For a distributed drive electric vehicle(DDEV) driven by four in-wheel motors, advanced vehicle dynamic control methods can be realized easily because motors can be controlled independently, quickly and precisely. A...For a distributed drive electric vehicle(DDEV) driven by four in-wheel motors, advanced vehicle dynamic control methods can be realized easily because motors can be controlled independently, quickly and precisely. And direct yaw-moment control(DYC) has been widely studied and applied to vehicle stability control. Good vehicle handling performance: quick yaw rate transient response, small overshoot, high steady yaw rate gain, etc, is required by drivers under normal conditions, which is less concerned, however. Based on the hierarchical control methodology, a novel control system using direct yaw moment control for improving handling performance of a distributed drive electric vehicle especially under normal driving conditions has been proposed. The upper-loop control system consists of two parts: a state feedback controller, which aims to realize the ideal transient response of yaw rate, with a vehicle sideslip angle observer; and a steering wheel angle feedforward controller designed to achieve a desired yaw rate steady gain. Under the restriction of the effect of poles and zeros in the closed-loop transfer function on the system response and the capacity of in-wheel motors, the integrated time and absolute error(ITAE) function is utilized as the cost function in the optimal control to calculate the ideal eigen frequency and damper coefficient of the system and obtain optimal feedback matrix and feedforward matrix. Simulations and experiments with a DDEV under multiple maneuvers are carried out and show the effectiveness of the proposed method: yaw rate rising time is reduced, steady yaw rate gain is increased, vehicle steering characteristic is close to neutral steer and drivers burdens are also reduced. The control system improves vehicle handling performance under normal conditions in both transient and steady response. State feedback control instead of model following control is introduced in the control system so that the sense of control intervention to drivers is relieved.展开更多
An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is foun...An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is found using the highly accurate, multi-reference averaged coupled-pair functional(ACPF) approach with the basis set, aug-cc-p V6 Z, and a finite-field with ±0.005 a.u.(The unit a.u. is the abbreviation of atomic unit). This ab initio EDMF is very consistent with the fitted ones. The vibrational transition matrix moments and the Herman–Wallis factors, calculated with the Rydberg–Klein–Rees(RKR) potential and the fitted and ab initio EDMFs, are compared with experimental measurements. The consistency of these line intensities with the high-resolution transmission(HITRAN) molecular database demonstrates the improved accuracy of the fitted and ab initio EDMFs derived in this work.展开更多
Recently, the diverse properties of Rydberg atoms, which probably arise from its large electric dipole moment (EDM), have been explored. In this paper, we report electric dipole moments along with Stark energies and...Recently, the diverse properties of Rydberg atoms, which probably arise from its large electric dipole moment (EDM), have been explored. In this paper, we report electric dipole moments along with Stark energies and charge densities of lithium Rydberg states in the presence of electric fields, calculated by matrix diagonalization. Huge electric dipole moments are discovered. In order to check the validity of the EDMs, we also use these electric dipole moments to calculate the Stark energies by numerical integration. The results agree with those calculated by matrix diagonalization.展开更多
Higher electric multipole moments for the ground-state electronic configuration of some polyatomicmolecules, i.e. CH4, NH3, H2O, were calculated from SCF-HFR wavefunctions using Slater-type orbital basis sets.The calc...Higher electric multipole moments for the ground-state electronic configuration of some polyatomicmolecules, i.e. CH4, NH3, H2O, were calculated from SCF-HFR wavefunctions using Slater-type orbital basis sets.The calculated results for electric multipole moments of these molecules are in good agreement with the theoretical andexperimental ones.展开更多
Electric quadrupole moments of low-lying excited states of Yb^+are calculated by relativistic coupled-cluster theory with perturbations from external fields.The field-dependent energy differentiation provides accurate...Electric quadrupole moments of low-lying excited states of Yb^+are calculated by relativistic coupled-cluster theory with perturbations from external fields.The field-dependent energy differentiation provides accurate values of the electric quadrupole moments of^2P3/2,^2D3/2,5/2,and^2F5/2,7/2 states which agree well with experimental values.The important role of the electronic correlation to the electric quadrupole moments is investigated.Our calculations indicate the early dispute of the electric quadrupole moment of the Yb^+(2F7/2)state for which the measured and theoretical values have a large discrepancy.These electric quadrupole moment values can help us to determine the electric quadrupole shifts in start-of-the-art experiments of the Yb+ion.展开更多
