Hold-up in Aerated Stirred Tanks

Gas holdups in ambient gassed and hot sparged systems with multiple modern impellers and the effect of temperature on gas holdup are reported. The operating temperature has a great impact on gas holdup though the gas dispersion regime in the hot sparged system is similar to the ambient gassed condition. The gas holdup under the elevated temperature and the ambient gassed operation is successfully correlated. With the same total gas flow rate and power input, the gas holdup in the hot sparged system (say near the boiling point) is only about half of that in the ambient system. The results imply that almost all existing hot sparged reactors have been designed on the basis of incorrect estimates of the gas holdup during operation.

Extending a release-and-recapture scheme to single atom optical tweezer for effective temperature evaluation

By recording the fluorescence fraction of the cold atoms remaining in the magneto-optical trap （MOT） as a function of the release time, the release-and-recapture （R＆R） method is utilized to evaluate the effective temperature of the cold atomic ensemble. We prepare a single atom in a large-magnetic-gradient MOT and then transfer the trapped single atom into a 1064-nm microscopic optical tweezer. The energy of the single atom trapped in the tweezer is further reduced by polarization gradient cooling （PGC） and the effective temperature is evaluated by extending the R-R technique to a single atom tweezer. The typical effective temperature of a single atom in the tweezer is improved from about 105 μK to about 17 μK by applying the optimum PGC phase.

Effective accumulated temperature and developmental threshold temperature for Semanotus bifasciatus(Motschulsky) in Beijing

In order to understand the occurrence and development of Semanotus bifasciatus （Motschulsky）, a borer insect of Platycladus orientalis in parts of northern and eastern China and to improve its prediction, the developmental threshold temperature （C1） and effective accumulated temperature （K） of S. bifasciatus were determined under conditions of constant and variable temperatures. The results show that under constant temperatures the value of C1 has a range of 8.90±1.77℃and the value of K lies between 95.19±13.14 degree-day for eggs; the values for larvae are C1= 13.26±3.06℃ and the number of degree-day is K 2,885.07±187.87 degree-day; for pupae the ranges are C1 = 8.93±2.49℃ and K= 131.20±25.63 degree-day. Under the condition of ambient temperatures, the values for eggs are C1= 17.33±1.24℃ and K= 70.79±8.99 degree-day. It is suggested that S. bifasciatus adults over-winter in a state of dormancy, not at a diapause. Warm winter may accelerate the life cycle ofS. bifasciatus. Equations can be used to predict an early occurrence ofS. bifasciatus.

Temperature effect on the structural strains of an ancient Tibetan building based on long-term monitoring data

Many studies have indicated that structural strain will be significantly influenced by temperature variations,and a good understanding of the effect of temperature on structural strain is essential.A structural health monitoring system has been installed in a typical Tibetan timber building to measure the structural strains and ambient temperature since 2012.This paper presents the correlation between temperature and strain data from the monitored structure.A method combining singular spectrum analysis and polynomial regression is proposed for modeling the temperature induced strains in the structure.Singular spectrum analysis is applied to smooth the temperature data,and the correlation between the resulting temperature time series and the measured strains is obtained by polynomial regression.Parameters of the singular spectrum analysis and the regression model are selected to have the least regression error.Results show that the proposed method has both good reproduction and prediction capabilities for temperature induced strains,and that the method is accurate and effective for eliminating the effect of temperature from the measured strain.A standardized Novelty Index based on the residual strain is also used for the condition assessment of the structure.

