A triboelectric nanogenerator （TENG） with an organic nanocomposite electret thin film as the triboelectric layer for mechanical energy harvesting was investigated systematically. In combination with corona charging,...A triboelectric nanogenerator （TENG） with an organic nanocomposite electret thin film as the triboelectric layer for mechanical energy harvesting was investigated systematically. In combination with corona charging, a TENG was fabricated by using embedded-nanocapacitor-structure polytetrafluoroethylene （PTFE） impregnated with gold nanoparticles （Au-NPs）. The output performances, stability, and durability of the TENGs with Au-PTFE nanocomposite films were characterized after being washed in water. It was found that the output current increases by 70% and the equivalent surface charge density （ESCD） reaches 85 μC/m^2 in comparison to the virgin PTFE film. Such outstanding performance is likely due to the equivalent nanocapacitors between the Au-NPs and PTFE molecules, which serve as nano charge traps in the nanocomposite electret film under negative high-voltage corona charging. This work not only expands the practical applications of TENGs, but also opens up new possibilities for the development of high performance triboelectric materials.展开更多
A triboelectric nanogenerator （TENG） is a simple and cost effective device that converts ambient mechanical energy into electricity based on the surface contact electrification of thin films. The limited surface cha...A triboelectric nanogenerator （TENG） is a simple and cost effective device that converts ambient mechanical energy into electricity based on the surface contact electrification of thin films. The limited surface charge density may affect the overall performance of the TENG. In this paper, a novel electret film based TENG （E-TENG） fabricated by corona charging is proposed that greatly enhances the effective surface charge density of the thin films as compared to those subjected to contact electrification. The short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENG have been investigated, using different corona charging voltages, pinpoint distances and times in order to explore the optimum experimental conditions. The short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENG are found to be about seven times larger than those of the ordinary polytetrafluoroethylene （PTFE） film based TENG. Based on corona charging, several multilayered E-TENGs have been fabricated, and the short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENGs with different number of layers are studied for achieving optimal performances. This work offers an effective approach for improving the effective surface charge density and thereby increasing the output capability of the TENG, which would greatly promote TENG applications in self-powered portable electronics and sensor networks.展开更多
The effect of heating treatment on the trap level distribution in polyamide 66 film electret is studied by thermally stimulated depolarization current （TSDC） technique. For annealed polyamide 66, there are three tra...The effect of heating treatment on the trap level distribution in polyamide 66 film electret is studied by thermally stimulated depolarization current （TSDC） technique. For annealed polyamide 66, there are three trap levels that respectively originate from space charge trapped in amorphous phase, interphase and crystalline phase. There is one peak that originates from space charge trapped in amorphous phase for quenched one. Using multi-point method to fit the experimental curves, the detrapping current peaks can be separated and the trap depth is obtained. The shallower trap levels trapped in amorphous phase and interphase are obviously close to the deeper trap level trapped in crystalline phase for annealed polyamide 66 as the polarization temperature increases, while the trap level distribution remains unaffected by polarization temperature for quenched one.展开更多
文摘A triboelectric nanogenerator （TENG） with an organic nanocomposite electret thin film as the triboelectric layer for mechanical energy harvesting was investigated systematically. In combination with corona charging, a TENG was fabricated by using embedded-nanocapacitor-structure polytetrafluoroethylene （PTFE） impregnated with gold nanoparticles （Au-NPs）. The output performances, stability, and durability of the TENGs with Au-PTFE nanocomposite films were characterized after being washed in water. It was found that the output current increases by 70% and the equivalent surface charge density （ESCD） reaches 85 μC/m^2 in comparison to the virgin PTFE film. Such outstanding performance is likely due to the equivalent nanocapacitors between the Au-NPs and PTFE molecules, which serve as nano charge traps in the nanocomposite electret film under negative high-voltage corona charging. This work not only expands the practical applications of TENGs, but also opens up new possibilities for the development of high performance triboelectric materials.
基金Acknowledgements The project is supported by National Natural Science Foundation of China （Nos. 51475099 and 51432005）,Beijing Natural Science Foundation （No. 4163077）, the ＂thousands talents＂ program for the pioneer researcher and his innovation team, China, and the Youth Innovation Promotion Association, CAS.
文摘A triboelectric nanogenerator （TENG） is a simple and cost effective device that converts ambient mechanical energy into electricity based on the surface contact electrification of thin films. The limited surface charge density may affect the overall performance of the TENG. In this paper, a novel electret film based TENG （E-TENG） fabricated by corona charging is proposed that greatly enhances the effective surface charge density of the thin films as compared to those subjected to contact electrification. The short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENG have been investigated, using different corona charging voltages, pinpoint distances and times in order to explore the optimum experimental conditions. The short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENG are found to be about seven times larger than those of the ordinary polytetrafluoroethylene （PTFE） film based TENG. Based on corona charging, several multilayered E-TENGs have been fabricated, and the short-circuit current, transferred electric charge density, and open-circuit voltage of the E-TENGs with different number of layers are studied for achieving optimal performances. This work offers an effective approach for improving the effective surface charge density and thereby increasing the output capability of the TENG, which would greatly promote TENG applications in self-powered portable electronics and sensor networks.
基金Project supported by the National Natural Science Foundation of China(Grant No.20974108)the Natural Science Foundation of Anhui Province,China(Grant No.1308085QB40)the Fundamental Research Funds for the Central Universities of Ministry of Education of China(Grant Nos.2013HGQC0016 and 2011HGBZ1323)
文摘The effect of heating treatment on the trap level distribution in polyamide 66 film electret is studied by thermally stimulated depolarization current （TSDC） technique. For annealed polyamide 66, there are three trap levels that respectively originate from space charge trapped in amorphous phase, interphase and crystalline phase. There is one peak that originates from space charge trapped in amorphous phase for quenched one. Using multi-point method to fit the experimental curves, the detrapping current peaks can be separated and the trap depth is obtained. The shallower trap levels trapped in amorphous phase and interphase are obviously close to the deeper trap level trapped in crystalline phase for annealed polyamide 66 as the polarization temperature increases, while the trap level distribution remains unaffected by polarization temperature for quenched one.