We show that it is possible to simulate an anyon by a trapped atom which possesses an induced electric dipole moment in the background of electric and magnetic fields in a specific configuration.The electric and magne...We show that it is possible to simulate an anyon by a trapped atom which possesses an induced electric dipole moment in the background of electric and magnetic fields in a specific configuration.The electric and magnetic fields we applied contain a magnetic and two electric fields.We find that when the atom is cooled down to the limit of the negligibly small kinetic energy,the atom behaves like an anyon because its angular momentum takes fractional values.The fractional part of the angular momentum is determined by both the magnetic and one of the electric fields.Roles electric and magnetic fields played are analyzed.展开更多
Highly charged nickel ions have been suggested as candidates for the ultra-precise optical clock, meanwhile the relevant experiment has been carried out. In the framework of the multiconfiguration Dirac–Hartree–Fock...Highly charged nickel ions have been suggested as candidates for the ultra-precise optical clock, meanwhile the relevant experiment has been carried out. In the framework of the multiconfiguration Dirac–Hartree–Fock(MCDHF)method, we calculated the hyperfine interaction constants, the Landég-factors, and the electric quadrupole moments for the low-lying states in the 61Ni11+,61Ni12+,61Ni14+, and61Ni15+ ions. These states are clock states of the selected clock transitions in highly charged nickel ions(see Fig. 1). Based on discussing the effects of the electron correlations, the Breit interaction, and quantum electrodynamics(QED) effect on these physical quantities, reasonable uncertainties were obtained for our calculated results. In addition, the electric quadrupole frequency shifts and the Zeeman frequency shifts of the clock transitions concerned were analyzed.展开更多
The single-particle Schrödinger fluid model is designed mainly to calculate the moments of inertia of the axially symmetric deformed nuclei by assuming that each nucleon in the nucleus is moving in a single-parti...The single-particle Schrödinger fluid model is designed mainly to calculate the moments of inertia of the axially symmetric deformed nuclei by assuming that each nucleon in the nucleus is moving in a single-particle potential which is deformed with time t, through its parametric dependence on a classical shape variable α(t). Also, the Nilsson model is designed for the calculations of the single-particle energy levels, the magnetic dipole moments, and the electric quadrupole moments of axially symmetric deformed nuclei by assuming that all the nucleons are moving in the field of an anisotropic oscillator potential. On the other hand, the nuclear superfluidity model is designed for the calculations of the nuclear moments of inertia and the electric quadrupole moments of deformed nuclei which have no axes of symmetry by assuming that the nucleons are moving in a quadruple deformed potential. Furthermore, the cranked Nilsson model is designed for the calculations of the total nuclear energy and the quadrupole moments of deformed nuclei which have no axes of symmetry by modifying the Nilsson potential to include second and fourth order oscillations. Accordingly, to investigate whether the six p-shell isotopes <sup>6</sup>Li, <sup>7</sup>Li, <sup>8</sup>Li, <sup>9</sup>Li, <sup>10</sup>Li, and <sup>11</sup>Li have axes of symmetry or not, we applied the four mentioned models to each nucleus by calculating their moments of inertia, their magnetic dipole moments, and their electric quadrupole moments by varying the deformation parameter β and the non-axiality parameter γ in wide ranges of values for this reason. Hence for the assumption that these isotopes are deformed and have axes of symmetry, we applied the single-particle Schrödinger fluid model and the Nilsson model. On the other hand, for the assumption that these isotopes are deformed and have no axes of symmetry, we applied the cranked Nilsson model and the nuclear super fluidity model. As a result of our calculations, we can conclude that the nucleus <sup>6</sup>Li may be assumed to be deformed and has an axis of symmetry.展开更多
The geometrical structures of wurtzite CrX (X=As, Sb, O, Se, and Te) were optimized, then their electric and magnetic properties were investigated by the first-principle calculations within the generalized gradient ...The geometrical structures of wurtzite CrX (X=As, Sb, O, Se, and Te) were optimized, then their electric and magnetic properties were investigated by the first-principle calculations within the generalized gradient approximation for the exchange-correlation functional based on the density functional theory. These Cr-phosphides and Cr-sulphides were predicted to be half-metallic ferromagnets whose spin-polarization at the Fermi level is absolutely 100%. The molecular magnetic moments of Cr-phosphides and Cr-sulphides are 3.00 and 4.00 μB, which arise mainly from Cr-ions, respectively. There is ferromagnetic coupling in both Cr- phosphides and Cr-sulphides. The Curie temperatures of Cr-sulphides and Cr-phosphides are high. The electronic structures of Cr-ions are a1g^2↑↓t1u^4↑↓t1u^1↑↓eg^2↑↓in Cr-phosphides and a1g^2↑↓t1u^4↑↓t1u^1↑t2g^3↑in Cr-sulphides, respectively.展开更多