Assessment of the effects of the shelterbelt on the soil temperature at regional scale based on MODIS data

At present, the most researches on the protected effect of shelterbelt are on the basis of the two scales of forest belts and networks. However, with the further research on the global environmental change, more attention was paid to the regional climate effect of shelterbelt. In present study, we analyzed the temperature effect of the shelterbelt at regional scale by using the land surface temperature （LST） data from the moderate resolution imaging spectroradiometer （MODIS） at Yushu, Nong＇an, Dehui, and Fuyu in Jilin Province of China from March to October in 2008. Results show that the shelterbelt can increase the soil temperature of the protected farmland as compared with no shelterbelt zone, with the increment of 0.57oC per day in fine shelterbelt and 0.38oC per day in the normal shelterbelt. Moreover, the correlation analysis of the air temperature, precipitation and the soil type and the shelterbelt effect shows that the air temperature and precipitation are negatively correlated with the shelterbelt effects, that is, the more the temperature and precipitation are, the less the effect produced. While the impact of the soil types on the shelterbelt＇s effect is not very obvious as a whole. This paper draws significance in terms of analyzing the effects of the shelterbelt on the soil temperature at regional scale utilizing the remotely sensed data and GIS technique.

Effective(kinetic freeze-out) temperature, transverse flow velocity, and kinetic freeze-out volume in high energy collisions

The transverse momentum spectra of different types of particles produced in central and peripheral gold–gold(Au–Au)and inelastic proton–proton(pp)collisions at the Relativistic Heavy Ion Collider,as well as in central and peripheral lead-lead(Pb–Pb)and pp collisions at the Large Hadron Collider,are analyzed by the multi-component standard(Boltzmann–Gibbs,Fermi–Dirac,and Bose–Einstein)distributions.The obtained results from the standard distribution give an approximate agreement with the measured experimental data by the STAR,PHENIX,and ALICE Collaborations.The behavior of the effective(kinetic freeze-out)temperature,transverse flow velocity,and kinetic freeze-out volume for particles with different masses is obtained,which observes the early kinetic freezeout of heavier particles as compared to the lighter particles.The parameters of emissions of different particles are observed to be different,which reveals a direct signature of the mass-dependent differential kinetic freeze-out.It is also observed that the peripheral nucleus–nucleus(AA)and pp collisions at the same center-of-mass energy per nucleon pair are in good agreement in terms of the extracted parameters.

Effects of Temperature and Drying and Wetting Alternation on Ammonium Fixation in Manured Loessial Soil

Effects of temperature and drying and wetting alternation(DWA)on ammonium fixation in manured loessial soil were studied by means of Batch Equilibrium with Varying concentration solutions of ammonium chloride,ammonium fixation time,and soil clay contents.The purpose of the research was to find out the pattern of ammonium fixation ted by the varying factors.The results showed a remarkable variation in ammonium fixation.Fixed ammonium increased with temperature and treatments of DWA.The ammonium fixation in manured loessial soil was characterized by the effect of temperature and DWA.

Temperature Effects of Parabolic Linear Bound Potential and Coulomb Bound Potential Quantum Dot Qubit

On the condition of electric-LO phonon strong coupling in a parabolic quantum dot,we obtain theeigenenergy and the eigenfunctions of the ground state and the first-excited state using the variational method ofPekar type.This system in a quantum dot may be employed as a two-level quantum system-qubit.When the electronis in the superposition state of the ground state and the first-excited state,we obtain the time evolution of the electrondensity.The relations of the probability density of electron on the temperature and the electron-LO-phonon couplingconstant and the relations of the period of oscillation on the temperature,the electron-LO-phonon coupling constant,the Coulomb binding parameter and the confinement length are derived.The results show that the probability densityof electron oscillates with a period when the electron is in the superposition state of the ground and the first-excitedstate,and show that there are different laws that the probability density of electron and the period of oscillation changewith the temperature and the electron-LO-phonon coupling constant when the temperature is lower or higher.Andit is obtained that the period of oscillation decreases with increasing the Coulomb bound potential and increases withincreasing the confinement length not only at lower temperatures but also at higher temperatures.

