A partition model of interference efficiency was constructed to study the coupling interference effect under combined internal and external flow.The concept of“internal flow efficiency”,“velocity ratio”and“interf...A partition model of interference efficiency was constructed to study the coupling interference effect under combined internal and external flow.The concept of“internal flow efficiency”,“velocity ratio”and“interference efficiency”were introduced to quantify the effect of internal flow and interference,and reveal the coupling mechanism among internal flow,external flow and interference effect.The results showed that the dynamic response of risers under variable angles was significantly different after considering the effect of internal flow.When the external flow velocity was smaller than 0.25 m/s,the vibration of risers was promoted by the internal flow.With the increase of external flow velocity,the effect of internal flow was weakened and the dynamic response of riser mainly depended on the external flow and interference effect.Under the effect of different internal flow,the interference efficiency had similar change trend.The interference effect amplified the complex secondary flow effect inside the riser,making the dynamic response of riser complex and random.In this paper,the overlap area and subdivision criterion of interference effect were constructed within the range of experimental velocity ratio,and the change curve of interference efficiency was obtained with an average meaning,which may have important practical meaning.展开更多
Peroxyacetyl nitrate (PAN) is an important indicator of photochemical smog and has adverse effects on human health and vegetation growth. A rapid and h!ghly selective technique of thermal dissociation chemical ioniz...Peroxyacetyl nitrate (PAN) is an important indicator of photochemical smog and has adverse effects on human health and vegetation growth. A rapid and h!ghly selective technique of thermal dissociation chemical ionization mass spectrometry (TD-CIMS) was recently developed to measure the abundance of PAN in real time; however, it may be subject to artifact in the presence of nitric oxide (NO). In this study, we tested the interference of the PAN signal induced by NO, evaluated the performance of TD- CIMS in an urban environment, and investigated the concentration and formation of PAN in urban Hong Kong. NO caused a significant underestimation of the PAN signal in TD-CIMS, with the underestimation increasing sharply with NO concentration and decreasing slightly with PAN abundance. A formula was derived to link the loss of PAN signal with the concentrations of NO and PAN, which can be used for data correction in PAN measurements. The corrected PAN data from TD- CIMS were consistent with those from the commonly used gas chromatography with electron capture detection, which confirms the utility of TD-CIMS in an urban environment in which NO is abundant. In autumn of 2010, the hourly average PAN mixing ratio varied from 0.06 ppbv to 5.17 ppbv, indicating the occurrence of photochemical pollution in urban Hong Kong. The tbrmation efficiency of PAN during pollution episodes was as high as 3.9 to 5.9 ppbv per 100 ppbv ozone. The efficiency showed a near-linear increase with NO, concentration, suggesting a control policy of NO,. reduction for PAN pollution.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51709161 and U2006226)the Key Technology Research and Development Program of Shandong Province(Grant No.2019GHY112061)+1 种基金the Natural Science Foundation of Shandong Province(Grant No.ZR2022QE118)the Youth Talent Introduction and Cultivation Program of College in Shandong Province。
文摘A partition model of interference efficiency was constructed to study the coupling interference effect under combined internal and external flow.The concept of“internal flow efficiency”,“velocity ratio”and“interference efficiency”were introduced to quantify the effect of internal flow and interference,and reveal the coupling mechanism among internal flow,external flow and interference effect.The results showed that the dynamic response of risers under variable angles was significantly different after considering the effect of internal flow.When the external flow velocity was smaller than 0.25 m/s,the vibration of risers was promoted by the internal flow.With the increase of external flow velocity,the effect of internal flow was weakened and the dynamic response of riser mainly depended on the external flow and interference effect.Under the effect of different internal flow,the interference efficiency had similar change trend.The interference effect amplified the complex secondary flow effect inside the riser,making the dynamic response of riser complex and random.In this paper,the overlap area and subdivision criterion of interference effect were constructed within the range of experimental velocity ratio,and the change curve of interference efficiency was obtained with an average meaning,which may have important practical meaning.
基金This work was supported by the Environment and Conservation Fund of Hung Kong (Project No. 2009-07), National Natural Science Foundation of China (Grant Nos. 41275123, 21407094 and 91544213), China Postdoctoral Science Foundation (No. 2014M561932), and the Jiangsu Collaborative Innovation Center for Climate Change. The authors thank Dr. Pamela Holt for proofreading the manuscript.
文摘Peroxyacetyl nitrate (PAN) is an important indicator of photochemical smog and has adverse effects on human health and vegetation growth. A rapid and h!ghly selective technique of thermal dissociation chemical ionization mass spectrometry (TD-CIMS) was recently developed to measure the abundance of PAN in real time; however, it may be subject to artifact in the presence of nitric oxide (NO). In this study, we tested the interference of the PAN signal induced by NO, evaluated the performance of TD- CIMS in an urban environment, and investigated the concentration and formation of PAN in urban Hong Kong. NO caused a significant underestimation of the PAN signal in TD-CIMS, with the underestimation increasing sharply with NO concentration and decreasing slightly with PAN abundance. A formula was derived to link the loss of PAN signal with the concentrations of NO and PAN, which can be used for data correction in PAN measurements. The corrected PAN data from TD- CIMS were consistent with those from the commonly used gas chromatography with electron capture detection, which confirms the utility of TD-CIMS in an urban environment in which NO is abundant. In autumn of 2010, the hourly average PAN mixing ratio varied from 0.06 ppbv to 5.17 ppbv, indicating the occurrence of photochemical pollution in urban Hong Kong. The tbrmation efficiency of PAN during pollution episodes was as high as 3.9 to 5.9 ppbv per 100 ppbv ozone. The efficiency showed a near-linear increase with NO, concentration, suggesting a control policy of NO,. reduction for PAN pollution.