In this paper,a kind of lateral stability control strategy is put forward about the four wheel independent drive electric vehicle.The design of control system adopts hierarchical structure.Unlike the previous control ...In this paper,a kind of lateral stability control strategy is put forward about the four wheel independent drive electric vehicle.The design of control system adopts hierarchical structure.Unlike the previous control strategy,this paper introduces a method which is the combination of sliding mode control and optimal allocation algorithm.According to the driver’s operation commands(steering angle and speed),the steady state responses of the sideslip angle and yaw rate are obtained.Based on this,the reference model is built.Upper controller adopts the sliding mode control principle to obtain the desired yawing moment demand.Lower controller is designed to satisfy the desired yawing moment demand by optimal allocation of the tire longitudinal forces.Firstly,the optimization goal is built to minimize the actuator cost.Secondly,the weighted least-square method is used to design the tire longitudinal forces optimization distribution strategy under the constraint conditions of actuator and the friction oval.Beyond that,when the optimal allocation algorithm is not applied,a method of axial load ratio distribution is adopted.Finally,Car Sim associated with Simulink simulation experiments are designed under the conditions of different velocities and different pavements.The simulation results show that the control strategy designed in this paper has a good following effect comparing with the reference model and the sideslip angle is controlled within a small rang at the same time.Beyond that,based on the optimal distribution mode,the electromagnetic torque phase of each wheel can follow the trend of the vertical force of the tire,which shows the effectiveness of the optimal distribution algorithm.展开更多
The 2×2× 1 rocksalt C-doped MgS supercells are optimized and their magnetic and electric properties, including the half-metallicity, the conductivity and the supercell magnetic moments, are calculated or ana...The 2×2× 1 rocksalt C-doped MgS supercells are optimized and their magnetic and electric properties, including the half-metallicity, the conductivity and the supercell magnetic moments, are calculated or analysed by the first- principles researches based on the density functional theory. Results show that the concentration of C-dopants may cause important influence on the magnetic and the electric properties of rocksalt MgS. C dopants are inclined to have a scattering distribution. MGC0.0625S0.9375^, aMgC0.1250S0.8750 and MgC0.1875S0.8125 have evident half-metallicity. They have wide spin energy gaps, thus high Curie temperature possibly. Their supercell magnetic moments are near to integral numbers 2.0, 4.0 and 6.0μB. The main reason for spin polarization and half-metallicity of C-doped MgS is that there are sp hybridized orbitals in ligand compound ML6 caused by covalent interaction between C-ions and Mg-ions.展开更多
s The geometrical structures of Cd0.75TM0.25Se (TM = Ti, V, Cr and Mn) are optimized, and then their electric and magnetic properties are investigated by performing first-principles calculations within the generaliz...s The geometrical structures of Cd0.75TM0.25Se (TM = Ti, V, Cr and Mn) are optimized, and then their electric and magnetic properties are investigated by performing first-principles calculations within the generalized gradient approximation for the exchange-correlation function based on density functional theory. Cd0.75TM0.25Se (TM =Ti and V) are found to have high spin-polarization near 100% at the Fermi level. Cd0.75TM0.25Se (TM = Cr and Mn) are half-metallic ferromagnets whose spin-polarization at the Fermi level is absolutely +100%. The supercell magnetic moments of Cd0.75Cr0.25Se and Cdo.75Mno.25Se are 4.00 and 5.00 μB, which arise mainly from Cr-ions and Mnions, respectively. The half-metallicity of Cdo.75Cro.25Se is more stable than that of Cd0.75Mn0.25Se. The electronic structures of Cr-ions and Mn-ions are Cr eg2↑t22g↑ and Mn e2 3 ↑t23g↑, respectively.展开更多
In the present work we calculate the energies,quadrupole moments,and electric field gradients(EFGs) of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force co...In the present work we calculate the energies,quadrupole moments,and electric field gradients(EFGs) of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force constant k2 is the product of charge and EFG at its equilibrium nuclear distance.The dipole charge distributions for these symmetrical molecules are all in equilibrium,however,the quadrupole charge distributions are far from equilibrium;among these,there is the most remarkable deviation from equilibrium for N2,for its many charges concentrate on two sides of the molecule,which is in agreement with the well-known characteristic of the nitrogen molecule.The relativistic effect is remarkable even for the same period.展开更多