Amount and temperature effects responsible for precipitation isotope variation in the southern slope of Himalayas

Seasonal variation of stable isotopes in precipitation of Kathmandu Valley on the southem slope of Himalaya was carried out to understand the controlling mechanism of amount and temperature effect on the basis of one year stable isotope data from 2010 to 2011. Highly depleted isotope values in major rainy period are obtained just after the onset of precipitation in summer, which ac- counts for ＂amount effect＂ due to saturation isotopic compositions in high moisture condition, whereas, the higher values in winter are indicative to regional vapors （temperature effect） recycling of various sources. An abrupt depletion of isotope values in mid- June, indicates the onset date of monsoon precipitation, by the replacement of winter air mass with southem monsoon. Thus, pre- cipitation isotopes are a tool revealing the onset date of summer monsoon and temporal features of variability, in local and regional monsoons precipitations. A comparison of long term monthly values of 5180, temperature, and precipitation with GNIP 6180 data shows the temporal variations of stable isotopes are mostly controlled by amount and temperature effects. During summer mon- soon, the amount effects are stronger for high values of precipitation （R=0.7） and altitude effect appears for low moisture in late rainy season, thus from December to June （winter to pre-monsoon） the controlling features of isotopes remains under the temper- ature effect. A temporal rate of temperature effect is derived as 0.04%0 per year which indicates a dry signal of atmospheric condition and a temperature relation 5180=（0.371±0.08）T＋（0.156±0.05） is obtained from this analysis. The meteoric water lines of Kathmandu before and after monsoon onset of 2011, are found as 5D=（4.36±0.3）5180＋（15.66±1.2） and 5D=（6.91±0.2）S180-（7.92±2.26） from lab samples result, and 5D=9.25180＋11.725 and 5D=8.535180＋16.65 from GNIP data, which lacks the consistency both for slopes and intercepts values for the study period. The mean lapse rate values of δ18O and δD from GNIP data are obtained as -0.002‰/m and -0.015 ‰/m, which indicate the altitudinal effects in regional precipitation of the southern slope of Himalayas. This study estimates new stable isotopes data in recent precipitation using simple methodology which can be important for regional precipitation monitoring systems, environmental change and paleo-climatic studies.

Effects of effective stress and temperature on permeability of sandstone from CO2-plume geothermal reservoir

Rock is generally complex and heterogeneous,therefore the heterogeneity effects of effective stress and temperature on permeability should be taken into account.In this study,two-part Hooke’s model（TPHM） is introduced to understand the influences of effective stress and temperature on permeability of soft and hard parts（two parts） of rock based on coupling thermo-hydro-mechanical tests.Under a fixed temperature level（25 ℃.35 ℃.50 ℃.65 ℃.80 ℃.90 ℃ and 95 ℃）.the tests were carried out in a conventional triaxial system whereas the confining pressure was remained at 50 MPa.and the pore pressure was increased to the specified levels step by step.i.e.8 MPa,18 MPa.28 MPa.38 MPa.41 MPa,44 MPa.46 MPa and 48 MPa.The temperature-dependent relationships for two parts permeabilities are proposed on the basis of the initial test results.We point out that temperature of 65 ℃-90 ℃ is the threshold for the development of CO2-plume geothermal（CPC） reservoir sandstone cracking under low effective stress（2-9 MPa） based on the relationship between temperature and soft part permeability.Furthermore,we discuss the effect of temperature on the two parts in the rock.The results indicate that as the temperature increases from 25 ℃ to 65 ℃.the flow channel in the hard part has a stronger response to temperature than that in the soft part at a fixed effective stress level,which is opposite to the situation of effective stress.Considering that natural rock is generally heterogeneous with non-uniform pore structure,we suggest a physical interpretation of the phenomenon that before the thermal cracking threshold the two parts have different responses to temperature.

