Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast...Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.展开更多
Dispersion of multi-walled carbon nanotubes in poly(p-phenylene) composite exposed to toluene was experimentally investigated. 3 mg of multi-walled carbon nanotubes with nominal size of 20 nm was compounded with 30 ...Dispersion of multi-walled carbon nanotubes in poly(p-phenylene) composite exposed to toluene was experimentally investigated. 3 mg of multi-walled carbon nanotubes with nominal size of 20 nm was compounded with 30 mg of poly(p-phenylene) with the presence of terpineol as binding initiator. To investigate an optimal condition for homogenizing all constituents, ultrasonication with an output power of 750W was employed with compounding time of 3, 10, 20 and 30 min. With FTIR analyses, it could be confirmed that homogeneous composite of multi-walled carbon nanotubes and poly(p-phenylene) could be prepared. SEM analyses were also conducted to examine the dispersion of multi-walled carbon nanotubes in the polymer matrix. Then intrinsic electrical resistance of the composites after being exposed to toluene was also investigated. It was found that the composite film prepared with ultrasonication for 20 min could provide sufficiently sensitive response with respect to varied concentration of toluene.展开更多
We present a novel configuration for carrier suppressed return-to-zero (CSRZ) signal generation, which only requires a single stage Mach-Zehnder (MZ) modulator in conjunction with an electrical mixer. Electrical band-...We present a novel configuration for carrier suppressed return-to-zero (CSRZ) signal generation, which only requires a single stage Mach-Zehnder (MZ) modulator in conjunction with an electrical mixer. Electrical band-limiting is also introduced to increase dispersion tolerance without causing additional penalty due to nonlinear effects in long haul dense wavelength division multiplexed (DWDM) CSRZ systems using conventional launch power levels.展开更多
Dispersion and surface deposition of charged particles by gas-solids jets in confined chambers are constantly encountered in many industrial applications such as in electrostatic precipitation and dry powder coating p...Dispersion and surface deposition of charged particles by gas-solids jets in confined chambers are constantly encountered in many industrial applications such as in electrostatic precipitation and dry powder coating processes. Understanding and control of flow patterns and trajectories of charged particles are important to the optimal design and operation of such devices. In this study, modeling of flow fields and particle trajectories of dilute gas-solid two-phase flows with charged particles in confined chambers is performed. The dilute gas-solid two-phase flows are simulated by use of a hybrid Eulerian-Lagrangian approach with the one-way coupling between the gaseous phase and particle phase. The space charge distribution is included as a source term in equations of motion or Lagrangian equation of charged particles, which in turn depends on the particle trajectories that determine the space charge distribution. Our modeling predictions suggested that the electrostatic charge plays a significant role in particle radial dispersion. Effect of voltage has limited influence on particle trajectories however it can have a big impact on the residence time. Cone angle has a significant effect on the structure of flow field. For cone with a larger cone angle (typically over 15°), there will be a flow separation along the side wall near the flow entrance region. By comparing with the conical chamber, the cylindrical chamber has a big vortex and three smaller vortexes in the lower part of the chamber, which would complicate the particle dispersion with or without the coupling of charging.展开更多
文摘Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.
基金supported by the Centennial Fund of Chula-longkorn UniversityAssoc.Prof. Mana Sriyuthsak for his suggestive and academic support insensor fabricationfinancial support from University of Pembangunan Nasional "Veteran" Yogyakarta, Indonesia
文摘Dispersion of multi-walled carbon nanotubes in poly(p-phenylene) composite exposed to toluene was experimentally investigated. 3 mg of multi-walled carbon nanotubes with nominal size of 20 nm was compounded with 30 mg of poly(p-phenylene) with the presence of terpineol as binding initiator. To investigate an optimal condition for homogenizing all constituents, ultrasonication with an output power of 750W was employed with compounding time of 3, 10, 20 and 30 min. With FTIR analyses, it could be confirmed that homogeneous composite of multi-walled carbon nanotubes and poly(p-phenylene) could be prepared. SEM analyses were also conducted to examine the dispersion of multi-walled carbon nanotubes in the polymer matrix. Then intrinsic electrical resistance of the composites after being exposed to toluene was also investigated. It was found that the composite film prepared with ultrasonication for 20 min could provide sufficiently sensitive response with respect to varied concentration of toluene.
文摘We present a novel configuration for carrier suppressed return-to-zero (CSRZ) signal generation, which only requires a single stage Mach-Zehnder (MZ) modulator in conjunction with an electrical mixer. Electrical band-limiting is also introduced to increase dispersion tolerance without causing additional penalty due to nonlinear effects in long haul dense wavelength division multiplexed (DWDM) CSRZ systems using conventional launch power levels.
文摘Dispersion and surface deposition of charged particles by gas-solids jets in confined chambers are constantly encountered in many industrial applications such as in electrostatic precipitation and dry powder coating processes. Understanding and control of flow patterns and trajectories of charged particles are important to the optimal design and operation of such devices. In this study, modeling of flow fields and particle trajectories of dilute gas-solid two-phase flows with charged particles in confined chambers is performed. The dilute gas-solid two-phase flows are simulated by use of a hybrid Eulerian-Lagrangian approach with the one-way coupling between the gaseous phase and particle phase. The space charge distribution is included as a source term in equations of motion or Lagrangian equation of charged particles, which in turn depends on the particle trajectories that determine the space charge distribution. Our modeling predictions suggested that the electrostatic charge plays a significant role in particle radial dispersion. Effect of voltage has limited influence on particle trajectories however it can have a big impact on the residence time. Cone angle has a significant effect on the structure of flow field. For cone with a larger cone angle (typically over 15°), there will be a flow separation along the side wall near the flow entrance region. By comparing with the conical chamber, the cylindrical chamber has a big vortex and three smaller vortexes in the lower part of the chamber, which would complicate the particle dispersion with or without the coupling of charging.