The present work devotes to studying the electric properties: electric quadrupole moment and electric field gradient (EFG) of molecules PdH and (PdH)-2 based on the full relativistic theory. It is the first time to ex...The present work devotes to studying the electric properties: electric quadrupole moment and electric field gradient (EFG) of molecules PdH and (PdH)-2 based on the full relativistic theory. It is the first time to explore that the force constants are essentially caused by electric field gradients, and indirectly with spectroscopic data. If EFG is positive, zero or negative, then the will be positive, zero or negative. Therefore, second order force constants are adjustable to changing the intensity of EFG.展开更多
Here, we initially introduced and demonstrated two principles: orientation OR principle and attraction AT principle of electrical dipoles. The OR principle stipulates that any two electrical dipoles P1A, P1B, from two...Here, we initially introduced and demonstrated two principles: orientation OR principle and attraction AT principle of electrical dipoles. The OR principle stipulates that any two electrical dipoles P1A, P1B, from two bodies A and B, at any distance in the free state each, will be reciprocally oriented parallel and in the same sense if the electrical interaction forces F between them are of decreasing type with distance r. If the electrical interaction forces F are of increasing type with distance, the two dipoles will be reciprocally oriented parallel but on the opposite sense. The AT principle stipulate that any two electrical dipoles P1A, P1B, at any distance in the free state each, will present always a reciprocal force of attraction FD in both cases of orientation accordingly to OR principle in case of any type of electrical force F decreasing or increasing with distance. These findings may complete our previous work where we found that FD force, between two electrical dipoles P1A, P1B considered at atomic and nuclear level, is in fact the actual gravitation Newton force FN. The paper must be considered together with this work for more consistency.展开更多
Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si...Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si(CH3 )2O double free radical were also calculated using time dependent density function theory(TD-DFT) with the same basis sets. It is found that the external electric field along the X,Y and Z axis affectdifferently on the excited states and other properties of Si(CH3)2O double free radical.展开更多
We have measured the electric dipole moment of several Scn-C60 molecules (n = 1 - 6) in gaseous phase, by coupling a matrix-assisted laser desorption source to an electric beam deflection setup which is an electric eq...We have measured the electric dipole moment of several Scn-C60 molecules (n = 1 - 6) in gaseous phase, by coupling a matrix-assisted laser desorption source to an electric beam deflection setup which is an electric equivalent of the famous Stern Gerlach [1] one. Experimental results are compared to a qualitative charge transfer that occurs between Sc and fullerene.展开更多
We propose that the QCD vacuum pion tetrahedron condensate density vary in space and drops to extremely low values in the Kennan, Barger and Cowie (KBC) void in analogy to earth’s atmospheric density drop with elevat...We propose that the QCD vacuum pion tetrahedron condensate density vary in space and drops to extremely low values in the Kennan, Barger and Cowie (KBC) void in analogy to earth’s atmospheric density drop with elevation from earth. We propose a formula for the gravitation acceleration based on the non-uniform pion tetrahedron condensate. Gravity may be due to the underlying microscopic attraction between quarks and antiquarks, which are part of the vacuum pion tetrahedron condensate. We propose an electron tetrahedron model, where electrons are comprised of tetraquark tetrahedrons, and . The quarks determine the negative electron charge and the or quarks determine the electron two spin states. The electron tetrahedron may perform a high frequency quark exchange reactions with the pion tetrahedron condensate by tunneling through the condensation gap creating a delocalized electron cloud with a fixed spin. The pion tetrahedron may act as a QCD glue bonding electron pairs in atoms and molecules and protons to neutrons in the nuclei. Conservation of valence quarks and antiquarks is proposed.展开更多
From the principles of electromechanical energy conversion and electromagnetic torque generation, our study evaluatedthe mathematical model of the electromagnetic torque and the vector control method of motors. An ana...From the principles of electromechanical energy conversion and electromagnetic torque generation, our study evaluatedthe mathematical model of the electromagnetic torque and the vector control method of motors. An analysis of motor typesindicates that the electromechanical energy conversion component is interchangeable. Three distinct types of motor structures,namely DC, induction, and synchronous, are possible, all three being commonly used in pure electric vehicles. For each motortype, simulation models were developed using Modelica, a modeling language for object-oriented multi-domain physicalsystem. A test model of each motor type was configured in the MWorks simulation platform. With a representative motor,specifically the permanent-magnet DC motor, the asynchronous induction motor, and the permanent-magnet synchronousmotor, mechanical properties were simulated and analyzed. The simulation results show that the characteristics of each motormodel are consistent with the theoretical and engineering performance of the representative motor. Therefore, modeling,motor control, and performance testing of a unified multi-pole-field motor, which is used in pure electric vehicles, have beenachieved.展开更多
