The arrangement of electrolyte inlet in the copper electro-refining(ER)cell has a great influence on the local flow field,which affects the distribution of electrical current density in consequence.In order to underst...The arrangement of electrolyte inlet in the copper electro-refining(ER)cell has a great influence on the local flow field,which affects the distribution of electrical current density in consequence.In order to understand the complicated phenomena ofelectrolyte flow behavior in vertical counter electrodes in full-scale copper ER cell,the three-dimensional computational fluiddynamics(CFD)models with four different arrangements of electrolyte inlets,i.e.,single inlet(SI),central bottom inlets(CBI),topside interlaced inlets(TII),and bottom side interlaced inlets(BII),were established to simulate the flow behavior.Simulation resultshave revealed that the parallel injection devices help to improve the electrolyte velocity between electrodes,and while the relativerange of electrolyte velocity in CBI exceeds that of TII and BII,which is more than4times,indicating its severer unequal flowdistribution.Meanwhile,the average velocity of electrolyte in BII is4times larger than that of SI due to its higher turbulenceintensity.Generally,one of the efficient ways to supply fresh copper solution rapidly and uniformly into the inter-electrode space is toadapt the arrangement of BII.By utilizing such an arrangement,the electro-refining under high electrical current density is possible,and the productivity can be increased in sequence.展开更多
This work will create an electro-dialysis cell model that has the purpose of refining anodic scrap copper—an element that currently must be returned to the copper conversion process. The cell modeling is based on Ohm...This work will create an electro-dialysis cell model that has the purpose of refining anodic scrap copper—an element that currently must be returned to the copper conversion process. The cell modeling is based on Ohm’s Law, while the resulting copper deposit morphology is studied through the thickness of the layer deposited on the surface and the electric current lines traced from the anode to the cathode. The use of the model demonstrated that it is possible to effectively predict the specific energy consumption required for the refinement of the anodic scrap copper, and the morphology of the cathode obtained, with a margin of error of 9%.展开更多
Despite functioning without major operational problems—copper electro-refining does not allow complete use of copper anodes, peaking at 85% of the copper anode in weight. Consequently, the remaining 15% of scrap copp...Despite functioning without major operational problems—copper electro-refining does not allow complete use of copper anodes, peaking at 85% of the copper anode in weight. Consequently, the remaining 15% of scrap copper must be recirculated into the copper smelting. The use of reactive electrodyalysis is a system capable of continuously electro-refining scrap, by using a stainless steel basket and a cationic exchanging membrane in order to increase production of copper cathodes at the same percentage;it currently today returns to the copper smelter. In terms of specific energy consumption, this process would use between 3 and 4 times the value of normal electro-refining.展开更多
基金Project(61321003)supported by the National Natural Science Foundation of China
文摘The arrangement of electrolyte inlet in the copper electro-refining(ER)cell has a great influence on the local flow field,which affects the distribution of electrical current density in consequence.In order to understand the complicated phenomena ofelectrolyte flow behavior in vertical counter electrodes in full-scale copper ER cell,the three-dimensional computational fluiddynamics(CFD)models with four different arrangements of electrolyte inlets,i.e.,single inlet(SI),central bottom inlets(CBI),topside interlaced inlets(TII),and bottom side interlaced inlets(BII),were established to simulate the flow behavior.Simulation resultshave revealed that the parallel injection devices help to improve the electrolyte velocity between electrodes,and while the relativerange of electrolyte velocity in CBI exceeds that of TII and BII,which is more than4times,indicating its severer unequal flowdistribution.Meanwhile,the average velocity of electrolyte in BII is4times larger than that of SI due to its higher turbulenceintensity.Generally,one of the efficient ways to supply fresh copper solution rapidly and uniformly into the inter-electrode space is toadapt the arrangement of BII.By utilizing such an arrangement,the electro-refining under high electrical current density is possible,and the productivity can be increased in sequence.
文摘This work will create an electro-dialysis cell model that has the purpose of refining anodic scrap copper—an element that currently must be returned to the copper conversion process. The cell modeling is based on Ohm’s Law, while the resulting copper deposit morphology is studied through the thickness of the layer deposited on the surface and the electric current lines traced from the anode to the cathode. The use of the model demonstrated that it is possible to effectively predict the specific energy consumption required for the refinement of the anodic scrap copper, and the morphology of the cathode obtained, with a margin of error of 9%.
文摘Despite functioning without major operational problems—copper electro-refining does not allow complete use of copper anodes, peaking at 85% of the copper anode in weight. Consequently, the remaining 15% of scrap copper must be recirculated into the copper smelting. The use of reactive electrodyalysis is a system capable of continuously electro-refining scrap, by using a stainless steel basket and a cationic exchanging membrane in order to increase production of copper cathodes at the same percentage;it currently today returns to the copper smelter. In terms of specific energy consumption, this process would use between 3 and 4 times the value of normal electro-refining.
