The mechanism of ionization and fragmentation for terphenyl (diphenylbenzene) with three structural ring isomers (ortho-, meta- and para-), and stilbene (1,2-diphenylethylene) with two geometrical isomers (trans- and ...The mechanism of ionization and fragmentation for terphenyl (diphenylbenzene) with three structural ring isomers (ortho-, meta- and para-), and stilbene (1,2-diphenylethylene) with two geometrical isomers (trans- and cis-) by EI mass spectrometry and ionization efficiency curves are investigation.展开更多
The allyl radical has been observed in a low-pressure premixed gasoline/oxygen/argon flame by using tunable vacuum ultraviolet photoionization mass spectrometry, The ionization potential of the allyl radical is derive...The allyl radical has been observed in a low-pressure premixed gasoline/oxygen/argon flame by using tunable vacuum ultraviolet photoionization mass spectrometry, The ionization potential of the allyl radical is derived to be （8.13 ±0.02） eV from photoionization efficiency curve, In addition, a high level ab initzo Gaussian-3 （G3） method was used to calculate the energies of tile radical and its cation. The calculated adiabatic ionization potential is 8.18 eV, which is in excellent agreement with the experimental value. The result is helpful for identifying the allyl radical formed from other flames and for understanding the mechanism of soot formation.展开更多
This paper derives alternative analytical expressions for classifier product distributions in terms of Gauss hypergeometric function, 2F1, by considering feed distribution defined in terms of Gates-Gaudin-Schumann fun...This paper derives alternative analytical expressions for classifier product distributions in terms of Gauss hypergeometric function, 2F1, by considering feed distribution defined in terms of Gates-Gaudin-Schumann function and efficiency curve defined in terms of a logistic function. It is shown that classifier distributions under dispersed conditions of classification pivot at a common size and the distributions are difference similar. The paper also addresses an inverse problem of classifier distributions wherein the feed distribution and efficiency curve are identified from the measured product distributions without needing to know the solid flow split of particles to any of the product streams.展开更多
文摘The mechanism of ionization and fragmentation for terphenyl (diphenylbenzene) with three structural ring isomers (ortho-, meta- and para-), and stilbene (1,2-diphenylethylene) with two geometrical isomers (trans- and cis-) by EI mass spectrometry and ionization efficiency curves are investigation.
基金This work Was supported by the Knowledge Innovation funding of CAS and the Natural Science Foundation of China（NSFC No.20473081）.
文摘The allyl radical has been observed in a low-pressure premixed gasoline/oxygen/argon flame by using tunable vacuum ultraviolet photoionization mass spectrometry, The ionization potential of the allyl radical is derived to be （8.13 ±0.02） eV from photoionization efficiency curve, In addition, a high level ab initzo Gaussian-3 （G3） method was used to calculate the energies of tile radical and its cation. The calculated adiabatic ionization potential is 8.18 eV, which is in excellent agreement with the experimental value. The result is helpful for identifying the allyl radical formed from other flames and for understanding the mechanism of soot formation.
文摘This paper derives alternative analytical expressions for classifier product distributions in terms of Gauss hypergeometric function, 2F1, by considering feed distribution defined in terms of Gates-Gaudin-Schumann function and efficiency curve defined in terms of a logistic function. It is shown that classifier distributions under dispersed conditions of classification pivot at a common size and the distributions are difference similar. The paper also addresses an inverse problem of classifier distributions wherein the feed distribution and efficiency curve are identified from the measured product distributions without needing to know the solid flow split of particles to any of the product streams.