基金Supported by National Basic Research Program of China(973 Program,Grant No.2011CB711200)National Science and Technology Support Program of China(Grant No.2015BAG17B00)National Natural Science Foundation of China(Grant No.51475333)
文摘For a distributed drive electric vehicle(DDEV) driven by four in-wheel motors, advanced vehicle dynamic control methods can be realized easily because motors can be controlled independently, quickly and precisely. And direct yaw-moment control(DYC) has been widely studied and applied to vehicle stability control. Good vehicle handling performance: quick yaw rate transient response, small overshoot, high steady yaw rate gain, etc, is required by drivers under normal conditions, which is less concerned, however. Based on the hierarchical control methodology, a novel control system using direct yaw moment control for improving handling performance of a distributed drive electric vehicle especially under normal driving conditions has been proposed. The upper-loop control system consists of two parts: a state feedback controller, which aims to realize the ideal transient response of yaw rate, with a vehicle sideslip angle observer; and a steering wheel angle feedforward controller designed to achieve a desired yaw rate steady gain. Under the restriction of the effect of poles and zeros in the closed-loop transfer function on the system response and the capacity of in-wheel motors, the integrated time and absolute error(ITAE) function is utilized as the cost function in the optimal control to calculate the ideal eigen frequency and damper coefficient of the system and obtain optimal feedback matrix and feedforward matrix. Simulations and experiments with a DDEV under multiple maneuvers are carried out and show the effectiveness of the proposed method: yaw rate rising time is reduced, steady yaw rate gain is increased, vehicle steering characteristic is close to neutral steer and drivers burdens are also reduced. The control system improves vehicle handling performance under normal conditions in both transient and steady response. State feedback control instead of model following control is introduced in the control system so that the sense of control intervention to drivers is relieved.
基金supported by the National Natural Science Foundation of China(Grant Nos.11374217 and 11474207)
文摘An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is found using the highly accurate, multi-reference averaged coupled-pair functional(ACPF) approach with the basis set, aug-cc-p V6 Z, and a finite-field with ±0.005 a.u.(The unit a.u. is the abbreviation of atomic unit). This ab initio EDMF is very consistent with the fitted ones. The vibrational transition matrix moments and the Herman–Wallis factors, calculated with the Rydberg–Klein–Rees(RKR) potential and the fitted and ab initio EDMFs, are compared with experimental measurements. The consistency of these line intensities with the high-resolution transmission(HITRAN) molecular database demonstrates the improved accuracy of the fitted and ab initio EDMFs derived in this work.
基金supported by the National Basic Research Program of China(Grant No.2012CB921603)the National Natural Science Foundation of China(GrantNos.61378039,61078013,61178009,and 11274209)+3 种基金the Program for Changjiang Scholars and Innovative Research Team in University,China(Grant No.IRT13076)the Fund for Fostering Talents in Basic Science of the National Natural Science Foundation of China(Grant No.J1210036)the Natural Science Foundation of Shanxi Province,China(Grant No.2012011003-2)the Shanxi International Collaboration Program,China(Grant No.2010081046)
文摘Recently, the diverse properties of Rydberg atoms, which probably arise from its large electric dipole moment (EDM), have been explored. In this paper, we report electric dipole moments along with Stark energies and charge densities of lithium Rydberg states in the presence of electric fields, calculated by matrix diagonalization. Huge electric dipole moments are discovered. In order to check the validity of the EDMs, we also use these electric dipole moments to calculate the Stark energies by numerical integration. The results agree with those calculated by matrix diagonalization.
文摘Higher electric multipole moments for the ground-state electronic configuration of some polyatomicmolecules, i.e. CH4, NH3, H2O, were calculated from SCF-HFR wavefunctions using Slater-type orbital basis sets.The calculated results for electric multipole moments of these molecules are in good agreement with the theoretical andexperimental ones.
基金Project supported by the National Natural Science Foundation of China(Grant No.11874064)the Strategic Priority and the Research Program of the Chinese Academy of Sciences(Grant No.XDB21030300)+3 种基金the National Key Research and Development Program of China(Grant No.2016YFA0302104)Yong Liu acknowledges the Project of Hebei Educational Department,China(Grant No.ZD2018015)the Natural Science Foundation of Hebei Province,China(Grant No.A2019203507)Bing-Bing Suo acknowledges the financial support from the National Natural Science foundation of China(Grant Nos.21673174 and 21873077).