Utilizing a new soil effective temperature scheme and archived satellite microwave brightness temperature data to estimate surface soil moisture in the Nagqu region, Tibetan Plateau of China

Since the early 2000s, many satellite passive microwave brightness temperature （BT） archives, such as the Advanced Microwave Scanning Radiometer for the Earth Observing System （AMSR-E） BTs, have become the useful resources for assessing the changes in the surface and deep soil moistures over both arid and semi-arid regions. In this study, we used a new soil effective temperature （T scheme and the archived AMSR-E BTs to estimate surface soil moisture （SM） over the Nagqu region in the central Tibetan Plateau, China. The surface and deep soil temperatures required for the calculation of regional-scale T were obtained from outputs of the Community Land Model version 4.5 （CLM4.5）. In situ SM measurements at the CEOP-CAMP/Tibet （Coordinated Enhanced Observing Period Asia-Australia Monsoon Project on the Tibetan Plateau） experimental sites were used to validate the AMSR-E-based SM estimations at regional and single-site scales. Furthermore, the spatial distribution of monthly mean surface SM over the Nagqu region was obtained from 16 daytime AMSR-E BT observations in July 2004 over the Nagqu region. Results revealed that the AMSR-E-based surface SM estimations agreed well with the in situ-based surface SM measurements, with the root mean square error （RMSE） ranging from 0.042 to 0.066 m3/m3 and the coefficient of determination （R2） ranging from 0.71 to 0.92 during the nighttime and daytime. The regional surface soil water state map showed a clear spatial pattern related to the terrain. It indicated that the lower surface SM values occurred in the mountainous areas of the northern, mid-western and southeastern parts of Nagqu region, while the higher surface SM values appeared in the low elevation areas such as the Tongtian River Basin, Namco Lake and bog meadows in the central part of Nagqu region. Our analysis also showed that the new T^scheme does not require special fitting parameters or additional assumptions, which simplifies the data requirements for regional-scale applications. This scheme combined with the archived satellite passive microwave BT observations can be used to estimate the historical surface SM for hydrological process studies over the Tibetan Plateau regions.

Effect of Sintering Temperature and Zinc Content on Some Properties of Li-Zn Ferrites

Li-Zn mixed ferrites with composition formula ZnxLi0.5-x/2Fe2.5-x/2O4 (0.2≤x≤0.8) were prepared by the usual ceramic method in 1000~1150℃. The effects of Zn substitution and sintering temperature on the formation, densification, microstructure and a.c. electrical conductivity have been studied. Under the effect of changing the firing temperature and Zn content, high sintered Li-Zn ferrite bodies are achieved. More fine structure bodies having high electrical resistance are obtained at high Zn content

Effect of the particle temperature on lift force of nanoparticle in a shear rarefied flow

The nanoparticles suspended in a shear flow are subjected to a shear lift force,which is of great importance for the nanoparticle transport.In previous theoretical analysis on the shear lift,it is usually assumed that the particle temperature is equal to the temperature of the surrounding gas media.However,in some particular applications,the particle temperature can significantly differ from the gas temperature.In the present study,the effect of particle temperature on the shear lift of nanoparticles is investigated and the corresponding formulas of shear lift force are derived based on the gas kinetic theory.For extremely small nanoparticles(with radius R<2 nm)or large nanoparticles(R>20 nm),the influence of the particle temperature can be neglected.For the intermediate particle size,the relative error induced by the equal gas–particle temperature can be significant.Our findings can bring an insight into accurate evaluation of the nanoparticle transport properties.

Effects of Temperature and Strain Rate on Dynamic Properties of Concrete

To study the dynamic properties of the concrete subjected to impulsive loading, stress-time curves of concrete in different velocities were measured using split Hopkinson pressure bar (SHPB).Effects of temperature and strain rate on the dynamic yield strength and constitutive relation of the con-crete were analyzed. The dynamic mechanical properties of the reinforced concrete are subjected to high strain rates when it is at a relatively low temperature. But with temperature increasing, the temperature softening effect makes the strength of the concrete weaken and the impact toughness of the concrete is saliently relative to strain rate effect. So, strain rate effect, strain hardening and temperature softening work together on the dynamic mechanical capability of concrete and the relation between them is relatively complex.