文摘Electric quadrupole moments of low-lying excited states of Yb^+are calculated by relativistic coupled-cluster theory with perturbations from external fields.The field-dependent energy differentiation provides accurate values of the electric quadrupole moments of^2P3/2,^2D3/2,5/2,and^2F5/2,7/2 states which agree well with experimental values.The important role of the electronic correlation to the electric quadrupole moments is investigated.Our calculations indicate the early dispute of the electric quadrupole moment of the Yb^+(2F7/2)state for which the measured and theoretical values have a large discrepancy.These electric quadrupole moment values can help us to determine the electric quadrupole shifts in start-of-the-art experiments of the Yb+ion.
基金the National Natural Science Foundation of China(Grant No.11465006),20200981-SIP-IPN,and the CONACyT(Grant No.288856-CB-2016).
文摘We show that it is possible to simulate an anyon by a trapped atom which possesses an induced electric dipole moment in the background of electric and magnetic fields in a specific configuration.The electric and magnetic fields we applied contain a magnetic and two electric fields.We find that when the atom is cooled down to the limit of the negligibly small kinetic energy,the atom behaves like an anyon because its angular momentum takes fractional values.The fractional part of the angular momentum is determined by both the magnetic and one of the electric fields.Roles electric and magnetic fields played are analyzed.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11704398 and 11934014)the National Key Research and Development Program of China(Grant No.2017YFA0304402)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB21030300)。
文摘Highly charged nickel ions have been suggested as candidates for the ultra-precise optical clock, meanwhile the relevant experiment has been carried out. In the framework of the multiconfiguration Dirac–Hartree–Fock(MCDHF)method, we calculated the hyperfine interaction constants, the Landég-factors, and the electric quadrupole moments for the low-lying states in the 61Ni11+,61Ni12+,61Ni14+, and61Ni15+ ions. These states are clock states of the selected clock transitions in highly charged nickel ions(see Fig. 1). Based on discussing the effects of the electron correlations, the Breit interaction, and quantum electrodynamics(QED) effect on these physical quantities, reasonable uncertainties were obtained for our calculated results. In addition, the electric quadrupole frequency shifts and the Zeeman frequency shifts of the clock transitions concerned were analyzed.
文摘The single-particle Schrödinger fluid model is designed mainly to calculate the moments of inertia of the axially symmetric deformed nuclei by assuming that each nucleon in the nucleus is moving in a single-particle potential which is deformed with time t, through its parametric dependence on a classical shape variable α(t). Also, the Nilsson model is designed for the calculations of the single-particle energy levels, the magnetic dipole moments, and the electric quadrupole moments of axially symmetric deformed nuclei by assuming that all the nucleons are moving in the field of an anisotropic oscillator potential. On the other hand, the nuclear superfluidity model is designed for the calculations of the nuclear moments of inertia and the electric quadrupole moments of deformed nuclei which have no axes of symmetry by assuming that the nucleons are moving in a quadruple deformed potential. Furthermore, the cranked Nilsson model is designed for the calculations of the total nuclear energy and the quadrupole moments of deformed nuclei which have no axes of symmetry by modifying the Nilsson potential to include second and fourth order oscillations. Accordingly, to investigate whether the six p-shell isotopes <sup>6</sup>Li, <sup>7</sup>Li, <sup>8</sup>Li, <sup>9</sup>Li, <sup>10</sup>Li, and <sup>11</sup>Li have axes of symmetry or not, we applied the four mentioned models to each nucleus by calculating their moments of inertia, their magnetic dipole moments, and their electric quadrupole moments by varying the deformation parameter β and the non-axiality parameter γ in wide ranges of values for this reason. Hence for the assumption that these isotopes are deformed and have axes of symmetry, we applied the single-particle Schrödinger fluid model and the Nilsson model. On the other hand, for the assumption that these isotopes are deformed and have no axes of symmetry, we applied the cranked Nilsson model and the nuclear super fluidity model. As a result of our calculations, we can conclude that the nucleus <sup>6</sup>Li may be assumed to be deformed and has an axis of symmetry.
基金ACKNOWLEDGMENTS This work was supported by the Chongqing Natural Science Foundation (No.CSTC2007BB4391 and No.CSTC2008BB4083) and the Chongqing Science and Technology Foundation (No.kj060515 and No.kj080518)
文摘The geometrical structures of wurtzite CrX (X=As, Sb, O, Se, and Te) were optimized, then their electric and magnetic properties were investigated by the first-principle calculations within the generalized gradient approximation for the exchange-correlation functional based on the density functional theory. These Cr-phosphides and Cr-sulphides were predicted to be half-metallic ferromagnets whose spin-polarization at the Fermi level is absolutely 100%. The molecular magnetic moments of Cr-phosphides and Cr-sulphides are 3.00 and 4.00 μB, which arise mainly from Cr-ions, respectively. There is ferromagnetic coupling in both Cr- phosphides and Cr-sulphides. The Curie temperatures of Cr-sulphides and Cr-phosphides are high. The electronic structures of Cr-ions are a1g^2↑↓t1u^4↑↓t1u^1↑↓eg^2↑↓in Cr-phosphides and a1g^2↑↓t1u^4↑↓t1u^1↑t2g^3↑in Cr-sulphides, respectively.
基金supported by the National Nature Science Foundation(U1664263)National Key R&D Program of China(2016YFB0101102)。
文摘In this paper,a kind of lateral stability control strategy is put forward about the four wheel independent drive electric vehicle.The design of control system adopts hierarchical structure.Unlike the previous control strategy,this paper introduces a method which is the combination of sliding mode control and optimal allocation algorithm.According to the driver’s operation commands(steering angle and speed),the steady state responses of the sideslip angle and yaw rate are obtained.Based on this,the reference model is built.Upper controller adopts the sliding mode control principle to obtain the desired yawing moment demand.Lower controller is designed to satisfy the desired yawing moment demand by optimal allocation of the tire longitudinal forces.Firstly,the optimization goal is built to minimize the actuator cost.Secondly,the weighted least-square method is used to design the tire longitudinal forces optimization distribution strategy under the constraint conditions of actuator and the friction oval.Beyond that,when the optimal allocation algorithm is not applied,a method of axial load ratio distribution is adopted.Finally,Car Sim associated with Simulink simulation experiments are designed under the conditions of different velocities and different pavements.The simulation results show that the control strategy designed in this paper has a good following effect comparing with the reference model and the sideslip angle is controlled within a small rang at the same time.Beyond that,based on the optimal distribution mode,the electromagnetic torque phase of each wheel can follow the trend of the vertical force of the tire,which shows the effectiveness of the optimal distribution algorithm.
基金Project supported by the Chongqing Natural Science Foundation,China(Grant Nos.CSTC2007BB4391,CSTC2007BB2448 and CSTC2008BB4083)the Chongqing Science and Technology Foundation,China(Grant Nos.KJ060515 and KJ080518)the Doctoral Foundation of Chongqing University of Posts and Telecommunications(Grant No.A2008-63)
文摘The 2×2× 1 rocksalt C-doped MgS supercells are optimized and their magnetic and electric properties, including the half-metallicity, the conductivity and the supercell magnetic moments, are calculated or analysed by the first- principles researches based on the density functional theory. Results show that the concentration of C-dopants may cause important influence on the magnetic and the electric properties of rocksalt MgS. C dopants are inclined to have a scattering distribution. MGC0.0625S0.9375^, aMgC0.1250S0.8750 and MgC0.1875S0.8125 have evident half-metallicity. They have wide spin energy gaps, thus high Curie temperature possibly. Their supercell magnetic moments are near to integral numbers 2.0, 4.0 and 6.0μB. The main reason for spin polarization and half-metallicity of C-doped MgS is that there are sp hybridized orbitals in ligand compound ML6 caused by covalent interaction between C-ions and Mg-ions.
基金Project supported by Chongqing Natural Science Foundation (Grant Nos. CSTC2007BB4391,CSTC2007BB2448,CSTC2007BB4385 and CSTC2008BB4083)Chongqing Science and Technology Foundation (Grant Nos. kj060515 andkj080518)
文摘s The geometrical structures of Cd0.75TM0.25Se (TM = Ti, V, Cr and Mn) are optimized, and then their electric and magnetic properties are investigated by performing first-principles calculations within the generalized gradient approximation for the exchange-correlation function based on density functional theory. Cd0.75TM0.25Se (TM =Ti and V) are found to have high spin-polarization near 100% at the Fermi level. Cd0.75TM0.25Se (TM = Cr and Mn) are half-metallic ferromagnets whose spin-polarization at the Fermi level is absolutely +100%. The supercell magnetic moments of Cd0.75Cr0.25Se and Cdo.75Mno.25Se are 4.00 and 5.00 μB, which arise mainly from Cr-ions and Mnions, respectively. The half-metallicity of Cdo.75Cro.25Se is more stable than that of Cd0.75Mn0.25Se. The electronic structures of Cr-ions and Mn-ions are Cr eg2↑t22g↑ and Mn e2 3 ↑t23g↑, respectively.
基金Project supported by the Fundamental Research Funds for the Central Universities
文摘In the present work we calculate the energies,quadrupole moments,and electric field gradients(EFGs) of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force constant k2 is the product of charge and EFG at its equilibrium nuclear distance.The dipole charge distributions for these symmetrical molecules are all in equilibrium,however,the quadrupole charge distributions are far from equilibrium;among these,there is the most remarkable deviation from equilibrium for N2,for its many charges concentrate on two sides of the molecule,which is in agreement with the well-known characteristic of the nitrogen molecule.The relativistic effect is remarkable even for the same period.
基金Project supported by the National Major Fundamental Research Program of China (2007CB925001)National Key Fundamental Research Development Planning Program of China (001CB610604)Natural Science Research Program of Education Department of Anhui Province (2006KJ266B, ZD2007003-1)
文摘The present work devotes to studying the electric properties: electric quadrupole moment and electric field gradient (EFG) of molecules PdH and (PdH)-2 based on the full relativistic theory. It is the first time to explore that the force constants are essentially caused by electric field gradients, and indirectly with spectroscopic data. If EFG is positive, zero or negative, then the will be positive, zero or negative. Therefore, second order force constants are adjustable to changing the intensity of EFG.
文摘Here, we initially introduced and demonstrated two principles: orientation OR principle and attraction AT principle of electrical dipoles. The OR principle stipulates that any two electrical dipoles P1A, P1B, from two bodies A and B, at any distance in the free state each, will be reciprocally oriented parallel and in the same sense if the electrical interaction forces F between them are of decreasing type with distance r. If the electrical interaction forces F are of increasing type with distance, the two dipoles will be reciprocally oriented parallel but on the opposite sense. The AT principle stipulate that any two electrical dipoles P1A, P1B, at any distance in the free state each, will present always a reciprocal force of attraction FD in both cases of orientation accordingly to OR principle in case of any type of electrical force F decreasing or increasing with distance. These findings may complete our previous work where we found that FD force, between two electrical dipoles P1A, P1B considered at atomic and nuclear level, is in fact the actual gravitation Newton force FN. The paper must be considered together with this work for more consistency.
文摘Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si(CH3 )2O double free radical were also calculated using time dependent density function theory(TD-DFT) with the same basis sets. It is found that the external electric field along the X,Y and Z axis affectdifferently on the excited states and other properties of Si(CH3)2O double free radical.
文摘We have measured the electric dipole moment of several Scn-C60 molecules (n = 1 - 6) in gaseous phase, by coupling a matrix-assisted laser desorption source to an electric beam deflection setup which is an electric equivalent of the famous Stern Gerlach [1] one. Experimental results are compared to a qualitative charge transfer that occurs between Sc and fullerene.
文摘We propose that the QCD vacuum pion tetrahedron condensate density vary in space and drops to extremely low values in the Kennan, Barger and Cowie (KBC) void in analogy to earth’s atmospheric density drop with elevation from earth. We propose a formula for the gravitation acceleration based on the non-uniform pion tetrahedron condensate. Gravity may be due to the underlying microscopic attraction between quarks and antiquarks, which are part of the vacuum pion tetrahedron condensate. We propose an electron tetrahedron model, where electrons are comprised of tetraquark tetrahedrons, and . The quarks determine the negative electron charge and the or quarks determine the electron two spin states. The electron tetrahedron may perform a high frequency quark exchange reactions with the pion tetrahedron condensate by tunneling through the condensation gap creating a delocalized electron cloud with a fixed spin. The pion tetrahedron may act as a QCD glue bonding electron pairs in atoms and molecules and protons to neutrons in the nuclei. Conservation of valence quarks and antiquarks is proposed.
文摘From the principles of electromechanical energy conversion and electromagnetic torque generation, our study evaluatedthe mathematical model of the electromagnetic torque and the vector control method of motors. An analysis of motor typesindicates that the electromechanical energy conversion component is interchangeable. Three distinct types of motor structures,namely DC, induction, and synchronous, are possible, all three being commonly used in pure electric vehicles. For each motortype, simulation models were developed using Modelica, a modeling language for object-oriented multi-domain physicalsystem. A test model of each motor type was configured in the MWorks simulation platform. With a representative motor,specifically the permanent-magnet DC motor, the asynchronous induction motor, and the permanent-magnet synchronousmotor, mechanical properties were simulated and analyzed. The simulation results show that the characteristics of each motormodel are consistent with the theoretical and engineering performance of the representative motor. Therefore, modeling,motor control, and performance testing of a unified multi-pole-field motor, which is used in pure electric vehicles, have beenachieved.